CN106311715B - A method of it is building materials to dispose red mud using permanent-magnet material and salt slurry - Google Patents

A method of it is building materials to dispose red mud using permanent-magnet material and salt slurry Download PDF

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CN106311715B
CN106311715B CN201610119528.XA CN201610119528A CN106311715B CN 106311715 B CN106311715 B CN 106311715B CN 201610119528 A CN201610119528 A CN 201610119528A CN 106311715 B CN106311715 B CN 106311715B
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red mud
slurry
permanent
monazite
mineral aggregate
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CN106311715A (en
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蔡其旺
钟云峰
陈志伟
刘和平
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Fujian Fude Lai Agricultural Technology Co.,Ltd.
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Fujian Yangyu Environmental Protection Technology Co Ltd
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B09DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
    • B09BDISPOSAL OF SOLID WASTE NOT OTHERWISE PROVIDED FOR
    • B09B3/00Destroying solid waste or transforming solid waste into something useful or harmless
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B03SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03CMAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03C1/00Magnetic separation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B09DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
    • B09BDISPOSAL OF SOLID WASTE NOT OTHERWISE PROVIDED FOR
    • B09B5/00Operations not covered by a single other subclass or by a single other group in this subclass

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  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Treatment Of Sludge (AREA)

Abstract

A method of it is building materials to dispose red mud using permanent-magnet material and salt slurry, is included the following steps:A, red mud is spent into ionized water slurrying, slurry carries out magnetic separation with permanent-magnet material, selects radioactivity mineral aggregate therein, including ilmenite, iron ore and monazite;B, remaining slurry removes heavy metal therein by dehydration.The present invention is by the mineral analysis to red mud, according to the physical difference of different minerals, by the way that by red mud slurry permanent magnetism, radioactivity mineral aggregate therein, including iron ore, ilmenite, monazite and other substances are separated.After radioactivity in red mud is eliminated, magneticly elect the ilmenite, iron ore, monazite come, and the mineral aggregates such as heavy metal, it can also recycle, eat it is dry bleed red mud useful value while, the environmental pollution and security risk that red mud dam is brought not only are completely eliminated, resource is also alleviated, the pressure that environment is brought, realizes the unification of economic benefit, social benefit and environmental benefit.

Description

A method of it is building materials to dispose red mud using permanent-magnet material and salt slurry
Technical field
It is the method for building materials that the present invention relates to a kind of using permanent-magnet material and salt slurry disposition red mud, belongs to environmental protection neck Domain.
Background technology
Red mud is the industrial solid wastes in aluminum oxide production process, generally often production 1t aluminium oxide just generate 1.0~ 1.8t red muds have the characteristics that strong basicity and high radioactivity two.According to the different process of alumina producing, red mud is divided into Bayer process With two kinds of different types of sintering process.Aluminium content is high in bauxite, and using Bayer process aluminium metallurgy, generated red mud claims Bayer process red Mud;Aluminium content is low in bauxite, and with sintering process aluminium metallurgy, generated red mud is known as red mud from sintering process.The disposition of red mud at present Method is mainly stacked in stockyard for a long time.The construction of red mud dump can utilize the landform such as mountain valley, dell in mountain area, be stacked with dell; Coastal area directly inputs deep-sea with pipeline, and natural sediment is in seabed.Above method will occupy a large amount of soils, and in red mud Chemical composition infiltrates soil, causes the ecological environment problems such as soil alkalization, underground water pollution.The comprehensive utilization of red mud, although having Many people carried out research, were such as used as building additive for building material field, be also useful for production sulfate cement brick, The construction materials such as ceramic tile, insulating brick, microporous calcium silicate;Adaptation to local conditions, the geographical conditions residing for aluminium manufacturer carry out soil filling With reclaim wasteland, with red mud filling stone pit, making roadbed, build sill may, neutralize acid soil etc.;It is prepared using red mud inorganic Chemical material, water purification adsorbent etc.;Recycle Al contained in red mud2O3、TiO2、SiO2、Na2O, the oxides such as CaO, and contain The metallic elements such as elements K, Mg, Ni, Zr, Sc, REE, radioactive element.But the above method rests on laboratory research more Stage is not implemented scale and utilizes.Currently, red mud utilization rate, less than 10%, the accumulative volume of cargo in storage in the country is more than 50,000,000 t.
Currently, the maximum field that can dispose red mud completely is building material industry, but high radioactivity is to restrict application Problem.There are strict demand in countries in the world to the specific radioactivity of construction material." radioactive material nucleic limits in China Amount " (GB656622001) provides that the specific radioactivity of natural radionuclide 226Ra, 232Th and 40K are lived in construction main body material When spending while meeting External Exposure Index IRa≤1.0 and Outreach services Ir≤1.0, production and marketing is unrestricted with use scope;Dress Repair in material the specific radioactivity of natural radionuclide 226Ra, 232Th and 40K at the same meet External Exposure Index IRa≤ 1.0 and Outreach services Ir≤1.3 requirements are A class finishing materials;A class finishing material production and marketing and use scope are unrestricted.
The radioactive elements preservations such as bauxite usually contained U, Th are in heavy metal and monazite.Heavy metal theoretical content is ZrO267.2%, SiO232.8%, usually contain 0.5%~4%HfO2, 0.35%Fe2O3, 0.05%~4%CaO and a small amount of The elements such as Re, Nb, Ta, Th, U.Monazite (RePO4) it is the phosphate mineral containing light rare earth elements, in addition to containing Th, U, still contain ZrO2、SiO2Equal impurity, mainly organizing becomes:Re2O3About 60%, ThO2About 12%, UO3With micro Ra (0.1%~0.3%); Hardness 5.0~5.5,4.6~5.4g/cm of density3.In aluminum oxide production process, 90% or more radioactive element is enriched to It is the universal higher basic reason of radioactivity in red mud in red mud.
Invention content
It is the method for building materials, Neng Gouhuan that the purpose of the present invention is to provide a kind of using permanent-magnet material and salt slurry disposition red mud It protects, at low cost detach the radioactive substance (heavy metal and monazite) in red mud from red mud slurry, being enriched with and come out, to reach It reduces, even be eliminated the radioactive purpose of red mud.
The present invention adopts the following technical scheme that:
A method of it is building materials to dispose red mud using permanent-magnet material and salt slurry, is included the following steps:A, red mud is spent Ionized water slurrying, slurry carry out magnetic separation with permanent-magnet material, select radioactivity mineral aggregate therein, including ilmenite, iron ore and solely Occupy stone;B, remaining slurry removes heavy metal therein by dehydration.
Further, the magnetic separation in the step a is that slurry passes through the permanent magnetism system that magnetic field intensity is 6500-6800 Gausses System, selects radioactivity mineral aggregate therein, including ilmenite, iron ore, monazite, the mineral aggregate selected is less than by magnetic field intensity again The magnetic separation system of 6500 Gausses selects mineral aggregate containing ferromagnetism, including iron ore, ilmenite, makes monazite and iron content radioactivity mineral aggregate Separation, makes monazite further be enriched with.
Further, the dehydration in the step b is:By weight, it is added by 50-150 in 1000 parts of slurries Part salt slurry, the dehydrating agent of 100-200 parts of ferric trichlorides composition, is dehydrated in the medium of pH >=12, will be weighed after mixing Metal is separated.
Further, the salt slurry that the dehydrating agent uses is chlor-alkali plant salt slurry.
Further, the pH value of the dehydration mediators is 12-12.5.
By the above-mentioned description of this invention it is found that compared to the prior art, the invention has the advantages that:
The present invention is by the mineral analysis to red mud, according to the physical difference of different minerals, by the way that red mud slurry is strong Magnetic separation (is more than 6500 Gausses), and radioactivity mineral aggregate therein, including iron ore, ilmenite, monazite and other substances are isolated Come, select ilmenite and iron ore using low intensity magnetic separation so that monazite separation, enrichment come out, and then will contain heavy metal The combination medicament that slurry is added based on salt slurry is dehydrated in high alkalinity (pH > 12) medium, and heavy metal is therefrom divided From, enrichment, with reduce even thoroughly eliminate red mud radioactivity, so that the radioactivity of its slag charge is reached radioactivity of building materials national standard A class building standards, production and marketing need not be restricted with use scope, carry forward vigorously red mud answering in building material field With.Tested through applicant, according to the method for the present invention treated red mud slurries, detect its radionuclide radium-226, thorium -232, Radiation specific activity Ira≤1.0, Ir≤1.0 of kalium-40.After radioactivity in red mud is eliminated, the ilmenite come, iron are magneticly elected The mineral aggregates such as mine, monazite and heavy metal, additionally it is possible to recycle, eat it is dry bleed red mud useful value while, it is not only thorough Bottom eliminates the environmental pollution and security risk that red mud dam is brought, and also alleviates resource, the pressure that environment is brought, realize through The unification for the benefit, social benefit and environmental benefit of helping.
Specific implementation mode
A method of it is building materials to dispose red mud using permanent-magnet material and salt slurry, is included the following steps:A, red mud is spent Ionized water slurrying, slurry carry out magnetic separation with permanent-magnet material, select radioactivity mineral aggregate therein, including ilmenite, iron ore and solely Occupy stone;B, remaining slurry removes heavy metal therein by dehydration.It can be by the radioactive substance in red mud by the above method Separation, enrichment, reduce the radioactivity of red mud.
Magnetic separation in the step a is slurry by the permanent magnet system that magnetic field intensity is 6500-6800 Gausses, is selected wherein Radioactivity mineral aggregate, including ilmenite, iron ore, monazite, the mineral aggregate selected is less than the magnetic of 6500 Gausses by magnetic field intensity again System is selected, mineral aggregate containing ferromagnetism, including iron ore, ilmenite are selected, so that monazite is detached with iron content radioactivity mineral aggregate, makes monazite Further enrichment.
Dehydration in the step b is:By weight, it is added in 1000 parts of slurries by 50-150 parts of salt slurries, The dehydrating agent of 100-200 parts of ferric trichlorides composition, is dehydrated in the medium of pH >=12, heavy metal is detached after mixing Out, it is chlor-alkali plant salt slurry to state the salt slurry that dehydrating agent uses.It is tested through applicant, is directly added into salt slurry, can also select a huge sum of money Belong to, but effect is not ideal enough.The proportioning of dehydrating agent of the present invention can be dehydrated in high alkalinity medium, and dehydration mediators PH value reach 12-12.5, dehydrating effect is best, to improve the pH value of dehydration mediators, reaches best dehydrating effect.Through application People tests, and the heavy metal dehydration rate of recovery in red mud can reach 80% or more.
Embodiment one
A method of it is building materials to dispose red mud using permanent-magnet material and salt slurry, is included the following steps:A, red mud is spent Ionized water slurrying, slurry carry out magnetic separation with permanent-magnet material, select radioactivity mineral aggregate therein, including ilmenite, iron ore and solely Occupy stone;B, remaining slurry removes heavy metal therein by dehydration.It can be by the radioactive substance in red mud by the above method Separation, enrichment, reduce the radioactivity of red mud.
Magnetic separation in the step a is slurry by the permanent magnet system that magnetic field intensity is 6600 Gausses, selects therein put Penetrating property mineral aggregate, including ilmenite, iron ore, monazite, the mineral aggregate selected are less than the magnetic separation system of 6500 Gausses by magnetic field intensity again System, selects mineral aggregate containing ferromagnetism, including iron ore, ilmenite, so that monazite is detached with iron content radioactivity mineral aggregate, make monazite into one Step enrichment.
Dehydration in the step b is:By weight, it is added in 1000 parts of slurries by 50 parts of salt slurries, 100 part three The dehydrating agent of iron chloride composition, is dehydrated in the medium of pH=12, heavy metal is separated, state dehydration after mixing The salt slurry that agent uses is chlor-alkali plant salt slurry.
Embodiment two
A method of it is building materials to dispose red mud using permanent-magnet material and salt slurry, is included the following steps:A, red mud is spent Ionized water slurrying, slurry carry out magnetic separation with permanent-magnet material, select radioactivity mineral aggregate therein, including ilmenite, iron ore and solely Occupy stone;B, remaining slurry removes heavy metal therein by dehydration.It can be by the radioactive substance in red mud by the above method Separation, enrichment, reduce the radioactivity of red mud.
Magnetic separation in the step a is slurry by the permanent magnet system that magnetic field intensity is 6700 Gausses, selects therein put Penetrating property mineral aggregate, including ilmenite, iron ore, monazite, the mineral aggregate selected are less than the magnetic separation system of 6500 Gausses by magnetic field intensity again System, selects mineral aggregate containing ferromagnetism, including iron ore, ilmenite, so that monazite is detached with iron content radioactivity mineral aggregate, make monazite into one Step enrichment.
Dehydration in the step b is:By weight, it is added in 1000 parts of slurries by 100 parts of salt slurries, 150 parts The dehydrating agent of ferric trichloride composition, is dehydrated in the medium of pH=12.25, heavy metal is separated after mixing, It is chlor-alkali plant salt slurry to state the salt slurry that dehydrating agent uses.
Embodiment three
A method of it is building materials to dispose red mud using permanent-magnet material and salt slurry, is included the following steps:A, red mud is spent Ionized water slurrying, slurry carry out magnetic separation with permanent-magnet material, select radioactivity mineral aggregate therein, including ilmenite, iron ore and solely Occupy stone;B, remaining slurry removes heavy metal therein by dehydration.It can be by the radioactive substance in red mud by the above method Separation, enrichment, reduce the radioactivity of red mud.
Magnetic separation in the step a is slurry by the permanent magnet system that magnetic field intensity is 6800 Gausses, selects therein put Penetrating property mineral aggregate, including ilmenite, iron ore, monazite, the mineral aggregate selected are less than the magnetic separation system of 6500 Gausses by magnetic field intensity again System, selects mineral aggregate containing ferromagnetism, including iron ore, ilmenite, so that monazite is detached with iron content radioactivity mineral aggregate, make monazite into one Step enrichment.
Dehydration in the step b is:By weight, it is added in 1000 parts of slurries by 150 parts of salt slurries, 200 parts The dehydrating agent of ferric trichloride composition, is dehydrated in the medium of pH=12.5, heavy metal is separated, stated after mixing The salt slurry that dehydrating agent uses is chlor-alkali plant salt slurry.
The above is only presently preferred embodiments of the present invention, is not intended to limit the present invention in any form, Ren Hewei Be detached from technical solution of the present invention content, according to the technical essence of the invention to made by above example it is any it is simple modification, etc. With variation and modification, in the range of still falling within technical solution of the present invention.

Claims (3)

1. a kind of disposing the method that red mud is building materials using permanent-magnet material and salt slurry, it is characterised in that:Include the following steps:A, will Red mud spends ionized water slurrying, and slurry carries out magnetic separation with permanent-magnet material, selects radioactivity mineral aggregate therein, including ilmenite, Iron ore and monazite;B, remaining slurry removes heavy metal therein by dehydration;Dehydration in the step b is:By weight Gauge is added in 1000 parts of slurries by 50-150 parts of salt slurries, and the dehydrating agent of 100-200 parts of ferric trichlorides composition is uniformly mixed It is dehydrated in the medium of pH >=12 afterwards, heavy metal is separated;The pH value of the dehydration mediators is 12-12.5.
2. according to claim 1 a kind of using permanent-magnet material and method that salt slurry disposition red mud is building materials, feature exists In:Magnetic separation in the step a is slurry by the permanent magnet system that magnetic field intensity is 6500-6800 Gausses, selects therein put Penetrating property mineral aggregate, including ilmenite, iron ore, monazite, the mineral aggregate selected are less than the magnetic separation system of 6500 Gausses by magnetic field intensity again System, selects mineral aggregate containing ferromagnetism, including iron ore, ilmenite, so that monazite is detached with iron content radioactivity mineral aggregate, make monazite into one Step enrichment.
3. according to claim 1 a kind of using permanent-magnet material and method that salt slurry disposition red mud is building materials, feature exists In:The salt slurry that the dehydrating agent uses is chlor-alkali plant salt slurry.
CN201610119528.XA 2016-03-03 2016-03-03 A method of it is building materials to dispose red mud using permanent-magnet material and salt slurry Active CN106311715B (en)

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CN102295396A (en) * 2011-06-20 2011-12-28 中国铝业股份有限公司 Reprocessing and comprehensive utilization method of red mud
CN102897816A (en) * 2012-09-29 2013-01-30 贵州绿水青山环保科技有限公司 Deep recycling method of red mud
CN102989581A (en) * 2012-09-29 2013-03-27 贵州绿水青山环保科技有限公司 Method for removing radioactivity of red mud
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CN102897816A (en) * 2012-09-29 2013-01-30 贵州绿水青山环保科技有限公司 Deep recycling method of red mud
CN102989581A (en) * 2012-09-29 2013-03-27 贵州绿水青山环保科技有限公司 Method for removing radioactivity of red mud
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