CN106290208A - A kind of ozone concentration determinator - Google Patents

A kind of ozone concentration determinator Download PDF

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Publication number
CN106290208A
CN106290208A CN201610604398.9A CN201610604398A CN106290208A CN 106290208 A CN106290208 A CN 106290208A CN 201610604398 A CN201610604398 A CN 201610604398A CN 106290208 A CN106290208 A CN 106290208A
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CN
China
Prior art keywords
air chamber
measured
ultraviolet
light
veiling glare
Prior art date
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Pending
Application number
CN201610604398.9A
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Chinese (zh)
Inventor
王新全
武婧
徐少才
梁永
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QINGDAO HAINA GUANGDIAN ENVIRONMENTAL PROTECTION CO Ltd
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QINGDAO HAINA GUANGDIAN ENVIRONMENTAL PROTECTION CO Ltd
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Priority to CN201610604398.9A priority Critical patent/CN106290208A/en
Publication of CN106290208A publication Critical patent/CN106290208A/en
Pending legal-status Critical Current

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    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N21/00Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
    • G01N21/17Systems in which incident light is modified in accordance with the properties of the material investigated
    • G01N21/25Colour; Spectral properties, i.e. comparison of effect of material on the light at two or more different wavelengths or wavelength bands
    • G01N21/31Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry
    • G01N21/33Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry using ultraviolet light
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N21/00Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
    • G01N21/01Arrangements or apparatus for facilitating the optical investigation
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N2201/00Features of devices classified in G01N21/00
    • G01N2201/06Illumination; Optics
    • G01N2201/061Sources
    • G01N2201/06113Coherent sources; lasers
    • G01N2201/0612Laser diodes
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N2201/00Features of devices classified in G01N21/00
    • G01N2201/06Illumination; Optics
    • G01N2201/064Stray light conditioning
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N2201/00Features of devices classified in G01N21/00
    • G01N2201/06Illumination; Optics
    • G01N2201/068Optics, miscellaneous

Abstract

A kind of ozone concentration determinator, including ultraviolet light emission device, air chamber to be measured, ultraviolet detector device, the entrance port of described air chamber to be measured injected by the ultraviolet light that wherein said ultraviolet light emission device sends, the emergent light of the exit portal of described air chamber to be measured is irradiated on described ultraviolet detector device after assembling, the front end light path of described ultraviolet detector device is provided with the veiling glare device that disappears, the described center disappearing veiling glare device has loophole, and described loophole is arranged on primary optical axis.The present invention solves prior art light source length stabilization time, starts the problem that voltage is high, the efficiency of light energy utilization is low, optical energy attenuation is fast.Improve the stability of air chamber light path simultaneously, improve contamination resistance, improve the ability of anti-veiling glare.

Description

A kind of ozone concentration determinator
Technical field
The present invention relates to ozone concentration detection apparatus field, a kind of ozone concentration determinator specifically, particularly one Plant the ultraviolet photometer for detecting ozone concentration.
Background technology
Ozone is the minimum gas that in air, chemical property is active, has strong oxidizing property, greenhouse effect and uv absorption Characteristic, and impact significant on weather, ecology, environment etc..Ozone is also in urban environment air of paramount importance two One of secondary pollutant, are one of main reason of degradation contamination phenomenon under acid rain, photochemical fog, atmospheric visibility, also can be right Human body causes serious harm.What ozone had become as developed country's air quality monitoring must survey project.Ozone also became in recent years The primary pollutant in Some Domestic city, the monitoring of ozone has been subjected to extensive concern.
Ozone analyzer for environment Determination of ozone mainly has the most on the market: the 49i type of Thermo company of (1) U.S. Ozone analyzer, 400 series ozone analysers of API company of (2) U.S., (3) Australia ECO company UV100 series smelly Oxygen analyzer, 106,202,205,211 series ozone analysers of 2B company of (4) U.S..These products the most also have in a large number Use, particularly Thermo company and the product of API company, it has also become the canonical reference product of domestic ozone monitoring.Above-mentioned product Product all use Ultraviolet Photometric Method, one of standard method of Ultraviolet Photometric Method Ye Shi China surrounding air Determination of ozone.
Ultraviolet Photometric Method is to utilize ozone molecule to have the characteristic of obtained the maximum absorption at 254nm at wavelength, in conjunction with Bill- Lambert's law calculates the concentration of ozone in sample gas, has and measures advantage easy, that rapid, capacity of resisting disturbance is strong.It is currently used for smelly The ultraviolet photometer that oxygen measures mainly uses mercury lamp as light source, and light beam of light source is incident, at glass from one end of glass tubing air chamber Alternately being passed through the reference gas removing ozone and the sample gas containing ozone in pipe air chamber, the other end at glass tubing air chamber uses light Electric explorer gathers the optical signal passed through, and calculates ozone concentration by the signal gathered in the case of two kinds is carried out process. There are the following problems for the existing ultraviolet photometer for Determination of ozone:
(1) use low pressure mercury lamp as light source, need longer pre-heat-stable time, need the startup voltage of kilovolt, Light source luminescent dissipates so that capacity usage ratio is low to surrounding, and luminous energy can be decayed with the lengthening of the time of use, affects the longevity of equipment Life.
(2) light beam that light source sends is directed through quartz window sheet and enters glass tubing air chamber, and in this mode, light beam freely enters Air inlet chamber, only a small amount of light directly arrives detector, and most of light can reflect on air chamber wall, such that through air chamber Light beam light path disunity, causes measurement result generation deviation.
(3) air chamber contamination resistance is poor, when front end preprocessing part to tested gas treatment thoroughly time, moisture or granule Thing is deposited on air chamber wall and causes air chamber wall reflection characteristic to change, and can make a big impact measurement result.
(4) photodetector direct detection passes through air chamber the light beam through quartz window sheet, and this detection mode can be subject to Interference of stray light so that the signal to noise ratio of detection declines.
(5) needing before photodetector photosurface to add a piece of UV interference filters, the transmitance of optical filter is relatively low, can be right Luminous energy causes the biggest decay, reduces signal to noise ratio.
It is illustrated in figure 1 the existing Ultraviolet Photometric Method photometric schematic diagram of ozone analyzer medium ultraviolet.Low pressure mercury lamp 11 Light beam 12 part gone out enters glass tubing air chamber 14 through front end quartz window sheet 13, after passing through through the light beam of glass tubing air chamber 14 Again through 254nm narrow band pass filter 16 after end quartz window sheet 15, the light beam filtered through narrow band pass filter 16 arrives ultraviolet photoelectric Survey device 17.The tested gas entering glass tubing air chamber 14 can produce absorption to the middle light beam of air chamber, utilizes UV photodetector 17 photosignals gathered can calculate gas concentration.There are the following problems for the existing ultraviolet photometer for Determination of ozone:
(1) low pressure mercury lamp 11 needs higher startup voltage (upper kilovolt), requires higher to drive circuit;Stabilization time Long, need the preheating of several tens minutes to stablize;Light beam 12 dissipates, and capacity usage ratio is low;Along with the lengthening of the time of use, energy Amount can accelerate decay, causes stability to decline, and needs frequently to demarcate.
(2) front end quartz window sheet 13 is flat glass plate, only serves the effect of printing opacity and sealing, and light beam is in air chamber Free propagation state, can occur multiple reflections on air chamber wall, and the beam state of different incidence angles is inconsistent, causes every Shu Guang's Light path is inconsistent.
(3) can reflect on glass tubing air chamber 14 inwall due to the light beam of significant proportion, if existed on air chamber wall When steam or Particulate Pollution, the biggest reflection loss can be caused, cause the instability measuring signal.
(4) rear end quartz window sheet 15 the most only serves printing opacity and sealing function, and the adjustment to light beam is not contributed, and goes out more greatly The light beam of firing angle is not up to UV photodetector 17.
(5) there is the spectral line of a plurality of wavelength due to low pressure mercury lamp 11, so needing to increase narrow band pass filter 16, only allowing The light transmission of 254nm, the transmitance of general spike interference filter is relatively low, and only about 20%, so narrow-band-filter sector-meeting makes Energy is substantially reduced.Above-mentioned existing scheme causes the efficiency of light energy utilization low, spuious wide, in order to improve power of test, and the side taked Method is to increase light source power, increases air chamber length, increases the average time that data process, and so can cause that equipment volume is big, merit Consumption is high, low-response.
The problems referred to above make existing ultraviolet photometer detectivity limited, need to use bigger light source power, longer Air chamber light path and bigger volume make up drawbacks described above, thus improve ozone power of test, and this is also to cause existing equipment body Long-pending big, power consumption height, the main cause of low-response.
Summary of the invention
It is an object of the invention to provide a kind of ozone concentration determinator, to reduce air chamber wall reflection light interference, improve letter Make an uproar ratio.
The purpose of the present invention implements by the following technical programs:
A kind of ozone concentration determinator, including ultraviolet light emission device, air chamber to be measured, ultraviolet detector device, wherein The entrance port of described air chamber to be measured injected by the ultraviolet light that described ultraviolet light emission device sends, the exit portal of described air chamber to be measured Emergent light is irradiated on described ultraviolet detector device after assembling, and is provided with and disappears in the front end light path of described ultraviolet detector device Veiling glare device, described in the disappear center of veiling glare device there is loophole, and described loophole is arranged on primary optical axis.
Preferably, the distance between veiling glare device and described air chamber exit portal to be measured that disappears described in disappears veiling glare device described in being more than And the distance between described ultraviolet detector device.
Preferably, the veiling glare device that disappears described in is diaphragm.
Preferably, described loophole is circular or square.
Preferably, described air chamber to be measured is tubular construction, and the wall of described air chamber to be measured is provided with air inlet and gives vent to anger Hole.
Preferably, described air inlet and described venthole are positioned at the two ends of described air chamber to be measured.
Preferably, being provided with projecting lens in the entrance port of described air chamber to be measured, the exit portal at described air chamber to be measured is provided with Collecting lens, described ultraviolet light emission device is arranged on the focal position of described projecting lens, and described ultraviolet detector device sets Put the rear at described diaphragm.
Preferably, described projecting lens, described collecting lens use with described air chamber to be measured and are tightly connected.
Preferably, described ultraviolet light emission device is ultraviolet LED lamp.
It is further preferred that the integrated spherical collecting lens in described ultraviolet LED lamp top, centre wavelength is 254nm and with arteries and veins The arrowband deep ultraviolet LED that the mode of punching works.
The present invention solves prior art light source length stabilization time, startup voltage is high, the efficiency of light energy utilization is low, optical energy attenuation is fast Problem.Improve the stability of air chamber light path simultaneously, improve contamination resistance, improve the ability of anti-veiling glare.
Accompanying drawing explanation
Below according to drawings and Examples, the present invention is described in further detail.
Fig. 1 is the schematic diagram of the existing ultraviolet photometer for Determination of ozone.In figure, 11 is low pressure mercury lamp bulb, and 12 are The light beam that low pressure mercury lamp bulb sends, 13 is front end quartz window sheet, and 14 is glass tubing air chamber, and 15 is rear end quartz window sheet, and 16 are 254nm narrow band pass filter, 17 is UV photodetector.
Fig. 2 is the schematic diagram of a kind of ozone concentration determinator that the present invention proposes.In figure, 21 is ultraviolet LED, and 22 is purple The light beam that outer LED sends, 23 is projecting lens, and 24 is glass tubing air chamber, and 25 is veiling glare, and 26 is collecting lens, and 27 is miscellaneous for disappearing Light diaphragm, 28 is UV photodetector.
Fig. 3 is the spectral power distribution schematic diagram of ultraviolet LED.
Fig. 4 is the encapsulation schematic diagram of ultraviolet LED light source.
Fig. 5 is the lighting angle schematic diagram of ultraviolet LED.
Detailed description of the invention
As shown in Figure 2-5, the invention provides a kind of ozone concentration determinator, including ultraviolet light emission device, to be measured Air chamber, ultraviolet detector device, the incidence of described air chamber to be measured injected by the ultraviolet light that wherein said ultraviolet light emission device sends Mouthful, the emergent light of the exit portal of described air chamber to be measured is irradiated on described ultraviolet detector device, at described ultraviolet light after assembling The front end light path of detection device is provided with the veiling glare device that disappears, described in the disappear center of veiling glare device there is loophole, and described Unthreaded hole is arranged on primary optical axis.
Wherein, described ultraviolet detector device is UV photodetector, and described UV photodetector can be at light Source luminescence spectral coverage has the photodetector of good spectral response, preferably ultraviolet enhancement photodiode detector.
The described distance disappeared between veiling glare device and described air chamber exit portal to be measured disappears veiling glare device with described described in being more than Distance between ultraviolet detector device.
The described veiling glare device that disappears is diaphragm.UV photodetector is placed on the rear of last a piece of diaphragm for eliminating stray light.
Wherein, the foil of perforate centered by diaphragm, perforate can be square hole or circular hole, and diaphragm for eliminating stray light is placed on convergence At the beam cross section minimum of lens rear.Diaphragm can have two or the thin metal of more than two center drillings the most at a distance Sheet forms, and forms the multistage veiling glare that disappears.
Described loophole is circular or square.
Described air chamber to be measured is tubular construction, and the wall of described air chamber to be measured is provided with air inlet and venthole.
Described air inlet and described venthole are positioned at the two ends of described air chamber to be measured.
Being provided with projecting lens in the entrance port of described air chamber to be measured, the exit portal at described air chamber to be measured is provided with convergence thoroughly Mirror, described ultraviolet light emission device is arranged on the focal position of described projecting lens, and described ultraviolet detector device is arranged on institute State the rear of diaphragm.
Described projecting lens, described collecting lens use with described air chamber to be measured and are tightly connected.
Wherein, projecting lens is the convex lens with convergence function, and the material of employing has at deep ultraviolet spectral coverage and well passes through Rate, and there is corrosion-resistant, the characteristic of not adsorbed gas, it is preferred to use JGS1 silica glass material.
Described collecting lens is convex lens, and the material of employing has good transmitance at deep ultraviolet spectral coverage, and has resistance to Corrosion, the characteristic of not adsorbed gas, it is preferred to use JGS1 silica glass material.
Described ultraviolet light emission device is ultraviolet LED lamp.
Wherein, the arrowband deep ultraviolet LED that ultraviolet LED uses centre wavelength to be 254nm, the integrated spherical collecting lens in top, Ultraviolet LED works in a pulsed fashion, improves service life and reduces average power consumption.
The present invention solves prior art light source length stabilization time, startup voltage is high, the efficiency of light energy utilization is low, optical energy attenuation is fast Problem.Improve the stability of air chamber light path simultaneously, improve contamination resistance, improve the ability of anti-veiling glare.
In order to allow those skilled in the art become apparent from the creation objective of the present invention, it is embodied as below in conjunction with the accompanying drawings and with one Example is illustrated:
As in figure 2 it is shown, light source uses ultraviolet LED 21, the light beam that ultraviolet LED 21 sends enters glass through projecting lens 23 Pipe air chamber 24, the ultraviolet light beam after projecting lens 23 is directly arrived by glass tubing air chamber 24 close to collimating status, major part Collecting lens 26, the light beam through collecting lens 26 is quickly assembled, and places diaphragm for eliminating stray light 27 at the minimum of convergent beam cross section, Diaphragm for eliminating stray light 27 is foil, central openings, and perforate can be circular or square.Control the size of diaphragm for eliminating stray light 27, make Must only without glass tubing air chamber 24 inwall reflection light beam by the veiling glare perforate that disappears.Light beam through diaphragm for eliminating stray light 27 can arrive Reach UV photodetector 28.In figure, 25 is the schematic diagram of a branch of veiling glare, and veiling glare is probably light or the warp that non-light source sends The light beam that glass tubing air chamber 24 inwall reflected, can be stopped by diaphragm for eliminating stray light 27 after the concentrated lens of veiling glare 25 26, it is impossible to Arrive detector.By adding collecting lens 26 and diaphragm for eliminating stray light 27, the efficiency of light energy utilization can not only be improved and can also effectively press down Veiling glare processed, the light arriving detector all reflects without glass tubing air chamber 24 inwall, thus the pollution of air chamber inwall will not be to survey Amount interferes, and is effectively improved the Stability and veracity of measurement.Ultraviolet LED 21 has luminous efficiency height, caloric value Little, moment is luminous, therefore drive circuit is relatively easy, and can work in a pulsed mode, can be effectively improved response time and Increase service life.
As it is shown on figure 3, the spectral power distribution that Fig. 3 is selected ultraviolet LED, the wherein a length of 254nm of cardiac wave, whole spectrum energy Amount is all in the range of the characteristic absorption of ozone, and therefore luminous energy service efficiency is the highest.Owing to there is no other invalid spectral component, so Without increasing ultraviolet spike interference filter before UV photodetector 28, conventional ultraviolet spike interference filter peak value is saturating The rate of mistake only has about 20%, cancels ultraviolet narrow band pass filter and can be effectively improved the efficiency of light energy utilization of system.
As shown in Figure 4, Fig. 4 is the packing forms schematic diagram of the ultraviolet LED that this programme selects, at the top collection of ultraviolet LED Glomeration collecting lens, so that the light beam of light source angle of divergence is the least.
As it is shown in figure 5, Fig. 5 is light beam of light source angle of divergence schematic diagram, the energy of more than 70% can concentrate on ± 7 ° within, The energy of more than 95% concentrates on ± 15 ° within.The less angle of divergence is added and be have employed projecting lens so that light source sends Light beam nearly all becomes to be used up, and strengthens the utilization rate that improve luminous energy.Under conditions of same measured index, light source can be made Power is lower, air chamber is shorter, thus effectively reduces power consumption and the volume of equipment.
Compared with prior art, the invention has the beneficial effects as follows:
(1) ultraviolet LED of the little lighting angle using centre wavelength to be 254nm, and work in a pulsed fashion, there is body Long-pending little, luminous efficiency is high, the efficiency of light energy utilization is high, power consumption is little, start that voltage is low, moment is stable, the advantage of life-span length.
(2) use lens on light source beam to nurse one's health, reduce beam divergence angle further and on the one hand improve the profit of luminous energy By rate, on the other hand reduce air chamber wall reflection light interference, improve signal to noise ratio.
(3) eliminate air chamber wall and pollute the reflectance decline the caused impact on measurement result.
(4) use collecting lens and increase diaphragm for eliminating stray light, effectively suppressing veiling glare, reducing interference so that light path is more Accurately, measurement result signal to noise ratio is higher.
(5) without using ultraviolet spike interference filter in the optical path, improve the efficiency of light energy utilization and signal to noise ratio, identical Certainty of measurement shortens light path in the case of requiring further so that volume is less, is more beneficial for instrument miniaturization.
Last it is noted that the foregoing is only the preferred embodiment of invention, it is not limited to invention, although Being described in detail invention with reference to previous embodiment, for a person skilled in the art, it still can be to front State the technical scheme described in each embodiment to modify, or wherein portion of techniques feature is carried out equivalent.All send out Within bright spirit and principle, any modification, equivalent substitution and improvement etc. made, should be included in invention protection domain it In.

Claims (10)

1. an ozone concentration determinator, including ultraviolet light emission device, air chamber to be measured, ultraviolet detector device, Qi Zhongsuo State the ultraviolet light that ultraviolet light emission device sends and inject the entrance port of described air chamber to be measured, going out of the exit portal of described air chamber to be measured Penetrate after light is assembled and be irradiated on described ultraviolet detector device, it is characterised in that at the front end light of described ultraviolet detector device Road is provided with the veiling glare device that disappears, described in the disappear center of veiling glare device there is loophole, and described loophole is arranged on primary optical axis On.
2. device as claimed in claim 1, it is characterised in that described in disappear between veiling glare device and described air chamber exit portal to be measured Distance be more than described in disappear the distance between veiling glare device and described ultraviolet detector device.
3. device as claimed in claim 1 or 2, it is characterised in that described in the veiling glare device that disappears be diaphragm.
4. device as claimed in claim 1 or 2, it is characterised in that described loophole is circular or square.
5. device as claimed in claim 1 or 2, it is characterised in that described air chamber to be measured is tubular construction, and described to be measured The wall of air chamber is provided with air inlet and venthole.
6. device as claimed in claim 5, it is characterised in that described air inlet and described venthole are positioned at described air chamber to be measured Two ends.
7. the device as described in claim 1 or 6, it is characterised in that be provided with projecting lens in the entrance port of described air chamber to be measured, Exit portal at described air chamber to be measured is provided with collecting lens, and described ultraviolet light emission device is arranged on the focus of described projecting lens Position, described ultraviolet detector device is arranged on the rear of described diaphragm.
8. device as claimed in claim 7, it is characterised in that described projecting lens, described collecting lens and described gas to be measured Room uses and is tightly connected.
9. device as claimed in claim 1, it is characterised in that described ultraviolet light emission device is ultraviolet LED lamp.
10. device as claimed in claim 9, it is characterised in that the integrated spherical collecting lens in described ultraviolet LED lamp top, in The a length of 254nm of cardiac wave and the arrowband deep ultraviolet LED worked in a pulsed fashion.
CN201610604398.9A 2016-07-28 2016-07-28 A kind of ozone concentration determinator Pending CN106290208A (en)

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107064039A (en) * 2017-04-19 2017-08-18 中国电子科技集团公司第四十九研究所 A kind of detection method of ozone monitoring sensor and its ozone concentration based on phase lock amplifying technology
CN107421906A (en) * 2017-06-13 2017-12-01 淄博前沿医疗器械有限公司 A kind of photometer of efficiently measurement concentration of ozone gas
CN107782689A (en) * 2017-08-21 2018-03-09 深圳欧威奇科技有限公司 Ozone gas concentration detection apparatus and ozone gas concentration detection method
CN107941730A (en) * 2017-11-16 2018-04-20 广东上风环保科技有限公司 A kind of method and apparatus for measuring Ozone in Atmosphere concentration
CN107966409A (en) * 2017-12-29 2018-04-27 青岛崂应环境科技有限公司 Gas concentration analysis method and device
CN109374536A (en) * 2018-12-13 2019-02-22 青岛海纳光电环保有限公司 Ozone concentration measurement device and method

Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1400464A (en) * 2001-08-07 2003-03-05 中国科学院大连化学物理研究所 Laser induced fluorescence detector
CN1485605A (en) * 2002-09-29 2004-03-31 �Ϻ���ͨ��ѧ Optical method for detecting discerptible medium skin layer and deep layer information
CN1844866A (en) * 2005-04-08 2006-10-11 中国科学院半导体研究所 Structure for decreasing stray light in spectrum instrument
CN1920533A (en) * 2005-08-24 2007-02-28 南引明 Ozone concentration measurer
CN201503396U (en) * 2009-08-31 2010-06-09 四川科奥达技术有限公司 Atmospheric transmission visibility meter
CN103033491A (en) * 2012-12-25 2013-04-10 中国科学院长春光学精密机械与物理研究所 Laboratory testing method for atmospheric transmissivity of multi-band light radiation
CN103454255A (en) * 2013-09-02 2013-12-18 中国科学院上海微系统与信息技术研究所 Terahertz-wave scanning imaging system and method
CN203772733U (en) * 2014-01-17 2014-08-13 浙江师范大学 Device for ozone concentration detection based on visible absorption spectrum technology
CN105548075A (en) * 2016-01-08 2016-05-04 楚天科技股份有限公司 Device and method for detecting oxygen content in glass medicine bottle

Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1400464A (en) * 2001-08-07 2003-03-05 中国科学院大连化学物理研究所 Laser induced fluorescence detector
CN1485605A (en) * 2002-09-29 2004-03-31 �Ϻ���ͨ��ѧ Optical method for detecting discerptible medium skin layer and deep layer information
CN1844866A (en) * 2005-04-08 2006-10-11 中国科学院半导体研究所 Structure for decreasing stray light in spectrum instrument
CN1920533A (en) * 2005-08-24 2007-02-28 南引明 Ozone concentration measurer
CN201503396U (en) * 2009-08-31 2010-06-09 四川科奥达技术有限公司 Atmospheric transmission visibility meter
CN103033491A (en) * 2012-12-25 2013-04-10 中国科学院长春光学精密机械与物理研究所 Laboratory testing method for atmospheric transmissivity of multi-band light radiation
CN103454255A (en) * 2013-09-02 2013-12-18 中国科学院上海微系统与信息技术研究所 Terahertz-wave scanning imaging system and method
CN203772733U (en) * 2014-01-17 2014-08-13 浙江师范大学 Device for ozone concentration detection based on visible absorption spectrum technology
CN105548075A (en) * 2016-01-08 2016-05-04 楚天科技股份有限公司 Device and method for detecting oxygen content in glass medicine bottle

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
叶盛祥: "《光电位移精密测量技术》", 30 June 2003 *

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107064039A (en) * 2017-04-19 2017-08-18 中国电子科技集团公司第四十九研究所 A kind of detection method of ozone monitoring sensor and its ozone concentration based on phase lock amplifying technology
CN107421906A (en) * 2017-06-13 2017-12-01 淄博前沿医疗器械有限公司 A kind of photometer of efficiently measurement concentration of ozone gas
CN107782689A (en) * 2017-08-21 2018-03-09 深圳欧威奇科技有限公司 Ozone gas concentration detection apparatus and ozone gas concentration detection method
CN107782689B (en) * 2017-08-21 2020-10-09 深圳康诚博信科技有限公司 Ozone gas concentration detection device and ozone gas concentration detection method
CN107941730A (en) * 2017-11-16 2018-04-20 广东上风环保科技有限公司 A kind of method and apparatus for measuring Ozone in Atmosphere concentration
CN107941730B (en) * 2017-11-16 2021-02-05 广东盈峰科技有限公司 Method and device for measuring concentration of ozone in atmosphere
CN107966409A (en) * 2017-12-29 2018-04-27 青岛崂应环境科技有限公司 Gas concentration analysis method and device
CN109374536A (en) * 2018-12-13 2019-02-22 青岛海纳光电环保有限公司 Ozone concentration measurement device and method

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