CN106282677A - One can anodic oxidation pack alloy - Google Patents

One can anodic oxidation pack alloy Download PDF

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Publication number
CN106282677A
CN106282677A CN201610856063.6A CN201610856063A CN106282677A CN 106282677 A CN106282677 A CN 106282677A CN 201610856063 A CN201610856063 A CN 201610856063A CN 106282677 A CN106282677 A CN 106282677A
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content
less
equal
anodic oxidation
pack alloy
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CN106282677B (en
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李新豪
陈苏坚
李升�
李旭涛
王永科
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Guangzhou Zhiyuan Alloy Product Co Ltd
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Guangzhou Zhiyuan Alloy Product Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C21/00Alloys based on aluminium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C1/00Making non-ferrous alloys
    • C22C1/02Making non-ferrous alloys by melting
    • C22C1/026Alloys based on aluminium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C1/00Making non-ferrous alloys
    • C22C1/06Making non-ferrous alloys with the use of special agents for refining or deoxidising
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C21/00Alloys based on aluminium
    • C22C21/10Alloys based on aluminium with zinc as the next major constituent

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Sealing Battery Cases Or Jackets (AREA)

Abstract

The invention discloses one can anodic oxidation pack alloy, its composition is, the content of silicon is less than or equal to 0.6%, the content of ferrum is 0.4% 1.2%, the content of copper is less than or equal to 1%, the content of manganese is less than or equal to 0.6%, the content of magnesium is less than or equal to 0.6%, the content of zinc is less than or equal to 0.6%, the content of lead is less than or equal to 0.1%, the content of stannum is less than or equal to 0.2%, and the content of cadmium is less than or equal to 0.01%, and the content of the most each composition is all for the ratio calculated according to weight.Present invention solves the technical problem that and be to overcome existing pack alloy to cannot be carried out anodised shortcoming, it is provided that one can anodic oxidation pack alloy.

Description

One can anodic oxidation pack alloy
Technical field
The present invention relates to field of aluminum alloys.Being specially one can anodic oxidation pack alloy.
Background technology
Aluminium alloy is the metal material being widely used in each field, in order to enable aluminum alloy to more corrosion-resistant and enable aluminum alloy to zero Part is painted, it will usually is put by aluminium alloy and carries out anodic oxidation in the electrolytic solution, thus forms layer oxide film on its surface, to protect Protect aluminium alloy and improve the hardness of aluminium alloy.But, conventional diecasting alloys such as alusil alloy, aluminium copper and almag are Cannot be carried out anode oxidation coloration.In pack alloy, it is generally the case that the most a height of 6%-12% of content of silicon, copper Content is the highest.And the silicon of high-load can make oxide-film graying, copper can make oxide-film blushing, and can destroy electrolyte matter Amount.The too high speckle that also can make to produce black on oxide-film of iron content in alloy.Therefore, existing pack alloy due to The reason of its composition cannot be carried out anodic oxidation.
Summary of the invention
Present invention solves the technical problem that and be to overcome existing pack alloy to cannot be carried out anodised shortcoming, carry Can anodic oxidation pack alloy for one.
The present invention can anodic oxidation pack alloy, the content of silicon be less than or equal to 0.6%, the content of ferrum is 0.8%-1.8%, the content of copper is less than or equal to 1%, and the content of manganese is 1.7%-3.3%, and the content of magnesium is less than or equal to 0.7%, the content of zinc is less than or equal to 3.5%, and the content of lead is less than or equal to 0.1%, and the content of stannum is less than or equal to 0.2%, the content of cadmium is less than or equal to 0.01%, and the content of the most each composition is all for the ratio calculated according to weight.
As preferably, the content of silicon is 0.5%-0.6%.
As preferably, the content of ferrum is 1.6%-1.8%.
As preferably, the content of copper is 0.6%-0.9%.
As preferably, the content of manganese is 2.5%-3.0%.
As preferably, the content of magnesium is 0.5%-0.7%.
As preferably, the content of zinc is 2.5%-2.9%.
The present invention can anodic oxidation pack alloy prior art compare, and has the advantages that
What the present invention provided can have good anodic oxidation effect by anodic oxidation pack alloy, the most also has good Corrosion resistance.Its liquidus temperature 656 DEG C, solid-state temperature is 651 DEG C.Under solid state shape, can anodic oxidation pack alloy Tensile strength be 150MPa, percentage elongation is 5%, and hardness is 54HB, and comprcssive strength is 340MPa, electrical conductivity 27%IACS, heat Conductivity 114W/m DEG C, processing characteristics and die casting characteristic are outstanding.This can carry out natural colour sun by anodic oxidation pack alloy Pole oxidation and hard anodizing, be highly suitable to be applied for the higher shell class of requirement of strength, structural member, decoration etc..
Detailed description of the invention
The present invention provide can anodic oxidation pack alloy, the content of silicon be less than or equal to 0.6%, the content of ferrum is 0.8%-1.8%, the content of copper is less than or equal to 1%, and the content of manganese is 1.7%-3.3%, and the content of magnesium is less than or equal to 0.7%, the content of zinc is less than or equal to 3.5%, and the content of lead is less than or equal to 0.1%, and the content of stannum is less than or equal to 0.2%, the content of cadmium is less than or equal to 0.01%, and the content of the most each composition is all for the ratio calculated according to weight.
In the first preferred version, the content of silicon is 0.5%-0.6%, and the content of ferrum is 1.6%-1.8%, containing of copper Amount can be 0.6%-0.9%, and the content of manganese is 2.5%-3.0%, and the content of magnesium is 0.5%-0.7%, and the content of zinc is 2.5%-2.9%, the content of lead is 0.04%-0.07%, and the content of stannum is 0.08%-0.15%, and the content of cadmium is 0.005- 0.008%.
In the second preferred version, the content of silicon is 0.3%-0.6%, and the content of ferrum is 0.9%-1.2%, containing of copper Amount is 0.5%-0.7%, and the content of manganese is 1.7%-2.0%, and the content of magnesium is 0.2%-0.3%, and the content of zinc is 3.0%- 3.4%, the content of lead is 0.02%-0.03%, and the content of stannum is 0.02%-0.03%, and the content of cadmium is 0.004%- 0.006%.
In the third preferred version, the content of silicon is 0.25%-0.38%, and the content of ferrum is 1.3%-1.5%, copper Content is 0.7%-0.95%, and the content of manganese is 3.0%-3.3%, and the content of magnesium is 0.4%-0.6%, and the content of zinc is 2.0%-2.4%, the content of lead is 0.06%-0.08%, and the content of stannum is 0.15%-0.18%, and the content of cadmium is 0.007%-0.009%.
In the 4th kind of preferred version, the content of silicon is 0.5%-0.58%, and the content of ferrum is 1.4%-1.7%, copper Content is 0.3%-0.4%, and the content of manganese is 2.1%-2.4%, and the content of magnesium is 0.25%-0.35%, the content of zinc 1.5%-1.9%, the content of lead is 0.02%-0.05%, and the content of stannum is 0.1%-0.15%, and the content of cadmium is 0.002%- 0.003%.
Through test of many times, what the present invention provided can have good anodic oxidation effect by anodic oxidation pack alloy, The most also there is good corrosion resistance.Its liquidus temperature 656 DEG C, solid-state temperature is 651 DEG C.Under solid state shape, can anode The tensile strength of oxidation pack alloy is 150MPa, and percentage elongation is 5%, and hardness is 54HB, and comprcssive strength is 340MPa, conductance Rate 27%IACS, pyroconductivity 114W/m DEG C, processing characteristics and die casting characteristic are outstanding.This can enter by anodic oxidation pack alloy Row natural colour anodic oxidation and hard anodizing, be highly suitable to be applied for the higher shell class of requirement of strength, structural member, Decoration etc..
Introduced below prepare the present invention can the method for anodic oxidation pack alloy, comprise the steps:
(1) composition carrying out proportioning, wherein, the content of silicon is less than or equal to 0.6%, and the content of ferrum is 0.8%- 1.8%, the content of copper is less than or equal to 1%, and the content of manganese is 1.7%-3.3%, and the content of magnesium is less than or equal to 0.7%, The content of zinc is less than or equal to 3.5%, and the content of lead is less than or equal to 0.1%, and the content of stannum is less than or equal to 0.2%, cadmium Content is less than or equal to 0.01%, and the content of the most each composition is all for the ratio calculated according to weight;
(2) clear up and the impurity that removes in smelting furnace, aluminium ingot put into smelting furnace fusing, molten metal be warming up to 880 DEG C- When 900 DEG C, put into chalybeate and manganese agent;
(3) molten metal is repeatedly stirred, stand after stirring every time;
(4) magnesium and zinc are put into molten metal fusing, and stir molten metal and make magnesium and zinc fully melt;
(5) add sodium-free refining agent when the temperature of alloy molten solution is at 780 DEG C-800 DEG C carry out refine and remove the gred;
(6) it is sufficiently stirred for rear sample examination;
(7) it is passed through nitrogen degasification to liquation;
(8) if the component content of chemical examination is in the range of setting, adding alterant in molten metal, alterant accounts for all The proportion of composition is 2.3%-2.7%, stirs and stands after adding alterant;
(9) casting, when casting, molten metal temperature is maintained at 780 DEG C-800 DEG C.
As preferably, in step (3), the time repeatedly stirred molten metal and stand is altogether no less than 60 points Clock.In step (7), lead to the time of nitrogen no less than 20 minutes to liquation.In step (8), alterant accounts for all the components Proportion is 2.3%-2.7%.In the present embodiment, the component content of the chemical examination described in step (8) refers to symbol in the range of setting Close the proportioning in step (1).
Above example is only the exemplary embodiment of the present invention, is not used in the restriction present invention, protection scope of the present invention It is defined by the claims.Those skilled in the art are in the essence and protection domain of the present invention, and that makes the present invention is various Amendment or equivalent are also within the scope of the present invention.

Claims (7)

1. one kind can anodic oxidation pack alloy, it is characterised in that: the content of silicon is less than or equal to 0.6%, the content of ferrum For 0.8%-1.8%, the content of copper is less than or equal to 1%, and the content of manganese is 1.7%-3.3%, the content of magnesium less than or etc. In 0.7%, the content of zinc is less than or equal to 3.5%, and the content of lead is less than or equal to 0.1%, and the content of stannum is less than or equal to 0.2%, the content of cadmium is less than or equal to 0.01%, and the content of the most each composition is all for the ratio calculated according to weight.
The most according to claim 1 can anodic oxidation pack alloy, it is characterised in that the content of silicon is 0.5%- 0.6%.
The most according to claim 1 can anodic oxidation pack alloy, it is characterised in that the content of ferrum is 1.6%- 1.8%.
The most according to claim 1 can anodic oxidation pack alloy, it is characterised in that the content of copper is 0.6%- 0.9%.
The most according to claim 1 can anodic oxidation pack alloy, it is characterised in that the content of manganese is 2.5%- 3.0%.
The most according to claim 1 can anodic oxidation pack alloy, it is characterised in that the content of magnesium is 0.5%- 0.7%.
The most according to claim 1 can anodic oxidation pack alloy, it is characterised in that the content of zinc is 2.5%- 2.9%.
CN201610856063.6A 2016-09-27 2016-09-27 One kind can anodic oxidation pack alloy Active CN106282677B (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109355532A (en) * 2018-10-25 2019-02-19 浙江日晟农林科技有限公司 One kind can anodic oxidation die-cast aluminum alloy material
CN110232233A (en) * 2019-06-03 2019-09-13 广州致远新材料科技有限公司 A kind of design method of die-cast aluminum alloy material

Citations (5)

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Publication number Priority date Publication date Assignee Title
JPS5356114A (en) * 1976-11-01 1978-05-22 Mitsubishi Metal Corp Bright corrosion resistant al alloy for die casting
CN104480353A (en) * 2014-12-12 2015-04-01 李树青 Formula of anodized pressure cast aluminum alloy
CN104775054A (en) * 2015-03-29 2015-07-15 深圳市欣茂鑫实业有限公司 Aluminum alloy product and preparation method thereof
CN105063431A (en) * 2015-07-31 2015-11-18 广东欧珀移动通信有限公司 Die-casting aluminum, structural part and electronic device
CN105316533A (en) * 2014-08-27 2016-02-10 深圳市欣茂鑫精密五金制品有限公司 Novel aluminum alloy

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5356114A (en) * 1976-11-01 1978-05-22 Mitsubishi Metal Corp Bright corrosion resistant al alloy for die casting
CN105316533A (en) * 2014-08-27 2016-02-10 深圳市欣茂鑫精密五金制品有限公司 Novel aluminum alloy
CN104480353A (en) * 2014-12-12 2015-04-01 李树青 Formula of anodized pressure cast aluminum alloy
CN104775054A (en) * 2015-03-29 2015-07-15 深圳市欣茂鑫实业有限公司 Aluminum alloy product and preparation method thereof
CN105063431A (en) * 2015-07-31 2015-11-18 广东欧珀移动通信有限公司 Die-casting aluminum, structural part and electronic device

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全国铸造协会 组编: "《压铸技术与生产》", 30 June 2008, 机械工业出版社 *

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109355532A (en) * 2018-10-25 2019-02-19 浙江日晟农林科技有限公司 One kind can anodic oxidation die-cast aluminum alloy material
CN110232233A (en) * 2019-06-03 2019-09-13 广州致远新材料科技有限公司 A kind of design method of die-cast aluminum alloy material

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