CN106281773B - A kind of transparent hand cleanser and preparation method thereof not adding polymeric rheology modifiers - Google Patents
A kind of transparent hand cleanser and preparation method thereof not adding polymeric rheology modifiers Download PDFInfo
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/94—Mixtures with anionic, cationic or non-ionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/044—Hydroxides or bases
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/046—Salts
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/33—Amino carboxylic acids
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/90—Betaines
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Abstract
The invention discloses the transparent hand cleanser and preparation method thereof that one kind does not add polymeric rheology modifiers.The transparent hand cleanser includes: A) accounting for the anionic surfactant of constituent content 2~15%；B the betaine type amphoteric ionic surface active agent of constituent content 2~8%) is accounted for；C the nonionic surfactant of component 0.5~5%) is accounted for；D the sodium hydroxide of component 0.1~5%) is accounted for；E the electrolyte of constituent content 0.1~5%) is accounted for；F the EDTA-2Na of component 0.05~1%) is accounted for；G the water of component 61.9~95.2%) is accounted for, each component is mass percent.The invention further relates to the processing methods for not adding polymeric rheology modifiers adjusting product low temperature rheologic behavior.Rheological property, product room temperature modest viscosity are adjusted through the invention, and use feeling when product low temperature is substantially improved in the good not muddy not jelly of low temperature flow.
Description
Technical field
The invention belongs to daily chemical products fields, and in particular to one kind does not add the transparent hand cleanser of polymeric rheology modifiers
And preparation method thereof.
Background technique
The thickening of liquid detergent customary thickeners prevents then with the rheological characteristic and state of rheology modifiers adjustment product
Product low temperature jelly.
Thickener is the hydrophilic substance that can increase system viscosity and keep its relative stability, is answered extensively in daily chemicals field
With.Common thickener is largely acrylate copolymer, and this kind of thickener passes through emulsion polymerization by various acrylic monomers
, it has excellent performance, significant effect.
Chinese patent CN1231565C discloses a kind of method that polyethers prepares thickener with (methyl) acrylic acid, the thickening
Agent can be used in liquid detergent.Chinese patent CN1259563 discloses a kind of detergent composition, and thickener used is propylene
Acid copolymer and polyol alkoxy ester.
Chinese patent CN103242974A discloses a kind of fruits and vegetables dish washing detergent that rheological characteristic is good, adds in detergent
Viscosity modifier: one or both of PPG-20 methyl glucose ether, PPG-10 methyl glucose ether, glycerol, propylene glycol with
On, to solve the problems, such as liquid detergent, viscosity is excessively high at low temperature.Chinese patent CN104531383A discloses a kind of liquid
Body detergent composition and the method for its rheological property is adjusted to solve liquid detergent rheology at 8 DEG C~40 DEG C various temperature
Performance.
Above-mentioned patent either thickens or improves rheological property, is all by additionally adding macromolecule polyalcohol or small point
Sub- solvent adjusts the rheological property of product.Part macromolecule polyalcohol transparency or poor solubility, are not suitable for transparent system.
In addition, above-mentioned patent is not directed to the scheme that product keeps good rheological characteristic at low temperature (≤5 DEG C).
Summary of the invention
The object of the present invention is to provide the transparent hand cleanser that one kind does not add polymeric rheology modifiers, use compounding skill
Art, it is ensured that the rheological property of transparent hand cleanser is not especially adding rheology modifiers additionally, and rheological characteristic uses item in given
Under part, simple and purposive variation compounding mode can reach.
Another object of the present invention is to provide a kind of above-mentioned transparent hand cleanser for not adding polymeric rheology modifiers
Preparation method.
The object of the invention to solve the technical problems adopts the following technical solutions to realize.It proposes according to the present invention
The transparent hand cleanser for not adding polymeric rheology modifiers, by percentage to the quality, include following each component:
A the anionic surfactant of constituent content 2~15%) is accounted for；
B the betaine type amphoteric ionic surface active agent of constituent content 2~8%) is accounted for；
C the nonionic surfactant of constituent content 0.5~5%) is accounted for.
D the sodium hydroxide of constituent content 0.1~5%) is accounted for；
E the electrolyte of constituent content 0.1~5%) is accounted for；
F the EDTA-2Na of constituent content 0.1%) is accounted for；
G the water of constituent content 61.9~95.2%) is accounted for.
Transparent hand cleanser of the invention, the anionic surfactant are selected from fatty alcohol-ether sodium sulfate, fatty alcohol ether sulphur
Sour ammonium, sodium alkyl benzene sulfonate, at least two or more mixture in sodium alkyl sulfate.
Transparent hand cleanser of the invention, the sodium alkyl benzene sulfonate be production when alkyl benzene sulphonate and sodium hydroxide it is direct in
With use.
Transparent hand cleanser of the invention, the betaine type amphoteric ionic surface active agent are selected from: lauramido sweet tea
Dish alkali, Cocoamidopropyl betaine, oleamide propyl betaine, alkyl dimethyl betaine at least one or two more than
Mixture.
Transparent hand cleanser of the invention, the nonionic surfactant are selected from coconut oil diethanol amine, palm-kernel oil two
At least one of ethanol amine, fatty acid alkanol amides or two or more mixtures.
Transparent hand cleanser of the invention, the electrolyte are selected from one of sodium chloride, potassium chloride.
Transparent hand cleanser of the invention, wherein the ratio of the ratio of various surfactants and surfactant and electrolyte
Example, need to compound in specific proportions and can be only achieved low temperature not jelly.
Transparent hand cleanser of the invention, also include the acceptable a small amount of moisturizer of transparent hand cleanser, preservative, fragrance,
Pigment.
Furthermore the present invention also provides a kind of preparation method of transparent hand cleanser for not adding polymeric rheology modifiers, include
Following steps:
1) suitable water is added in reactor tank, 0.1~5% sodium hydroxide is added, benzene sulfonamide is added after dissolution
Acid adjusts pH to 3.0~4.0；The feed ratio of alkyl benzene sulphonate and sodium hydroxide is 8~12:1.
2) sodium alkyl benzene sulfonate made from 2~8% steps 1) is added.
3) be added 3~12% remaining anionic surfactant, 2~8% betaine type amphoteric surfac-tant,
0.5~5% nonionic surfactant, 0.1% EDTA-2Na, is stirred well to and is completely dissolved；
4) preservative is added, required viscosity is adjusted to finally by 0.1~5% electrolyte, it is filling after mixing evenly
?.
This product is colorless transparent viscous liquid.
Through the above technical solutions, the invention has the following advantages that
1) by many experiments, it is surprisingly found that the rheological property of transparent hand cleanser can be by above-mentioned compounding mode by electricity
Matter is solved to change.The present invention is according in surfactant system, and electrolyte concentration is bell-like to the relation curve of viscosity, with electricity
The increase of matter concentration is solved, viscosity sharply increases, and after reaching a peak value, with the increase of electrolyte, viscosity sharply declines again.And
The peak value of electrolyte thickening is different again to different surfaces activating agent.
2) therefore, the present invention by select surfactant type and ratio when, cleverly by adjusting electrolyte
Dosage adjusts rheological property when system high/low temperature.Electrolyte dosage makes viscosity reach peak value at 15 DEG C~20 DEG C, works as temperature
When being raised and lowered, viscosity decline.It is bell-like that product viscosity varies with temperature curve.
3) rheological property is adjusted through the invention, product room temperature modest viscosity, the good not muddy not jelly of low temperature flow, greatly
Width promotes use feeling when product low temperature.
Specific embodiment
Following embodiment is intended to illustrate invention rather than limitation of the invention further.Unless stated otherwise, this hair
Bright all percentages are all calculated with the mass percentage of composition, and all proportions are mass percent.
Embodiment 1
A kind of transparent hand cleanser not adding polymeric rheology modifiers includes by percentage to the quality following each component:
Fatty alcohol-ether sodium sulfate: 4%；
Coconut oil diethanol amine: 1%；
Lauramido glycine betaine: 4%；
Alkyl benzene sulphonate: 2.5%；
Sodium hydroxide: 0.1~0.2%；
Sodium chloride: 1.0%；
EDTA-2Na:0.1%；
Preservative: 0.1%；
Water: 100% is added to；
The preparation method of the transparent hand cleanser of above-described embodiment, comprising the following steps:
1) suitable water is added in reactor tank, 0.1~2% sodium hydroxide is added, 2.5% alkyl is added after dissolution
Benzene sulfonic acid adjusts pH to 3.0~4.0；
2) 4% fatty alcohol-ether sodium sulfate is added, 4% lauramido glycine betaine is stirred well to and is completely dissolved；
3) 1% coconut oil diethanol amine is added, 0.1% EDTA-2Na is stirred well to and is completely dissolved；
4) 0.1% preservative is added, required viscosity is adjusted to finally by 1% electrolyte, is stirred evenly filling.
Embodiment 2
A kind of transparent hand cleanser not adding polymeric rheology modifiers includes by percentage to the quality following each component:
Fatty alcohol-ether sodium sulfate: 4.5%；
Coconut oil diethanol amine: 1%；
Lauramido glycine betaine: 4%；
Alkyl benzene sulphonate: 1.5%；
Sodium hydroxide: 0.1~0.2%；
Sodium chloride: 1.2%；
EDTA-2Na:0.1%；
Preservative: 0.1%；
Water: 100% is added to；
The preparation method of the transparent hand cleanser of above-described embodiment, comprising the following steps:
1) suitable water is added in reactor tank, 0.1~2% sodium hydroxide is added, 1.5% alkyl is added after dissolution
Benzene sulfonic acid adjusts pH to 3.0~4.0；
2) 4.5% fatty alcohol-ether sodium sulfate is added, 4% lauramido glycine betaine is stirred well to and is completely dissolved；
3) 1% coconut oil diethanol amine is added, 0.1% EDTA-2Na is stirred well to and is completely dissolved；
4) 0.1% preservative is added, required viscosity is adjusted to finally by 1.2% electrolyte, is stirred evenly filling.
Embodiment 3
A kind of transparent hand cleanser not adding polymeric rheology modifiers includes by percentage to the quality following each component:
Fatty alcohol-ether sodium sulfate: 4.5%；
Coconut oil diethanol amine: 1.5%；
Lauramido glycine betaine: 5%；
Alkyl benzene sulphonate: 2.0%；
Sodium hydroxide: 0.2~0.4%；
Sodium chloride: 1%；
EDTA-2Na:0.1%；
Preservative: 0.1%；
Water: 100% is added to；
The preparation method of the transparent hand cleanser of above-described embodiment, comprising the following steps:
1) suitable water is added in reactor tank, 0.2~0.4% sodium hydroxide is added, 2.0% alkane is added after dissolution
Base benzene sulfonic acid adjusts pH to 3.0~4.0；
2) 4.5% fatty alcohol-ether sodium sulfate is added, 5% lauramido glycine betaine is stirred well to and is completely dissolved；
3) 1.5% coconut oil diethanol amine is added, 0.1% EDTA-2Na is stirred well to and is completely dissolved；
4) 0.1% preservative is added, required viscosity is adjusted to finally by 1% electrolyte, is stirred evenly filling.
Embodiment 4
A kind of transparent hand cleanser not adding polymeric rheology modifiers includes by percentage to the quality following each component:
Fatty alcohol-ether sodium sulfate: 3.5%；
Coconut oil diethanol amine: 2%；
Lauramido glycine betaine: 4%；
Alkyl benzene sulphonate: 2.5%；
Sodium hydroxide: 0.2~0.4%；
Sodium chloride: 0.7%；
EDTA-2Na:0.1%；
Preservative: 0.1%；
Water: 100% is added to；
The preparation method of the transparent hand cleanser of above-described embodiment, comprising the following steps:
1) suitable water is added in reactor tank, 0.2~0.4% sodium hydroxide is added, 2.5% alkane is added after dissolution
Base benzene sulfonic acid adjusts pH to 3.0~4.0；
2) 3.5% fatty alcohol-ether sodium sulfate is added, 4% lauramido glycine betaine is stirred well to and is completely dissolved；
3) 1.5% coconut oil diethanol amine is added, 0.1% EDTA-2Na is stirred well to and is completely dissolved；
4) 0.1% preservative is added, required viscosity is adjusted to finally by 0.7% electrolyte, is stirred evenly filling.
Embodiment 5
A kind of transparent hand cleanser not adding polymeric rheology modifiers includes by percentage to the quality following each component:
Fatty alcohol-ether sodium sulfate: 5%；
Coconut oil diethanol amine: 1.5%；
Lauramido glycine betaine: 5%；
Alkyl benzene sulphonate: 2%；
Sodium hydroxide: 0.1~0.2%；
Sodium chloride: 1.5%；
EDTA-2Na:0.1%；
Preservative: 0.1%；
Water: 100% is added to；
The preparation method of the transparent hand cleanser of above-described embodiment, comprising the following steps:
1) suitable water is added in reactor tank, 0.1~0.2% sodium hydroxide is added, 2.5% alkane is added after dissolution
Base benzene sulfonic acid adjusts pH to 3.0~4.0；
2) 5% fatty alcohol-ether sodium sulfate is added, 5% lauramido glycine betaine is stirred well to and is completely dissolved；
3) 1.5% coconut oil diethanol amine is added, 0.1% EDTA-2Na is stirred well to and is completely dissolved；
4) 0.1% preservative is added, required viscosity is adjusted to finally by 1.5% electrolyte, is stirred evenly filling.
Comparative example 1
A kind of transparent hand cleanser not adding polymeric rheology modifiers includes by percentage to the quality following each component:
Fatty alcohol-ether sodium sulfate: 5%；
Coconut oil diethanol amine: 1.0%；
Lauramido glycine betaine: 4%；
Alkyl benzene sulphonate: 5%；
Sodium hydroxide: 0.1~0.5%；
Sodium chloride: 2%；
EDTA-2Na:0.1%；
Preservative: 0.1%；
Water: 100% is added to；
The preparation method of above-mentioned transparent hand cleanser, comprising the following steps:
1) suitable water is added in reactor tank, sodium hydroxide is added, is added alkyl benzene sulphonate after dissolution, adjust pH to
4.0~5.0；
2) addition fatty alcohol-ether sodium sulfate, coconut oil diethanol amine, lauramido glycine betaine, EDTA-2Na, sufficiently
Stirring and dissolving；
3) preservative is added, required viscosity is adjusted to finally by chlorate, it is filling after mixing evenly.
Comparative example 2
A kind of transparent hand cleanser adding polymeric rheology modifiers includes by percentage to the quality following each component:
Fatty alcohol-ether sodium sulfate: 5%；
Coconut oil diethanol amine: 1%；
Lauramido glycine betaine: 5%；
Sodium alkyl benzene sulfonate: 2.5%；
Hydroxypropyl cellulose: 0.2%；
EDTA-2Na:0.1%；
Water: 100% is added to；
The preparation method of above-mentioned transparent hand cleanser, comprising the following steps:
1) suitable water is added in reactor tank, sodium alkyl benzene sulfonate, fatty alcohol-ether sodium sulfate, coconut oil diethyl is added
Hydramine, lauramido glycine betaine, hydroxypropyl cellulose, EDTA-2Na, is stirred well to and is completely dissolved；
3) preservative, essence is added, required viscosity is adjusted to finally by chlorate, it is filling after mixing evenly.
The following are effect application test examples.
1, by the physical function parameter of hand cleanser made from the transparent hand cleanser of the embodiment of the present invention 1~5 and comparative example 1,
Mainly viscosity parameter carries out the comparison such as the following table 1.
The physical function parameter (viscosity: cps) of hand cleanser made from 1 Examples 1 to 5 of table and comparative example 1
| Embodiment/comparative example | PH value/25 DEG C | 3℃/cps | 5℃/cps | 25℃/cps | 35℃/cps |
| Embodiment 1 | 6.3 | 2500 | 3000 | 5050 | 4300 |
| Embodiment 2 | 6.8 | 2000 | 2500 | 6000 | 3600 |
| Embodiment 3 | 7.2 | 2600 | 2900 | 5300 | 4500 |
| Embodiment 4 | 6.2 | 3000 | 4000 | 5000 | 3500 |
| Embodiment 5 | 6.5 | 1800 | 2500 | 4000 | 3000 |
| Comparative example 1 | 7.0 | 15000 | 11000 | 5000 | 4000 |
| Comparative example 2 | 6.8 | 9000 | 7800 | 5000 | 4100 |
Seen from table 1, Examples 1 to 5 moderately declines in 3 DEG C~5 DEG C viscosity, and low temperature flow is better than addition polymer flow
Become the comparative example 2 of modifying agent, the viscosity at 3~5 DEG C of comparative example 1 is substantially increased, and mobility is deteriorated.Examples 1 to 5 viscosity is with temperature
Degree change curve is bell-like, the temperature of peak viscosity appearance can be changed by adjusting the dosage of electrolyte, so that stream when low temperature
Denaturation is best.Viscosity with temperature change curve is bell-like, so that product is consistent with use feeling when high temperature in low temperature.
2, the physical property of hand cleanser made from the transparent hand cleanser of the embodiment of the present invention 1~5 and comparative example 1-2 is joined
Number, mainly product appearance and state carry out the comparison such as the following table 2.
Table 2 is the product appearance and state of hand cleanser made from Examples 1 to 5 and comparative example 1~2
| Embodiment/comparative example | 3℃ | 5℃ | 25℃ | 35℃ |
| Embodiment 1 | It is transparent, flowable | It is transparent, flowable | It is transparent, flowable | It is transparent, flowable |
| Embodiment 2 | It is transparent, flowable | It is transparent, flowable | It is transparent, flowable | It is transparent, flowable |
| Embodiment 3 | It is transparent, flowable | It is transparent, flowable | It is transparent, flowable | It is transparent, flowable |
| Embodiment 4 | It is transparent, flowable | It is transparent, flowable | It is transparent, flowable | It is transparent, flowable |
| Embodiment 5 | It is transparent, flowable | It is transparent, flowable | It is transparent, flowable | It is transparent, flowable |
| Comparative example 1 | Opaque, jelly | Transparent, jelly | It is transparent, flowable | It is transparent, flowable |
| Comparative example 2 | It is transparent, flowable | It is transparent, flowable | It is transparent, flowable | It is transparent, flowable |
As can be seen from Table 2, Examples 1 to 5 has as the comparative example 2 of addition polymeric rheology modifiers than comparative example 1
Broader thermal adaptability, product stability is high, and transparency is good.
3, the physical property of hand cleanser made from the transparent hand cleanser of the embodiment of the present invention 1~5 and comparative example 1-2 is joined
Number, mainly product foaming power and washability can be carried out the comparison such as the following table 3.
Table 3 is the foaming power and flushing performance of hand cleanser made from Examples 1 to 3 and comparative example 1~3.
| Embodiment/comparative example | Foaming power/mm | Rinse performance */s |
| Embodiment 1 | 60 | 8 |
| Embodiment 2 | 75 | 6 |
| Embodiment 3 | 65 | 9 |
| Embodiment 4 | 66 | 7 |
| Embodiment 5 | 70 | 10 |
| Comparative example 1 | 55 | 15 |
| Comparative example 2 | 65 | 10 |
It rinses performance *: after referring to that blistering is washed in wetting by rubbing with the hands, starting bath to rinsing the required time well.
Seen from table 3, Examples 1 to 5 has richer foam than comparative example 1~2, while being easier to rinse.
The above described is only a preferred embodiment of the present invention, be not intended to limit the present invention in any form, therefore
Without departing from the technical solutions of the present invention, to the above embodiments according to the technical essence of the invention any simply to repair
Change, equivalent variations and modification, all of which are still within the scope of the technical scheme of the invention.
Claims (5)
1. one kind does not add the transparent hand cleanser of polymeric rheology modifiers, which is characterized in that by percentage to the quality, be by with
Lower each group is grouped as:
A the anionic surfactant of constituent content 2~15%) is accounted for；The anionic surfactant is selected from fatty alcohol ether sulphur
Sour sodium, fatty alcohol ether ammonium sulfate, sodium alkyl benzene sulfonate, at least two or more mixture in sodium alkyl sulfate；
B the betaine type amphoteric ionic surface active agent of constituent content 2~8%) is accounted for；Meet component A and B between the component
Proportionate relationship is 1~2:1, and the total content of the two accounts for composition weight 4~23%；
C the nonionic surfactant of constituent content 0.5~5%) is accounted for, the nonionic surfactant is selected from coconut oil diethyl
At least one of hydramine, palm-kernel oil diethanol amine, fatty acid alkanol amides or two or more mixtures；Described group point it
Between to meet the proportionate relationship of component (A+B) and C be 5~10:1, the total content of the two accounts for composition weight 4.5~28%；
D the sodium hydroxide of constituent content 0.1~5%) is accounted for；
E the electrolyte of constituent content 0.1~5%) is accounted for；
F the EDTA-2Na of constituent content 0.1%) is accounted for；
G the deionized water of constituent content 61.9~95.2%) is accounted for；It also include the acceptable a small amount of moisturizer of hand cleanser, anti-corrosion
Agent, fragrance, pigment.
2. transparent hand cleanser according to claim 1, it is characterised in that: the alkylbenzene when sodium alkyl benzene sulfonate is production
Sulfonic acid and sodium hydroxide directly neutralize use.
3. transparent hand cleanser according to claim 1, it is characterised in that: the betaine type amphoteric ionic surface active agent
Selected from lauramido glycine betaine, Cocoamidopropyl betaine, oleamide propyl betaine, in alkyl dimethyl betaine
Mixture more than at least one or two.
4. transparent hand cleanser according to claim 1, it is characterised in that: the electrolyte is in sodium chloride, potassium chloride
One kind.
5. the preparation method of the transparent hand cleanser of any of claims 1-4 for not adding polymeric rheology modifiers,
It is characterized in that comprising the steps of:
1) suitable water is added in reactor tank, 0.1~5% sodium hydroxide is added, alkyl benzene sulphonate is added after dissolution, adjusted
Save pH to 3.0~4.0；The feed ratio of alkyl benzene sulphonate and sodium hydroxide is 8~12:1；
2) sodium alkyl benzene sulfonate made from 2~8% steps 1) is added；
3) be added 3~12% remaining anionic surfactant, 2~8% betaine type amphoteric surfac-tant, 0.5~
5% nonionic surfactant, 0.1% EDTA-2Na, is stirred well to and is completely dissolved；Remaining described anion surface active
Agent is selected from fatty alcohol ether ammonium sulfate, fatty alcohol-ether sodium sulfate, at least two or more mixture in sodium alkyl sulfate；
4) preservative, essence is added, required viscosity is adjusted to finally by 0.1~5% electrolyte, it is filling after mixing evenly
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Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
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| US4668422A (en) * | 1985-05-31 | 1987-05-26 | A. E. Staley Manufacturing Company | Liquid hand-soap or bubble bath composition |
| CN1047334A (en) * | 1990-05-30 | 1990-11-28 | 李洪耀 | High stable, multi-usage, the simple anhydrous washing hand liquid of technology |
| CN1112157A (en) * | 1994-05-20 | 1995-11-22 | 武汉化院精细化工技术公司 | Skin-care hand-washing lotion |
| CN1248284A (en) * | 1997-12-18 | 2000-03-22 | 宇野酱油株式会社 | Transparent liquid detergent containing sodium silicate |
| CN1687344A (en) * | 2005-05-20 | 2005-10-26 | 云南盐化股份有限公司 | Emulsified salt type hands washing liquid and preparation method thereof |
| CN101381656A (en) * | 2008-10-30 | 2009-03-11 | 九三粮油工业集团有限公司 | Method for preparing soya bean lecithin hand cleanser |
| CN104726226A (en) * | 2013-12-18 | 2015-06-24 | 江南大学 | Formula of high-foam mild liquid soap |
-
2016
- 2016-08-15 CN CN201610671156.1A patent/CN106281773B/en not_active Expired - Fee Related
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4668422A (en) * | 1985-05-31 | 1987-05-26 | A. E. Staley Manufacturing Company | Liquid hand-soap or bubble bath composition |
| CN1047334A (en) * | 1990-05-30 | 1990-11-28 | 李洪耀 | High stable, multi-usage, the simple anhydrous washing hand liquid of technology |
| CN1112157A (en) * | 1994-05-20 | 1995-11-22 | 武汉化院精细化工技术公司 | Skin-care hand-washing lotion |
| CN1248284A (en) * | 1997-12-18 | 2000-03-22 | 宇野酱油株式会社 | Transparent liquid detergent containing sodium silicate |
| CN1687344A (en) * | 2005-05-20 | 2005-10-26 | 云南盐化股份有限公司 | Emulsified salt type hands washing liquid and preparation method thereof |
| CN101381656A (en) * | 2008-10-30 | 2009-03-11 | 九三粮油工业集团有限公司 | Method for preparing soya bean lecithin hand cleanser |
| CN104726226A (en) * | 2013-12-18 | 2015-06-24 | 江南大学 | Formula of high-foam mild liquid soap |
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