CN106280083A - One has high water-disintegrable thin-film material - Google Patents
One has high water-disintegrable thin-film material Download PDFInfo
- Publication number
- CN106280083A CN106280083A CN201610642627.6A CN201610642627A CN106280083A CN 106280083 A CN106280083 A CN 106280083A CN 201610642627 A CN201610642627 A CN 201610642627A CN 106280083 A CN106280083 A CN 106280083A
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- Prior art keywords
- parts
- high water
- thin
- nano
- film material
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08L27/06—Homopolymers or copolymers of vinyl chloride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/18—Manufacture of films or sheets
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2327/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
- C08J2327/02—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
- C08J2327/04—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08J2327/06—Homopolymers or copolymers of vinyl chloride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2463/00—Characterised by the use of epoxy resins; Derivatives of epoxy resins
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/16—Applications used for films
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
Abstract
The invention discloses one and there is high water-disintegrable thin-film material, this thin film is with Corvic, epoxy resin and diethyl phthalate as raw material, also include antioxidant, nano-sized filler, compatilizer and stabilizer, the weight portion of its component is respectively as follows: Corvic 70 80 parts, epoxy resin 40 50 parts, diethyl phthalate 10 15 parts, 13 parts of antioxidant, nano-sized filler 46 parts, compatilizer 24 parts, stabilizer 35 parts.The invention has the beneficial effects as follows: the epoxy resin of interpolation and diethyl phthalate can make the water-disintegrable raising of thin film, the interpolation of other material simultaneously effectively, can improve the stability of thin film, extend service life.
Description
Technical field
The present invention relates to a kind of thin-film material, particularly relate to one and there is high water-disintegrable thin-film material.
Background technology
Thermoplastic elastomer (TPE) due to its excellent extension at break, resilience, wearability, weatherability and more excellent than cast polyurethane
Processing molding method more, and be increasingly widely applied.Especially because the fast development of polyurethane industries among others, promote again
The production capacity of raw material producer constantly expands so that cost constantly declines, thus promotes the new application and development taking turns polyurethane products.But it is existing
The hydrolytic stability of some thermoplastic elastomer (TPE)s is poor.The poor reason of thermoplastic elastomer (TPE) hydrolytic stability is that water penetrates into elasticity
There occurs chemical reaction with the group in thermoplastic elastomer (TPE) after body, create chemical degradation, the chemical composition of elastomer and thing
Manage destructurized, and hydrolysis is irreversible.
Therefore, for solving the problems referred to above, a kind of new technical scheme of special offer.
Summary of the invention
The present invention provides one to have high water-disintegrable thin-film material.
The technical solution used in the present invention is:
One has high water-disintegrable thin-film material, and this thin film is with Corvic, epoxy resin and diethyl phthalate
For raw material, also including antioxidant, nano-sized filler, compatilizer and stabilizer, the weight portion of its component is respectively as follows: polrvinyl chloride tree
Fat 70-80 part, epoxy resin 40-50 part, diethyl phthalate 10-15 part, antioxidant 1-3 part, nano-sized filler 4-6
Part, compatilizer 2-4 part, stabilizer 3-5 part.
Preferably, described stabilizer is organic phosphite, ethylene-vinyl acetate copolymer or stearate.
Preferably, described compatilizer is ethylene propylene diene rubber or polybutylene terephthalate (PBT).
Preferably, described nano-sized filler is nano silicon or nano-calcium carbonate.
The invention has the beneficial effects as follows: the epoxy resin of interpolation and diethyl phthalate can make the water of thin film effectively
Solution improves, and the interpolation of other material simultaneously can improve the stability of thin film, extend service life.
Detailed description of the invention
In order to deepen the understanding of the present invention, below in conjunction with embodiment, the invention will be further described, this embodiment
It is only used for explaining the present invention, is not intended that the restriction to protection scope of the present invention.
Embodiment 1
One has high water-disintegrable thin-film material, and this thin film is with Corvic, epoxy resin and diethyl phthalate
For raw material, also including antioxidant, nano silicon, ethylene propylene diene rubber and organic phosphite, the weight portion of its component divides
It is not: Corvic 70 parts, epoxy resin 40 parts, diethyl phthalate 10 parts, 1 part of antioxidant, nanometer titanium dioxide
Silicon 4 parts, ethylene propylene diene rubber 2 parts, organic phosphite 3 parts.
Embodiment 2
One has high water-disintegrable thin-film material, and this thin film is with Corvic, epoxy resin and diethyl phthalate
For raw material, also include antioxidant, nano-calcium carbonate, polybutylene terephthalate (PBT) and ethylene-vinyl acetate copolymer, its
The weight portion of component is respectively as follows: Corvic 75 parts, epoxy resin 45 parts, diethyl phthalate 12 parts, antioxidant 2
Part, nano-calcium carbonate 5 parts, polybutylene terephthalate (PBT) 3 parts, ethylene-vinyl acetate copolymer 4 parts.
Embodiment 3
One has high water-disintegrable thin-film material, and this thin film is with Corvic, epoxy resin and diethyl phthalate
For raw material, also including antioxidant, nano-calcium carbonate, ethylene propylene diene rubber and stearate, the weight portion of its component is respectively as follows: poly-
Vinyl chloride resin 80 parts, epoxy resin 50 parts, diethyl phthalate 15 parts, 3 parts of antioxidant, nano-calcium carbonate 6 parts, ternary
4 parts of EP rubbers, stearate 5 parts.
The invention has the beneficial effects as follows: the epoxy resin of interpolation and diethyl phthalate can make the water of thin film effectively
Solution improves, and the interpolation of other material simultaneously can improve the stability of thin film, extend service life.
The above, be only presently preferred embodiments of the present invention, is not the limit that the present invention makees any other form
System, and any amendment made according to the technical spirit of the present invention or equivalent variations, still fall within present invention model required for protection
Enclose.
Claims (4)
1. one kind has high water-disintegrable thin-film material, it is characterised in that: this thin film is with Corvic, epoxy resin and adjacent benzene
Dicarboxylate is raw material, also includes antioxidant, nano-sized filler, compatilizer and stabilizer, and the weight portion of its component is respectively
For: Corvic 70-80 part, epoxy resin 40-50 part, diethyl phthalate 10-15 part, antioxidant 1-3 part, receive
Scaled fillers 4-6 part, compatilizer 2-4 part, stabilizer 3-5 part.
One the most according to claim 1 has high water-disintegrable thin-film material, it is characterised in that: described stabilizer is organic
Phosphite ester, ethylene-vinyl acetate copolymer or stearate.
One the most according to claim 1 has high water-disintegrable thin-film material, it is characterised in that: described compatilizer is ternary
EP rubbers or polybutylene terephthalate (PBT).
One the most according to claim 1 has high water-disintegrable thin-film material, it is characterised in that: described nano-sized filler is
Nano silicon or nano-calcium carbonate.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610642627.6A CN106280083A (en) | 2016-08-09 | 2016-08-09 | One has high water-disintegrable thin-film material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610642627.6A CN106280083A (en) | 2016-08-09 | 2016-08-09 | One has high water-disintegrable thin-film material |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106280083A true CN106280083A (en) | 2017-01-04 |
Family
ID=57666290
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610642627.6A Pending CN106280083A (en) | 2016-08-09 | 2016-08-09 | One has high water-disintegrable thin-film material |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106280083A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107298816A (en) * | 2017-08-18 | 2017-10-27 | 苏州卡佩罗尔高分子材料有限公司 | One kind has high water-disintegrable thin-film material |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103059464A (en) * | 2012-12-25 | 2013-04-24 | 东莞市祺龙电业有限公司 | High tenacity and environment-friendly polyvinyl chloride (PVC) modified materials and preparation method thereof |
| CN105038018A (en) * | 2015-07-24 | 2015-11-11 | 南通慧源塑胶有限公司 | Thin-film material with high hydrolytic property |
| CN105670157A (en) * | 2014-11-19 | 2016-06-15 | 天津儒创新材料科技有限公司 | Anti-aging polyvinyl chloride material |
-
2016
- 2016-08-09 CN CN201610642627.6A patent/CN106280083A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103059464A (en) * | 2012-12-25 | 2013-04-24 | 东莞市祺龙电业有限公司 | High tenacity and environment-friendly polyvinyl chloride (PVC) modified materials and preparation method thereof |
| CN105670157A (en) * | 2014-11-19 | 2016-06-15 | 天津儒创新材料科技有限公司 | Anti-aging polyvinyl chloride material |
| CN105038018A (en) * | 2015-07-24 | 2015-11-11 | 南通慧源塑胶有限公司 | Thin-film material with high hydrolytic property |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107298816A (en) * | 2017-08-18 | 2017-10-27 | 苏州卡佩罗尔高分子材料有限公司 | One kind has high water-disintegrable thin-film material |
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| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20170104 |
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| RJ01 | Rejection of invention patent application after publication |