CN106280702A - A kind of noble metal preparation of silk screen printing - Google Patents

A kind of noble metal preparation of silk screen printing Download PDF

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Publication number
CN106280702A
CN106280702A CN201610668957.2A CN201610668957A CN106280702A CN 106280702 A CN106280702 A CN 106280702A CN 201610668957 A CN201610668957 A CN 201610668957A CN 106280702 A CN106280702 A CN 106280702A
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CN
China
Prior art keywords
noble metal
screen printing
silk screen
preparation
metal preparation
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610668957.2A
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Chinese (zh)
Inventor
杨任松
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shantou City Jin New Materials Co Ltd
Original Assignee
Shantou City Jin New Materials Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shantou City Jin New Materials Co Ltd filed Critical Shantou City Jin New Materials Co Ltd
Priority to CN201610668957.2A priority Critical patent/CN106280702A/en
Publication of CN106280702A publication Critical patent/CN106280702A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/02Printing inks
    • C09D11/10Printing inks based on artificial resins
    • C09D11/106Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C09D11/107Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds from unsaturated acids or derivatives thereof
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/02Printing inks
    • C09D11/03Printing inks characterised by features other than the chemical nature of the binder
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/02Printing inks
    • C09D11/03Printing inks characterised by features other than the chemical nature of the binder
    • C09D11/033Printing inks characterised by features other than the chemical nature of the binder characterised by the solvent

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Printing Methods (AREA)
  • Inks, Pencil-Leads, Or Crayons (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)

Abstract

The invention discloses the noble metal preparation of a kind of silk screen printing, it carries out noble metal decoration at substrate surface, and described base material includes pottery, glass or porcelain, and described decorating method uses direct silk screen printing or indirect screen printing.The invention provides long shelf-life, adhesive force is good, and has the noble metal preparation of cracking resistance and good rheological performance, solves the technological deficiency of existing existence.

Description

A kind of noble metal preparation of silk screen printing
Technical field
The invention belongs to printing technology, be specifically related to the noble metal preparation of a kind of silk screen printing.
Background technology
For producing noble metal decoration on decoration, the base material that can fire, typically contain one or more gold, silver, rhodium, Bismuth, aluminum, silicon and other base metal resinate, its printing quality is that the adhesive system consisted of resin compound improves 's.Adhesive system has the biggest relation, current binding agent shelf-life to shelf-life and the printing quality of noble metal preparation Too short, easily become viscous or thinning.
Summary of the invention
It is an object of the invention to provide a kind of long shelf-life, adhesive force is good, and has cracking resistance and good rheological performance Noble metal preparation, solves the technological deficiency of existing existence.
The noble metal preparation of a kind of silk screen printing, carries out noble metal decoration at substrate surface, described base material include pottery, Glass or porcelain, described decorating method uses direct silk screen printing or indirect screen printing.
Described decoration formula includes precious metal material, binding agent, thixotropic agent, solvent and defoamer, and its proportioning is as follows: your gold Belong to material 22-30 part, binding agent 20-45 part, thixotropic agent 0.1-3 part, solvent 30-45 part and defoamer 0.5-2 part.
Described precious metal material uses mercaptan gold/palladium/platinum or noble metal organic compound.
Described noble metal organic compound employing industrialization organic precious metal compounds, employing isooctyl acid silver/rhodium/bismuth/chromium/ Aluminum/silicon.
Described binding agent uses plasticizing methacrylic resin.
Described thixotropic agent is the mixture of castor oil hydrogenated, polyamide wax, polyureas.
The regulation ratio of described thixotropic agent is castor oil hydrogenated: polyamide wax: polyureas=1:0.3-0.5:0.1-0.4.
Described solvent uses Ketohexamethylene, naphthane or ketone.
Its preparation process is as follows:
Step 1, weighs raw material on request;
Step 2, heats mix and blend by binding agent, precious metal material and solvent, until stirring, heating-up temperature is 60-70 DEG C, mixing speed is 1000-2000r/min, and mixing time is 10-15min;
Step 3, by adding thixotropic agent under the conditions of constant temperature 60 DEG C, naturally cools to room temperature after stirring, mixing speed is 1500- 2000r/min, mixing time is 5-9min;
Step 4, i.e. can get final products after stirring at normal temperature 1-2min.
Compared with prior art, the method have the advantages that
1, preparation method of the present invention can obtain by being directly or indirectly printed onto on glass, pottery or the porcelain base material that can fire Decorative effect is honorable, without the noble metal decoration of cracking.
2, the present invention provides a kind of long shelf-life, and adhesive force is good, and has the noble metal of cracking resistance and good rheological performance Preparation, solves the technological deficiency of existing existence.
Detailed description of the invention
Below in conjunction with embodiment, the present invention is described further:
Embodiment 1
The noble metal preparation of a kind of silk screen printing, carries out noble metal decoration at substrate surface, and described base material includes pottery, described Decorating method uses direct silk screen printing.
Described decoration formula includes precious metal material, binding agent, thixotropic agent, solvent and defoamer, and its proportioning is as follows: your gold Belong to material 22 parts, binding agent 20 parts, thixotropic agent 0.1 part, solvent 30 parts and defoamer 0.5 part.
Described precious metal material uses mercaptan
Described binding agent uses plasticizing methacrylic resin.
Described thixotropic agent is the mixture of castor oil hydrogenated, polyamide wax, polyureas.
The regulation ratio of described thixotropic agent is castor oil hydrogenated: polyamide wax: polyureas=1:0.3:0.1.
Described solvent uses Ketohexamethylene.
Its preparation process is as follows:
Step 1, weighs raw material on request;
Step 2, heats mix and blend by binding agent, precious metal material and solvent, until stirring, heating-up temperature is 60 DEG C, Mixing speed is 1000r/min, and mixing time is 10min;
Step 3, by adding thixotropic agent under the conditions of constant temperature 60 DEG C, naturally cools to room temperature after stirring, mixing speed is 1500r/min, mixing time is 5min;
Step 4, i.e. can get final products after stirring at normal temperature 1min.
Embodiment 2
The noble metal preparation of a kind of silk screen printing, carries out noble metal decoration at substrate surface, and described base material includes glass, described Decorating method uses direct silk screen printing or indirect screen printing.
Described decoration formula includes precious metal material, binding agent, thixotropic agent, solvent and defoamer, and its proportioning is as follows: your gold Belong to material 30 parts, binding agent 45 parts, thixotropic agent 3 parts, solvent 45 parts and defoamer 2 parts.
Described precious metal material uses mercaptan palladium.
Described binding agent uses plasticizing methacrylic resin.
Described thixotropic agent is the mixture of castor oil hydrogenated, polyamide wax, polyureas.
The regulation ratio of described thixotropic agent is castor oil hydrogenated: polyamide wax: polyureas=1:0.5:0.4.
Described solvent uses naphthane.
Its preparation process is as follows:
Step 1, weighs raw material on request;
Step 2, heats mix and blend by binding agent, precious metal material and solvent, until stirring, heating-up temperature is 70 DEG C, Mixing speed is 2000r/min, and mixing time is 15min;
Step 3, by adding thixotropic agent under the conditions of constant temperature 60 DEG C, naturally cools to room temperature after stirring, mixing speed is 2000r/min, mixing time is 9min;
Step 4, i.e. can get final products after stirring at normal temperature 2min.
Embodiment 3
The noble metal preparation of a kind of silk screen printing, carries out noble metal decoration at substrate surface, and described base material includes pottery, glass Or porcelain, described decorating method uses direct silk screen printing or indirect screen printing.
Described decoration formula includes precious metal material, binding agent, thixotropic agent, solvent and defoamer, and its proportioning is as follows: your gold Belong to material 26 parts, binding agent 37 parts, thixotropic agent 1.5 parts, solvent 28 parts and defoamer 1.4 parts.
Described noble metal organic compound uses industrialization organic precious metal compounds, uses isooctyl acid silver.
Described binding agent uses plasticizing methacrylic resin.
Described thixotropic agent is the mixture of castor oil hydrogenated, polyamide wax, polyureas.
The regulation ratio of described thixotropic agent is castor oil hydrogenated: polyamide wax: polyureas=1:0.4:0.3.
Acetone adopted by described solvent.
Its preparation process is as follows:
Step 1, weighs raw material on request;
Step 2, heats mix and blend by binding agent, precious metal material and solvent, until stirring, heating-up temperature is 65 DEG C, Mixing speed is 1500r/min, and mixing time is 12min;
Step 3, by adding thixotropic agent under the conditions of constant temperature 60 DEG C, naturally cools to room temperature after stirring, mixing speed is 1800r/min, mixing time is 7min;
Step 4, i.e. can get final products after stirring at normal temperature 1.5min.
The foregoing is only one embodiment of the invention, be not limiting as the present invention, all employing equivalents or equivalent transformation The technical scheme that obtained of mode, all fall within protection scope of the present invention.

Claims (9)

1. the noble metal preparation of a silk screen printing, it is characterised in that: it carries out noble metal decoration, described base at substrate surface Material includes pottery, glass or porcelain, and described decorating method uses direct silk screen printing or indirect screen printing.
2. according to the noble metal preparation of a kind of silk screen printing described in claims 1, it is characterised in that described decoration formula Including precious metal material, binding agent, thixotropic agent, solvent and defoamer, its proportioning is as follows: precious metal material 22-30 part, binding agent 20-45 part, thixotropic agent 0.1-3 part, solvent 30-45 part and defoamer 0.5-2 part.
3. according to the noble metal preparation of a kind of silk screen printing described in claims 2, it is characterised in that described noble metal material Material uses mercaptan gold/palladium/platinum or noble metal organic compound.
4. according to the noble metal preparation of a kind of silk screen printing described in claims 3, it is characterised in that described noble metal has Machine compound uses industrialization organic precious metal compounds, uses isooctyl acid silver/rhodium/bismuth/chromium/aluminum/silicon.
5. according to the noble metal preparation of a kind of silk screen printing described in claims 2, it is characterised in that described binding agent is adopted With plasticizing methacrylic resin.
6. according to the noble metal preparation of a kind of silk screen printing described in claims 2, it is characterised in that described thixotropic agent is Castor oil hydrogenated, polyamide wax, the mixture of polyureas.
7. according to the noble metal preparation of a kind of silk screen printing described in claims 6, it is characterised in that described thixotropic agent Regulation ratio is castor oil hydrogenated: polyamide wax: polyureas=1:0.3-0.5:0.1-0.4.
8. according to the noble metal preparation of a kind of silk screen printing described in claims 2, it is characterised in that described solvent uses Ketohexamethylene, naphthane or ketone.
9. according to the noble metal preparation of a kind of silk screen printing described in claims 2, it is characterised in that its preparation process is such as Under:
Step 1, weighs raw material on request;
Step 2, heats mix and blend by binding agent, precious metal material and solvent, until stirring, heating-up temperature is 60-70 DEG C, mixing speed is 1000-2000r/min, and mixing time is 10-15min;
Step 3, by adding thixotropic agent under the conditions of constant temperature 60 DEG C, naturally cools to room temperature after stirring, mixing speed is 1500- 2000r/min, mixing time is 5-9min;
Step 4, i.e. can get final products after stirring at normal temperature 1-2min.
CN201610668957.2A 2016-08-15 2016-08-15 A kind of noble metal preparation of silk screen printing Pending CN106280702A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610668957.2A CN106280702A (en) 2016-08-15 2016-08-15 A kind of noble metal preparation of silk screen printing

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610668957.2A CN106280702A (en) 2016-08-15 2016-08-15 A kind of noble metal preparation of silk screen printing

Publications (1)

Publication Number Publication Date
CN106280702A true CN106280702A (en) 2017-01-04

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112735631A (en) * 2020-12-21 2021-04-30 有研工程技术研究院有限公司 Low-viscosity organic gold paste capable of being sintered on surface of circuit board substrate at low temperature

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1060483A (en) * 1990-09-14 1992-04-22 日本金液株式会社 The overglaze color composition that contains precious metal that is used for pottery
CN1097230A (en) * 1993-05-13 1995-01-11 三菱电机株式会社 Metal lagging and manufacture method thereof
CN1241544A (en) * 1998-07-11 2000-01-19 凯尔迪克陶瓷颜料股份公司 Noble metal preparation and its use to produce noble metal decorations by direct and indirect printing
CN1531577A (en) * 2000-10-13 2004-09-22 �����ɷ� Noble metal preparation and use thereof for production of noble metal decorations by means of direct and indirect printing
CN1637096A (en) * 2003-12-17 2005-07-13 W.C.贺利氏有限公司 Noble metal preparations and lustring preparations for direct and indirect screen printing
CN1753957A (en) * 2003-02-28 2006-03-29 费柔股份有限公司 Radiohardenable printing media, transfer pictures produced therewith, and method for producing ceramic decorations
CN101555163A (en) * 2009-05-13 2009-10-14 深圳市永丰源实业有限公司 Noble metal preparation or luster preparation for direct or indirect silk screen printing
CN101781093A (en) * 2010-01-19 2010-07-21 深圳市永丰源实业有限公司 Noble metal preparation with stable microwave resistant function and manufacturing process and application thereof

Patent Citations (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1060483A (en) * 1990-09-14 1992-04-22 日本金液株式会社 The overglaze color composition that contains precious metal that is used for pottery
CN1097230A (en) * 1993-05-13 1995-01-11 三菱电机株式会社 Metal lagging and manufacture method thereof
CN1241544A (en) * 1998-07-11 2000-01-19 凯尔迪克陶瓷颜料股份公司 Noble metal preparation and its use to produce noble metal decorations by direct and indirect printing
CN1151088C (en) * 1998-07-11 2004-05-26 凯尔迪克陶瓷颜料股份公司 Noble metal preparation and its use to produce noble metal decorations by direct and indirect printing
CN1531577A (en) * 2000-10-13 2004-09-22 �����ɷ� Noble metal preparation and use thereof for production of noble metal decorations by means of direct and indirect printing
CN1242004C (en) * 2000-10-13 2006-02-15 费柔股份有限公司 Noble metal preparation and use thereof for production of noble metal decorations by means of direct and indirect printing
CN1753957A (en) * 2003-02-28 2006-03-29 费柔股份有限公司 Radiohardenable printing media, transfer pictures produced therewith, and method for producing ceramic decorations
CN1637096A (en) * 2003-12-17 2005-07-13 W.C.贺利氏有限公司 Noble metal preparations and lustring preparations for direct and indirect screen printing
CN100339450C (en) * 2003-12-17 2007-09-26 W.C.贺利氏有限公司 Noble metal preparations and lustring preparations for direct and indirect screen printing
CN101555163A (en) * 2009-05-13 2009-10-14 深圳市永丰源实业有限公司 Noble metal preparation or luster preparation for direct or indirect silk screen printing
CN101781093A (en) * 2010-01-19 2010-07-21 深圳市永丰源实业有限公司 Noble metal preparation with stable microwave resistant function and manufacturing process and application thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112735631A (en) * 2020-12-21 2021-04-30 有研工程技术研究院有限公司 Low-viscosity organic gold paste capable of being sintered on surface of circuit board substrate at low temperature

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