CN106281089A - Heat discoloration type adhesive material - Google Patents

Heat discoloration type adhesive material Download PDF

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Publication number
CN106281089A
CN106281089A CN201610705388.4A CN201610705388A CN106281089A CN 106281089 A CN106281089 A CN 106281089A CN 201610705388 A CN201610705388 A CN 201610705388A CN 106281089 A CN106281089 A CN 106281089A
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CN
China
Prior art keywords
heat discoloration
parts
layering
retardant
belt body
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Granted
Application number
CN201610705388.4A
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Chinese (zh)
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CN106281089B (en
Inventor
陈灏渠
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Huizhou Haoming Technology Co Ltd
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Huizhou Haoming Technology Co Ltd
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Priority to CN201610705388.4A priority Critical patent/CN106281089B/en
Publication of CN106281089A publication Critical patent/CN106281089A/en
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Publication of CN106281089B publication Critical patent/CN106281089B/en
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L67/00Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
    • C08L67/02Polyesters derived from dicarboxylic acids and dihydroxy compounds
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/18Layered products comprising a layer of synthetic resin characterised by the use of special additives
    • B32B27/20Layered products comprising a layer of synthetic resin characterised by the use of special additives using fillers, pigments, thixotroping agents
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B3/00Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form
    • B32B3/02Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by features of form at particular places, e.g. in edge regions
    • B32B3/08Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by features of form at particular places, e.g. in edge regions characterised by added members at particular parts
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2405/00Adhesive articles, e.g. adhesive tapes
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2301/00Additional features of adhesives in the form of films or foils
    • C09J2301/10Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet
    • C09J2301/16Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet by the structure of the carrier layer
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2301/00Additional features of adhesives in the form of films or foils
    • C09J2301/40Additional features of adhesives in the form of films or foils characterized by the presence of essential components
    • C09J2301/41Additional features of adhesives in the form of films or foils characterized by the presence of essential components additives as essential feature of the carrier layer
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2467/00Presence of polyester
    • C09J2467/006Presence of polyester in the substrate

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Adhesive Tapes (AREA)

Abstract

A kind of heat discoloration type adhesive material, including gluing belt body and reel, gluing belt body stacks gradually and is wound on reel, gluing belt body includes substrate layer, adhesive layer and the adherent layer being cascading, two sides of substrate layer protrude respectively and are provided with a positive stop strip, surrounding a storage tank between two positive stop strips, adhesive layer is placed in storage tank, and adherent layer is fitted with positive stop strip.Substrate layer includes base material layering and heat discoloration layering.Above-mentioned heat discoloration type adhesive material is by arranging reel and gluing belt body, and two sides of the substrate layer of gluing belt body protrude respectively and are provided with a positive stop strip, adhesive layer can be limited by two positive stop strips and flow out the side of substrate layer, it is thus possible to reduce gluing belt body package packaging or use time because of excessive compression time, adherent layer substrate layer side occur " leakage glue " problem occur.

Description

Heat discoloration type adhesive material
Technical field
The present invention relates to adhesive material technical field, particularly relate to a kind of heat discoloration type adhesive material.
Background technology
At present, adhesive material be material the most frequently used in daily life one of, it is mainly by base material and adhesive layer two Part composition, makes two or more disjunct object link together by bonding.One layer of adhesive is scribbled on its surface.? Adhesive early is from animal and plant, and at 19th-century, rubber is the Main Ingredients and Appearance of adhesive;Modern times are the most extensively applied respectively Plant polymer.Adhesive can cling thing, is the intermolecular formation bond of the molecule due to itself and article to be connected, this Bond can be bonded together molecule firmly.
In order to preferably transport and preserve adhesive material, such as, in order to preferably transport and preserve adhesive tape, it is generally required to will Adhesive material stacking is wound on reel, for making adhesive material winding form ring-type film roll structure, so, it is possible preferably Transport and preservation adhesive material, and the space taken is less.
But, due to the characteristic of adhesive layer structure, during external force extrudes, easily at base material side, " leakage occurs Glue " problem, the side of the multilamellar adhesive material under reeling condition can be caused to be bonded to each other, during use, it is not easy to tear Open, and the problem still causing the glue spilt to stick on foreign object occurs.
Summary of the invention
Based on this, it is necessary to provide a kind of and can reduce the heat discoloration type adhesive material that side leakage glue problem occurs.
A kind of heat discoloration type adhesive material, including:
Gluing belt body and reel, described gluing belt body stacks gradually and is wound on described reel, and described gluing belt body includes Substrate layer, adhesive layer and the adherent layer being cascading, two sides of described substrate layer protrude respectively and are provided with a limit Position bar, surrounds a storage tank between two described positive stop strips, described adhesive layer is placed in described storage tank, and described adherent layer Fit with described positive stop strip;
Described substrate layer includes base material layering and heat discoloration layering, and two described positive stop strips are respectively arranged at described base material On two sides of layering, the layering of described heat discoloration fits in the described base material layering one side away from described adhesive layer;
The layering of described heat discoloration includes each component of following mass parts:
Polyethylene terephthalate 10 parts~50 parts;
Polydimethylsiloxane 1 part~3.5 parts;
1 part~1.5 parts of heat discoloration powder.
Wherein in an embodiment, the layering of described heat discoloration includes each component of following mass parts:
Polyethylene terephthalate 15 parts~46.8 parts;
Polydimethylsiloxane 1.5 parts~2.4 parts;
1.1 parts~1.5 parts of heat discoloration powder.
Wherein in an embodiment, the layering of described heat discoloration includes each component of following mass parts:
Polyethylene terephthalate 23.5 parts~46.5 parts;
Polydimethylsiloxane 2.1 parts~2.4 parts;
1.3 parts~1.5 parts of heat discoloration powder.
Wherein in an embodiment, the layering of described heat discoloration includes each component of following mass parts:
Polyethylene terephthalate 45.5 parts;
Polydimethylsiloxane 2.2 parts;
1.4 parts of heat discoloration powder.
Wherein in an embodiment, the thickness of described base material layering is 1 with the thickness proportion of described heat discoloration layering: (0.9~1.2).
Wherein in an embodiment, the thickness of described base material layering is 1 with the thickness proportion of described heat discoloration layering: (1.1~1.2).
Wherein in an embodiment, the thickness of described base material layering is 1 with the thickness proportion of described heat discoloration layering: 1.2。
Above-mentioned heat discoloration type adhesive material by arranging reel and gluing belt body, and the two of the substrate layer of gluing belt body Individual side protrudes respectively and is provided with a positive stop strip, can limit adhesive layer by two positive stop strips and flow out the side of substrate layer, It is thus possible to reduce gluing belt body package packaging or use time because of excessive compression time, adherent layer substrate layer side occur " leakage Glue " problem occur.
Accompanying drawing explanation
Fig. 1 is the structural representation of the heat discoloration type adhesive material of an embodiment of the present invention;
Fig. 2 is the structural representation of another angle of the heat discoloration type adhesive material shown in Fig. 1;
Fig. 3 is the structural representation of the gluing belt body of another embodiment of the present invention;
Fig. 4 is the structural representation of the gluing belt body of another embodiment of the present invention;
Fig. 5 is the structural representation of the gluing belt body of another embodiment of the present invention;
Fig. 6 is the structural representation of the gluing belt body of another embodiment of the present invention;
Fig. 7 is the structural representation of the gluing belt body of another embodiment of the present invention;
Fig. 8 is the structural representation of the gluing belt body of another embodiment of the present invention;
Fig. 9 is the structural representation of the gluing belt body of another embodiment of the present invention;
Figure 10 is the partial structurtes schematic diagram of the heat discoloration type adhesive material of invention one embodiment;
Figure 11 is the structural representation of the reel of invention one embodiment;
Figure 12 is the structural representation of another angle of the heat discoloration type adhesive material shown in Fig. 1;
Figure 13 is the Figure 12 cut-away view along line A-A;
Figure 14 is the structural representation of the fire extinguishing monomer of an embodiment of the present invention;
Figure 15 is the structural representation of another angle of the fire extinguishing monomer shown in Figure 14;
Figure 16 is the Figure 15 cut-away view along line B-B;
Figure 17 is the structural representation of the flame-retardant monomer of an embodiment of the present invention;
Figure 18 is the structural representation of another angle of the flame-retardant monomer shown in Figure 17;
Figure 19 is the Figure 18 cut-away view along line C-C.
Detailed description of the invention
For the ease of understanding the present invention, below with reference to relevant drawings, the present invention is described more fully.In accompanying drawing Give the better embodiment of the present invention.But, the present invention can realize in many different forms, however it is not limited to herein Described embodiment.On the contrary, providing the purpose of these embodiments is to make to understand the disclosure more Add thorough comprehensive.
It should be noted that when element is referred to as " being fixed on " another element, and it can be directly on another element Or element placed in the middle can also be there is.When an element is considered as " connection " another element, and it can be to be directly connected to To another element or may be simultaneously present centering elements.Term as used herein " vertical ", " level ", " left ", For illustrative purposes only, being not offered as is unique embodiment for " right " and similar statement.
Unless otherwise defined, all of technology used herein and scientific terminology and the technical field belonging to the present invention The implication that technical staff is generally understood that is identical.The term used the most in the description of the invention is intended merely to describe tool The purpose of the embodiment of body, it is not intended that in limiting the present invention.Term as used herein " and/or " include one or more Arbitrary and all of combination of relevant Listed Items.
Such as, a kind of heat discoloration type adhesive material, including: gluing belt body and reel, described gluing belt body stacks gradually Being wound on described reel, described gluing belt body includes substrate layer, adhesive layer and the adherent layer being cascading, described base material Two sides of layer protrude respectively and are provided with a positive stop strip, surround a storage tank between two described positive stop strips, described gluing Layer is placed in described storage tank, and described adherent layer is fitted with described positive stop strip;Described substrate layer includes base material layering and sense Temperature variable color layering, two described positive stop strips are respectively arranged on two sides of described base material layering, and described heat discoloration is layered Fit in the described base material layering one side away from described adhesive layer;The layering of described heat discoloration includes each group of following mass parts Point: polyethylene terephthalate 10 parts~50 parts;Polydimethylsiloxane 1 part~3.5 parts;1 part of heat discoloration powder~1.5 Part.
In order to further illustrate above-mentioned heat discoloration type adhesive material, another example is to see also Fig. 1 and Fig. 2, Heat discoloration type adhesive material 30 includes that reel 10 and gluing belt body 20, gluing belt body 20 stack gradually and is wound on reel 10, The gluing belt body 20 of banding or lamellar for making elongate configuration is wound on reel 10, so that gluing belt body 20 forms tool Having ring-type film roll structure, i.e. reel 10 as core arrangement, the gluing belt body 20 after winding is as layer structure, so, more Be conducive to the storage and transport of heat discoloration type adhesive material 30, decrease the sky shared by heat discoloration type adhesive material 30 Between.
Such as, described gluing belt body has initiating terminal and clearing end, and described initiating terminal is fixed on described reel, afterwards, Described gluing belt body, using described initiating terminal as starting point, carries out operating winding on described reel, until described clearing end is fitted In the agent structure of described gluing belt body, now, described gluing belt body completes operating winding, forms described heat discoloration type gluing Material.
Referring to Fig. 3, gluing belt body 20 includes substrate layer 21, adhesive layer 22 and the adherent layer 23 being cascading, when When needing to use gluing belt body 20, the part of required gluing belt body 20 is torn from by the reeling condition of reel 10, afterwards, will Adherent layer 23 removes, and viscous adhesive layer 22 is held thing towards treating, directly treats that viscous thing of holding glues with adhesive layer 22 and holds, finally, to substrate layer 21 apply pressure, to improve adhesive layer 22 further and to treat the viscous viscous holding force holding between thing.
In order to improve the performance of described adherent layer, and then improve the overall performance of described adherent layer, such as, described adherent layer Material be polypropylene separate paper or anti-adhesive silicone layer, so, it is possible to improve the performance of described adherent layer, and then improve described The overall performance of adherent layer.
In order to optimize in described gluing belt body the thickness between each layer, for improving the overall performance of described gluing belt body, Such as, the thickness of described adhesive layer is 15 μm~35 μm;And for example, the thickness of described gluing belt body is 1.2mm~2.5mm;And for example, The thickness of described gluing belt body is 1.5mm~2.4mm, so, it is possible to optimize the thickness between each layer in described gluing belt body, uses In the overall performance improving described gluing belt body.Certainly, according to actual needs, e.g., in order to make described gluing belt body possess more Function, can thickness between the flexible described each layer of gluing belt body, and the thickness proportion between the described each layer of gluing belt body, with And the gross thickness of described gluing belt body, however it is not limited to above-mentioned concrete thickness.
Referring to Fig. 3, two sides of substrate layer 21 protrude respectively and are provided with a positive stop strip 21a, two positive stop strip 21a Between surround a storage tank 21b, adhesive layer 22 is placed in storage tank 21b, and adherent layer 23 is fitted with positive stop strip 21a, so, Utilize two positive stop strip 21a can limit adhesive layer 22 and flow out the side of substrate layer 21 such that it is able to reduce gluing belt body 20 and exist Time when package packaging or use because of excessive compression, at substrate layer 21 side, adherent layer 23 occurs that the problem of " leakage glue " occurs, and then The problem generation that the gluing belt body 20 of stacking is inter-adhesive can be reduced.Additionally, utilize positive stop strip 21a can also reduce the external world The unfavorable factors such as steam, dust, oil stain penetrate into the problem in adhesive layer 22 from the side of substrate layer 21 and occur.
Above-mentioned heat discoloration type adhesive material 30 is by arranging reel 10 and gluing belt body 20, and the base of gluing belt body 20 Two sides of sheet material layers 21 protrude respectively and are provided with a positive stop strip 21a, can limit adhesive layer 22 by two positive stop strip 21a Flow out substrate layer 21 side such that it is able to reduce gluing belt body 20 package packaging or use time because of excessive compression time, antiseized At substrate layer 21 side, layer 23 occurs that the problem of " leakage glue " occurs.
In order to improve the appearance glue rate of described gluing belt body further, such as, refer to Fig. 4, substrate layer 21b is positioned at described The bottom of storage tank offers multiple glue groove 211b, is provided with interval, glue groove between two adjacent glue groove 211b 211b has strip structure, being at least partly placed in glue groove 211b of described adhesive layer, and so, substrate layer 21b is by opening If glue groove 211b, it is possible to accommodating higher volume of described adhesive layer, and then the appearance glue rate of described gluing belt body can be improved.Again As, described glue groove has the cross section of triangular structure;And for example, described glue groove has the cross section of equilateral triangle structure; And for example, multiple described glue grooves are spaced setting the most successively;And for example, the degree of depth of described glue groove and the thickness of described substrate layer Ratio is 1:(3~5);And for example, the degree of depth of described glue groove is 1:(3~5 with the thickness proportion of described substrate layer);And for example, institute The thickness proportion of the degree of depth and described substrate layer of stating glue groove is 1:(3.5~5.5);And for example, the degree of depth of described glue groove and institute The thickness proportion stating substrate layer is 1:(4.5).
In order to make described gluing belt body have antistatic performance, such as, refer to Fig. 5, substrate layer 21c and include that base material is layered 211c and antistatic layering 212c, two described positive stop strips are respectively arranged on two sides of base material layering 211c, antistatic Layering 212c fits in the base material layering 211c one side away from described adhesive layer;And for example, the layering of described antistatic includes as follows Each component of mass parts: polyethylene film 10 parts~46 parts;Polypropylene screen 5 parts~15 parts;Polychloroethylene film 3.4 parts~12.8 parts; And for example, the layering of described antistatic includes each component of following mass parts: polyethylene film 20 parts~45 parts;Polypropylene screen 5 parts~8.6 Part;Polychloroethylene film 4.1 parts~13.2 parts;And for example, the layering of described antistatic includes each component of following mass parts: polyethylene film 25 parts~43.2 parts;Polypropylene screen 6.8 parts~12.5 parts;Polychloroethylene film 3.4 parts~12.8 parts;And for example, described antistatic divides Layer includes each component of following mass parts: polyethylene film 42 parts;Polypropylene screen 9.2 parts;Polychloroethylene film 4.6 parts;And for example, described Base material layering and the thickness that is layered of described antistatic ratio is for 1:(2~3.5);And for example, the layering of described base material divides with described antistatic The thickness of layer ratio is for 1:(2.4~3.2);And for example, the layering of described base material and the thickness that is layered of described antistatic ratio for 1:3.1, this Sample, substrate layer 21c is by arranging base material layering 211c and antistatic layering 212c, it is possible to make described gluing belt body have antistatic Performance.
In order to make described gluing belt body have fire resistance, such as, refer to Fig. 6, substrate layer 21d and include that base material is layered 211d and fire-retardant layering 212d, two described positive stop strips are respectively arranged on two sides of base material layering 211d, fire-retardant layering 212d fits in base material layering 211d away from the one side of described adhesive layer, described fire-retardant be layered as flame retardant polyethylene thin film or Anti-flammability nylon film, wherein, flame retardant polyethylene thin film or anti-flammability nylon film all have fire-retardant advantage;And for example, described The thickness of base material layering is 1:(0.5~2.4 with the thickness proportion of described fire-retardant layering);And for example, the thickness of described base material layering It is 1:(0.5~1.5 with the thickness proportion of described fire-retardant layering);And for example, thickness and the described fire-retardant layering of described base material layering Thickness proportion be 1:1.2;And for example, described fire-retardant it is layered as anti-flammability nylon film;And for example, the thickness of described adhesive layer is 15 μm~35 μm;And for example, the thickness of described gluing belt body is 1.2mm~2.5mm;And for example, the thickness of described gluing belt body is 1.5mm ~2.4mm, so, substrate layer 21d is by arranging base material layering 211d and fire-retardant layering 212d, it is possible to make described gluing belt body have There is fire resistance.
In order to make described gluing belt body have shock-absorbing capacity, to improve the resistance to external impacts performance of described gluing belt body, example As, referring to Fig. 7, substrate layer 21e and include base material layering 211e and buffering layering 212e, two described positive stop strips are respectively arranged at On two sides of base material layering 211e, buffering layering 212e fits in the base material layering 211e side away from described adhesive layer Face, described buffering is layered as resiliency two-ply foam thin film or PE Foam thin film, wherein, two-ply foam thin film or PE Foam thin film There is good shock-absorbing capacity;And for example, the thickness of described base material layering is 1:(3.2 with the ratio of the thickness of described buffering layering ~4.3);And for example, the thickness of described base material layering is 1:(3.5~4.1 with the ratio of the thickness of described buffering layering);And for example, The thickness of described base material layering is 1:4 with the ratio of the thickness of described buffering layering;And for example, described buffering is layered as resiliency pair Layer foam film;And for example, the thickness of described gluing belt body is 1.2mm~2.5mm;And for example, the thickness of described gluing belt body is 1.5mm~2.4mm;And for example, the thickness of described adhesive layer is 15 μm~35 μm, and so, substrate layer 21e is layered by arranging base material 211e and buffering layering 212e, it is possible to make described gluing belt body have shock-absorbing capacity, to improve the resistance to external force of described gluing belt body Impact property.
In order to make described gluing belt body have heat discoloration effect, for meeting the heat discoloration need of described gluing belt body Ask, such as, refer to Fig. 8, substrate layer 21f and include base material layering 211f and heat discoloration layering 212f, two described positive stop strips Being respectively arranged on two sides of base material layering 211f, heat discoloration layering 212f fits in base material layering 211f away from described The one side of adhesive layer, the layering of described heat discoloration includes each component of following mass parts: polyethylene terephthalate 10 parts ~50 parts;Polydimethylsiloxane 1 part~3.5 parts;1 part~1.5 parts of heat discoloration powder, wherein said heat discoloration powder is existing Heat discoloration powder disclosed in technology, its concrete operation principle refer to prior art and realizes, do not repeats them here;And for example, The layering of described heat discoloration includes each component of following mass parts: polyethylene terephthalate 15 parts~46.8 parts;Poly-diformazan Radical siloxane 1.5 parts~2.4 parts;1.1 parts~1.5 parts of heat discoloration powder;And for example, the layering of described heat discoloration includes following quality Each component of part: polyethylene terephthalate 23.5 parts~46.5 parts;Polydimethylsiloxane 2.1 parts~2.4 parts;Temperature-sensitive becomes Toner 1.3 parts~1.5 parts;And for example, the layering of described heat discoloration includes each component of following mass parts: poly terephthalic acid second two Ester 45.5 parts;Polydimethylsiloxane 2.2 parts;1.4 parts of heat discoloration powder;And for example, thickness and the described sense of described base material layering The thickness proportion of temperature variable color layering is 1:(0.9~1.2);And for example, the thickness of described base material layering is layered with described heat discoloration Thickness proportion be 1:(1.1~1.2);And for example, the thickness proportion that the thickness of described base material layering is layered with described heat discoloration For 1:1.2, so, substrate layer 21f is by arranging base material layering 211f and heat discoloration layering 212f, it is possible to make described adhesive tape Body has heat discoloration effect, for meeting the heat discoloration demand of described gluing belt body.
In order to make described gluing belt body have fire resistance, for improving the security performance of described gluing belt body, such as, please Including that base material is layered 211g and heat insulation layering 212g refering to Fig. 9, substrate layer 21g, two described positive stop strips are respectively arranged at base material On two sides of layering 211g, heat insulation layering 212g fits in the base material layering 211g one side away from described adhesive layer, every Thermally stratified layer 212g includes heat insulation sublayer 213g and porous aerogel sublayer 214g, and heat insulation sublayer 213g fits in base material layering 211g On side away from described adhesive layer, porous aerogel sublayer 214g fits in heat insulation sublayer 213g away from base material layering 211g's On side, the material of described heat insulation sublayer is polyimides, and the material of described porous aerogel sublayer is porous silica gas Gel, so, substrate layer 21g is by arranging base material layering 211g and heat insulation layering 212g, it is possible to make described gluing belt body have Fire resistance, for improving the security performance of described gluing belt body, wherein, described porous silica silica aerogel is prior art Disclosed porous silica silica aerogel, it has heat-proof quality, and its concrete operation principle refer to prior art and realizes, This repeats no more;And for example, the thickness of described base material layering is 1:(2.5~3.8 with the thickness proportion of described heat insulation layering);Again As, the thickness of described base material layering is 1:(2.7~3.5 with the thickness proportion of described heat insulation layering);And for example, described base material layering The thickness proportion of thickness and described heat insulation layering be 1:3.1 and for example, described gluing belt body has the banded structure that strip is square; And for example, described porous silica silica aerogel is nano porous silicon dioxide aerogel, wherein, and described nano-stephanoporate silicon dioxide Aeroge is nano porous silicon dioxide aerogel disclosed in prior art, and it is real that its concrete operation principle refer to prior art Existing.
In order to improve the performance of described base material layering, and then improve the overall performance of described gluing belt body, such as, described base The material of material layering is polypropylene screen (BOPP film) or polyester film (PET film), so, it is possible to improve the performance of described substrate layer, And then improve the overall performance of described gluing belt body.
It should be noted that owing to the described gluing belt body of above-mentioned heat discoloration type adhesive material has the flammable of height Property, especially concentrate at above-mentioned heat discoloration type adhesive material and store the occasion stacked, such as, in workshop or in warehouse, its The probability that combustion explosion occurs is bigger, brings person property and greatly threatens, therefore, it is necessary to improve described heat discoloration The fire retardant performance of type adhesive material, for improving the safety of described heat discoloration type adhesive material.
In order to improve the fire retardant performance of described heat discoloration type adhesive material, gluing to improve described heat discoloration type The safety of material, such as, the described reel of an embodiment includes: runner assembly, fire extinguishing assembly, fire-retardant assembly and capping, Described fire extinguishing assembly fixed cover is placed in described runner assembly, and described fire-retardant assembly is arranged on the outer surface of described fire extinguishing assembly, The end of described runner assembly, described fire extinguishing assembly and described fire-retardant assembly is all connected with described capping, and described gluing belt body depends on Secondary stacking is wound on described fire extinguishing assembly and described fire-retardant assembly;Described runner assembly includes fixing cylinder, rotary shaft and multiple Roller bearing, described fixing cylinder has the regular hexagon tubular structure of hollow, and the inner space of described fixing cylinder is formed and rotates cavity, institute The lateral wall stating fixing cylinder arranges six fixing sides, and described rotary shaft wears described fixing cylinder, and two of described rotary shaft End is placed on outside described rotation cavity, and multiple described roller bearings are arranged around described rotary shaft, and described roller bearing is respectively with described The lateral wall of rotary shaft and the medial wall of described fixing cylinder support, and are used for making described rotary shaft rotate relative to described fixing cylinder;Institute Stating fire extinguishing assembly and include six fire extinguishing honeycomb cylinders and multiple inflammable portion, described fire extinguishing honeycomb cylinder has the regular hexagon tubular of hollow Structure, the inner space of described fire extinguishing honeycomb cylinder forms fire extinguishing cavity, and each described fire extinguishing honeycomb cylinder one_to_one corresponding is arranged at On one described fixing side, six described fire extinguishing honeycomb cylinders are sequentially connected with, and six described fire extinguishing honeycomb cylinders are with described fixing The central axis of cylinder radially distributes, and is provided with multiple fire extinguishing monomer being sequentially connected with, described fire extinguishing in described fire extinguishing cavity Monomer includes inflammable housing, fire extinguishing filling part and multiple fire extinguishing air bag, and described fire extinguishing filling part is filled with in described inflammable shell Internal, multiple described fire extinguishing air bags are all embedded in described fire extinguishing filling part, and multiple described fire extinguishing air bag is spaced setting successively, The sidewall of described fire extinguishing honeycomb cylinder offers multiple fire extinguishing and triggers hole, and each described inflammable portion one_to_one corresponding is embedded at an institute State fire extinguishing to trigger in hole, be used for closing described fire extinguishing and trigger hole;Described fire-retardant assembly includes six fire-retardant cylinders and multiple ignites Portion, described fire-retardant cylinder has the cylinder-like structure of hollow, and the inner space of described fire-retardant cylinder forms fire-retardant cavity, described resistance Combustion cylinder is fixed at the link position of adjacent two described fire extinguishing honeycomb cylinders, and six described fire-retardant cylinders are spaced successively and set Putting, six described fire-retardant cylinders radially distribute with the central axis of described fixing cylinder, are provided with many in described fire-retardant cavity The individual flame-retardant monomer being sequentially connected with, described flame-retardant monomer includes inflammable shell, flame resistant filler portion and fire-retardant air bag, described fire-retardant fills out The portion of filling is filled with in described inflammable shell, and multiple described fire-retardant air bags are all placed in described inflammable shell, and described resistance Combustion gas capsule contacts with described flame resistant filler portion, and the sidewall of described fire-retardant cylinder offers multiple fire-retardant triggering hole, described in each The portion one_to_one corresponding of igniting is embedded in a described fire-retardant triggering hole, is used for closing described fire-retardant triggering hole;Described gluing belt body Stack gradually and be wound on described fire extinguishing honeycomb cylinder and described fire-retardant cylinder;Described cap cover is located at the opening position of described fixing cylinder Put at the aperture position of place, described fire extinguishing honeycomb cylinder and at the aperture position of described fire-retardant cylinder on, be used for closing off described Rotating cavity, described fire extinguishing cavity and described fire-retardant cavity, described capping offers rotation hole, and described rotary shaft wears described turning Move hole, and described rotary shaft rotates relative to described capping.
In order to illustrate the described reel of above-mentioned heat discoloration type adhesive material further, another example is, please In the lump refering to Fig. 2, Figure 10 and Figure 11, reel 10 includes: runner assembly 100, fire extinguishing assembly 200, fire-retardant assembly 300 and capping 400, fire extinguishing assembly 200 fixed cover is placed in runner assembly 100, and fire-retardant assembly 300 is arranged on the outer surface of fire extinguishing assembly 200, The end of runner assembly 100, fire extinguishing assembly 200 and fire-retardant assembly 300 is all connected with capping 400.Gluing belt body 20 stacks gradually Being wound on fire extinguishing assembly 200 and fire-retardant assembly 300, concrete, gluing belt body 20 stacks gradually and is wound in fire extinguishing assembly 200 On the outward flange of outward flange and fire-retardant assembly 300.
Seeing also Figure 11, Figure 12 and Figure 13, runner assembly 100 includes fixing cylinder 110, rotary shaft 120 and multiple rolling Axle 130, fixing cylinder 110 has the regular hexagon tubular structure of hollow, and the lateral wall of fixing cylinder 110 arranges six fixing sides 111, two adjacent fixing sides 111 form the angle of 120 degree.The inner space of fixing cylinder 110 is formed and rotates cavity, described Rotating cavity and be used for housing rotary shaft 120 and multiple roller bearing 130, such as, described rotation cavity has columnar structure, rotates The cavity wall of cavity has circular curved surface structure.Rotary shaft 120 wears fixing cylinder 110, and two ends of rotary shaft 120 are placed on Outside described rotation cavity, multiple roller bearings 130 are arranged around rotary shaft 120, and roller bearing 130 respectively with the lateral wall of rotary shaft 120 And the medial wall of fixing cylinder 110 supports, wherein, the medial wall of fixing cylinder 110 is the cavity wall of described rotation cavity, rotary shaft 120 are relatively fixed cylinder 110 can rotate, so, by between the medial wall of the lateral wall of rotary shaft 120 and fixing cylinder 110 Multiple roller bearing 130 is set, so that rotary shaft 120 rotation is more smooth and easy.
Be appreciated that when needs use described heat discoloration type adhesive material attach until viscous hold thing time, especially need Adhere to volume bigger viscous when holding thing, it usually needs operator go to rotate described adhesive tape body with hands and form film roll, to reach Attach the effect of described gluing belt body smoothly, but, use the manual adhesive tape body that rotates to form film roll, attach inefficient, Attach operation more complicated, keep the posture of wrist reciprocally swinging for a long time, easily cause operator's fatigue of joint, above-mentioned The reel 10 of heat discoloration type adhesive material, by arranging runner assembly 100, only need to be fixed with hands, as gripped or grip rotary shaft 120, now, the film roll that described adhesive tape body is formed can rotate relative to described rotary shaft, such that it is able to be continuously completed glue The operation of the adhesion of adhesive tape body, attaches efficiency higher, attaches operation more simple and convenient.Additionally, by the outside of rotary shaft 120 Multiple roller bearing 130 is set between the medial wall of wall and fixing cylinder 110, it is also possible to improves further and attaches the efficiency of operation and convenient Property.
In order to make multiple described roller bearing rotate in described fixing cylinder more swimmingly, to avoid described roller bearing from described fixing Departing from cylinder, such as, the identical length of the length of described fixing cylinder, the length of described rotary shaft and multiple described roller bearing is with setting Put, by being respectively provided with two described cappings at the two ends of described fixing cylinder, be used for closing described fixing cylinder, so that multiple described Roller bearing rotates more swimmingly in described fixing cylinder, to avoid described roller bearing to depart from described fixing cylinder.
Such as, the material of described fixing cylinder, described rotary shaft and multiple described roller bearing is aluminium alloy, as such, it is possible to rise To certain flame retardant effect, and quality is lighter, is more beneficial for transport and preserves, further, described fixing cylinder, described rotary shaft and The material of multiple described roller bearings is foam aluminium alloy, as such, it is possible to alleviate the quality of described runner assembly further, more favorably In transport and preservation, and more save material.
Seeing also Figure 11, Figure 12 and Figure 13, fire extinguishing assembly 200 includes six fire extinguishing honeycomb cylinders 210 and multiple inflammable Portion 220, fire extinguishing honeycomb cylinder 210 has the regular hexagon tubular structure of hollow, and the inner space of fire extinguishing honeycomb cylinder 210 forms fire extinguishing Cavity 211, fire extinguishing cavity 211 is used for housing multiple fire extinguishing monomer.
Such as, the regular hexagon tubular structure of the described hollow of described fire extinguishing honeycomb cylinder and the described hollow of described fixing cylinder The identical setting of regular hexagon tubular structure, the side of the area of the described fixing side of described fixing cylinder and described fire extinguishing honeycomb cylinder The identical setting of area in face, and for example, the length of described fire extinguishing honeycomb cylinder, the length of described fixing cylinder, the length of described rotary shaft And the identical length of multiple described roller bearing is with arranging.
Seeing also Figure 11, Figure 12 and Figure 13, each fire extinguishing honeycomb cylinder 210 one_to_one corresponding is arranged at a fixing side On face 111, six fire extinguishing honeycomb cylinders 210 are sequentially connected with, and six fire extinguishing honeycomb cylinders 210 with the central axis of fixing cylinder 110 in Radial distribution, such as, six described fire extinguishing honeycomb cylinders radially distribute with the central axis of described fixing cylinder.
It should be noted that had the described fire extinguishing honeycomb cylinder of the regular hexagon tubular structure of hollow and described by setting After fixing cylinder, and both connections, there is the structure that stability is higher, there is more preferable external force resistance impact property, and quality is more Gently, and both spaces of internal each self-forming can also house miscellaneous part, and structure is the compactest.
Such as, after six described fire extinguishing honeycomb cylinders and a described fixing cylinder connect, alveolate texture, described honeycomb are formed Shape structure is centered by described fixing cylinder;And for example, the material of described fire extinguishing honeycomb cylinder is aluminium alloy, as such, it is possible to play certain Flame retardant effect, and quality is lighter, is more beneficial for transport and preserves, further, the material of fire extinguishing honeycomb cylinder is foam aluminium alloy, As such, it is possible to alleviate the quality of described fire extinguishing honeycomb cylinder further, it is more beneficial for transport and preserves, and more saving material;And for example, Described fixing cylinder and described fire extinguishing honeycomb cylinder are formed in one structure, e.g., realize described fixing by the way of casting or extrusion Cylinder and the integrated formed structure of described fire extinguishing honeycomb cylinder.
Refer to Figure 13, be provided with multiple fire extinguishing monomer 212 being sequentially connected with in fire extinguishing cavity 211, say, that multiple It is in close contact between described fire extinguishing monomer, so, it is possible to reduce touching between each fire extinguishing monomer within described fire extinguishing cavity 211 Hit/rub, and then described fire extinguishing monomer can be reduced in its inoperative condition, described fire extinguishing monomer damaging problem occurs, can Enough reduce described fire extinguishing monomer under conditions of described gluing belt body does not occurs burning fire, occur described fire extinguishing monomer breakage to ask Topic.
Referring to Figure 11, the sidewall of fire extinguishing honeycomb cylinder 210 offers multiple fire extinguishing and triggers hole 213, each inflammable portion 220 One_to_one corresponding is embedded at a fire extinguishing and triggers in hole 213, triggers hole 213 for smothering, say, that when described adhesive tape When the environment of body or described gluing belt body periphery is not under fired state, described inflammable portion is in off working state, i.e. institute Stating inflammable portion and fusing or burning will not occur, now, described fire extinguishing honeycomb cylinder is in sealing state;But, when described inflammable portion Ignited by the described gluing belt body of described burning or affected generation by periphery high temperature when melting phenomenon, described inflammable portion can quickly and Burn totally or fusion piercing in time so that described fire extinguishing honeycomb cylinder triggers hole by described fire extinguishing and is in communication with the outside, i.e. institute In stating fire extinguishing honeycomb cylinder, multiple described fire extinguishing monomers are directly in communication with the outside, and are used for causing described fire extinguishing monomer to play fire extinguishing effect Really, for aflame described gluing belt body being played fire extinguishing function, and to its at the deposit position of described gluing belt body His comburant plays fire extinguishing function, and then plays the effect of fireproof fire-extinguishing, for improving described heat discoloration type adhesive material Security performance.
In order to improve the inflammability in described inflammable portion further, and then can be when there is the condition of a fire, it is possible to go out described in making Described fire extinguishing monomer in fire honeycomb cylinder quickly and in time with extraneous contact, such as, the material in described inflammable portion is inflammable moulding Material, has higher sensitivity, fusing or burning, specifically, institute i.e. easily occurs in high temperature or flame high temperature or flame The material stating inflammable portion is celluloid (nitrocellulose plastics), and it has certain inflammability, it is possible at described gluing belt body or When material at person's deposit position periphery occurs burning, feed back in time, burning or fusing occur i.e. in time, makes described fire extinguishing honeycomb Cylinder is in communication with the outside by described triggering hole of putting out a fire, and in the most described fire extinguishing honeycomb cylinder, multiple described fire extinguishing monomers directly connect with extraneous Logical, it is used for causing described fire extinguishing monomer to play extinguishing effect, for aflame described gluing belt body is played fire extinguishing function, with And other comburants at the deposit position of described gluing belt body are played fire extinguishing function, and then play the effect of fireproof fire-extinguishing, For improving the security performance of described heat discoloration type adhesive material.
Such as, described inflammable portion triggers the identical setting of shape in hole with described fire extinguishing;And for example, described fire extinguishing triggers the number in hole Amount, described fire extinguishing trigger the dense degree of pore size distribution, described fire extinguishing triggers the diameter in hole, the thickness in described inflammable portion and described The size in inflammable portion, is adjusted according to actual needs, e.g., according to the size of described fire extinguishing honeycomb cylinder and/or deposit position The safe coefficient at the place of putting is adjusted, as long as guaranteeing that the condition of a fire, described fire extinguishing honeycomb cylinder can feed back in time with outer in described inflammable portion The contact area in portion and the structural strength in described inflammable portion, such as, a wherein side of described fire extinguishing honeycomb cylinder Width is 3.1cm~4.1cm, described fire extinguishing trigger hole a diameter of 3cm~4cm, the thickness in described inflammable portion be 2mm~ 4.5mm, owing to above-mentioned numerical value is limited by the overall dimensions of described reel, no longer goes to live in the household of one's in-laws on getting married to more concrete numerical value at this State.
Seeing also Figure 14 to Figure 16, fire extinguishing monomer 212 includes inflammable housing 2121, fire extinguishing filling part 2122 and multiple Fire extinguishing air bag 2123, fire extinguishing filling part 2122 is filled with in inflammable housing 2121, and multiple fire extinguishing air bags 2121 are all embedded at In fire extinguishing filling part 2122, and multiple fire extinguishing air bag 2122 is spaced setting, successively when described inflammable portion is by described in described burning Gluing belt body ignite or by periphery high temperature affected generation melt phenomenon time, described inflammable portion can quickly and in time burn totally or Fusion piercing so that described fire extinguishing honeycomb cylinder triggers hole by described fire extinguishing and is in communication with the outside, many in the most described fire extinguishing honeycomb cylinder When individual described fire extinguishing monomer is directly in communication with the outside, now, inflammable housing 2121 is affected by extraneous high temperature or flame, Burning or melting phenomenon also can occur, and now, fire extinguishing filling part 2122 is directly affected by high temperature or flame, changes Learn decomposition, volatilize substantial amounts of fire-retardant gas, e.g., volatilize substantial amounts of carbon dioxide, thus play certain isolating oxygen The effect of gas, is used for playing extinguishing effect.Such as, the material of described inflammable housing is inflammable plastics, has high temperature or flame , i.e. easily there is fusing or burning in higher sensitivity in high temperature or flame, specifically, the material of described inflammable housing is match Fine jade Luo (nitrocellulose plastics), it has certain inflammability, and described inflammable housing is easily destroyed by high temperature or flame, and then Can preferably make to produce fire extinguishing function, for avoiding spreading of the intensity of a fire with the described fire extinguishing filling part in inflammable housing, it is to avoid Large-scale fire occurs, and security performance is higher.
In order to make described fire extinguishing filling part play preferable extinguishing effect, such as, the material of described fire extinguishing filling part is phosphorus Acid ammonium salt or sodium bicarbonate, so, so, it is possible to make described fire extinguishing filling part play preferable extinguishing effect.Wherein, phosphoric acid is worked as Endothermic decomposition can go out ammonia and phosphoric acid when ammonium salt is affected by high temperature or flame, subsequently generate P205.Every single step reaction is all heat absorption Reaction, therefore have preferable cooling effect;Decompose the OH radical reaction that the free ammonia produced can produce in reacting with flame combustion, Reduce and terminate the free radical that combustion reaction produces, reduce combustion rate, when in flame, the concentration of free ammonia is sufficiently high, with Flame contact area is sufficiently large, and free radical stops the speed that speed generates more than combustion reaction, and looping combustion reaction is terminated, and leads Cause fray-out of flame.Described fire extinguishing filling part is the fire extinguishing filling part of ultra-fine grain diameter, and its particle diameter is less than or equal to 0.45 μm, preferably For less than 0.45 μm, so, utilizing the mobility of himself, can reach the fire extinguishing system of powder body-gas, its security performance is more High.
Additionally, described fire extinguishing air bag 2121 also can release fire-suppressant gas, such as nitrogen, it is possible to further function as the effect of fire extinguishing Really, and due to the existence of described fire extinguishing air bag, it is possible to when described fire extinguishing air bag is vanished, increase within described fire extinguishing filling part Hollow out degree, i.e. increases described fire extinguishing filling part and extraneous exposure level, it is possible to increase the fire extinguishing effect of described fire extinguishing filling part Really.Such as, described fire extinguishing air bag content is equipped with nitrogen, for starvation to a certain extent, and for example, described fire extinguishing air bag bag Nitrogen accommodating in including hollow utricule and described utricule, and for example, described utricule is plastic sheeting, e.g., polyethylene film, it is possible to At high temperature rapid melting, and then release the nitrogen in described utricule, for playing the effect of auxiliary fire extinguishing.
Such as, number and the size of described fire extinguishing monomer can be adjusted flexibly, and such as, described fire extinguishing monomer has hollow Orthohexagonal tubular structure or the cylinder-like structure of hollow;And for example, the width of one of them side of described fire extinguishing monomer For 3.1cm~4.1cm, and for example, the lateral wall of described fire extinguishing monomer supports or fixing with the medial wall of described fire extinguishing honeycomb cylinder, many Individual described fire extinguishing monomer spread configuration is inside a described fire extinguishing honeycomb cylinder, and the most multiple described fire extinguishing monomers head and the tail connect;Again As, when the size of described fire extinguishing honeycomb cylinder is bigger, described fire extinguishing honeycomb cylinder can house in the axial direction multiple described in go out Fire monomer.
Seeing also Figure 11, Figure 12 and Figure 13, fire-retardant assembly 300 includes six fire-retardant cylinders 310 and multiple portion of igniting 310, fire-retardant cylinder 310 has the cylinder-like structure of hollow, and the inner space of fire-retardant cylinder 310 forms fire-retardant cavity 311, fire-retardant Cavity 311 is used for housing multiple flame-retardant monomer.
Such as, described fire-retardant cylinder, the length of described fire extinguishing honeycomb cylinder, the length of described fixing cylinder, described rotary shaft The identical length of length and multiple described roller bearing is with arranging.
Seeing also Figure 11, Figure 12 and Figure 13, fire-retardant cylinder 310 is fixed on the company of 210, adjacent two fire extinguishing honeycombs Connect position, and six fire-retardant cylinders 310 be spaced setting successively, six fire-retardant cylinders 310 with the central axis of fixing cylinder 110 in Radial distribution, such as, six described fire-retardant cylinders radially distribute with the central axis of described fixing cylinder.
It should be noted that be there is by setting the described fire-retardant cylinder of the cylinder-like structure of hollow and there is hollow just The described fire extinguishing honeycomb cylinder of hexagon tubular structure, the most described fire-retardant cylinder is fixed on the company of adjacent two described fire extinguishing honeycomb cylinders After connecing position, and both connections, there is the structure that stability is higher, there is more preferable external force resistance impact property, and quality is more Gently, and both spaces of internal each self-forming can also house miscellaneous part, and structure is the compactest.
Such as, the material of described fire-retardant cylinder is aluminium alloy, as such, it is possible to play certain flame retardant effect, and quality is lighter, Being more beneficial for transport and preserve, further, the material of fire-retardant cylinder is foam aluminium alloy, as such, it is possible to alleviate institute further State the quality of fire-retardant cylinder, be more beneficial for transport and preserve, and more saving material;And for example, described fixing cylinder, described fire extinguishing honeycomb Cylinder and described fire-retardant cylinder are formed in one structure, e.g., realize described fixing cylinder, described fire extinguishing by the way of casting or extrusion Honeycomb cylinder and the integrated formed structure of described fire-retardant cylinder.
See also Figure 11, Figure 12 and Figure 13, in fire-retardant cavity 311, be provided with multiple flame-retardant monomer being sequentially connected with 312, be in close contact between multiple described flame-retardant monomers, so, it is possible to reduce described fire-retardant inside cavity each flame-retardant monomer it Between collision/friction, and then described flame-retardant monomer can be reduced in its inoperative condition, occur described flame-retardant monomer breakage to ask Topic, i.e. can reduce described flame-retardant monomer under conditions of described gluing belt body does not occurs burning fire, described fire-retardant list occurs Body damaging problem.
Referring to Figure 11, the sidewall of fire-retardant cylinder 310 offers multiple fire-retardant triggering hole 313, portion of igniting described in each 320 one_to_one corresponding are embedded in a described fire-retardant triggering hole 313, are used for closing fire-retardant triggering hole 313, say, that work as institute State the environment of gluing belt body or described gluing belt body periphery when being not under fired state, described in the portion of igniting be in inoperative shape State, i.e. described in the portion of igniting will not occur fusing or burning, now, described fire-retardant cylinder is in sealing state;But, draw when described Ignited by the described gluing belt body of described burning or affected generation by periphery high temperature when melting phenomenon in combustion portion, described in the portion of igniting can be fast Speed and in time burning or fusion piercing so that described fire-retardant cylinder is in communication with the outside by described fire-retardant triggering hole, i.e. described In fire-retardant cylinder, multiple described flame-retardant monomers are directly in communication with the outside, and are used for causing described flame-retardant monomer to play flame retardant effect, use In aflame described gluing belt body being played fire retardation, and to other burnings at the deposit position of described gluing belt body Thing plays fire retardation, and then plays the effect of fire protection flame retarding, for improving the safety of described heat discoloration type adhesive material Energy.
For the inflammability in portion of igniting described in improving further, and then can be when there is the condition of a fire, it is possible to make described resistance Described flame-retardant monomer in combustion cylinder quickly and in time with extraneous contact, such as, described in the ignite material in portion be inflammable plastics, High temperature or flame are had higher sensitivity, fusing or burning i.e. easily occur in high temperature or flame, specifically, described in draw The material in combustion portion is celluloid (nitrocellulose plastics), and it has certain inflammability, it is possible at described gluing belt body or deposit When putting the material generation burning at the periphery of position, feed back in time, burning occur i.e. in time or melts, making described fire-retardant cylinder pass through Described fire-retardant triggering hole is in communication with the outside, and in the most described fire-retardant cylinder, multiple described flame-retardant monomers are directly in communication with the outside, and are used for Described flame-retardant monomer is caused to play flame retardant effect, for aflame described gluing belt body is played fire retardation, and to institute State other comburants at the deposit position of gluing belt body and play fire extinguishing function, and then play the effect of fire protection flame retarding, be used for carrying The security performance of high described heat discoloration type adhesive material.Additionally, in conjunction with the extinguishing effect of described fire extinguishing monomer so that both Synergism, it is possible to further enhance fire extinguishing flame retardant effect and the security performance of described heat discoloration type adhesive material.
Such as, ignite described in the portion's identical setting of shape with described fire-retardant triggering hole;And for example, the number in described fire-retardant triggering hole Amount, the dense degree of described fire-retardant triggering pore size distribution, the diameter in described fire-retardant triggering hole, described in ignite the thickness in portion and described Ignite the size in portion, be adjusted according to actual needs, e.g., according to size, the described fire-retardant cylinder of described fire extinguishing honeycomb cylinder Safe coefficient at the size of body and/or deposit position is adjusted, as long as the portion of igniting described in guaranteeing can feed back in time The condition of a fire, described fire-retardant cylinder and outside contact area and described in ignite the structural strength in portion, such as, described fire-retardant cylinder A diameter of 2.5cm~3.5cm of body, a diameter of 2.4cm~3.4cm in described fire-retardant triggering hole, described in the ignite thickness in portion be 2mm~4.5mm, owing to above-mentioned numerical value is limited by the overall dimensions of described reel, at this no longer to more concrete numerical value Repeat.
Seeing also Figure 17 to Figure 19, flame-retardant monomer 312 includes inflammable shell 3121, flame resistant filler portion 3122 and fire-retardant Air bag 3123, flame resistant filler portion 3122 is filled with in inflammable shell 3121, and multiple fire-retardant air bags 3123 are all placed in described In inflammable shell 3121, and fire-retardant air bag 3123 contacts with flame resistant filler portion 3122, when described portion of igniting is by the institute of described burning State gluing belt body burning or by periphery high temperature affected generation melt phenomenon time, described in the portion of igniting can quickly and in time be melted or Burning so that described fire-retardant cylinder is in communication with the outside by described fire-retardant triggering hole, multiple in the most described fire-retardant cylinder described in go out When fire monomer is directly in communication with the outside, now, inflammable shell 3121 is affected by extraneous high temperature or flame, also can occur Burning or melting phenomenon, now, flame resistant filler portion 3122 can flow directed along the described fire-retardant triggering hole of described fire-retardant cylinder Go out to the external world, e.g., flow out on aflame described gluing belt body or on periphery comburant, at these comburants Form isolation liquid film or penetrate in comburant, thus play the effect of certain starvation and cooling, be used for playing fire-retardant Effect.Such as, the material of described inflammable shell is inflammable plastics, has higher sensitivity to high temperature or flame, i.e. easily exists Fusing or burning occur in high temperature or flame, and specifically, the material of described inflammable shell is celluloid (nitrocellulose plastics), its Having certain inflammability, described inflammable shell is easily destroyed by high temperature or flame, so can preferably make with inflammable outside Described flame resistant filler portion in shell produces fire retardation, in conjunction with the effect of described fire extinguishing monomer so that both produce collaborative work With, the most described fire extinguishing monomer produces the extinguishing effect of starvation in main body for producing, and described flame-retardant monomer is used for into one Step reduces contacting of comburant and oxygen, and then it can be avoided that the spreading of the intensity of a fire, it is to avoid there is large-scale fire, security performance Higher.
In order to make described flame resistant filler portion play preferable flame retardant effect, such as, the material in described flame resistant filler portion is water, So, so, the external world is flowed out to when described flame resistant filler portion, i.e. water directed along the described fire-retardant triggering hole of described fire-retardant cylinder In, e.g., flow out on aflame described gluing belt body or on periphery comburant, it is possible on these comburants, form isolation Liquid film or penetrate in comburant, thus play the effect of certain starvation and cooling, it is used for playing flame retardant effect, as This, it is possible to play, with described fire extinguishing filling part, the effect that collaborative fire extinguishing is fire-retardant.
Additionally, described fire-retardant air bag also can release fire-retardant gas, such as nitrogen, it is possible to further function as fire-retardant effect, example As, it is equipped with nitrogen in described fire-retardant air bag, for starvation to a certain extent, and for example, described fire-retardant air bag includes sky Nitrogen accommodating in the utricule of the heart and described utricule, and for example, described utricule is plastic sheeting, e.g., polyethylene film, it is possible at height The lower rapid melting of temperature, and then release the nitrogen in described utricule, for playing the effect of assisting flame-resistant.
It is further preferred that due to fluid during described flame resistant filler portion, described fire-retardant air bag is at described flame resistant filler Position in portion is not fixing, and the most described fire-retardant air bag position in described inflammable shell is not fixing, such as, Referring to Figure 19, now, multiple fire-retardant air bags 3123 are in released state, and its reason is: described heat discoloration type adhesive material Being in transport carrying state, the most described the most described flame-retardant monomer of fire-retardant cylinder is in vibrations or vibrating state, based on described The active force that the interior flowing in described inflammable shell of the flame resistant filler portion produces makes multiple fire-retardant air bag 3123 be in released state, As, unordered or orderly released state, and for example, when multiple described fire-retardant air bags are in the state being connected with each other or mutually supporting Time, e.g., effect based on buoyancy, described fire-retardant air bag supports with the medial wall of described inflammable shell, and its reason is: described temperature-sensitive During color changing type adhesive material remains static, e.g., it is in storage configuration.
Such as, the number of described flame-retardant monomer and size can be adjusted flexibly, and such as, described fire extinguishing monomer has hollow Cylinder-like structure;And for example, a diameter of 2.1cm~3.1cm of described fire extinguishing monomer, and for example, the lateral wall of described flame-retardant monomer Supporting with the medial wall of described fire-retardant cylinder or fixing, multiple described flame-retardant monomer spread configurations are in a described fire-retardant cylinder Portion, the most multiple described flame-retardant monomers head and the tail connect;And for example, when the size of described fire-retardant cylinder cylinder is bigger, described fire-retardant cylinder Body can house multiple described flame-retardant monomer in the axial direction.
Such as, described gluing belt body stacks gradually and is wound on described fire extinguishing honeycomb cylinder and described fire-retardant cylinder;And for example, institute State gluing belt body to stack gradually on the lateral wall of lateral wall and the described fire-retardant cylinder being wound in described fire extinguishing honeycomb cylinder;And for example, Described gluing belt body stacks gradually on the outward flange of outward flange and the described fire-retardant cylinder being wound in described fire extinguishing honeycomb cylinder.
Referring to Fig. 2, capping 400 covers at the aperture position of described fixing cylinder, the opening position of described fire extinguishing honeycomb cylinder Put at the aperture position of place and described fire-retardant cylinder, be used for closing off described rotation cavity, described fire extinguishing cavity and described Fire-retardant cavity, capping 400 offers rotation hole, and described rotary shaft wears described rotation hole, and described rotary shaft is relatively described Capping rotates.Such as, described reel arranges two described cappings, and two described cappings are for encapsulating the two of described reel respectively End, plays the described rotation cavity of closing, described fire extinguishing cavity and the effect of described fire-retardant cavity.
Such as, described capping is that hollow is arranged, and its material is inflammable plastics, plays formation prompting cavity, described prompting chamber Internal being equipped with allyl isosulfocyanate, when there is the condition of a fire, there is burning or fusing, described isothiocyanic acid allyl in described capping Ester can volatilize irritative gas in a large number, for reminding staff to have the condition of a fire to occur.
Such as, described fixed cylinder, described fire extinguishing honeycomb cylinder and described fire-retardant cylinder are aluminum alloy material, and three is not Can burn, and light, mechanical strength is preferable, it is also possible to recycle.
Such as, above-mentioned heat discoloration type adhesive material is by arranging the reel described in any of the above-described embodiment, especially suitable In a large amount of warehouses stacking adhesive material, and make large-sized adhesive material.
It should be noted that other embodiments of the present invention also include that the technical characteristic in the various embodiments described above be combined with each other The heat discoloration type adhesive material that can implement formed.
Each technical characteristic of embodiment described above can combine arbitrarily, for making description succinct, not to above-mentioned reality The all possible combination of each technical characteristic executed in example is all described, but, as long as the combination of these technical characteristics is not deposited In contradiction, all it is considered to be the scope that this specification is recorded.
The above embodiment only have expressed the several embodiments of the present invention, and it describes more concrete and detailed, but Therefore the restriction to the scope of the claims of the present invention can not be interpreted as.It should be pointed out that, for the ordinary skill people of this area For Yuan, without departing from the inventive concept of the premise, it is also possible to make some deformation and improvement, these broadly fall into the present invention's Protection domain.Therefore, the protection domain of patent of the present invention should be as the criterion with claims.

Claims (7)

1. a heat discoloration type adhesive material, it is characterised in that including:
Gluing belt body and reel, described gluing belt body stacks gradually and is wound on described reel, and described gluing belt body includes successively Substrate layer, adhesive layer and the adherent layer that stacking is arranged, two sides of described substrate layer protrude respectively and are provided with a positive stop strip, Surrounding a storage tank between two described positive stop strips, described adhesive layer is placed in described storage tank, and described adherent layer and institute State positive stop strip laminating;
Described substrate layer includes that base material layering and heat discoloration layering, two described positive stop strips are respectively arranged at the layering of described base material Two sides on, the layering of described heat discoloration fits in the layering of described base material away from the one side of described adhesive layer;
The layering of described heat discoloration includes each component of following mass parts:
Polyethylene terephthalate 10 parts~50 parts;
Polydimethylsiloxane 1 part~3.5 parts;
1 part~1.5 parts of heat discoloration powder.
Heat discoloration type adhesive material the most according to claim 1, it is characterised in that described heat discoloration layering include as Each component of lower mass parts:
Polyethylene terephthalate 15 parts~46.8 parts;
Polydimethylsiloxane 1.5 parts~2.4 parts;
1.1 parts~1.5 parts of heat discoloration powder.
Heat discoloration type adhesive material the most according to claim 2, it is characterised in that described heat discoloration layering include as Each component of lower mass parts:
Polyethylene terephthalate 23.5 parts~46.5 parts;
Polydimethylsiloxane 2.1 parts~2.4 parts;
1.3 parts~1.5 parts of heat discoloration powder.
Heat discoloration type adhesive material the most according to claim 3, it is characterised in that described heat discoloration layering include as Each component of lower mass parts:
Polyethylene terephthalate 45.5 parts;
Polydimethylsiloxane 2.2 parts;
1.4 parts of heat discoloration powder.
Heat discoloration type adhesive material the most according to claim 1, it is characterised in that the thickness of described base material layering and institute The thickness proportion stating heat discoloration layering is 1:(0.9~1.2).
Heat discoloration type adhesive material the most according to claim 5, it is characterised in that the thickness of described base material layering and institute The thickness proportion stating heat discoloration layering is 1:(1.1~1.2).
Heat discoloration type adhesive material the most according to claim 6, it is characterised in that the thickness of described base material layering and institute The thickness proportion stating heat discoloration layering is 1:1.2.
CN201610705388.4A 2016-08-22 2016-08-22 Temperature-sensitive color-changing adhesive material Active CN106281089B (en)

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Cited By (6)

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CN109294472A (en) * 2018-10-22 2019-02-01 江苏东台实力工业材料有限公司 A kind of porous permeable formula adhesive tape and preparation method thereof
CN109370467A (en) * 2018-10-22 2019-02-22 江苏东台实力工业材料有限公司 A kind of filled type adhesive tape and preparation method thereof
CN109370464A (en) * 2018-10-22 2019-02-22 江苏东台实力工业材料有限公司 A kind of middle transition formula adhesive tape and preparation method thereof
CN109370466A (en) * 2018-10-22 2019-02-22 江苏东台实力工业材料有限公司 A kind of internal frame formula adhesive tape and preparation method thereof
CN109370468A (en) * 2018-10-22 2019-02-22 江苏东台实力工业材料有限公司 A kind of twisted formula adhesive tape and preparation method thereof
CN114989743A (en) * 2022-07-15 2022-09-02 上海商寰航空科技有限公司 Adhesive thermochromic identification adhesive tape and preparation method thereof

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CN104845543A (en) * 2014-12-31 2015-08-19 东莞市纳利光学材料有限公司 High-transmittance protective film capable of automatically adjusting color and preparation method

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Publication number Priority date Publication date Assignee Title
CN2552693Y (en) * 2002-07-11 2003-05-28 焦林 Cell label with insulating sealing edge
CN104845543A (en) * 2014-12-31 2015-08-19 东莞市纳利光学材料有限公司 High-transmittance protective film capable of automatically adjusting color and preparation method

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109294472A (en) * 2018-10-22 2019-02-01 江苏东台实力工业材料有限公司 A kind of porous permeable formula adhesive tape and preparation method thereof
CN109370467A (en) * 2018-10-22 2019-02-22 江苏东台实力工业材料有限公司 A kind of filled type adhesive tape and preparation method thereof
CN109370464A (en) * 2018-10-22 2019-02-22 江苏东台实力工业材料有限公司 A kind of middle transition formula adhesive tape and preparation method thereof
CN109370466A (en) * 2018-10-22 2019-02-22 江苏东台实力工业材料有限公司 A kind of internal frame formula adhesive tape and preparation method thereof
CN109370468A (en) * 2018-10-22 2019-02-22 江苏东台实力工业材料有限公司 A kind of twisted formula adhesive tape and preparation method thereof
CN114989743A (en) * 2022-07-15 2022-09-02 上海商寰航空科技有限公司 Adhesive thermochromic identification adhesive tape and preparation method thereof

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