CN106278191A - 一种复合氧化物Al2Ca3MgSb2O12作为温度稳定型微波介电陶瓷的应用 - Google Patents

一种复合氧化物Al2Ca3MgSb2O12作为温度稳定型微波介电陶瓷的应用 Download PDF

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CN106278191A
CN106278191A CN201610625844.4A CN201610625844A CN106278191A CN 106278191 A CN106278191 A CN 106278191A CN 201610625844 A CN201610625844 A CN 201610625844A CN 106278191 A CN106278191 A CN 106278191A
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苏聪学
郑彬宁
李纯纯
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Guilin University of Technology
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Abstract

本发明公开了一种复合氧化物Al2Ca3MgSb2O12作为温度稳定型超低介电常数微波介电陶瓷的应用及其制备方法。(1)将化学原料MgO、Al2O3、CaCO3和Sb2O5粉末按化学计量式Al2Ca3MgSb2O12称量配料；(2)将步骤(1)原料湿式球磨混合12小时，球磨介质为蒸馏水，烘干后在1100℃大气气氛中预烧6小时；(3)在步骤(2)制得的粉末中添加粘结剂并造粒后，再压制成型，最后在1150～1200℃大气气氛中烧结4小时；所述的粘结剂采用质量浓度为5％的聚乙烯醇溶液，聚乙烯醇的添加量占粉末总质量的3％。本发明制备的陶瓷在1200℃以下烧结良好，介电常数达到8.1～8.5，其品质因数Qf值高达80400‑91300GHz，谐振频率温度系数小，在工业上有着极大的应用价值。

Description

一种复合氧化物Al2Ca3MgSb2O12作为温度稳定型微波介电陶瓷 的应用
技术领域
本发明涉及介电陶瓷材料，特别是涉及用于制造微波频率使用的陶瓷基板、谐振器与滤波器等微波元器件的介电陶瓷材料及其制备方法。
背景技术
微波介电陶瓷是指应用于微波频段(主要是UHF和SHF频段)电路中作为介质材料并完成一种或多种功能的陶瓷，在现代通讯中被广泛用作谐振器、滤波器、介质基片和介质导波回路等元器件，是现代通信技术的关键基础材料，已在便携式移动电话、汽车电话、无绳电话、电视卫星接受器和军事雷达等方面有着十分重要的应用，在现代通讯工具的小型化、集成化过程中正发挥着越来越大的作用。
应用于微波频段的介电陶瓷，应满足如下介电特性的要求：(1)系列化介电常数εr以适应不同频率及不同应用场合的要求；(2)高的品质因数Q值或低的介电损耗tanδ以降低噪音，一般要求Qf≥3000GHz；(3)谐振频率的温度系数τf尽可能小以保证器件具有好的热稳定性，一般要求-10ppm/℃≤τf≤+10ppm/℃。国际上从20世纪30年代末就有人尝试将电介质材料应用于微波技术,并制备出TiO2微波介质滤波器，但其谐振频率温度系数τf太大而无法实用化。上世纪70年代以来，开始了大规模的对介质陶瓷材料的开发工作,根据相对介电常数εr的大小与使用频段的不同，通常可将已被开发和正在开发的微波介质陶瓷分为4类。
(1)超低介电常数微波介电陶瓷，主要代表是Al2O3-TiO2、Y2BaCuO5、MgAl2O4和Mg2SiO4等，其εr≤20，品质因数Q×f≥50000GHz，τf≤10ppm/℃。主要用于微波基板以及高端微波元器件。
(2)低εr和高Q值的微波介电陶瓷，主要是BaO-MgO-Ta2O5,BaO-ZnO-Ta2O5或BaO-MgO-Nb2O5,BaO-ZnO-Nb2O5系统或它们之间的复合系统MWDC材料。其εr＝20～35,Q＝(1～2)×104(在f≥10GHz下),τf≈0。主要应用于f≥8GHz的卫星直播等微波通信机中作为介质谐振器件。
(3)中等εr和Q值的微波介电陶瓷，主要是以BaTi4O9、Ba2Ti9O20和(Zr、Sn)TiO4等为基的MWDC材料,其εr＝35～45，Q＝(6～9)×103(在f＝3～－4GHz下)，τf≤5ppm/℃。主要用于4～8GHz频率范围内的微波军用雷达及通信系统中作为介质谐振器件。
(4)高εr而Q值较低的微波介电陶瓷，主要用于0.8～4GHz频率范围内民用移动通讯系统，这也是微波介电陶瓷研究的重点。80年代以来，Kolar、Kato等人相继发现并研究了类钙钛矿钨青铜型BaO—Ln2O3—TiO2系列(Ln＝La、Sm、Nd或Pr等,简称BLT系)、复合钙钛矿结构CaO—Li2O—Ln2O3—TiO2系列、铅基系列材料、Ca1-xLn2x/3TiO3系等高εr微波介电陶瓷，其中BLT体系的BaO—Nd2O3—TiO2材料介电常数达到90，铅基系列(Pb,Ca)ZrO3介电常数达到105。
由于微波介电陶瓷的三个性能指标(εr与Q·f和τf)之间是相互制约的关系(见文献：微波介质陶瓷材料介电性能间的制约关系，朱建华，梁飞，汪小红，吕文中，电子元件与材料，2005年3月第3期)，满足三个性能要求且可低温烧结的单相微波介质陶瓷非常少，主要是它们的谐振频率温度系数通常过大或者品质因数偏低而无法实际应用要求。目前对微波介质陶瓷的研究大部分是通过大量实验而得出的经验总结,却没有完整的理论来阐述微观结构与介电性能的关系，因此，在理论上还无法从化合物的组成与结构上预测其谐振频率温度系数和品质因数等微波介电性能，这在很大程度上限制了低温共烧技术及微波多层器件的发展。探索与开发既能低温烧结同时具有近零谐振频率温度系数(-10ppm/℃≤τf≤+10ppm/℃)与较高品质因数的微波介电陶瓷是本领域技术人员一直渴望解决但始终难以获得成功的难题。我们对非石榴石结构，且组成为Al2Ca3MgSb2O12、Al2Ca3ZnSb2O12与Al2Ca3MgV2O12的陶瓷进行了烧结与微波介电性能研究，发现它们的烧结温度低于1200℃，但只有Al2Ca3MgSb2O12具有近零谐振频率温度系数与高品质因数，Al2Ca3MgV2O12为半导体，在微波频段介电损耗太大而无法作为可实用化的微波介质陶瓷，Al2Ca3ZnSb2O12的谐振频率温度系数为-52ppm/℃，也无法作为实用化的微波介质陶瓷。
发明内容
本发明的目的是提供一种具有良好的热稳定性与低损耗的超低介电常数微波介电陶瓷材料及其制备方法。
本发明的微波介电陶瓷材料的化学组成为Al2Ca3MgSb2O12。
本微波介电陶瓷材料的制备方法步骤为：
(1)将化学原料MgO、Al2O3、CaCO3和Sb2O5粉末按化学计量式Al2Ca3MgSb2O12称量配料。
(2)将步骤(1)原料湿式球磨混合12小时，球磨介质为蒸馏水，烘干后在1100℃大气气氛中预烧6小时。
(3)在步骤(2)制得的粉末中添加粘结剂并造粒后，再压制成型，最后在1150～1200℃大气气氛中烧结4小时；所述的粘结剂采用质量浓度为5％的聚乙烯醇溶液，聚乙烯醇添加量占粉末总质量的3％。
本发明的优点：Al2Ca3MgSb2O12陶瓷烧结温度低，原料成本低；其品质因数Qf值高达80400-91300GHz,介电常数达到8.1～8.5，其谐振频率的温度系数τf小，温度稳定性好；可广泛用于各种介质基板、谐振器和滤波器等微波器件的制造，可满足低温共烧技术及微波多层器件的技术需要。
具体实施方式
实施例：
表1示出了构成本发明的不同烧结温度的3个具体实施例及其微波介电性能。其制备方法如上所述，用圆柱介质谐振器法进行微波介电性能的评价。
本陶瓷可广泛用于各种介质基板、谐振器和滤波器等微波器件的制造，可满足移动通信和卫星通信等系统的技术需要。
表1：

Claims (1)

1.一种复合氧化物作为温度稳定型超低介电常数微波介电陶瓷的应用，其特征在于所述复合氧化物的化学组成为：Al2Ca3MgSb2O12；
所述复合氧化物的制备方法具体步骤为：
(1)将化学原料MgO、Al2O3、CaCO3和Sb2O5粉末按化学计量式Al2Ca3MgSb2O12称量配料；
(2)将步骤(1)原料湿式球磨混合12小时，球磨介质为蒸馏水，烘干后在1100℃大气气氛中预烧6小时；
(3)在步骤(2)制得的粉末中添加粘结剂并造粒后，再压制成型，最后在1150～1200℃大气气氛中烧结4小时；所述的粘结剂采用质量浓度为5％的聚乙烯醇溶液，聚乙烯醇添加量占粉末总质量的3％。
CN201610625844.4A 2016-08-01 2016-08-01 一种复合氧化物Al2Ca3MgSb2O12作为温度稳定型微波介电陶瓷的应用 Pending CN106278191A (zh)

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Cited By (3)

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Publication number Priority date Publication date Assignee Title
CN111087234A (zh) * 2019-12-27 2020-05-01 杭州电子科技大学 一种具有优异温度敏感特性微波介质陶瓷及其制备方法
CN113683399A (zh) * 2021-07-23 2021-11-23 桂林理工大学 一种低介电常数微波介质陶瓷及其制备方法
CN114479855A (zh) * 2022-02-28 2022-05-13 大连民族大学 一种紫外和蓝光双重激发近红外荧光粉、制备方法及应用

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CN1524792A (zh) * 2003-02-28 2004-09-01 新加坡纳米材料科技有限公司 一种制备各种晶态钙钛矿类化合物粉体的方法
CN104671783A (zh) * 2015-02-10 2015-06-03 桂林理工大学 低损耗的温度稳定型微波介电陶瓷LiMg3NbWO9

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CN1524792A (zh) * 2003-02-28 2004-09-01 新加坡纳米材料科技有限公司 一种制备各种晶态钙钛矿类化合物粉体的方法
CN104671783A (zh) * 2015-02-10 2015-06-03 桂林理工大学 低损耗的温度稳定型微波介电陶瓷LiMg3NbWO9

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111087234A (zh) * 2019-12-27 2020-05-01 杭州电子科技大学 一种具有优异温度敏感特性微波介质陶瓷及其制备方法
CN111087234B (zh) * 2019-12-27 2022-05-20 杭州电子科技大学 一种具有优异温度敏感特性陶瓷在谐振器温度传感器中的应用
CN113683399A (zh) * 2021-07-23 2021-11-23 桂林理工大学 一种低介电常数微波介质陶瓷及其制备方法
CN114479855A (zh) * 2022-02-28 2022-05-13 大连民族大学 一种紫外和蓝光双重激发近红外荧光粉、制备方法及应用

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Application publication date: 20170104