CN106279910A - A kind of fire-retardant mildewproof plastics - Google Patents
A kind of fire-retardant mildewproof plastics Download PDFInfo
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- CN106279910A CN106279910A CN201610704179.8A CN201610704179A CN106279910A CN 106279910 A CN106279910 A CN 106279910A CN 201610704179 A CN201610704179 A CN 201610704179A CN 106279910 A CN106279910 A CN 106279910A
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- retardant
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/06—Polyethene
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The present invention relates to a kind of fire-retardant mildewproof plastics, including the raw material of following parts by weight: polystyrene resin 30 50 parts, Pentachorophenol 3 10 parts, polyethylene 65 75 parts, cellulose acetate micropowder 10 15 parts, phenol 5 10 parts, barium stearate 15 parts, 15 parts of copper sulfate, dimethyl methyl phosphonate 5 10 parts, antimony oxide 5 10 parts, thiodipropionic acid dilauryl silicone grease 38 parts, 27 parts of mercuric chloride, benzophenone 10 15 parts, heat stabilizer 26 parts, coupling agent 5 10 parts.The fire-retardant mildewproof plastics of the present invention is not easy burning at high temperature or other dangerous situations, use safer insurance, and elastic force is uniform, stable, life-time service will not be deformed, and have the premium properties of other macromolecular materials concurrently, improve mildew-resistant intensity, toughness and the heat resistance of product, reduce production cost, it is possible to replace general-purpose plastics.
Description
Technical field
The present invention relates to a kind of fire-retardant mildewproof plastics, belong to chemical material field.
Background technology
Plastics replace metal to be promoted in a lot of fields.At present, along with the progress of technology, ubiquitous new product
Product, new things bring convenient and swift hungry service to the life of people, work, and the life of people there occurs earth-shaking change
Change.In order to ensure country's public property and citizen's personal safety, in order to eliminate disaster hidden-trouble, enjoying life comfortable, fast
Meanwhile, " high-quality is lived safely " will be increasingly becoming key factor indispensable in life.In the epoch the most at a tremendous pace
Under background, fire retardant plastic material has the most just become the favorite in market.This material because of have good anti-flammability, low-density, low cost,
The characteristic that good combination property etc. are superior is applicable to switch on wall, socket, tubing, breaker of plastic casing, motor component, sheet material etc.
Field.In recent years, the most also have many manufacturing enterprises to begin one's study and develop flame retardant plastics, but the fire retardant added at present with
Halogenated flame retardant is more, especially can produce the noxious substance of hydrogen halides in combustion process, to people during life-time service
Health and environment all can cause greatly harm.
Summary of the invention
It is uniform, stable that the technical problem to be solved is to provide a kind of elastic force, and life-time service will not be deformed
Fire-retardant mildewproof plastics, the fire-retardant mildewproof plastics of the present invention high temperature or other dangerous situations be not easy burning, use safer
Insurance, and elastic force is uniform, stable, life-time service will not be deformed, and has the premium properties of other macromolecular materials concurrently, carries
High mildew-resistant intensity, toughness and the heat resistance of product, reduces production cost, it is possible to replace general-purpose plastics.
The technical scheme is that a kind of fire-retardant mildewproof plastics, including following weight portion
The raw material of number:
Polystyrene resin 30-50 part, polyethylene 65-75 part, cellulose acetate micropowder 10-15 part, phenol 5-10 part, firmly
Fat acid barium 1-5 part, copper sulfate 1-5 part, dimethyl methyl phosphonate 5-10 part, antimony oxide 5-10 part, thiodipropionic acid dilauryl
Silicone grease 3-8 part, mercuric chloride 2-7 part, benzophenone 10-15 part, heat stabilizer 2-6 part, coupling agent 5-10 part.
The invention has the beneficial effects as follows:
The fire-retardant mildewproof plastics of the present invention is not easy burning at high temperature or other dangerous situations, uses safer insurance, and
Elastic force is uniform, stable, and life-time service will not be deformed, and has the premium properties of other macromolecular materials concurrently, improves product
Mildew-resistant intensity, toughness and the heat resistance of product, reduces production cost, it is possible to replace general-purpose plastics.
On the basis of technique scheme, the present invention can also do following improvement.
Further, described fire-retardant mildewproof plastics preferred value includes the raw material of following parts by weight:
Polystyrene resin 30-40 part, Pentachorophenol 3-7 part, polyethylene 68-72 part, cellulose acetate micropowder 12-14 part,
Phenol 6-8 part, barium stearate 2-5 part, copper sulfate 2-4 part, dimethyl methyl phosphonate 6-8 part, antimony oxide 6-9 part, sulfur generation
Dipropionic acid silicone grease in February 4-7 part, mercuric chloride 3-5 part, benzophenone 12-14 part, heat stabilizer 3-5 part, coupling agent 6-8 part.
Optimum includes the raw material of following parts by weight:
Polystyrene resin 50 parts, Pentachorophenol 10 parts, polyethylene 70 parts, cellulose acetate micropowder 13 parts, phenol 7 parts, firmly
Fat acid barium 4 parts, 3 parts of copper sulfate, dimethyl methyl phosphonate 7 parts, antimony oxide 8 parts, thiodipropionic acid dilauryl silicone grease 5 parts, chlorine
Change hydrargyrum 4 parts, benzophenone 13 parts, heat stabilizer 4 parts, coupling agent 7 parts.
Further, described heat stabilizer is dibutyitin maleate.
Further, described coupling agent is coupling agent A151.
Detailed description of the invention
Principle and feature to the present invention are described below, and example is served only for explaining the present invention, is not intended to limit
Determine the scope of the present invention.
Embodiment 1
A kind of fire-retardant mildewproof plastics, including the raw material of following parts by weight:
Pentachorophenol 10 parts, polyethylene 65 parts, cellulose acetate micropowder 10 parts, phenol 5 parts, barium stearate 1 part, copper sulfate 1
Part, dimethyl methyl phosphonate 5 parts, antimony oxide 5 parts, thiodipropionic acid dilauryl silicone grease 3 parts, 2 parts of mercuric chloride, benzophenone 10
Part, heat stabilizer 2 parts, coupling agent 5 parts.
Preparation method:
Mediate 20 minutes in adding kneader according to above-mentioned formula after being measured by each raw material in order, available institute of the present invention
The fire-retardant mildewproof plastics stated.
Embodiment 2
A kind of fire-retardant mildewproof plastics, including the raw material of following parts by weight:
Pentachorophenol 7 parts, polyethylene 75 parts, cellulose acetate micropowder 15 parts, phenol 10 parts, barium stearate 5 parts, copper sulfate 5
Part, dimethyl methyl phosphonate 10 parts, antimony oxide 10 parts, thiodipropionic acid dilauryl silicone grease 8 parts, 7 parts of mercuric chloride, benzophenone
15 parts, heat stabilizer 6 parts, coupling agent 10 parts.
Preparation method:
Mediate 20 minutes in adding kneader according to above-mentioned formula after being measured by each raw material in order, available institute of the present invention
The fire-retardant mildewproof plastics stated.
Embodiment 3
A kind of fire-retardant mildewproof plastics, including the raw material of following parts by weight:
Pentachorophenol 3 parts, polyethylene 68 parts, cellulose acetate micropowder 12 parts, phenol 6 parts, barium stearate 2 parts, copper sulfate 2
Part, dimethyl methyl phosphonate 6 parts, antimony oxide 6 parts, thiodipropionic acid dilauryl silicone grease 4 parts, 3 parts of mercuric chloride, benzophenone 12
Part, heat stabilizer 3 parts, coupling agent 6 parts.
Preparation method:
Mediate 20 minutes in adding kneader according to above-mentioned formula after being measured by each raw material in order, available institute of the present invention
The fire-retardant mildewproof plastics stated.
Embodiment 4
A kind of fire-retardant mildewproof plastics, including the raw material of following parts by weight:
Pentachorophenol 6 parts, polyethylene 72 parts, cellulose acetate micropowder 14 parts, phenol 8 parts, barium stearate 5 parts, copper sulfate 4
Part, dimethyl methyl phosphonate 8 parts, antimony oxide 9 parts, thiodipropionic acid dilauryl silicone grease 7 parts, 5 parts of mercuric chloride, benzophenone 14
Part, heat stabilizer 3-5 part, coupling agent 8 parts.
Preparation method:
Mediate 20 minutes in adding kneader according to above-mentioned formula after being measured by each raw material in order, available institute of the present invention
The fire-retardant mildewproof plastics stated.
Embodiment 5
A kind of fire-retardant mildewproof plastics, including the raw material of following parts by weight:
Pentachorophenol 7 parts, polyethylene 70 parts, cellulose acetate micropowder 13 parts, phenol 7 parts, barium stearate 4 parts, copper sulfate 3
Part, dimethyl methyl phosphonate 7 parts, antimony oxide 8 parts, thiodipropionic acid dilauryl silicone grease 5 parts, 4 parts of mercuric chloride, benzophenone 13
Part, heat stabilizer 4 parts, coupling agent 7 parts.
Preparation method:
Mediate 20 minutes in adding kneader according to above-mentioned formula after being measured by each raw material in order, available institute of the present invention
The fire-retardant mildewproof plastics stated.
The foregoing is only presently preferred embodiments of the present invention, not in order to limit the present invention, all spirit in the present invention and
Within principle, any modification, equivalent substitution and improvement etc. made, should be included within the scope of the present invention.
Claims (5)
1. a fire-retardant mildewproof plastics, it is characterised in that include the raw material of following parts by weight:
Polystyrene resin 30-50 part, Pentachorophenol 3-10 part, polyethylene 65-75 part, cellulose acetate micropowder 10-15 part, phenol
5-10 part, barium stearate 1-5 part, copper sulfate 1-5 part, dimethyl methyl phosphonate 5-10 part, antimony oxide 5-10 part, sulfur generation two
Propanoic acid silicone grease in February 3-8 part, mercuric chloride 2-7 part, benzophenone 10-15 part, heat stabilizer 2-6 part, coupling agent 5-10 part.
Fire-retardant mildewproof plastics the most according to claim 1, it is characterised in that include the raw material of following parts by weight:
Polystyrene resin 30-40 part, Pentachorophenol 3-7 part, polyethylene 68-72 part, cellulose acetate micropowder 12-14 part, phenol
6-8 part, barium stearate 2-5 part, copper sulfate 2-4 part, dimethyl methyl phosphonate 6-8 part, antimony oxide 6-9 part, sulfur is for dipropyl
Acid silicone grease 4-7 part in February, mercuric chloride 3-5 part, benzophenone 12-14 part, heat stabilizer 3-5 part, coupling agent 6-8 part.
Fire-retardant mildewproof plastics the most according to claim 2, it is characterised in that include the raw material of following parts by weight:
Polystyrene resin 50 parts, Pentachorophenol 10 parts, polyethylene 70 parts, cellulose acetate micropowder 13 parts, phenol 7 parts, stearic acid
Barium 4 parts, 3 parts of copper sulfate, dimethyl methyl phosphonate 7 parts, antimony oxide 8 parts, thiodipropionic acid dilauryl silicone grease 5 parts, mercuric chloride 4
Part, benzophenone 13 parts, heat stabilizer 4 parts, coupling agent 7 parts.
4. according to the fire-retardant mildewproof plastics described in any one of claims 1 to 3, it is characterised in that described heat stabilizer is Malaysia
Acid dibutyl tin.
5. according to the fire-retardant mildewproof plastics described in any one of claims 1 to 3, it is characterised in that described coupling agent is coupling agent
A151。
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CN201610704179.8A CN106279910A (en) | 2016-08-22 | 2016-08-22 | A kind of fire-retardant mildewproof plastics |
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CN201610704179.8A CN106279910A (en) | 2016-08-22 | 2016-08-22 | A kind of fire-retardant mildewproof plastics |
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CN106279910A true CN106279910A (en) | 2017-01-04 |
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CN201610704179.8A Pending CN106279910A (en) | 2016-08-22 | 2016-08-22 | A kind of fire-retardant mildewproof plastics |
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Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103554616A (en) * | 2013-10-31 | 2014-02-05 | 合肥得润电子器件有限公司 | Modified polyethylene insulating material for wire harness of communication equipment |
CN104844899A (en) * | 2015-04-28 | 2015-08-19 | 芜湖众力部件有限公司 | Modified plastic with antibacterial mould-proof performance and production method thereof |
-
2016
- 2016-08-22 CN CN201610704179.8A patent/CN106279910A/en active Pending
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103554616A (en) * | 2013-10-31 | 2014-02-05 | 合肥得润电子器件有限公司 | Modified polyethylene insulating material for wire harness of communication equipment |
CN104844899A (en) * | 2015-04-28 | 2015-08-19 | 芜湖众力部件有限公司 | Modified plastic with antibacterial mould-proof performance and production method thereof |
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Application publication date: 20170104 |