CN103497477B - A kind of HIPS flame retardant plastics - Google Patents
A kind of HIPS flame retardant plastics Download PDFInfo
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- CN103497477B CN103497477B CN201310371466.8A CN201310371466A CN103497477B CN 103497477 B CN103497477 B CN 103497477B CN 201310371466 A CN201310371466 A CN 201310371466A CN 103497477 B CN103497477 B CN 103497477B
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Abstract
The invention discloses a kind of HIPS flame retardant plastics, be made up of following weight parts component: 105-110 mass parts HIPS, 10-15 mass parts nano silicon, 10-15 mass parts melamine cyanurate, 10-15 mass parts glass fibre, 10-12 mass parts metaantimmonic acid are received, 8-11 part vinylbenzene, 14-16 part benzene sulfonamide acid esters, 2-3 part cupric oxalate, 10-20 mass parts triphenyl-thiophosphate and 10 mass parts zirconium whites.The HIPS flame retardant plastics that the present invention obtains has good anti-flaming function, and consumption seldom just obviously can play fire retardation; And do not affect the physical strength of plastics, particularly do not reduce the heat-drawn wire of plastics, mechanics temperature and electrical insulation capability; Be easy in the plastic be uniformly dispersed, good weatherability, persistence is good, makes plastics have long-term flame retardant resistance.
Description
Technical field
The invention belongs to polymeric material field, be specifically related to a kind of HIPS flame retardant plastics.
Technical background
Along with science and technology and economic development, play more and more important effect in daily life by the daily living article of plastics-production.But plastics easy firing, and combustionvelocity is fast, can produce a large amount of toxic gas according to statistics, according to statistics, because the loss of life and personal injury of suffocating and smoke poisoning causes accounts for 50 ~ 80% of the total casualties of fire in fire.Along with the widespread use of plastics in building, furniture, traffic, Aeronautics and Astronautics, electrical equipment etc., the fire simultaneously caused due to plastic products is also innumerable, fire hazard situation allows of no optimist, some fire disaster accidents occur again and again, and be much all that the inflammable material such as nylon wire, polyurethane foam burns rapidly, shine into the loss of people's casualties and property.Most plastics are all inflammable substances, but all need plastics not burn at the material of construction, communications and transportation material, home electric appliance material etc. of plastics, have good flame retardant properties, require that the degree of being fuming of plastics in big fire is little.For this reason, in plastic formula, select to add fire retardant and just become extremely important.Fire retardant uses in the U.S. at first, and after the sixties in 20th century, consumption increases severely, and current consumption is only second to softening agent.The plastics variety consuming fire retardant maximum is polyvinyl chloride, polystyrene, urethane foam, unsaturated polyester, ABS resin and polypropylene.In the life of people, at present now a lot of formula of flame-retardant plastic produces toxic gas and causes poison gas and flue gas in fire to suffocate to human body the physical and mental health of side effect, grievous injury people when materials pyrolysis, and environmental-protecting performance is very undesirable.In recent years, the fast development of electronic apparatus, building, aviation and automobile industry higher requirement that the performance of plastics is proposed.Wherein, the plastics of flame retardant type are nonflammable, and rate of flame propagation is little, mass loss rate and heat release rate lower, and there is certain self-extinguishing.But the flame retardant plastics performance used at present can not meet the demands, and adopts halogen flame more, and combustion processes can be released hydrogen halide and be caused serious harm to human body.So the selection of fire retardant in plastics, be a very complicated process, above-mentioned every factor must be considered.Give such as in existing textbook: the mechanism such as protective membrane mechanism, not so gas mechanism, coolant mechanism and terminating chain lock reactor mechanism; these can select to provide a fuzzy direction to fire retardant, but but cannot provide real effectively helps.
Summary of the invention
For above shortcomings in prior art, the object of the invention is to provide a kind of HIPS flame retardant plastics.
The object of the invention is to be achieved through the following technical solutions: a kind of HIPS flame retardant plastics, is made up of following weight parts component: 105-110 mass parts HIPS, 10-15 mass parts nano silicon, 10-15 mass parts melamine cyanurate, 10-15 mass parts glass fibre, 10-12 mass parts metaantimmonic acid are received, 8-11 part vinylbenzene, 14-16 part benzene sulfonamide acid esters, 2-3 part cupric oxalate, 10-20 mass parts triphenyl-thiophosphate and 10 mass parts zirconium whites.
The beneficial effect that the present invention has: the HIPS flame retardant plastics that the present invention obtains has good anti-flaming function, consumption seldom just obviously can play fire retardation; And do not affect the physical strength of plastics, particularly do not reduce the heat-drawn wire of plastics, mechanics temperature and electrical insulation capability; Be easy in the plastic be uniformly dispersed, good weatherability, persistence is good, makes plastics have long-term flame retardant resistance.
Embodiment
Example of the present invention can not limit the present invention to explanation of the present invention, and any change in the implication suitable with the present invention and scope and adjustment, all should think within the scope of the invention.
embodiment 1
The preparation of HIPS flame retardant plastics: 105-110 mass parts HIPS, 10-15 mass parts nano silicon, 10-15 mass parts melamine cyanurate, 10-15 mass parts glass fibre, 10-12 mass parts metaantimmonic acid are received, the mixing of 8-11 part vinylbenzene, 14-16 part benzene sulfonamide acid esters, 2-3 part cupric oxalate, 10-20 mass parts triphenyl-thiophosphate and 10 mass parts zirconium whites puts into stirrer, put into Banbury mixer banburying after stirring, internally mix temperature is 140-145 DEG C, rotating speed is 900-950rpm; Then by the mixture after banburying through granulator granulation, obtain particle, particle put into tank cooling, then dry at normal temperatures; The salient features of the material that the present embodiment is prepared is as follows: tensile strength MPa(GB/T1040-2006): 35-38, elongation at break %(GB/T1040-2006): 11-12; Shock strength kJ/m
2(GB/T1043-2008): 5.0; Flexural strength MPa(GB/T9341-2000): 42-45; Oxygen index %(GB/T2406-1993): 37; Vertical combustion rank UL-94:V0.Thermotolerance and the flame retardant resistance of flame retardant plastics of the present invention are more excellent, and preparation technology is simple, and product cost is low, and the over-all properties of product is more excellent.
Claims (1)
1. a HIPS flame retardant plastics, is characterized in that being made up of following weight parts component: 105-110 mass parts HIPS, 10-15 mass parts nano silicon, 10-15 mass parts melamine cyanurate, 10-15 mass parts glass fibre, 10-12 mass parts sodium antimonate, 8-11 part vinylbenzene, 14-16 part benzene sulfonamide acid esters, 2-3 part cupric oxalate, 10-20 mass parts triphenyl-thiophosphate and 10 mass parts zirconium whites.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310371466.8A CN103497477B (en) | 2013-08-23 | 2013-08-23 | A kind of HIPS flame retardant plastics |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310371466.8A CN103497477B (en) | 2013-08-23 | 2013-08-23 | A kind of HIPS flame retardant plastics |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103497477A CN103497477A (en) | 2014-01-08 |
| CN103497477B true CN103497477B (en) | 2015-12-09 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310371466.8A Expired - Fee Related CN103497477B (en) | 2013-08-23 | 2013-08-23 | A kind of HIPS flame retardant plastics |
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| CN (1) | CN103497477B (en) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2016056271A (en) | 2014-09-09 | 2016-04-21 | カンナテクノロジー株式会社 | Foam polystyrene resin molding comprising rubber-like latex and melamine cyanurate and method for producing the same |
| CN111423546A (en) * | 2020-05-20 | 2020-07-17 | 界首市亚鑫塑业科技有限公司 | Flame-retardant plastic tray and preparation method thereof |
| CN115395174B (en) * | 2022-09-01 | 2023-06-06 | 欣旺达电动汽车电池有限公司 | Composite diaphragm, secondary battery and electric equipment |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102115579A (en) * | 2010-01-04 | 2011-07-06 | 佛山市顺德区威林工程塑料有限公司 | High-toughness high-glowing-filament-ignition-temperature flame-retardant reinforced PBT (polybutylene terephthalate) material and preparation method thereof |
| CN102888024A (en) * | 2012-10-25 | 2013-01-23 | 上海韬鸿化工科技有限公司 | Composite environment-friendly flame retardant for high impact polystyrene (HIPS), and HIPS flame retardant plastic |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| IL162449A (en) * | 2004-06-10 | 2010-05-17 | Bromine Compounds Ltd | Fire retardant formulations and styrene polymer compositions containing them |
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Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102115579A (en) * | 2010-01-04 | 2011-07-06 | 佛山市顺德区威林工程塑料有限公司 | High-toughness high-glowing-filament-ignition-temperature flame-retardant reinforced PBT (polybutylene terephthalate) material and preparation method thereof |
| CN102888024A (en) * | 2012-10-25 | 2013-01-23 | 上海韬鸿化工科技有限公司 | Composite environment-friendly flame retardant for high impact polystyrene (HIPS), and HIPS flame retardant plastic |
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| CN103497477A (en) | 2014-01-08 |
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Granted publication date: 20151209 Termination date: 20160823 |
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| CF01 | Termination of patent right due to non-payment of annual fee |