CN106280189A - Aging resistance HIPS plastic - Google Patents
Aging resistance HIPS plastic Download PDFInfo
- Publication number
- CN106280189A CN106280189A CN201610686093.7A CN201610686093A CN106280189A CN 106280189 A CN106280189 A CN 106280189A CN 201610686093 A CN201610686093 A CN 201610686093A CN 106280189 A CN106280189 A CN 106280189A
- Authority
- CN
- China
- Prior art keywords
- ester
- phenyl
- aging resistance
- tricresyl phosphate
- hips
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
- C08K13/02—Organic and inorganic ingredients
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/04—Carbon
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
- C08K3/36—Silica
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/17—Amines; Quaternary ammonium compounds
- C08K5/18—Amines; Quaternary ammonium compounds with aromatically bound amino groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
- C08K5/51—Phosphorus bound to oxygen
- C08K5/52—Phosphorus bound to oxygen only
- C08K5/521—Esters of phosphoric acids, e.g. of H3PO4
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/20—Applications use in electrical or conductive gadgets
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a kind of aging resistance HIPS plastic, the raw material of following weight parts be prepared from: HIPS 95 105 parts, silicon dioxide 5 15 parts, activated carbon 6 16 parts, fire retardant 15 parts, 0.6 1.8 parts of antioxidant.A kind of aging resistance HIPS plastic of the present invention, by rational proportioning, preferably go out to be suitable for improve the inorganic filler of plastics, fire retardant, the kind of antioxidant and consumption, improve fire resistance, ageing resistace and intensity, can be widely used in preparing household appliances shell.
Description
Technical field
The present invention relates to a kind of plastics, particularly relate to a kind of aging resistance HIPS plastic.
Background technology
Since Germany scientist Bayer synthetic phenolic resin first in 1872, the research of macromolecular material with should
Have become as one of most important material with having obtained development at full speed, especially plastics, be widely used in each of national economy
Individual field.Plastic, with the profile of its grace, gay colours and cheap price, has light weight, anti-corrosion, insulating properties simultaneously
The advantages such as good, specific strength height, processing technique are simple, with low cost so that it is quite varied in household electrical appliances sector application.
Along with science and technology and economic development, the daily living article of plastics-production play in daily life more to come
The most important effect.But plastics easy firing, and burning velocity is fast, can produce a large amount of toxic gas according to statistics, according to statistics, fire
The middle casualties because suffocating and smoke poisoning causes accounts for the 50-80% of the total number of casualties of fire.Along with plastics are in building, family
The extensive application of the aspects such as tool, traffic, Aeronautics and Astronautics, electrical equipment, simultaneously because the fire that plastic products cause is the most innumerable, fire
Calamity situation allows of no optimist, and some fire disaster accidents occur again and again, and is much all the combustible material such as nylon wire, polyurethane foam
Burning rapidly, shines into people's casualties and the loss of property.Most of plastics are all inflammable substances, but building at plastics
Build material, transportation material, home electric appliance material etc. to be required for plastic and do not burn, have good fire resistance, it is desirable to
Plastics degree of being fuming in big fire is little.To this end, in plastic formula, select to add fire retardant and just become extremely important.Resistance
Combustion agent initially uses in the U.S., and after the sixties in 20th century, consumption increases severely, and current consumption is only second to plasticizer.Consumption fire retardant is most
Plastics variety be polrvinyl chloride, polystyrene, polyurethane foam plastics, unsaturated polyester (UP), ABS resin and polypropylene.People
Life in, at present now a lot of formula of flame-retardant plastics produce toxic gas and cause poison and cigarette in fire when materials pyrolysis
Human body is suffocated side effect by gas, and the serious physical and mental health damaging people, environmental-protecting performance is the most undesirable.In recent years, electronic apparatus, build
Build, higher requirement that the performance of plastics is proposed by the fast development of aviation and automobile industry.Wherein, the plastics of flame retardant type are difficult to
Burning, rate of flame propagation is little, and mass loss rate and heat release rate are relatively low, and has certain self-extinguishment.
The invention provides a kind of plastics, intensity is high, and has the aging resistance of excellence, fire resistance.
Summary of the invention
For above-mentioned deficiency present in prior art, the technical problem to be solved is to provide a kind of aging resistance
HIPS plastic.
The present invention seeks to be achieved through the following technical solutions:
A kind of aging resistance HIPS plastic, is prepared from by the raw material of following weight parts: HIPS 95-105 part, silicon dioxide
5-15 part, activated carbon 6-16 part, fire retardant 1-5 part, antioxidant 0.6-1.8 part.
Preferably, described fire retardant is three (2-chloroethyl) phosphate ester, tricresyl phosphate (butoxyethyl group) ester, tricresyl phosphate
The mixture of one or more in (1-chloro-2-propyl group) ester.
It is highly preferred that described fire retardant is by three (2-chloroethyl) phosphate ester, tricresyl phosphate (butoxyethyl group) ester, tricresyl phosphate
(1-chloro-2-propyl group) ester mixes, described three (2-chloroethyl) phosphate ester, tricresyl phosphate (butoxyethyl group) ester, tricresyl phosphate (1-
Chloro-2-propyl group) mass ratio of ester is (1-3): (1-3): (1-3).
Preferably, described antioxidant is that N-isopropyl-N-phenyl-pphenylenediamine, N-cyclohexyl-N'-phenyl are to benzene two
Amine, N, the mixture of one or more in N-di-sec-butyl-p-phenyl enediamine.
It is highly preferred that described antioxidant by N-isopropyl-N-phenyl-pphenylenediamine, N-cyclohexyl-N'-phenyl to benzene
Diamidogen, N, N-di-sec-butyl-p-phenyl enediamine mixes, described N-isopropyl-N-phenyl-pphenylenediamine, N-cyclohexyl-N'-benzene
Base p-phenylenediamine, N, the mass ratio of N-di-sec-butyl-p-phenyl enediamine is (1-3): (1-3): (1-3).
A kind of aging resistance HIPS plastic of the present invention, by rational proportioning, preferably goes out to be suitable for improve the inorganic of plastics
Filler, fire retardant, the kind of antioxidant and consumption, improve fire resistance, ageing resistace and intensity, can be widely used in system
Standby household appliances shell.
Detailed description of the invention
Below in conjunction with embodiment, the present invention is described further, the following stated, is only the preferable enforcement to the present invention
Example, not does the restriction of other forms to the present invention, and any those skilled in the art are possibly also with the disclosure above
Technology contents be changed to the Equivalent embodiments that changes on an equal basis.Every without departing from the present invention program content, according to the present invention
Technical spirit any simple modification that following example are done or equivalent variations, all fall within protection scope of the present invention.
Each raw material introduction in embodiment:
HIPS: the concrete HIPS that the trade mark is PH-88 using Taiwan Qimei Industry Co., Ltd. to produce.
Silicon dioxide, No. CAS: 7631-86-9, the concrete model using Guangzhou Science and Technology Ji Sheng Industrial Co to produce
For HB-132, mesh number is the silicon dioxide of 7-40 nanometer.
Activated carbon, No. CAS: 64365-11-3, concrete 320 mesh that upper Asterias amurensis Lutken moon Energy Science Co., Ltd's offer is provided,
Classification is the activated carbon of primary carbon.
Three (2-chloroethyl) phosphate ester, No. CAS: 115-96-8.
Tricresyl phosphate (butoxyethyl group) ester, No. CAS: 78-51-3.
Tricresyl phosphate (1-chloro-2-propyl group) ester, No. CAS: 13674-84-5.
N-isopropyl-N-phenyl-pphenylenediamine, No. CAS: 3085-82-3.
N cyclohexyl N' phenyl P phenylene diamine, No. CAS: 101-87-1.
N, N-di-sec-butyl-p-phenyl enediamine, No. CAS: 101-96-2.
Embodiment 1
Aging resistance HIPS plastic raw material (weight portion): HIPS 100 parts, silicon dioxide 8 parts, activated carbon 8 parts, fire retardant 3
Part, 1.2 parts of antioxidant.
Described fire retardant is by three (2-chloroethyl) phosphate ester, tricresyl phosphate (butoxyethyl group) ester, tricresyl phosphate (the chloro-2-of 1-
Propyl group) ester is uniformly mixed for 1:1:1 in mass ratio and obtains.
Described antioxidant is by N-isopropyl-N-phenyl-pphenylenediamine, N cyclohexyl N' phenyl P phenylene diamine, N, N-
Di-sec-butyl-p-phenyl enediamine is uniformly mixed for 1:1:1 in mass ratio and obtains.
Prepared by aging resistance HIPS plastic:
Joining in high-speed mixer by each component, under room temperature, control rotating speed is at 350 revs/min, mixes 8 minutes, after taking-up
Proceeding in double screw extruder, the processing temperature of double screw extruder 220 DEG C, engine speed is 350 revs/min；Cool down after extrusion
Check rod, air-dried pelletizing.Obtain the aging resistance HIPS plastic of embodiment 1.
Embodiment 2
Substantially the same manner as Example 1, differ only in: described fire retardant is by tricresyl phosphate (butoxyethyl group) ester, phosphoric acid
Three (1-chloro-2-propyl group) ester is uniformly mixed for 1:1 in mass ratio and obtains.Obtain the aging resistance HIPS plastic of embodiment 2.
Embodiment 3
Substantially the same manner as Example 1, differ only in: described fire retardant is by three (2-chloroethyl) phosphate ester, tricresyl phosphate
(1-chloro-2-propyl group) ester is uniformly mixed for 1:1 in mass ratio and obtains.Obtain the aging resistance HIPS plastic of embodiment 3.
Embodiment 4
Substantially the same manner as Example 1, differ only in: described fire retardant is by three (2-chloroethyl) phosphate ester, tricresyl phosphate
(butoxyethyl group) ester is uniformly mixed for 1:1 in mass ratio and obtains.Obtain the aging resistance HIPS plastic of embodiment 4.
Embodiment 5
Substantially the same manner as Example 1, differ only in: described antioxidant by N cyclohexyl N' phenyl P phenylene diamine,
N, N-di-sec-butyl-p-phenyl enediamine is uniformly mixed for 1:1 in mass ratio and obtains.The aging resistance HIPS obtaining embodiment 5 moulds
Material.
Embodiment 6
Substantially the same manner as Example 1, differ only in: described antioxidant by N-isopropyl-N-phenyl-pphenylenediamine,
N, N-di-sec-butyl-p-phenyl enediamine is uniformly mixed for 1:1 in mass ratio and obtains.The aging resistance HIPS obtaining embodiment 6 moulds
Material.
Embodiment 7
Substantially the same manner as Example 1, differ only in: described antioxidant by N-isopropyl-N-phenyl-pphenylenediamine,
N cyclohexyl N' phenyl P phenylene diamine is uniformly mixed for 1:1 in mass ratio and obtains.Obtain the aging resistance HIPS of embodiment 7
Plastics.
Test case 1
The fire resistance of aging resistance HIPS plastic embodiment 1-7 prepared respectively is tested.Test index is the limit
Oxygen index (OI), (Guangzhou letter standing grain electronics sets to use SH5706 plastic burning oxygen index measurer
Standby company limited) test according to the method for GB/T2406-2009.Concrete outcome is shown in Table 1.
Table 1: test result table
| Limited oxygen index (%) | |
| Embodiment 1 | 38 |
| Embodiment 2 | 28 |
| Embodiment 3 | 30 |
| Embodiment 4 | 27 |
| Embodiment 5 | 32 |
| Embodiment 6 | 32 |
| Embodiment 7 | 33 |
Comparing embodiment 1 and embodiment 2-4, embodiment 1 (three (2-chloroethyl) phosphate ester, tricresyl phosphate (butoxyethyl group)
Ester, tricresyl phosphate (1-chloro-2-propyl group) ester are compounding) fire resistance is substantially better than embodiment 2-4 (three (2-chloroethyl) phosphate ester, phosphorus
In acid three (butoxyethyl group) ester, tricresyl phosphate (1-chloro-2-propyl group) ester, arbitrarily the two is compounding)；Comparing embodiment 1 and embodiment 5-
7, (N-isopropyl-N-phenyl-pphenylenediamine, N cyclohexyl N' phenyl P phenylene diamine, N, N-di-sec-butyl are to benzene for embodiment 1
Diamidogen compounds) fire resistance is substantially better than embodiment 5-7 (N-isopropyl-N-phenyl-pphenylenediamine, N-cyclohexyl-N'-phenyl
P-phenylenediamine, N, in N-di-sec-butyl-p-phenyl enediamine, arbitrarily the two is compounding).
Test case 2
The aging resistance HIPS plastic that embodiment 1-7 is prepared ageing resistace test, old according to hot oxygen
Changing experimental standard GB/T7141-2008, the plastics preparing embodiment 1-7 carry out artificially roughening (90 DEG C, 500h).
Concrete test result is shown in Table 2.
Table 2: ageing resistace test table (90 DEG C, 500h)
Comparing embodiment 1 and embodiment 2-4, embodiment 1 (three (2-chloroethyl) phosphate ester, tricresyl phosphate (butoxyethyl group)
Ester, tricresyl phosphate (1-chloro-2-propyl group) ester are compounding) ageing resistace be substantially better than embodiment 2-4 (three (2-chloroethyl) phosphate ester,
In tricresyl phosphate (butoxyethyl group) ester, tricresyl phosphate (1-chloro-2-propyl group) ester, arbitrarily the two is compounding)；Comparing embodiment 1 and embodiment
5-7, embodiment 1 (N-isopropyl-N-phenyl-pphenylenediamine, N cyclohexyl N' phenyl P phenylene diamine, N, N-di-sec-butyl pair
Phenylenediamine compounds) ageing resistace is substantially better than embodiment 5-7 (N-isopropyl-N-phenyl-pphenylenediamine, N-cyclohexyl-N'-
Diphenyl-para-phenylene diamine, N, in N-di-sec-butyl-p-phenyl enediamine, arbitrarily the two is compounding).
Test case 3
The anti-microbial property of the aging resistance HIPS plastic preparing embodiment 1-7 is tested, and anti-(carefully) bacterium detection is pressed
According to GB GB21551.2-2010, " antibacterial, degerming, the special of purification function anti-biotic material of domestic and similar applications electrical equipment are wanted
Ask " test.Escherichia coli ATYCC 25922, staphylococcus aureus ATCC 6538.Concrete test result is shown in Table 3.
Table 3: anti-microbial property test result table
| Sample | Escherichia coli sterilizing rate, % | Staphylococcus aureus sterilizing rate, % |
| Embodiment 1 | 95.2 | 96.3 |
| Embodiment 2 | 93.1 | 93.4 |
| Embodiment 3 | 92.7 | 94.2 |
| Embodiment 4 | 92.9 | 93.3 |
| Embodiment 5 | 91.8 | 91.2 |
| Embodiment 6 | 92.5 | 91.5 |
| Embodiment 7 | 91.4 | 92.1 |
Comparing embodiment 1 and embodiment 2-4, embodiment 1 (three (2-chloroethyl) phosphate ester, tricresyl phosphate (butoxyethyl group)
Ester, tricresyl phosphate (1-chloro-2-propyl group) ester are compounding) anti-microbial property is substantially better than embodiment 2-4 (three (2-chloroethyl) phosphate ester, phosphorus
In acid three (butoxyethyl group) ester, tricresyl phosphate (1-chloro-2-propyl group) ester, arbitrarily the two is compounding)；Comparing embodiment 1 and embodiment 5-
7, (N-isopropyl-N-phenyl-pphenylenediamine, N cyclohexyl N' phenyl P phenylene diamine, N, N-di-sec-butyl are to benzene for embodiment 1
Diamidogen compounds) anti-microbial property is substantially better than embodiment 5-7 (N-isopropyl-N-phenyl-pphenylenediamine, N-cyclohexyl-N'-phenyl
P-phenylenediamine, N, in N-di-sec-butyl-p-phenyl enediamine, arbitrarily the two is compounding).
Claims (1)
1. an aging resistance HIPS plastic, it is characterised in that be prepared from by the raw material of following weight parts: HIPS 95-105 part,
Silicon dioxide 5-15 part, activated carbon 6-16 part, fire retardant 1-5 part, antioxidant 0.6-1.8 part.
Described fire retardant is by three (2-chloroethyl) phosphate ester, tricresyl phosphate (butoxyethyl group) ester, tricresyl phosphate (1-chloro-2-propyl group)
Ester mixes, described three (2-chloroethyl) phosphate ester, tricresyl phosphate (butoxyethyl group) ester, tricresyl phosphate (1-chloro-2-propyl group) ester
Mass ratio be (1-3): (1-3): (1-3).
Described antioxidant is by N-isopropyl-N-phenyl-pphenylenediamine, N cyclohexyl N' phenyl P phenylene diamine, N, N-di-secondary
Butyl p-phenylenediamine mixes, described N-isopropyl-N-phenyl-pphenylenediamine, N cyclohexyl N' phenyl P phenylene diamine, N,
The mass ratio of N-di-sec-butyl-p-phenyl enediamine is (1-3): (1-3): (1-3).
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610686093.7A CN106280189A (en) | 2016-08-18 | 2016-08-18 | Aging resistance HIPS plastic |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610686093.7A CN106280189A (en) | 2016-08-18 | 2016-08-18 | Aging resistance HIPS plastic |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106280189A true CN106280189A (en) | 2017-01-04 |
Family
ID=57678565
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610686093.7A Withdrawn CN106280189A (en) | 2016-08-18 | 2016-08-18 | Aging resistance HIPS plastic |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106280189A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107118455A (en) * | 2017-05-23 | 2017-09-01 | 东至县科创塑料制品有限公司 | A kind of anti-aging, flame retardant plastics |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103160036A (en) * | 2011-12-16 | 2013-06-19 | 合肥杰事杰新材料股份有限公司 | Anti-flaming high-impact modified polystyrene resin and preparation method thereof |
| CN103951926A (en) * | 2014-05-20 | 2014-07-30 | 上海玉城灿星塑料材料有限公司 | Flame-retardant HIPS (high impact polystyrene) resin and preparation method thereof |
| CN105295281A (en) * | 2015-12-04 | 2016-02-03 | 青岛海信电器股份有限公司 | Shell material of electronic equipment and preparation method thereof |
-
2016
- 2016-08-18 CN CN201610686093.7A patent/CN106280189A/en not_active Withdrawn
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103160036A (en) * | 2011-12-16 | 2013-06-19 | 合肥杰事杰新材料股份有限公司 | Anti-flaming high-impact modified polystyrene resin and preparation method thereof |
| CN103951926A (en) * | 2014-05-20 | 2014-07-30 | 上海玉城灿星塑料材料有限公司 | Flame-retardant HIPS (high impact polystyrene) resin and preparation method thereof |
| CN105295281A (en) * | 2015-12-04 | 2016-02-03 | 青岛海信电器股份有限公司 | Shell material of electronic equipment and preparation method thereof |
Non-Patent Citations (4)
| Title |
|---|
| GEORGE WYPYCH编著，程斌等译: "《填料手册 第二版》", 31 October 2002 * |
| 吴培熙等: "《塑料制品生产工艺手册 第三版》", 31 October 2004 * |
| 李凯等: "《化工行业大气污染控制》", 31 January 2016 * |
| 李祥高等: "《精细化学品化学》", 30 April 2013 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107118455A (en) * | 2017-05-23 | 2017-09-01 | 东至县科创塑料制品有限公司 | A kind of anti-aging, flame retardant plastics |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN106977844B (en) | A kind of environmental protection, fire-retardant PVC wood plastic composite material and preparation method thereof | |
| CN103923412A (en) | PVC (Polyvinyl Chloride) sealing strip and application thereof | |
| CN103087504B (en) | Flame-retardant thermoplastic polyurethane and preparation method thereof | |
| CN102181108A (en) | Crosslinked high flame-retardant foamed polyvinyl chloride modified material | |
| CN104513420B (en) | A kind of Halogen no red phosphorus heat-shrinkable T bush and preparation method thereof | |
| CN102250383A (en) | Halogen-free fire retardant containing benzoxazine and polymer material comprising same | |
| CN103319836A (en) | Highlight flame retarding ABS/PMMA alloy | |
| CN109880248A (en) | A kind of methyl eight bromo ether material flame retardant polystyrene composite and preparation method thereof | |
| CN103450549A (en) | Expansive type halogen-free flame-retardant cable material | |
| CN106280189A (en) | Aging resistance HIPS plastic | |
| CN105038191B (en) | A kind of halogen-free flame-retardant thermoplastic elastomer and preparation method thereof | |
| CN106243565A (en) | White domestic appliances plastics | |
| CN104927316B (en) | A kind of high heat-resisting composite and preparation method thereof | |
| CN103497477B (en) | A kind of HIPS flame retardant plastics | |
| CN106317822A (en) | Infrared signal attenuation-reducing engineering plastic for televisions | |
| CN108359178A (en) | Fire-retardant hollow plate composition and preparation method, fire-retardant hollow plate and its application | |
| CN106336608A (en) | Luminescent plastics for televisions | |
| CN106519553A (en) | ABS flame retardant plastic and preparation method thereof | |
| CN106916403A (en) | A kind of flame retardant plastics | |
| CN101230276A (en) | Novel phosphorous-nitrogen system bittern-free flame-proof material | |
| CN104961973A (en) | Flame-retardant modified plastic | |
| CN106084484A (en) | Refrigerator inner panel aging resistance plastics | |
| CN104356541A (en) | High-tenacity high temperature resistant plastic alloy material | |
| CN106167582A (en) | White domestic appliances modified plastics | |
| CN106117947A (en) | Black household appliances modification HIPS plastic |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WW01 | Invention patent application withdrawn after publication |
Application publication date: 20170104 |
|
| WW01 | Invention patent application withdrawn after publication |