CN106283106B - Image processing-based automatic analysis system for solid-liquid interface electrode process - Google Patents
Image processing-based automatic analysis system for solid-liquid interface electrode process Download PDFInfo
- Publication number
- CN106283106B CN106283106B CN201610590487.2A CN201610590487A CN106283106B CN 106283106 B CN106283106 B CN 106283106B CN 201610590487 A CN201610590487 A CN 201610590487A CN 106283106 B CN106283106 B CN 106283106B
- Authority
- CN
- China
- Prior art keywords
- container
- valve
- tube chamber
- gas tank
- electrode
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B15/00—Operating or servicing cells
- C25B15/02—Process control or regulation
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B1/00—Electrolytic production of inorganic compounds or non-metals
- C25B1/01—Products
- C25B1/02—Hydrogen or oxygen
- C25B1/04—Hydrogen or oxygen by electrolysis of water
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/36—Hydrogen production from non-carbon containing sources, e.g. by water electrolysis
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Automation & Control Theory (AREA)
- Inorganic Chemistry (AREA)
- Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
- Fuel Cell (AREA)
Abstract
The automatic analysis system of the solid-liquid interface electrode process based on image processing is characterized in that: comprises an electrolysis device, a control system, a hydrogen production and power generation module and a camera device. The invention has the advantages of low cost, flexible application, long service life, difficult damage, stability, reliability and quick and reliable analysis.
Description
Technical field
The invention belongs to electricity fields, and in particular to the solid liquid interface electrode process based on image procossing, which automatically analyzes, is
System.
Background technology
During the liquid electrolytic of solid state electrode, the rising of the bubble near electrode surface merges, and easily influences
Contact of the electrode surface with liquid, influences the movement of liquid intermediate ion, and the reduction of the contact area of electrode surface and liquid is caused to be led
The generation of solution efficiency bottle neck is sent a telegraph, scientific research personnel studies this process and is conducive to break through electrolytic efficiency bottleneck.
During the liquid electrolytic of solid state electrode, the merging and explosion of the bubble near electrode surface, easily in office
Portion's high temperature and powerful impact force, cause solid state electrode to be corroded, and influence the service life of electrode, scientific research personnel, which studies this process, to be had
The electrolysis electrode more long-lived beneficial to relatively existing electrolysis electrode is researched and developed.
Scientific research personnel is on the surface that analysis solid state electrode electrolyte is electrode（That is solid liquid interface）State when there are all
It is mostly inconvenient；If there is a kind of system that can be realized and automatical analysis is carried out to electrode process, then scientific research personnel can be improved
To the efficiency of research and development of electrolysis electrode.
The content of the invention
To solve the problems, such as to describe in technical background, the present invention proposes the solid liquid interface electrode process based on image procossing
Automatic analysis system, present system can realize the automatical analysis of electrode process, improve scientific research efficiency.
The present invention has following technology contents.
1st, the solid liquid interface electrode process automatic analysis system based on image procossing, it is characterised in that：Including electrolysis unit,
Control system, preparing hydrogen, generating power module, photographic device；
Electrolysis unit includes：Equalizing reservoir（10）, the first container（11）, second container（12）, the first evacuated tube（110）、
Second evacuated tube（120）, first emptying valve（F1）, second emptying valve（F2）, first electrode（DJ1）, second electrode（DJ2）；
In electrolysis unit:Equalizing reservoir（10）For column, equalizing reservoir（10）Upper end opening；
In electrolysis unit:The first container（11）For column, the first container（11）Upper end and the first evacuated tube（110）Phase
It is logical；
In electrolysis unit:Second container（12）For column, second container（12）Upper end and the second evacuated tube（120）Phase
It is logical；
In electrolysis unit:Equalizing reservoir（10）, the first container（11）, second container（12）Bottom communicates；Electrolysis unit
In:First emptying valve（F1）Positioned at the first evacuated tube（110）Pipeline on, first emptying valve（F1）The first emptying can be controlled
Pipe（110）Break-make situation；
In electrolysis unit:Second emptying valve（F2）Positioned at the second evacuated tube（120）Pipeline on, second emptying valve（F2）
The second evacuated tube can be controlled（120）Break-make situation；
In electrolysis unit:First electrode（DJ1）Positioned at the first container（11）It is interior；Second electrode（DJ2）Positioned at second container
（12）It is interior.
Electrolysis unit further includes liquid feed valve（F4）, liquid feed valve（F4）；Liquid feed valve（F4）Positioned at inlet tube（14）Pipeline on,
Inlet tube（14）Interior liquid can be flowed into equalizing reservoir（10）In.
Electrolysis unit further includes tapping valve（F3）；Tapping valve（F3）Installation at one end with equalizing reservoir（10）Communicate one end with
On the pipeline that outside communicates, tapping valve（F3）For drained liquid, tapping valve（F3）Liquid equal height less than the first container（11）
Cavity volume the top.
Electrolysis unit further includes scale（2）；Scale（2）Scale extension direction and second container（12）Axial direction phase
Together.
Control system includes control module, programmable power supply, and control module mutually directly has with programmable power supply to be electrically connected, and is controlled
Molding block can control programmable power supply；Have between photographic device and control system and be electrically connected, photographic device can be to control
Module transfer image data, the camera lens of photographic device are shot for the first container（11）, second container（12）Radial direction, camera shooting
Device can shoot the first container（11）Interior image.
The control module and first emptying valve of control system（F1）Between have be electrically connected, the control module of control system
First emptying valve can be controlled（F1）；The control module and second emptying valve of control system（F2）Between have be electrically connected, control
The control module of system processed can control second emptying valve（F2）.
The control module of control system also with tapping valve（F3）Between have be electrically connected, the control module energy of control system
Enough control tapping valve（F3）；The control module and liquid feed valve of control system（F4）Between have be electrically connected, the control of control system
Molding block can control liquid feed valve（F4）.
Control system has used autocontrol method；Autocontrol method is characterized in that：Comprise the following steps,
Step 1, inaccessible drain valve（F3）
Step 2 opens first emptying valve（F1）And second emptying valve（F2）；
Step 3 opens liquid feed valve（F4）Liquid to be electrolysed is made to flow into equalizing reservoir（10）;
Step 4 judges first emptying valve（F1）Or second emptying valve（F2）Whether overflowing liquid, if overflow if into step
Rapid 5, Xun Huan reenters this step if not overflowing；
Step 5, inaccessible first emptying valve（F1）And second emptying valve（F2）；
Step 6 extracts current information from the information bank of stored current data, and current information is strong including but not limited to electric current
Degree, waveform, cycle, most long energization period；
Step 7 starts image identification function；
Step 8, the current data gone according to step 6 tune control programmable power supply output current；
Step 9 judges whether to reach maximum energization period, and 11 are entered step if maximum energization period is reached, if
It is not reaching to maximum energization period and then enters step 10；
Step 10 reads gas column height by image identification function, and judges whether gas column height is more than warning value, if
Gas column height then enters step 11 more than warning value, and 9 are entered step if gas column height is not above warning value；
Step 11 makes programmable power supply stop electric current output；
Step 12 judges gas column height by image identification function, and preserves gas column height value.
Step 13 terminates.
There is electroanalysis method, electroanalysis method is based on control module and is filled from camera shooting in the control module of control system
It puts the image of acquisition and is analyzed, photographic device is imaged using laser or X-ray, and bladdery region liquid is to laser in image
Or the absorption of X-ray is fewer, and correspondence image regional exposure is strong, using the one side away from electrode as X-axis, using electrode bottom as Y-axis,
Using the intersection point of X-axis and Y-axis as origin；Processing step is as follows：
Step 1 carries out gray proces to forming image, and the stronger area grayscale numerical value of exposure is higher；
Step 2, the color gray value for each point that adds up and the product of point to electrode surface distance obtain assay value, and assay value is got over
Minute bubbles are smaller to electrode surface and the influence of the contact of liquid.
Preparing hydrogen, generating power module, it is characterised in that：Including anti-mixing arrangement（LXQ）, the first container（L1）, second container
（L2）, filling opening, filling valve（F3）, first electrode（DJ1）, second electrode（DJ2）, first pipe（GD1）, second pipe
（GD2）, the first air pump（B1）, the second air pump（B2）, the first check valve（DF1）, the second check valve（DF2）, the first gas tank
（Q1）, the second gas tank（Q2）, first entrance air valve（F1）, second entrance air valve（F2）, the first pressure maintaining valve（W1）, the second voltage stabilizing
Valve（W2）, hydrogen fuel cell（BAT1）, the 3rd pipeline（GD3）, the 4th pipeline（GD4）, circulating valve（F4）, degasification container
（YLG）；
The anti-mixing arrangement of preparing hydrogen, generating power module includes housing (LXQ), spiral tube chamber（LXG）, the first tube chamber（ZG1）,
Two tube chambers（ZG1）；Spiral tube chamber（LXG）For helical form, spiral tube chamber（LXG）It has a first end and a second end；First tube chamber
（ZG1）Axis direction and spiral tube chamber（LXG）Axis of screw direction it is identical, the first tube chamber（ZG1）Positioned at spiral tube chamber
（LXG）Helix within, the first tube chamber（ZG1）Length be more than spiral tube chamber（LXG）Two endpoints where and spiral
Tube chamber（LXG）The distance in the vertical face of axis；First tube chamber（ZG1）With connecting pin and openend（JK1）；First tube chamber
（ZG1）Connecting pin and spiral tube chamber（LXG）First end communicate；First tube chamber（ZG1）It is through entire spiral tube chamber（LXG）
Section, and the first tube chamber（ZG1）Openend（JK1）Beyond spiral tube chamber（LXG）Second end；Second tube chamber（ZG2）Axis
Direction and spiral tube chamber（LXG）Axis of screw direction it is identical, the second tube chamber（ZG2）Positioned at spiral tube chamber（LXG）Helix
Within, the second tube chamber（ZG1）Length be more than spiral tube chamber（LXG）Two endpoints where with spiral tube chamber（LXG）Axis
The distance in vertical face；Second tube chamber（ZG2）With connecting pin and openend（JK1）；Second tube chamber（ZG2）Connecting pin with
Spiral tube chamber（LXG）Second end communicate；Second tube chamber（ZG2）It is through entire spiral tube chamber（LXG）Section, and the second tube chamber
（ZG2）Openend（JK1）Beyond spiral tube chamber（LXG）First end.
In preparing hydrogen, generating power module：The first container（L1）Bottom and anti-mixing arrangement（LXQ）One end communicate, second container
（L2）Bottom and anti-mixing arrangement（LXQ）The other end communicate；That is the first container（L1）Bottom, second hold
Device（L2）Bottom pass through anti-mixing arrangement（LXQ）It communicates；
In preparing hydrogen, generating power module：First electrode（DJ1）Device is in the first container（L1）Cavity volume in, first electrode（DJ1）
The lowermost horizontal level be higher than the first container（L1）With anti-mixing arrangement（LXQ）Communicate the horizontal level of interface；
In preparing hydrogen, generating power module：Second electrode（DJ2）Device is in second container（L2）Cavity volume in, second electrode（DJ2）
The lowermost horizontal level be higher than second container（L2）With anti-mixing arrangement（LXQ）Communicate the horizontal level of interface；When first
Container（L1）, second container（L2）Cell reaction can be terminated when draught head is too big during electrolysis since liquid departs from electrode；
In preparing hydrogen, generating power module：The first container（L1）Top pass through first pipe（GD1）Via the first air pump（B1）,
One check valve（DF1）With the first gas tank（Q1）It communicates, the first air pump（B1）By the first container（L1）Interior gas-powered is to first
Gas tank（Q1）It is interior, the first check valve（DF1）Allow the first container（L1）Interior gas flow to the first gas tank（Q1）, first is single
To valve（DF1）The first gas tank is not allowed（Q1）It flow to the first container（L1）It is interior；
In preparing hydrogen, generating power module：Second container（L2）Top pass through second pipe（GD2）Via the second air pump（B2）,
Two check valves（DF2）With the second gas tank（Q2）It communicates, the second air pump（B2）By second container（L2）Interior gas-powered is to second
Gas tank（Q2）It is interior, the second check valve（DF2）Allow second container（L2）Interior gas flow to the second gas tank（Q2）, second is single
To valve（DF2）The second gas tank is not allowed（Q2）It flow to second container（L2）It is interior；
In preparing hydrogen, generating power module：First gas tank（Q1）With hydrogen fuel cell（BAT1）An inlet channel be connected, first
Gas tank（Q1）With hydrogen fuel cell（BAT1）Communication path on have the first pressure maintaining valve（W1）, the first pressure maintaining valve（W1）Allow
Fluid is from the first gas tank（Q1）Flow to hydrogen fuel cell（BAT1）, the first pressure maintaining valve（W1）Fluid is not allowed from hydrogen fuel cell
（BAT1）Flow to the first gas tank（Q1）, the first pressure maintaining valve（W1）The first gas tank can be controlled（Q1）The hydrogen fuel cell connected
（BAT1）An inlet channel air pressure；
In preparing hydrogen, generating power module：Second gas tank（Q2）With hydrogen fuel cell（BAT1）An inlet channel be connected, second
Gas tank（Q2）With hydrogen fuel cell（BAT1）Communication path on have the second pressure maintaining valve（W2）, the second pressure maintaining valve（W2）Allow
Fluid is from the second gas tank（Q2）Flow to hydrogen fuel cell（BAT1）, the second pressure maintaining valve（W2）Fluid is not allowed from hydrogen fuel cell
（BAT1）Flow to the second gas tank（Q2）, the second pressure maintaining valve（W2）The second gas tank can be controlled（Q2）The hydrogen fuel cell connected
（BAT1）An inlet channel air pressure；
In preparing hydrogen, generating power module：3rd pipeline（GD3）Upper end and hydrogen fuel cell（BAT1）Discharge outlet communicate, the 3rd
Pipeline（GD3）Lower end and degasification container（YLG）Cavity volume communicate；4th pipeline（GD4）Upper end and degasification container（YLG）
Cavity volume communicate, the 4th pipeline（GD4）Lower end via circulating valve（F4）With the first container（L1）It communicates so that hydrogen fuel electricity
Pond（BAT1）Product water can back flow back into the first container（L1）, second container（L2）In the electrolysis cavity volume of composition, cycling makes
With；3rd pipeline（GD3）Lower ending opening horizontal level be less than the 4th pipeline（GD4）Upper end opening horizontal level, can
To prevent gas from entering the first container（L1）, second container（L2）In the electrolysis cavity volume of composition；
In preparing hydrogen, generating power module：Also there is supersonic generator（C1）, supersonic generator（C1）Positioned at degasification container
（YLG）It is internal；Also there is exhaust outlet, degasification container（YLG）Pass through the 5th pipeline（GD5）It is communicated with gas vent, the 5th pipeline
（GD5）Fluid path in also have the 5th pump（B5）, air bleeding valve（F5）；By controlling degasification container（YLG）When degasification operates
In supersonic generator（C1）While open air bleeding valve（F5）And open the 5th pump（B5）Reduce degasification container（YLG）Gas
Pressure, so that hydrogen fuel cell（BAT1）Product water in dissolve gas abjection, supersonic generator（C1）While degassing
Reduce degasification container（YLG）Air pressure the design hardware cost that deaerate it is very low and effect is fine；
In preparing hydrogen, generating power module：Hydrogen fuel cell（BAT1）With power supply output point（VCC1）, power supply place（GND1）；
Preparing hydrogen, generating power module is connected with the control module of control system as electrical energy storage device, preparing hydrogen, generating power module and journey
Power supply connected devices are controlled, situation about powering off suddenly can be tackled.
2nd, the solid liquid interface electrode process automatic analysis system based on image procossing as described in technology contents 1, feature
It is：Equalizing reservoir（10）It is made using glass.
3rd, the solid liquid interface electrode process automatic analysis system based on image procossing as described in technology contents 1, feature
It is：The first container of electrolysis unit（11）It is made using glass.
4th, the solid liquid interface electrode process automatic analysis system based on image procossing as described in technology contents 1, feature
It is：
The second container of electrolysis unit（12）It is made using glass.
5th, the solid liquid interface electrode process automatic analysis system based on image procossing as described in technology contents 1, feature
It is：
The first emptying valve of electrolysis unit（F1）For solenoid valve.
6th, the solid liquid interface electrode process automatic analysis system based on image procossing as described in technology contents 1, feature
It is：The scale of electrolysis unit（2）Scale be made of metal.
7th, the solid liquid interface electrode process automatic analysis system based on image procossing as described in technology contents 1, feature
It is：The tapping valve of electrolysis unit（F3）For solenoid valve.
8th, the solid liquid interface electrode process automatic analysis system based on image procossing as described in technology contents 1, feature
It is：Control system includes a computer for being equipped with windows systems.
9th, the solid liquid interface electrode process automatic analysis system based on image procossing as described in technology contents 1, feature
It is：Control system includes a microcontroller.
10th, the solid liquid interface electrode process automatic analysis system based on image procossing as described in technology contents 9, feature
It is：The microcontroller is C51 microcontrollers.
Technology contents illustrate and its advantage.
The present invention is of low cost, using it is flexible, service life is long, be hardly damaged, reliable and stable, analysis is fast and reliable..
Description of the drawings
Fig. 1,2,3 are the schematic diagram of the electrolysis unit of embodiment 1；Fig. 1 is top view, Fig. 2 for radiation or
The light or ray that the side view equipment 3 of the equipment 3 of ray emits pass through equalizing reservoir（10）, the first container（11）, second hold
Device（12）In at least one container be used for camera 4 imaging；Fig. 3 is that the lateral view of embodiment 1 wherein depicts control
System, this is to intuitively embody connection relation.
Fig. 4 is the schematic diagram of the operating process of embodiment 1.
Fig. 5, the 6 abstract representations schematic diagrames explained for the auxiliary ' electrode analysis algorithm ' of embodiment 1.
Fig. 7 is the schematic diagram of the preparing hydrogen, generating power module of embodiment 1.
Fig. 8 is the schematic diagram of the electrolysis unit of embodiment 4.
Example is embodied
Below in conjunction with embodiment, the present invention will be described.
Embodiment 1, as shown in figs. 1-7 the solid liquid interface electrode process automatic analysis system based on image procossing, it is special
Sign is：Including electrolysis unit, control system, preparing hydrogen, generating power module, photographic device；
Electrolysis unit includes：Equalizing reservoir（10）, the first container（11）, second container（12）, the first evacuated tube（110）、
Second evacuated tube（120）, first emptying valve（F1）, second emptying valve（F2）, first electrode（DJ1）, second electrode（DJ2）；
In electrolysis unit:Equalizing reservoir（10）For column, equalizing reservoir（10）Upper end opening；
In electrolysis unit:The first container（11）For column, the first container（11）Upper end and the first evacuated tube（110）Phase
It is logical；
In electrolysis unit:Second container（12）For column, second container（12）Upper end and the second evacuated tube（120）Phase
It is logical；
In electrolysis unit:Equalizing reservoir（10）, the first container（11）, second container（12）Bottom communicates；Electrolysis unit
In:First emptying valve（F1）Positioned at the first evacuated tube（110）Pipeline on, first emptying valve（F1）The first emptying can be controlled
Pipe（110）Break-make situation；
In electrolysis unit:Second emptying valve（F2）Positioned at the second evacuated tube（120）Pipeline on, second emptying valve（F2）
The second evacuated tube can be controlled（120）Break-make situation；
In electrolysis unit:First electrode（DJ1）Positioned at the first container（11）It is interior；Second electrode（DJ2）Positioned at second container
（12）It is interior.
Electrolysis unit further includes liquid feed valve（F4）, liquid feed valve（F4）；Liquid feed valve（F4）Positioned at inlet tube（14）Pipeline on,
Inlet tube（14）Interior liquid can be flowed into equalizing reservoir（10）In.
Electrolysis unit further includes tapping valve（F3）；Tapping valve（F3）Installation at one end with equalizing reservoir（10）Communicate one end with
On the pipeline that outside communicates, tapping valve（F3）For drained liquid, tapping valve（F3）Liquid equal height less than the first container（11）
Cavity volume the top.
Electrolysis unit further includes scale（2）；Scale（2）Scale extension direction and second container（12）Axial direction phase
Together.
Control system includes control module, programmable power supply, and control module mutually directly has with programmable power supply to be electrically connected, and is controlled
Molding block can control programmable power supply；Have between photographic device and control system and be electrically connected, photographic device can be to control
Module transfer image data, the camera lens of photographic device are shot for the first container（11）, second container（12）Radial direction, camera shooting
Device can shoot the first container（11）Interior image.
The control module and first emptying valve of control system（F1）Between have be electrically connected, the control module of control system
First emptying valve can be controlled（F1）；The control module and second emptying valve of control system（F2）Between have be electrically connected, control
The control module of system processed can control second emptying valve（F2）.
The control module of control system also with tapping valve（F3）Between have be electrically connected, the control module energy of control system
Enough control tapping valve（F3）；The control module and liquid feed valve of control system（F4）Between have be electrically connected, the control of control system
Molding block can control liquid feed valve（F4）.
Control system has used autocontrol method；Autocontrol method is characterized in that：Comprise the following steps,
Step 1, inaccessible drain valve（F3）
Step 2 opens first emptying valve（F1）And second emptying valve（F2）；
Step 3 opens liquid feed valve（F4）Liquid to be electrolysed is made to flow into equalizing reservoir（10）;
Step 4 judges first emptying valve（F1）Or second emptying valve（F2）Whether overflowing liquid, if overflow if into step
Rapid 5, Xun Huan reenters this step if not overflowing；
Step 5, inaccessible first emptying valve（F1）And second emptying valve（F2）；
Step 6 extracts current information from the information bank of stored current data, and current information is strong including but not limited to electric current
Degree, waveform, cycle, most long energization period；
Step 7 starts image identification function；
Step 8, the current data gone according to step 6 tune control programmable power supply output current；
Step 9 judges whether to reach maximum energization period, and 11 are entered step if maximum energization period is reached, if
It is not reaching to maximum energization period and then enters step 10；
Step 10 reads gas column height by image identification function, and judges whether gas column height is more than warning value, if
Gas column height then enters step 11 more than warning value, and 9 are entered step if gas column height is not above warning value；
Step 11 makes programmable power supply stop electric current output；
Step 12 judges gas column height by image identification function, and preserves gas column height value.
Step 13 terminates.
There is electroanalysis method, electroanalysis method is based on control module and is filled from camera shooting in the control module of control system
It puts the image of acquisition and is analyzed, photographic device is imaged using laser or X-ray, and bladdery region liquid is to laser in image
Or the absorption of X-ray is fewer, and correspondence image regional exposure is strong, using the one side away from electrode as X-axis, using electrode bottom as Y-axis,
Using the intersection point of X-axis and Y-axis as origin；Processing step is as follows：
Step 1 carries out gray proces to forming image, and the stronger area grayscale numerical value of exposure is higher；
Step 2, the color gray value for each point that adds up and the product of point to electrode surface distance obtain assay value, and assay value is got over
Minute bubbles are smaller to electrode surface and the influence of the contact of liquid.
Preparing hydrogen, generating power module, it is characterised in that：Including anti-mixing arrangement（LXQ）, the first container（L1）, second container
（L2）, filling opening, filling valve（F3）, first electrode（DJ1）, second electrode（DJ2）, first pipe（GD1）, second pipe
（GD2）, the first air pump（B1）, the second air pump（B2）, the first check valve（DF1）, the second check valve（DF2）, the first gas tank（Q1）、
Second gas tank（Q2）, first entrance air valve（F1）, second entrance air valve（F2）, the first pressure maintaining valve（W1）, the second pressure maintaining valve（W2）、
Hydrogen fuel cell（BAT1）, the 3rd pipeline（GD3）, the 4th pipeline（GD4）, circulating valve（F4）, degasification container（YLG）；
The anti-mixing arrangement of preparing hydrogen, generating power module includes housing (LXQ), spiral tube chamber（LXG）, the first tube chamber（ZG1）,
Two tube chambers（ZG1）；Spiral tube chamber（LXG）For helical form, spiral tube chamber（LXG）It has a first end and a second end；First tube chamber
（ZG1）Axis direction and spiral tube chamber（LXG）Axis of screw direction it is identical, the first tube chamber（ZG1）Positioned at spiral tube chamber
（LXG）Helix within, the first tube chamber（ZG1）Length be more than spiral tube chamber（LXG）Two endpoints where and spiral
Tube chamber（LXG）The distance in the vertical face of axis；First tube chamber（ZG1）With connecting pin and openend（JK1）；First tube chamber
（ZG1）Connecting pin and spiral tube chamber（LXG）First end communicate；First tube chamber（ZG1）It is through entire spiral tube chamber（LXG）
Section, and the first tube chamber（ZG1）Openend（JK1）Beyond spiral tube chamber（LXG）Second end；Second tube chamber（ZG2）Axis
Direction and spiral tube chamber（LXG）Axis of screw direction it is identical, the second tube chamber（ZG2）Positioned at spiral tube chamber（LXG）Helix
Within, the second tube chamber（ZG1）Length be more than spiral tube chamber（LXG）Two endpoints where with spiral tube chamber（LXG）Axis
The distance in vertical face；Second tube chamber（ZG2）With connecting pin and openend（JK1）；Second tube chamber（ZG2）Connecting pin with
Spiral tube chamber（LXG）Second end communicate；Second tube chamber（ZG2）It is through entire spiral tube chamber（LXG）Section, and the second tube chamber
（ZG2）Openend（JK1）Beyond spiral tube chamber（LXG）First end.
In preparing hydrogen, generating power module：The first container（L1）Bottom and anti-mixing arrangement（LXQ）One end communicate, second container
（L2）Bottom and anti-mixing arrangement（LXQ）The other end communicate；That is the first container（L1）Bottom, second hold
Device（L2）Bottom pass through anti-mixing arrangement（LXQ）It communicates；
In preparing hydrogen, generating power module：First electrode（DJ1）Device is in the first container（L1）Cavity volume in, first electrode（DJ1）
The lowermost horizontal level be higher than the first container（L1）With anti-mixing arrangement（LXQ）Communicate the horizontal level of interface；
In preparing hydrogen, generating power module：Second electrode（DJ2）Device is in second container（L2）Cavity volume in, second electrode（DJ2）
The lowermost horizontal level be higher than second container（L2）With anti-mixing arrangement（LXQ）Communicate the horizontal level of interface；When first
Container（L1）, second container（L2）Cell reaction can be terminated when draught head is too big during electrolysis since liquid departs from electrode；
In preparing hydrogen, generating power module：The first container（L1）Top pass through first pipe（GD1）Via the first air pump（B1）,
One check valve（DF1）With the first gas tank（Q1）It communicates, the first air pump（B1）By the first container（L1）Interior gas-powered is to first
Gas tank（Q1）It is interior, the first check valve（DF1）Allow the first container（L1）Interior gas flow to the first gas tank（Q1）, first is single
To valve（DF1）The first gas tank is not allowed（Q1）It flow to the first container（L1）It is interior；
In preparing hydrogen, generating power module：Second container（L2）Top pass through second pipe（GD2）Via the second air pump（B2）,
Two check valves（DF2）With the second gas tank（Q2）It communicates, the second air pump（B2）By second container（L2）Interior gas-powered is to second
Gas tank（Q2）It is interior, the second check valve（DF2）Allow second container（L2）Interior gas flow to the second gas tank（Q2）, second is single
To valve（DF2）The second gas tank is not allowed（Q2）It flow to second container（L2）It is interior；
In preparing hydrogen, generating power module：First gas tank（Q1）With hydrogen fuel cell（BAT1）An inlet channel be connected, first
Gas tank（Q1）With hydrogen fuel cell（BAT1）Communication path on have the first pressure maintaining valve（W1）, the first pressure maintaining valve（W1）Allow
Fluid is from the first gas tank（Q1）Flow to hydrogen fuel cell（BAT1）, the first pressure maintaining valve（W1）Fluid is not allowed from hydrogen fuel cell
（BAT1）Flow to the first gas tank（Q1）, the first pressure maintaining valve（W1）The first gas tank can be controlled（Q1）The hydrogen fuel cell connected
（BAT1）An inlet channel air pressure；
In preparing hydrogen, generating power module：Second gas tank（Q2）With hydrogen fuel cell（BAT1）An inlet channel be connected, second
Gas tank（Q2）With hydrogen fuel cell（BAT1）Communication path on have the second pressure maintaining valve（W2）, the second pressure maintaining valve（W2）Allow
Fluid is from the second gas tank（Q2）Flow to hydrogen fuel cell（BAT1）, the second pressure maintaining valve（W2）Fluid is not allowed from hydrogen fuel cell
（BAT1）Flow to the second gas tank（Q2）, the second pressure maintaining valve（W2）The second gas tank can be controlled（Q2）The hydrogen fuel cell connected
（BAT1）An inlet channel air pressure；
In preparing hydrogen, generating power module：3rd pipeline（GD3）Upper end and hydrogen fuel cell（BAT1）Discharge outlet communicate, the 3rd
Pipeline（GD3）Lower end and degasification container（YLG）Cavity volume communicate；4th pipeline（GD4）Upper end and degasification container（YLG）
Cavity volume communicate, the 4th pipeline（GD4）Lower end via circulating valve（F4）With the first container（L1）It communicates so that hydrogen fuel electricity
Pond（BAT1）Product water can back flow back into the first container（L1）, second container（L2）In the electrolysis cavity volume of composition, cycling makes
With；3rd pipeline（GD3）Lower ending opening horizontal level be less than the 4th pipeline（GD4）Upper end opening horizontal level, can
To prevent gas from entering the first container（L1）, second container（L2）In the electrolysis cavity volume of composition；
In preparing hydrogen, generating power module：Also there is supersonic generator（C1）, supersonic generator（C1）Positioned at degasification container
（YLG）It is internal；Also there is exhaust outlet, degasification container（YLG）Pass through the 5th pipeline（GD5）It is communicated with gas vent, the 5th pipeline
（GD5）Fluid path in also have the 5th pump（B5）, air bleeding valve（F5）；By controlling degasification container（YLG）When degasification operates
In supersonic generator（C1）While open air bleeding valve（F5）And open the 5th pump（B5）Reduce degasification container（YLG）Gas
Pressure, so that hydrogen fuel cell（BAT1）Product water in dissolve gas abjection, supersonic generator（C1）While degassing
Reduce degasification container（YLG）Air pressure the design hardware cost that deaerate it is very low and effect is fine；
In preparing hydrogen, generating power module：Hydrogen fuel cell（BAT1）With power supply output point（VCC1）, power supply place（GND1）；
Preparing hydrogen, generating power module is connected with the control module of control system as electrical energy storage device, preparing hydrogen, generating power module and journey
Power supply connected devices are controlled, situation about powering off suddenly can be tackled.
Embodiment 2, modification control system based on embodiment 1 control module in there is electroanalysis method；Electricity
Solution analysis method is analyzed based on control module from the image that photographic device obtains, photographic device using laser or X-ray into
Picture, bladdery region liquid is fewer to the absorption of laser or X-ray in image, and correspondence image regional exposure is strong, with away from electricity
The one side of pole is X-axis, using electrode bottom as Y-axis, using the intersection point of X-axis and Y-axis as origin；Processing step is as follows：
Step 1 carries out image gray proces, and the stronger area grayscale numerical value of exposure is higher, and minimum value is more than zero, maximum
For Z；
Step 2, the gray scale of point each to image carry out computing S=S%Z；
The product of step 3, the color gray value of cumulative each point and Y-coordinate value obtains assay value, and assay value gets over air pocket pair
Electrode surface and the influence of the contact of liquid are smaller.
Embodiment 3, modification control system based on embodiment 1 control module in there is electroanalysis method；Electricity
Solution analysis method is analyzed based on control module from the image that photographic device obtains, photographic device using laser or X-ray into
Picture, bladdery region liquid is fewer to the absorption of laser or X-ray in image, and correspondence image regional exposure is strong, with close to electricity
The one side of pole is X-axis, using electrode bottom as Y-axis, using the intersection point of X-axis and Y-axis as origin；Processing step is as follows：
Step 1 carries out gray proces to forming image, and the stronger area grayscale numerical value of exposure is higher, and minimum value is more than zero, most
Big value is Z；
Step 2, the gray scale S of point each to image carry out computing S=S%Z；
Step 3, the color gray value for each point that adds up and the product of point to electrode surface distance obtain assay value, and assay value is got over
Air pocket is smaller to electrode surface and the influence of the contact of liquid.
Increase anti-mixing arrangement on the basis of embodiment 4, embodiment 1 for electrolysis unit, anti-mixing arrangement includes shell
Body (LXQ), spiral tube chamber（LXG）, the first tube chamber（ZG1）, the second tube chamber（ZG2）, spiral tube chamber（LXG）For helical form, spiral
Tube chamber（LXG）It has a first end and a second end, the first tube chamber（ZG1）Axis direction and spiral tube chamber（LXG）The axis of screw
Direction is identical, the first tube chamber（ZG1）Positioned at spiral tube chamber（LXG）Helix within, the first tube chamber（ZG1）Length be more than spiral shell
Coil chamber（LXG）Two endpoints where with spiral tube chamber（LXG）The distance in the vertical face of axis, the first tube chamber（ZG1）Tool
There are connecting pin and openend（JK1）, the first tube chamber（ZG1）Connecting pin and spiral tube chamber（LXG）First end communicate, first pipe
Chamber（ZG1）It is through entire spiral tube chamber（LXG）Section, and the first tube chamber（ZG1）Openend（JK1）Beyond spiral tube chamber（LXG）
Second end, the second tube chamber（ZG2）Axis direction and spiral tube chamber（LXG）Axis of screw direction it is identical, the second tube chamber
（ZG1）Positioned at spiral tube chamber（LXG）Helix within, the second tube chamber（ZG2）Length be more than spiral tube chamber（LXG）Two
Where endpoint with spiral tube chamber（LXG）The distance in the vertical face of axis, the second tube chamber（ZG2）With connecting pin and openend
（JK1）, the second tube chamber（ZG2）Connecting pin and spiral tube chamber（LXG）Second end communicate, the second tube chamber（ZG2）It is through entire
Spiral tube chamber（LXG）Section, and the second tube chamber（ZG2）Openend（JK1）Beyond spiral tube chamber（LXG）First end；Electrolysis dress
The first end of anti-mixing arrangement put is communicated with the first container of electrolysis unit；The second end of the anti-mixing arrangement of electrolysis unit
It is communicated with the second container of electrolysis unit.
In hydrogen fuel cell on the basis of embodiment 5, embodiment 1（BAT1）With power supply output point（VCC1）, electricity
Source place（GND1）Between connect a filter capacitor, filter capacitor one end power supply output point（VCC1）The other end and power supply place
（GND1）It is connected.
The control module of control system further includes CUDA processing hardware on the basis of embodiment 6, embodiment 1.
The unknown place of this explanation is the prior art or common knowledge, therefore is not repeated.
Claims (1)
1. the solid liquid interface electrode process automatic analysis system based on image procossing, it is characterised in that：Including electrolysis unit, control
System, preparing hydrogen, generating power module, photographic device；
Electrolysis unit includes：Equalizing reservoir（10）, the first container, second container（12）, the first evacuated tube（110）, second emptying
Pipe（120）, first emptying valve, second emptying valve, first electrode, second electrode；
In electrolysis unit:Equalizing reservoir（10）For column, equalizing reservoir（10）Upper end opening；
In electrolysis unit:The first container is column, the upper end of the first container and the first evacuated tube（110）It communicates；
In electrolysis unit:Second container（12）For column, second container（12）Upper end and the second evacuated tube（120）It communicates；
In electrolysis unit:Equalizing reservoir（10）, the first container, second container（12）Bottom communicates；
In electrolysis unit:First emptying valve is located at the first evacuated tube（110）Pipeline on, first emptying valve can control first row
Blank pipe（110）Break-make situation；
In electrolysis unit:Second emptying valve is located at the second evacuated tube（120）Pipeline on, second emptying valve can control second row
Blank pipe（120）Break-make situation；
In electrolysis unit:First electrode is located in the first container；Second electrode is located at second container（12）It is interior；
Electrolysis unit further includes liquid feed valve；Liquid feed valve is located at inlet tube（14）Pipeline on, inlet tube（14）Interior liquid can
It is flowed into equalizing reservoir（10）In；
Electrolysis unit further includes tapping valve（F3）；Tapping valve（F3）Installation at one end with equalizing reservoir（10）Communicate one end and outside
On the pipeline communicated, tapping valve（F3）For drained liquid, tapping valve（F3）Liquid put down cavity volume of the height less than the first container
Topmost；
Electrolysis unit further includes scale（2）；Scale（2）Scale extension direction and second container（12）Axial direction it is identical；
Control system includes control module, programmable power supply, and control module mutually directly has with programmable power supply to be electrically connected, and controls mould
Block can control programmable power supply；Have between photographic device and control system and be electrically connected, photographic device can be to control module
Image data is transmitted, the camera lens of photographic device is shot for the first container, second container（12）Radial direction, photographic device can
Shoot the image in the first container；
Have between the control module and first emptying valve of control system and be electrically connected, the control module of control system can control
First emptying valve；Have between the control module and second emptying valve of control system and be electrically connected, the control module of control system
Second emptying valve can be controlled；
The control module of control system also with tapping valve（F3）Between have be electrically connected, the control module of control system can be controlled
Tapping valve processed（F3）；Have between the control module and liquid feed valve of control system and be electrically connected, the control module energy of control system
Enough control liquid feed valve；
Control system has used autocontrol method；Autocontrol method is characterized in that：Comprise the following steps,
Step 1, inaccessible tapping valve（F3）;
Step 2 opens first emptying valve and second emptying valve；
Step 3 opens liquid feed valve liquid to be electrolysed is made to flow into equalizing reservoir（10）;
Step 4, judge first emptying valve or second emptying valve whether overflowing liquid, 5 are entered step if overflowing, if inexcessive
Go out, Xun Huan reenters this step；
Step 5, inaccessible first emptying valve and second emptying valve；
Step 6 extracts current information from the information bank of stored current data, and current information includes current strength, waveform, week
Phase, most long energization period；
Step 7 starts image identification function；
Step 8, the current data transferred according to step 6 control programmable power supply output current；
Step 9 judges whether to reach maximum energization period, 11 is entered step if maximum energization period is reached, if do not had
Reach maximum energization period and then enter step 10；
Step 10 reads gas column height by image identification function, and judges whether gas column height is more than warning value, if air column
11 are then highly entered step more than warning value, 9 are entered step if gas column height is not above warning value；
Step 11 makes programmable power supply stop electric current output；
Step 12 judges gas column height by image identification function, and preserves gas column height value；
Step 13 terminates；
There is electroanalysis method, electroanalysis method is obtained based on control module from photographic device in the control module of control system
Image and analyzed, photographic device is imaged using laser or X-ray, and bladdery region liquid is to laser or X in image
The absorption of light is fewer, and correspondence image regional exposure is strong, using the one side away from electrode as X-axis, using electrode bottom as Y-axis, with X
Axis and the intersection point of Y-axis are origin；Processing step is as follows：
Step 1 carries out gray proces to forming image, and the stronger area grayscale numerical value of exposure is higher；
Step 2, the color gray value for each point that adds up and the product of point to electrode surface distance obtain assay value, and assay value is more stingy
Bubble is smaller to electrode surface and the influence of the contact of liquid；
Preparing hydrogen, generating power module, including anti-mixing arrangement, the first container, second container, filling opening, filling valve, first electrode, second
Electrode, first pipe, second pipe, the first air pump, the second air pump, the first check valve, the second check valve, the first gas tank, second
Gas tank, first entrance air valve, second entrance air valve, the first pressure maintaining valve, the second pressure maintaining valve, hydrogen fuel cell, the 3rd pipeline, the 4th
Pipeline, circulating valve, degasification container；
The anti-mixing arrangement of preparing hydrogen, generating power module includes housing, spiral tube chamber, the first tube chamber, the second tube chamber；Spiral tube chamber is spiral shell
Shape is revolved, spiral tube chamber has a first end and a second end；The axis of screw direction phase of the axis direction of first tube chamber and spiral tube chamber
Together, the first tube chamber is located within the helix of spiral tube chamber, and the length of the first tube chamber is more than where two endpoints of spiral tube chamber
The face vertical with helix tube cavity axis distance；First tube chamber has connecting pin and openend；The connecting pin of first tube chamber with
The first end of spiral tube chamber communicates；First tube chamber is through entire spiral tube chamber section, and the openend of the first tube chamber exceeds helix tube
The second end of chamber；The axis direction of second tube chamber is identical with the axis of screw direction of spiral tube chamber, and the second tube chamber is located at helix tube
Within the helix of chamber, the length of the second tube chamber is vertical with helix tube cavity axis where more than two endpoints of spiral tube chamber
The distance in face；Second tube chamber has connecting pin and openend；The connecting pin of second tube chamber is communicated with the second end of spiral tube chamber；The
Two tube chambers are through entire spiral tube chamber section, and the openend of the second tube chamber exceeds the first end of spiral tube chamber；
In preparing hydrogen, generating power module：The bottom of the first container is communicated with one end of anti-mixing arrangement, and the bottom of second container is with preventing
The other end of mixing arrangement communicates；That is the bottom of the first container, the bottom of second container pass through anti-mixing arrangement
It communicates；
In preparing hydrogen, generating power module：First electrode device is in the cavity volume of the first container, the lowermost horizontal level of first electrode
The horizontal level of interface is communicated with anti-mixing arrangement higher than the first container；
In preparing hydrogen, generating power module：Second electrode device is in the cavity volume of second container, the lowermost horizontal level of second electrode
The horizontal level of interface is communicated with anti-mixing arrangement higher than second container；When the first container, second container electrolysis when draught head too
Cell reaction can be terminated when big since liquid departs from electrode；
In preparing hydrogen, generating power module：The top of the first container is by first pipe via the first air pump, the first check valve and the first gas
Tank communicates, and by the gas-powered in the first container to the first gas tank, the first check valve allows in the first container the first air pump
Gas flow to the first gas tank, and the first check valve does not allow the first gas tank to flow in the first container；
In preparing hydrogen, generating power module：The top of second container is by second pipe via the second air pump, the second check valve and the second gas
Tank communicates, and by the gas-powered in second container to the second gas tank, the second check valve allows in second container the second air pump
Gas flow to the second gas tank, and the second check valve does not allow the second gas tank to flow in second container；
In preparing hydrogen, generating power module：First gas tank is connected with an inlet channel of hydrogen fuel cell, the first gas tank and hydrogen fuel electricity
There is the first pressure maintaining valve on the communication path in pond, the first pressure maintaining valve allows fluid to flow to hydrogen fuel cell from the first gas tank, and first
Pressure maintaining valve does not allow fluid to flow to the first gas tank from hydrogen fuel cell, and the first pressure maintaining valve can control the hydrogen that the first gas tank is connected
The air pressure of one inlet channel of fuel cell；
In preparing hydrogen, generating power module：Second gas tank is connected with an inlet channel of hydrogen fuel cell, the second gas tank and hydrogen fuel electricity
There is the second pressure maintaining valve on the communication path in pond, the second pressure maintaining valve allows fluid to flow to hydrogen fuel cell from the second gas tank, and second
Pressure maintaining valve does not allow fluid to flow to the second gas tank from hydrogen fuel cell, and the second pressure maintaining valve can control the hydrogen that the second gas tank is connected
The air pressure of one inlet channel of fuel cell；
In preparing hydrogen, generating power module：The upper end of 3rd pipeline is communicated with the discharge outlet of hydrogen fuel cell, and the lower end of the 3rd pipeline is with removing
The cavity volume of gas container communicates；The upper end of 4th pipeline is communicated with the cavity volume of degasification container, and the lower end of the 4th pipeline is via circulating valve
It is communicated with the first container so that the electrolysis that the product water of hydrogen fuel cell can back flow back into the first container, second container is formed
In cavity volume, recycle；The horizontal level of the lower ending opening of 3rd pipeline is less than the horizontal level of the upper end opening of the 4th pipeline,
It can prevent gas from entering in the first container, the electrolysis cavity volume that second container is formed；
In preparing hydrogen, generating power module：Also there is supersonic generator, supersonic generator is located inside degasification container；Also there is exhaust
Mouthful, degasification container is communicated by the 5th pipeline with gas vent, also has the 5th pump, air bleeding valve in the fluid path of the 5th pipeline；
Air bleeding valve is opened while supersonic generator and the 5th pump of opening reduces degasification when being operated by controlling the degasification of degasification container
The air pressure of container so that the gas abjection dissolved in the product water of hydrogen fuel cell, supersonic generator reduce while degassing
The design of the air pressure of degasification container so that degassing hardware cost is very low and effect is fine;
In preparing hydrogen, generating power module：Hydrogen fuel cell has power supply output point, power supply place；
Preparing hydrogen, generating power module is connected with the control module of control system as electrical energy storage device, preparing hydrogen, generating power module and program-controlled electric
Source connected devices can tackle situation about powering off suddenly；Equalizing reservoir is made using glass；The first container of electrolysis unit uses
Glass is made.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610590487.2A CN106283106B (en) | 2016-07-26 | 2016-07-26 | Image processing-based automatic analysis system for solid-liquid interface electrode process |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610590487.2A CN106283106B (en) | 2016-07-26 | 2016-07-26 | Image processing-based automatic analysis system for solid-liquid interface electrode process |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN106283106A CN106283106A (en) | 2017-01-04 |
| CN106283106B true CN106283106B (en) | 2018-05-25 |
Family
ID=57652189
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610590487.2A Active CN106283106B (en) | 2016-07-26 | 2016-07-26 | Image processing-based automatic analysis system for solid-liquid interface electrode process |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106283106B (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109886188B (en) * | 2019-02-19 | 2021-02-19 | 武汉理工大学 | Image processing-based PEMFC cathode runner water visualization processing method |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105790387A (en) * | 2016-05-16 | 2016-07-20 | 江苏师范大学 | Hydrogen production power generation module, circulating battery and bidirectional inverter for electric energy storage |
-
2016
- 2016-07-26 CN CN201610590487.2A patent/CN106283106B/en active Active
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105790387A (en) * | 2016-05-16 | 2016-07-20 | 江苏师范大学 | Hydrogen production power generation module, circulating battery and bidirectional inverter for electric energy storage |
Non-Patent Citations (2)
| Title |
|---|
| Sensing of the dynamic concentration field at the solid/liquid interface using a Mach-Zehnder interferometer;BoYo yuan等;《Sensors and Actuators B:Chemical》;20121202;第176卷;第510页，图1 * |
| 基于全息技术的金属电化学腐蚀过程在线检测方法研究;袁博宇;《中国博士学位论文全文数据库》;20151225(第12期);第16-27页 * |
Also Published As
| Publication number | Publication date |
|---|---|
| CN106283106A (en) | 2017-01-04 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN106654464B (en) | A kind of aluminium-air cell electrolyte circulation system based on hydraulic cyclone effect | |
| CN106283106B (en) | Image processing-based automatic analysis system for solid-liquid interface electrode process | |
| CN109449544A (en) | A kind of aluminum air battery system and control method | |
| US11584666B2 (en) | Apparatus for manufacturing hydrogen-containing water | |
| CN106011913B (en) | Electrolysis unit comprising tapping valve, solid liquid interface electrode process analysis system | |
| CN106048643B (en) | Electrolysis process analysis system of electrolysis unit, novel battery electrode with scale and feed liquor valve | |
| CN106222695B (en) | Electrolysis device with drain valve and liquid inlet valve and automatic analysis system for electrolysis process | |
| CN106191904B (en) | Electrolysis unit with scale and tapping valve and liquid feed valve, battery electrode performance intelligent analysis system | |
| CN106283107B (en) | Full-automatic system for analyzing solid-liquid interface electrode process | |
| CN106226242A (en) | The electrode process with special pattern processing method analyzes system | |
| CN106020065B (en) | Solid-liquid interface electrode process analysis system and graph processing method thereof | |
| CN106198684A (en) | The electrode process comprising CUDA processing unit analyzes system | |
| CN106198685A (en) | The solid liquid interface electrode process with scale based on CUDA technology analyzes system | |
| CN106198686A (en) | Solid liquid interface electrode process automatic analysis system based on CUDA technology | |
| CN106248530A (en) | The solid liquid interface electrode process with special pattern processing method analyzes system | |
| CN106200470A (en) | Solid liquid interface electrode process based on X-ray imaging and CUDA technology analyzes system | |
| CN106198687A (en) | The solid liquid interface electrode process with laser imaging and CUDA technology analyzes system | |
| CN106226380A (en) | There is the electrolysis unit of scale, electrolytic process automatic analysis system based on X-ray imaging | |
| CN209274157U (en) | A kind of cooling device of gravure ink | |
| CN106248529A (en) | There is the electrolysis unit of liquid feed valve, electrode analysis system based on X-ray imaging | |
| CN208776496U (en) | A kind of hydrogen-rich heavy-oxygen-enriched water manufacturing machine | |
| CN106248531A (en) | There is the electrolysis unit of threeway container, electrode analysis system based on laser imaging | |
| CN205355201U (en) | Alkaline electrolysis fluid recovery unit | |
| CN215338489U (en) | Condensate fine treatment resin interface detection device | |
| CN204582571U (en) | The parallel evaporation and concentration instrument of full-automatic or semi-automatic vacuum nitrogen |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| CB03 | Change of inventor or designer information | ||
| CB03 | Change of inventor or designer information |
Inventor after: Zhao Xinsheng Inventor after: Nie Xinming Inventor after: Tian Yaping Inventor after: Yuan Boyu Inventor after: Wang Chao Inventor after: Li Liang Inventor before: Yuan Boyu Inventor before: Wang Chao Inventor before: Li Liang Inventor before: Nie Xinming Inventor before: Tian Yaping Inventor before: Zhao Xinsheng |
|
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20190815 Address after: 221000 No. 88 Liaohe West Road, Pizhou Economic Development Zone, Xuzhou City, Jiangsu Province Patentee after: SU Normal University Semiconductor Materials and Equipment Research Institute (Pizhou) Co., Ltd. Address before: 221116 Shanghai Road, Copper Mt. District, Jiangsu, No. 101, No. Patentee before: Jiangsu Normal University |
|
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20220519 Address after: 221300 506, block B, electronic industrial park, Pizhou Economic Development Zone, Xuzhou City, Jiangsu Province Patentee after: Xuzhou Bochuang Construction Development Group Co.,Ltd. Address before: 221000 No.88, Liaohe West Road, Pizhou Economic Development Zone, Xuzhou City, Jiangsu Province Patentee before: SU Normal University Semiconductor Materials and Equipment Research Institute (Pizhou) Co.,Ltd. |