CN106222695B - Electrolysis device with drain valve and liquid inlet valve and automatic analysis system for electrolysis process - Google Patents
Electrolysis device with drain valve and liquid inlet valve and automatic analysis system for electrolysis process Download PDFInfo
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- CN106222695B CN106222695B CN201610590492.3A CN201610590492A CN106222695B CN 106222695 B CN106222695 B CN 106222695B CN 201610590492 A CN201610590492 A CN 201610590492A CN 106222695 B CN106222695 B CN 106222695B
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- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B15/00—Operating or servicing cells
- C25B15/02—Process control or regulation
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B1/00—Electrolytic production of inorganic compounds or non-metals
- C25B1/01—Products
- C25B1/02—Hydrogen or oxygen
- C25B1/04—Hydrogen or oxygen by electrolysis of water
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- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B9/00—Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
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- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N27/00—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means
- G01N27/26—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating electrochemical variables; by using electrolysis or electrophoresis
- G01N27/416—Systems
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- G—PHYSICS
- G06—COMPUTING; CALCULATING OR COUNTING
- G06T—IMAGE DATA PROCESSING OR GENERATION, IN GENERAL
- G06T2207/00—Indexing scheme for image analysis or image enhancement
- G06T2207/10—Image acquisition modality
- G06T2207/10116—X-ray image
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/36—Hydrogen production from non-carbon containing sources, e.g. by water electrolysis
Abstract
The electrolysis device with a drain valve and a liquid inlet valve comprises a balance container, a first container, a second container, a first emptying pipe (110), a second emptying pipe, a first emptying valve, a second emptying valve, a first electrode and a second electrode; the electrolysis device also comprises a liquid inlet valve and a liquid inlet valve; the liquid inlet valve is positioned on the pipeline of the liquid inlet pipe, and liquid in the liquid inlet pipe can flow into the balance container; the liquid discharge valve is arranged on a pipeline, one end of the pipeline is communicated with the balance container, the other end of the pipeline is communicated with the outside, the liquid discharge valve is used for discharging liquid, and the liquid level of the liquid discharge valve is lower than the uppermost end of the cavity of the first container. The invention has the advantages of low cost, flexible application, long service life, difficult damage, stability, reliability and quick and reliable analysis.
Description
Technical field
The invention belongs to electricity field, and in particular to have the electrolysis unit of tapping valve and liquid feed valve.
Background technology
During the liquid electrolytic of solid state electrode, the rising of the bubble near electrode surface, merge, easily have influence on
Contact of the electrode surface with liquid, influences the motion of liquid intermediate ion, causes the contact area of electrode surface and liquid to reduce and leads
The generation of solution efficiency bottle neck is sent a telegraph, scientific research personnel studies this process and is advantageous to break through electrolytic efficiency bottleneck.
During the liquid electrolytic of solid state electrode, the merging and explosion of the bubble near electrode surface, easily in office
Portion's high temperature and powerful impulsive force, cause solid state electrode to be corroded, and influence the life-span of electrode, scientific research personnel, which studies this process, to be had
The electrolysis electrode more long-lived beneficial to relatively existing electrolysis electrode is researched and developed.
Scientific research personnel is on the surface that analysis solid state electrode electrolyte is electrode（That is solid liquid interface）State when exist it is all
It is more inconvenient；If there is a kind of system that can be realized and automatical analysis is carried out to electrode process, then scientific research personnel can be improved
To the efficiency of research and development of electrolysis electrode.
The content of the invention
To solve the problems, such as to describe in technical background, the present invention proposes the solid liquid interface electrode process based on image procossing
Automatic analysis system, present system can realize the automatical analysis of electrode process, improve scientific research efficiency.
The present invention has following technology contents.
1st, there is the electrolysis unit of tapping valve and liquid feed valve, it is characterised in that：Including equalizing reservoir（10）, the first container
（11）, second container（12）, the first evacuated tube（110）, the second evacuated tube（120）, first emptying valve（F1）, second emptying valve
（F2）, first electrode（DJ1）, second electrode（DJ2）；
Equalizing reservoir（10）For column, equalizing reservoir（10）Upper end open；
First container（11）For column, the first container（11）Upper end and the first evacuated tube（110）Communicate；
Second container（12）For column, second container（12）Upper end and the second evacuated tube（120）Communicate；
Equalizing reservoir（10）, the first container（11）, second container（12）Bottom communicates；In electrolysis unit:First emptying valve
（F1）Positioned at the first evacuated tube（110）Pipeline on, first emptying valve（F1）The first evacuated tube can be controlled（110）Break-make
Situation；
Second emptying valve（F2）Positioned at the second evacuated tube（120）Pipeline on, second emptying valve（F2）Second can be controlled
Evacuated tube（120）Break-make situation；
First electrode（DJ1）Positioned at the first container（11）It is interior；Second electrode（DJ2）Positioned at second container（12）It is interior;
Electrolysis unit also includes liquid feed valve（F4）, liquid feed valve（F4）；Liquid feed valve（F4）Positioned at feed tube（14）Pipeline on,
Feed tube（14）Interior liquid can be flowed into equalizing reservoir（10）In;
Electrolysis unit also includes tapping valve（F3）；Tapping valve（F3）Installation at one end with equalizing reservoir（10）Communicate one end with
On the pipeline that outside communicates, tapping valve（F3）For drained liquid, tapping valve（F3）The flat height of liquid be less than the first container（11）
Cavity volume the top.
2nd, the electrolysis unit with tapping valve and liquid feed valve as described in technology contents 1, it is characterised in that：Equalizing reservoir
（10）It is made using glass.
3rd, the electrolysis unit with tapping valve and liquid feed valve as described in technology contents 1, it is characterised in that：Electrolysis unit
First container（11）It is made using glass.
4th, the electrolysis unit with tapping valve and liquid feed valve as described in technology contents 1, it is characterised in that：Electrolysis unit
Second container（12）It is made using glass.
5th, the electrolysis unit with tapping valve and liquid feed valve as described in technology contents 1, it is characterised in that：Electrolysis unit
First emptying valve（F1）For magnetic valve.
6th, the electrolysis unit with tapping valve and liquid feed valve as described in technology contents 1, it is characterised in that：Electrolysis unit
Liquid feed valve（F4）For magnetic valve.
7th, electrolytic process automatic analysis system, it is characterised in that：With as described in technology contents 1 with tapping valve and entering
The electrolysis unit of liquid valve.
Technology contents illustrate and its advantage.
Cost of the present invention is cheap, using it is flexible, service life is long, be hardly damaged, reliable and stable, analysis is fast and reliable..
Brief description of the drawings
Fig. 1,2,3 are the schematic diagram of the electrolysis unit of embodiment 1；Fig. 1 for top view, Fig. 2 be ray or
The light or ray that the side view equipment 3 of the equipment 3 of ray is launched pass through equalizing reservoir（10）, the first container（11）, second hold
Device（12）In at least one container be used for camera 4 imaging；Fig. 3 is that the lateral view of embodiment 1 wherein depicts control
System, this is to intuitively embody annexation.
Fig. 4 is the schematic diagram of the operating process of embodiment 1.
Fig. 5, the 6 abstract representations schematic diagrames explained for the auxiliary ' electrode analysis algorithm ' of embodiment 1.
Fig. 7 is the schematic diagram of the preparing hydrogen, generating power module of embodiment 1.
Fig. 8 is the schematic diagram of the electrolysis unit of embodiment 4.
Example is embodied
Below in conjunction with embodiment, the present invention will be described.
Embodiment 1, as shown in figs. 1-7 the solid liquid interface electrode process automatic analysis system based on image procossing, it is special
Sign is：Including electrolysis unit, control system, preparing hydrogen, generating power module, camera device；
Electrolysis unit includes：Equalizing reservoir（10）, the first container（11）, second container（12）, the first evacuated tube（110）、
Second evacuated tube（120）, first emptying valve（F1）, second emptying valve（F2）, first electrode（DJ1）, second electrode（DJ2）；
In electrolysis unit:Equalizing reservoir（10）For column, equalizing reservoir（10）Upper end open；
In electrolysis unit:First container（11）For column, the first container（11）Upper end and the first evacuated tube（110）Phase
It is logical；
In electrolysis unit:Second container（12）For column, second container（12）Upper end and the second evacuated tube（120）Phase
It is logical；
In electrolysis unit:Equalizing reservoir（10）, the first container（11）, second container（12）Bottom communicates；Electrolysis unit
In:First emptying valve（F1）Positioned at the first evacuated tube（110）Pipeline on, first emptying valve（F1）The first evacuated tube can be controlled
（110）Break-make situation；
In electrolysis unit:Second emptying valve（F2）Positioned at the second evacuated tube（120）Pipeline on, second emptying valve（F2）
The second evacuated tube can be controlled（120）Break-make situation；
In electrolysis unit:First electrode（DJ1）Positioned at the first container（11）It is interior；Second electrode（DJ2）Positioned at second container
（12）It is interior.
Electrolysis unit also includes liquid feed valve（F4）, liquid feed valve（F4）；Liquid feed valve（F4）Positioned at feed tube（14）Pipeline on,
Feed tube（14）Interior liquid can be flowed into equalizing reservoir（10）In.
Electrolysis unit also includes tapping valve（F3）；Tapping valve（F3）Installation at one end with equalizing reservoir（10）Communicate one end with
On the pipeline that outside communicates, tapping valve（F3）For drained liquid, tapping valve（F3）The flat height of liquid be less than the first container（11）
Cavity volume the top.
Electrolysis unit also includes scale（2）；Scale（2）Yardstick extension direction and second container（12）Axial direction phase
Together.
Control system includes control module, programmable power supply, and control module mutually directly has with programmable power supply to be electrically connected, and is controlled
Molding block can control programmable power supply；Have between camera device and control system and be electrically connected, camera device can be to control
Module transfer image data, the lens shooting of camera device is the first container（11）, second container（12）Radial direction, take the photograph
As device can shoot the first container（11）Interior image.
The control module and first emptying valve of control system（F1）Between have be electrically connected, the control module of control system
First emptying valve can be controlled（F1）；The control module and second emptying valve of control system（F2）Between have be electrically connected, control
The control module of system processed can control second emptying valve（F2）.
The control module of control system also with tapping valve（F3）Between have be electrically connected, the control module energy of control system
Enough control tapping valve（F3）；The control module and liquid feed valve of control system（F4）Between have be electrically connected, the control of control system
Molding block can control liquid feed valve（F4）.
Control system has used autocontrol method；Autocontrol method, it is characterised by：Comprise the following steps,
Step 1, inaccessible draining valve（F3）
Step 2, open first emptying valve（F1）And second emptying valve（F2）；
Step 3, open liquid feed valve（F4）Liquid to be electrolysed is set to flow into equalizing reservoir（10）;
Step 4, judge first emptying valve（F1）Or second emptying valve（F2）Whether overflowing liquid, if overflow if enter step
Rapid 5, circulated if not overflowing and reenter this step；
Step 5, inaccessible first emptying valve（F1）And second emptying valve（F2）；
Step 6, current information is extracted from the information bank of stored current data, current information is strong including but not limited to electric current
Degree, waveform, cycle, most long energization period；
Step 7, start image identification function；
Step 8, the current data control programmable power supply output current gone is adjusted according to step 6；
Step 9, judge whether to reach maximum energization period, step 11 is entered if maximum energization period is reached, if
It is not reaching to maximum energization period and then enters step 10；
Step 10, gas column height read by image identification function, and judge whether gas column height exceedes warning value, if
Gas column height then enters step 11 more than warning value, and step 9 is entered if gas column height is not above warning value；
Step 11, programmable power supply is set to stop electric current output；
Step 12, gas column height is judged by image identification function, and preserve gas column height value.
Step 13, terminate.
There is electroanalysis method, electroanalysis method is based on control module and filled from shooting in the control module of control system
Put the image of acquisition and analyzed, camera device is imaged using laser or X-ray, and alveolate region liquid is to swashing in image
The absorption of light or X light is fewer, and correspondence image regional exposure is strong, using the side away from electrode as X-axis, using electrode bottom as Y
Axle, using X axles and the intersection point of Y-axis as origin；Processing step is as follows：
Step 1, gray proces are carried out to forming image, the stronger area grayscale numerical value of exposure is higher；
Step 2, the color gray value for each point that adds up obtain assay value with the product put to electrode surface distance, and assay value is got over
Minute bubbles are smaller to electrode surface and the influence of the contact of liquid.
Preparing hydrogen, generating power module, it is characterised in that：Including anti-mixing arrangement（LXQ）, the first container（L1）, second container
（L2）, filling opening, filling valve（F3）, first electrode（DJ1）, second electrode（DJ2）, the first pipeline（GD1）, second pipe
（GD2）, the first air pump（B1）, the second air pump（B2）, the first check valve（DF1）, the second check valve（DF2）, the first gas tank（Q1）、
Second gas tank（Q2）, first entrance air valve（F1）, second entrance air valve（F2）, the first pressure maintaining valve（W1）, the second pressure maintaining valve（W2）、
Hydrogen fuel cell（BAT1）, the 3rd pipeline（GD3）, the 4th pipeline（GD4）, circulating valve（F4）, degasification container（YLG）；
The anti-mixing arrangement of preparing hydrogen, generating power module includes housing (LXQ), spiral tube chamber（LXG）, the first tube chamber（ZG1）,
Two tube chambers（ZG2）；Spiral tube chamber（LXG）For helical form, spiral tube chamber（LXG）With first end and the second end；First tube chamber
（ZG1）Axis direction and spiral tube chamber（LXG）Axis of screw direction it is identical, the first tube chamber（ZG1）Positioned at spiral tube chamber
（LXG）Helix within, the first tube chamber（ZG1）Length be more than spiral tube chamber（LXG）Two end points where and spiral
Tube chamber（LXG）The distance in the vertical face of axis；First tube chamber（ZG1）With connection end and openend（JK1）；First tube chamber
（ZG1）Connection end and spiral tube chamber（LXG）First end communicate；First tube chamber（ZG1）It is through whole spiral tube chamber（LXG）
Section, and the first tube chamber（ZG1）Openend（JK1）Beyond spiral tube chamber（LXG）The second end；Second tube chamber（ZG2）Axis
Direction and spiral tube chamber（LXG）Axis of screw direction it is identical, the second tube chamber（ZG2）Positioned at spiral tube chamber（LXG）Helix
Within, the second tube chamber（ZG2）Length be more than spiral tube chamber（LXG）Two end points where with spiral tube chamber（LXG）Axis
The distance in vertical face；Second tube chamber（ZG2）With connection end and openend（JK1）；Second tube chamber（ZG2）Connection end and spiral shell
Coil chamber（LXG）The second end communicate；Second tube chamber（ZG2）It is through whole spiral tube chamber（LXG）Section, and the second tube chamber（ZG2）
Openend（JK1）Beyond spiral tube chamber（LXG）First end.
In preparing hydrogen, generating power module：First container（L1）Bottom and anti-mixing arrangement（LXQ）One end communicate, second container
（L2）Bottom and anti-mixing arrangement（LXQ）The other end communicate；That is the first container（L1）Bottom, second hold
Device（L2）Bottom pass through anti-mixing arrangement（LXQ）Communicate；
In preparing hydrogen, generating power module：First electrode（DJ1）Device is in the first container（L1）Cavity volume in, first electrode（DJ1）
The horizontal level of bottom be higher than the first container（L1）With anti-mixing arrangement（LXQ）Communicate the horizontal level of interface；
In preparing hydrogen, generating power module：Second electrode（DJ2）Device is in second container（L2）Cavity volume in, second electrode（DJ2）
The horizontal level of bottom be higher than second container（L2）With anti-mixing arrangement（LXQ）Communicate the horizontal level of interface；When first
Container（L1）, second container（L2）Cell reaction can be terminated when draught head is too big during electrolysis because liquid departs from electrode；
In preparing hydrogen, generating power module：First container（L1）Top pass through the first pipeline（GD1）Via the first air pump（B1）,
One check valve（DF1）With the first gas tank（Q1）Communicate, the first air pump（B1）By the first container（L1）Interior gas-powered is to first
Gas tank（Q1）It is interior, the first check valve（DF1）Allow the first container（L1）Interior gas flow to the first gas tank（Q1）, first is unidirectional
Valve（DF1）The first gas tank is not allowed（Q1）It flow to the first container（L1）It is interior；
In preparing hydrogen, generating power module：Second container（L2）Top pass through second pipe（GD2）Via the second air pump（B2）,
Two check valves（DF2）With the second gas tank（Q2）Communicate, the second air pump（B2）By second container（L2）Interior gas-powered is to second
Gas tank（Q2）It is interior, the second check valve（DF2）Allow second container（L2）Interior gas flow to the second gas tank（Q2）, second is unidirectional
Valve（DF2）The second gas tank is not allowed（Q2）It flow to second container（L2）It is interior；
In preparing hydrogen, generating power module：First gas tank（Q1）With hydrogen fuel cell（BAT1）An inlet channel be connected, first
Gas tank（Q1）With hydrogen fuel cell（BAT1）Communication path on there is the first pressure maintaining valve（W1）, the first pressure maintaining valve（W1）Allow
Fluid is from the first gas tank（Q1）Flow to hydrogen fuel cell（BAT1）, the first pressure maintaining valve（W1）Fluid is not allowed from hydrogen fuel cell
（BAT1）Flow to the first gas tank（Q1）, the first pressure maintaining valve（W1）The first gas tank can be controlled（Q1）The hydrogen fuel cell connected
（BAT1）An inlet channel air pressure；
In preparing hydrogen, generating power module：Second gas tank（Q2）With hydrogen fuel cell（BAT1）An inlet channel be connected, second
Gas tank（Q2）With hydrogen fuel cell（BAT1）Communication path on there is the second pressure maintaining valve（W2）, the second pressure maintaining valve（W2）Allow
Fluid is from the second gas tank（Q2）Flow to hydrogen fuel cell（BAT1）, the second pressure maintaining valve（W2）Fluid is not allowed from hydrogen fuel cell
（BAT1）Flow to the second gas tank（Q2）, the second pressure maintaining valve（W2）The second gas tank can be controlled（Q2）The hydrogen fuel cell connected
（BAT1）An inlet channel air pressure；
In preparing hydrogen, generating power module：3rd pipeline（GD3）Upper end and hydrogen fuel cell（BAT1）Discharge outlet communicate, the 3rd
Pipeline（GD3）Lower end and degasification container（YLG）Cavity volume communicate；4th pipeline（GD4）Upper end and degasification container（YLG）
Cavity volume communicate, the 4th pipeline（GD4）Lower end via circulating valve（F4）With the first container（L1）Communicate so that hydrogen fuel cell
（BAT1）Product water can back flow back into the first container（L1）, second container（L2）In the electrolysis cavity volume of composition, recycle；
3rd pipeline（GD3）The horizontal level of lower ending opening be less than the 4th pipeline（GD4）Upper end open horizontal level, can be to prevent
Only gas enters the first container（L1）, second container（L2）In the electrolysis cavity volume of composition；
In preparing hydrogen, generating power module：Also there is supersonic generator（C1）, supersonic generator（C1）Positioned at degasification container
（YLG）It is internal；Also there is exhaust outlet, degasification container（YLG）Pass through the 5th pipeline（GD5）Communicated with steam vent, the 5th pipeline
（GD5）Fluid path in also there is the 5th pump（B5）, air bleeding valve（F5）；By controlling degasification container（YLG）When degasification operates
In supersonic generator（C1）While open air bleeding valve（F5）And open the 5th pump（B5）Reduce degasification container（YLG）Gas
Pressure, so that hydrogen fuel cell（BAT1）Product water in dissolve gas abjection, supersonic generator（C1）While degassing
Reduce degasification container（YLG）Air pressure the design hardware cost that to deaerate it is very low and effect is fine；
In preparing hydrogen, generating power module：Hydrogen fuel cell（BAT1）With power supply output point（VCC1）, power supply place（GND1）；
Preparing hydrogen, generating power module is connected with the control module of control system is used as electrical energy storage device, preparing hydrogen, generating power module and journey
Power supply connected devices are controlled, situation about powering off suddenly can be tackled.
Embodiment 2, modification control system based on embodiment 1 control module in there is electroanalysis method；Electricity
Solution analysis method is analyzed based on control module from the image that camera device obtains, camera device using laser or X-ray into
Picture, absorption of the alveolate region liquid to laser or X-ray is fewer in image, and correspondence image regional exposure is strong, with away from electricity
The side of pole is X-axis, using electrode bottom as Y-axis, using the intersection point of X-axis and Y-axis as origin；Processing step is as follows：
Step 1, gray proces are carried out to image, the stronger area grayscale numerical value of exposure is higher, and minimum value is more than zero, maximum
For Z；
Step 2, the gray scale of point each to image carry out computing S=S%Z；
The product of step 3, the color gray value of cumulative each point and Y-coordinate value obtains assay value, and assay value gets over air pocket pair
Electrode surface and the influence of the contact of liquid are smaller.
Embodiment 3, modification control system based on embodiment 1 control module in there is electroanalysis method；Electricity
Solution analysis method is analyzed based on control module from the image that camera device obtains, camera device using laser or X-ray into
Picture, absorption of the alveolate region liquid to laser or X-ray is fewer in image, and correspondence image regional exposure is strong, with close to electricity
The side of pole is X-axis, using electrode bottom as Y-axis, using the intersection point of X-axis and Y-axis as origin；Processing step is as follows：
Step 1, gray proces are carried out to forming image, the stronger area grayscale numerical value of exposure is higher, and minimum value is more than zero, most
Big value is Z；
Step 2, the gray scale S of point each to image carry out computing S=S%Z；
Step 3, the color gray value for each point that adds up obtain assay value with the product put to electrode surface distance, and assay value is got over
Air pocket is smaller to electrode surface and the influence of the contact of liquid.
Increase anti-mixing arrangement on the basis of embodiment 4, embodiment 1 for electrolysis unit, anti-mixing arrangement includes shell
Body (LXQ), spiral tube chamber（LXG）, the first tube chamber（ZG1）, the second tube chamber（ZG2）, spiral tube chamber（LXG）For helical form, spiral
Tube chamber（LXG）With first end and the second end, the first tube chamber（ZG1）Axis direction and spiral tube chamber（LXG）The axis of screw
Direction is identical, the first tube chamber（ZG1）Positioned at spiral tube chamber（LXG）Helix within, the first tube chamber（ZG1）Length be more than spiral shell
Coil chamber（LXG）Two end points where with spiral tube chamber（LXG）The distance in the vertical face of axis, the first tube chamber（ZG1）Tool
There are connection end and openend（JK1）, the first tube chamber（ZG1）Connection end and spiral tube chamber（LXG）First end communicate, first pipe
Chamber（ZG1）It is through whole spiral tube chamber（LXG）Section, and the first tube chamber（ZG1）Openend（JK1）Beyond spiral tube chamber（LXG）
The second end, the second tube chamber（ZG2）Axis direction and spiral tube chamber（LXG）Axis of screw direction it is identical, the second tube chamber
（ZG2）Positioned at spiral tube chamber（LXG）Helix within, the second tube chamber（ZG2）Length be more than spiral tube chamber（LXG）Two
Where end points with spiral tube chamber（LXG）The distance in the vertical face of axis, the second tube chamber（ZG2）With connection end and openend
（JK1）, the second tube chamber（ZG2）Connection end and spiral tube chamber（LXG）The second end communicate, the second tube chamber（ZG2）It is through whole
Spiral tube chamber（LXG）Section, and the second tube chamber（ZG2）Openend（JK1）Beyond spiral tube chamber（LXG）First end；Electrolysis dress
The first end for the anti-mixing arrangement put communicates with the first container of electrolysis unit；Second end of the anti-mixing arrangement of electrolysis unit
Communicated with the second container of electrolysis unit.
In hydrogen fuel cell on the basis of embodiment 5, embodiment 1（BAT1）With power supply output point（VCC1）, electricity
Source place（GND1）Between connect a filter capacitor, filter capacitor one end power supply output point（VCC1）The other end is with power supply
Point（GND1）It is connected.
The control module of control system also includes CUDA processing hardware on the basis of embodiment 6, embodiment 1.
The unknown place of this explanation is prior art or common knowledge, therefore is not repeated.
Claims (2)
1. the electrolysis unit with tapping valve and liquid feed valve, it is characterised in that：Including equalizing reservoir（10）, the first container（11）、
Second container（12）, the first evacuated tube（110）, the second evacuated tube（120）, first emptying valve（F1）, second emptying valve（F2）,
One electrode（DJ1）, second electrode（DJ2）；
Equalizing reservoir（10）For column, equalizing reservoir（10）Upper end open；
First container（11）For column, the first container（11）Upper end and the first evacuated tube（110）Communicate；
Second container（12）For column, second container（12）Upper end and the second evacuated tube（120）Communicate；
Equalizing reservoir（10）, the first container（11）, second container（12）Bottom communicates；In electrolysis unit:First emptying valve（F1）
Positioned at the first evacuated tube（110）Pipeline on, first emptying valve（F1）The first evacuated tube can be controlled（110）Break-make feelings
Condition；
Second emptying valve（F2）Positioned at the second evacuated tube（120）Pipeline on, second emptying valve（F2）The second emptying can be controlled
Pipe（120）Break-make situation；
First electrode（DJ1）Positioned at the first container（11）It is interior；Second electrode（DJ2）Positioned at second container（12）It is interior;
Electrolysis unit also includes liquid feed valve（F4）；Liquid feed valve（F4）Positioned at feed tube（14）Pipeline on, feed tube（14）Interior
Liquid can be flowed into equalizing reservoir（10）In;
Electrolysis unit also includes tapping valve（F3）；Tapping valve（F3）Installation at one end with equalizing reservoir（10）Communicate one end and outside
On the pipeline communicated, tapping valve（F3）For drained liquid, tapping valve（F3）The flat height of liquid be less than the first container（11）Appearance
The top of chamber.
2. electrolytic process automatic analysis system, it is characterised in that：With as claimed in claim 1 with tapping valve and liquid feed valve
Electrolysis unit.
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| CN201610590492.3A CN106222695B (en) | 2016-07-26 | 2016-07-26 | Electrolysis device with drain valve and liquid inlet valve and automatic analysis system for electrolysis process |
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| CN201610590492.3A CN106222695B (en) | 2016-07-26 | 2016-07-26 | Electrolysis device with drain valve and liquid inlet valve and automatic analysis system for electrolysis process |
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| CN106222695B true CN106222695B (en) | 2018-03-09 |
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