CN106278123A - A kind of novel wall flame-proof thermal insulation material and preparation method thereof - Google Patents
A kind of novel wall flame-proof thermal insulation material and preparation method thereof Download PDFInfo
- Publication number
- CN106278123A CN106278123A CN201610634510.3A CN201610634510A CN106278123A CN 106278123 A CN106278123 A CN 106278123A CN 201610634510 A CN201610634510 A CN 201610634510A CN 106278123 A CN106278123 A CN 106278123A
- Authority
- CN
- China
- Prior art keywords
- insulation material
- thermal insulation
- novel wall
- proof thermal
- wall flame
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/30—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing magnesium cements or similar cements
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00431—Refractory materials
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2201/00—Mortars, concrete or artificial stone characterised by specific physical values
- C04B2201/20—Mortars, concrete or artificial stone characterised by specific physical values for the density
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2201/00—Mortars, concrete or artificial stone characterised by specific physical values
- C04B2201/30—Mortars, concrete or artificial stone characterised by specific physical values for heat transfer properties such as thermal insulation values, e.g. R-values
- C04B2201/32—Mortars, concrete or artificial stone characterised by specific physical values for heat transfer properties such as thermal insulation values, e.g. R-values for the thermal conductivity, e.g. K-factors
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2201/00—Mortars, concrete or artificial stone characterised by specific physical values
- C04B2201/50—Mortars, concrete or artificial stone characterised by specific physical values for the mechanical strength
Abstract
The invention discloses a kind of novel wall flame-proof thermal insulation material, including the component of following precentagewise mixing: sulfur lemon magnesium cement cementitious 55 ~ 85%;Light thermal-insulation aggregate 10 ~ 30%;Foaming agent 3 ~ 9%;Hydrophober 0.4 ~ 1.2%;Anti-crack fiber 0.4 ~ 0.6%.Novel wall flame-proof thermal insulation material disclosed by the invention is prepared by each constituent mix and blend.The present invention has the premium properties such as insulation, lightweight, fire-resistant, waterproof, high-strength, lower shrinkage, overcomes defect and deficiency that Conventional insulation exists.
Description
Technical field
The present invention relates to building material technical field, be specifically related to a kind of its preparation side of novel wall flame-proof thermal insulation material
Method.
Background technology
In the face of the energy problem of whole world growing tension, energy-conservation being paid much attention to by national governments, developed country is from 20 generation
Record and act the problem beginning to pay close attention to building energy conservation the seventies.Building energy conservation refers to by taking rational architectural design and selecting symbol
Close the measure such as the materials for wall of power conservation requirement, roof insulation material, door and window, air-conditioning, the house so built, and do not take
The house of conservation measures is compared, and under the conditions of ensureing identical indoor thermal comfort environment of rural, it can improve efficiency, subtracts
Few building energy consumption.
Research data shows, the heat for building house consumes main two parts composition, i.e. the heat transfer of building enclosure disappears
The air penetration of the positions such as consumption and door-window opening consumes composition.The former account for more than the 75% of enclosed structure heat transfer consumption, the latter
Account for about 25%.Such that it is able to know that the key position of building energy conservation is building enclosure in whole building structure, carries out and goes along with sb. to guard him
The energy conservation of structure becomes most important, and in building maintenance structure, body of wall account for major part, therefore building outer wall
Insulation is one of important way of building energy conservation realization.
Materials for wall consumption shelter has first of construction material under construction, reaches 70%, and traditional wall heat insulation material
There is all defects and deficiency.Along with building develops to high level, alleviate the deadweight of materials for wall and improve its insulation joint
Can effect, and meet fire protection requirement become materials for wall reform and development direction.
Summary of the invention
For solving the problem that prior art exists, the present invention provides a kind of its preparation side of novel wall flame-proof thermal insulation material
Method, has the premium properties such as insulation, lightweight, fire-resistant, waterproof, high-strength, lower shrinkage.
For achieving the above object, the technical solution used in the present invention is:
A kind of novel wall flame-proof thermal insulation material, including the component of following precentagewise mixing:
Sulfur lemon magnesium cement cementitious 55 ~ 85%;
Light thermal-insulation aggregate 10 ~ 30%;
Foaming agent 3 ~ 9%;
Hydrophober 0.4 ~ 1.2%;
Anti-crack fiber 0.4 ~ 0.6%.
What described sulfur lemon magnesium was cement cementitious be grouped point includes light calcined magnesia, Magnesium sulfate heptahydrate, water and citric acid, described
The mass ratio of light calcined magnesia and Magnesium sulfate heptahydrate is 1.7, and water and Magnesium sulfate heptahydrate mass ratio are 1.0, citric acid and light-burned oxygen
The mass ratio changing magnesium is 1.3%.
In described light calcined magnesia, the content of magnesium oxide is more than 85%.
Described light thermal-insulation aggregate is glass bead, and granularity is 0.5 ~ 1.5mm.
Described foaming agent is hydrogen peroxide.
Described hydrophober is powder type waterproofing agent of organosilicon.
Described anti-crack fiber is polypropene staple, a length of 9mm.
The preparation method of described a kind of novel wall flame-proof thermal insulation material, including step in detail below:
(1) it is first according to above-mentioned quality proportioning and weighs each component, citric acid and anti-crack fiber C are added to the water stirring 30 seconds, make
Fiber is completely dispersed, and citric acid is dissolved completely in water;
(2) then Magnesium sulfate heptahydrate crystal addition aqueous solution is stirred into uniform magnesium sulfate solution, low rate mixing sulfur
Acid magnesium solution, while adding light calcined magnesia, is treated that light calcined magnesia the most quickly stirs 5 minutes after adding, is stirred into uniform
Sulfur lemon magnesium cement paste;
(3) glass bead is finally added, hydrophober A and hydrogen peroxide, stir 30 seconds;
(4) being injected in time in wallboard by the slurry mixed and stirred, under the conditions of 25 DEG C, sealed maintenance is to 28d age.
Beneficial effects of the present invention:
The vitrified microsphere insulating material that the present invention uses compensate for traditional granular polystyrene and normal expanded perlite in performance
Many defects in lightweight aggregate insulation material and deficiency, overcome the efflorescence big, easy of expanded perlite lightweight aggregate water absorption, in construction
The defects such as middle cubical contraction is big, easily cause that product later strength is low and hollowing cracking and reduce the drawbacks such as heat-insulating property, simultaneously
Compensate for that granular polystyrene organic material is inflammable, fire line is poor, high temperature time produce harmful gas and weatherability is poor, construction bounce-back greatly etc.
Defect.Vitrified microsphere insulating material is a kind of Green Product truly.
The bond that the sulfur lemon magnesium of present invention employing is cement cementitious is strong, intensity is high, slurry denseness is big, pouring stability good,
More bubble and light-weight aggregate can be mixed into and the mould that is difficult to collapse, and still can keep of a relatively high in the case of air pocket volume
Intensity, additionally the density of material of itself is low, is suitable for producing the insulation material of low-density and high-strength.
The sulfur lemon magnesium of present invention employing is cement cementitious is a kind of high refractory material.The refractoriness of magnesite light burnt powder occupies fire proofed wood
The hat of material, reaches 2200 DEG C, and its foaming insulation board can be used for the use environment of more than 1200 DEG C, the cement foamed guarantor of magnesium therefore made
Temperature plate very advantageous in terms of refractory heat-insulating.
The present invention has the premium properties such as insulation, lightweight, fire-resistant, waterproof, high-strength, lower shrinkage, is a kind of novel body of wall
Material.
Detailed description of the invention
Below in conjunction with embodiment, the present invention is further described.
Embodiment 1
A kind of novel wall flame-proof thermal insulation material, including the component of following precentagewise mixing:
Sulfur lemon magnesium cement cementitious 75%;Light thermal-insulation aggregate 15%;Foaming agent 8.4%;Hydrophober 1.2%;Anti-crack fiber
0.4%。
What described sulfur lemon magnesium was cement cementitious be grouped point includes light calcined magnesia, Magnesium sulfate heptahydrate, water and citric acid, described
The mass ratio of light calcined magnesia and Magnesium sulfate heptahydrate is 1.7, and water and Magnesium sulfate heptahydrate mass ratio are 1.0, citric acid and light-burned oxygen
The mass ratio changing magnesium is 1.3%.
In described light calcined magnesia, the content of magnesium oxide is more than 85%.
Described light thermal-insulation aggregate is glass bead, and granularity is 0.5 ~ 1.5mm.
Described foaming agent is hydrogen peroxide.
Described hydrophober is powder type waterproofing agent of organosilicon.
Described anti-crack fiber is polypropene staple, a length of 9mm.
The preparation method of described a kind of novel wall flame-proof thermal insulation material, including step in detail below:
(1) it is first according to above-mentioned quality proportioning and weighs each component, citric acid and anti-crack fiber C are added to the water stirring 30 seconds, make
Fiber is completely dispersed, and citric acid is dissolved completely in water;
(2) then Magnesium sulfate heptahydrate crystal addition aqueous solution is stirred into uniform magnesium sulfate solution, low rate mixing sulfur
Acid magnesium solution, while adding light calcined magnesia, is treated that light calcined magnesia the most quickly stirs 5 minutes after adding, is stirred into uniform
Sulfur lemon magnesium cement paste;
(3) glass bead is finally added, hydrophober A and hydrogen peroxide, stir 30 seconds;
(4) being injected in time in wallboard by the slurry mixed and stirred, under the conditions of 25 DEG C, sealed maintenance is to 28d age.
Recording the density of novel wall flame-proof thermal insulation material in this specific embodiment is 297 kg m-3, heat conductivity be
0.079 W/m k, comprcssive strength are 0.89 MPa, rupture strength is 0.82 MPa, water absorption rate is 17.4%.
Embodiment 2
A kind of novel wall flame-proof thermal insulation material, including the component of following precentagewise mixing:
Sulfur lemon magnesium cement cementitious 67%;Light thermal-insulation aggregate 28%;Foaming agent 4%;Hydrophober 0.4%;Anti-crack fiber 0.6%.
What described sulfur lemon magnesium was cement cementitious be grouped point includes light calcined magnesia, Magnesium sulfate heptahydrate, water and citric acid, described
The mass ratio of light calcined magnesia and Magnesium sulfate heptahydrate is 1.7, and water and Magnesium sulfate heptahydrate mass ratio are 1.0, citric acid and light-burned oxygen
The mass ratio changing magnesium is 1.3%.
In described light calcined magnesia, the content of magnesium oxide is more than 85%.
Described light thermal-insulation aggregate is glass bead, and granularity is 0.5 ~ 1.5mm.
Described foaming agent is hydrogen peroxide.
Described hydrophober is powder type waterproofing agent of organosilicon.
Described anti-crack fiber is polypropene staple, a length of 9mm.
The preparation method of described a kind of novel wall flame-proof thermal insulation material, including step in detail below:
(1) it is first according to above-mentioned quality proportioning and weighs each component, citric acid and anti-crack fiber C are added to the water stirring 30 seconds, make
Fiber is completely dispersed, and citric acid is dissolved completely in water;
(2) then Magnesium sulfate heptahydrate crystal addition aqueous solution is stirred into uniform magnesium sulfate solution, low rate mixing sulfur
Acid magnesium solution, while adding light calcined magnesia, is treated that light calcined magnesia the most quickly stirs 5 minutes after adding, is stirred into uniform
Sulfur lemon magnesium cement paste;
(3) glass bead is finally added, hydrophober A and hydrogen peroxide, stir 30 seconds;
(4) being injected in time in wallboard by the slurry mixed and stirred, under the conditions of 25 DEG C, sealed maintenance is to 28d age.
Recording the density of novel wall flame-proof thermal insulation material in this specific embodiment is 306 kg m-3, heat conductivity be
0.072 W/m k, comprcssive strength are 0.84 MPa, rupture strength is 0.56 MPa, water absorption rate is 16.8%.
Embodiment 3
A kind of novel wall flame-proof thermal insulation material, including the component of following precentagewise mixing:
Sulfur lemon magnesium cement cementitious 82%;Light thermal-insulation aggregate 10%;Foaming agent 6.6%;Hydrophober 1.0%;Anti-crack fiber
0.4%。
What described sulfur lemon magnesium was cement cementitious be grouped point includes light calcined magnesia, Magnesium sulfate heptahydrate, water and citric acid, described
The mass ratio of light calcined magnesia and Magnesium sulfate heptahydrate is 1.7, and water and Magnesium sulfate heptahydrate mass ratio are 1.0, citric acid and light-burned oxygen
The mass ratio changing magnesium is 1.3%.
In described light calcined magnesia, the content of magnesium oxide is more than 85%.
Described light thermal-insulation aggregate is glass bead, and granularity is 0.5 ~ 1.5mm.
Described foaming agent is hydrogen peroxide.
Described hydrophober is powder type waterproofing agent of organosilicon.
Described anti-crack fiber is polypropene staple, a length of 9mm.
The preparation method of described a kind of novel wall flame-proof thermal insulation material, including step in detail below:
(1) it is first according to above-mentioned quality proportioning and weighs each component, citric acid and anti-crack fiber C are added to the water stirring 30 seconds, make
Fiber is completely dispersed, and citric acid is dissolved completely in water;
(2) then Magnesium sulfate heptahydrate crystal addition aqueous solution is stirred into uniform magnesium sulfate solution, low rate mixing sulfur
Acid magnesium solution, while adding light calcined magnesia, is treated that light calcined magnesia the most quickly stirs 5 minutes after adding, is stirred into uniform
Sulfur lemon magnesium cement paste;
(3) glass bead is finally added, hydrophober A and hydrogen peroxide, stir 30 seconds;
(4) being injected in time in wallboard by the slurry mixed and stirred, under the conditions of 25 DEG C, sealed maintenance is to 28d age.
Recording the density of novel wall flame-proof thermal insulation material in this specific embodiment is 308 kg m-3, heat conductivity be
0.081 W/m k, comprcssive strength are 0.92 MPa, rupture strength is 0.76 MPa, water absorption rate is 19.2%.
Material composition, preparation method and the technical characterstic of the present invention have more than been shown and described.The technical staff of the industry
It should be appreciated that the present invention is not restricted to the described embodiments, described in above-described embodiment and description, the present invention is simply described
Principle, without departing from the spirit and scope of the present invention, the present invention also has various changes and modifications, these change and
Improvement both falls within scope of the claimed invention.Claimed scope is by appending claims and equivalence thereof
Thing defines.
Claims (8)
1. a novel wall flame-proof thermal insulation material, it is characterised in that include the component that following precentagewise mixes:
Sulfur lemon magnesium cement cementitious 55 ~ 85%;
Light thermal-insulation aggregate 10 ~ 30%;
Foaming agent 3 ~ 9%;
Hydrophober 0.4 ~ 1.2%;
Anti-crack fiber 0.4 ~ 0.6%.
A kind of novel wall flame-proof thermal insulation material the most according to claim 1, it is characterised in that described sulfur lemon magnesium cement gel
Solidifying being grouped point includes light calcined magnesia, Magnesium sulfate heptahydrate, water and citric acid, described light calcined magnesia and Magnesium sulfate heptahydrate
Mass ratio is 1.7, and water and Magnesium sulfate heptahydrate mass ratio are 1.0, citric acid is 1.3% with the mass ratio of light calcined magnesia.
A kind of novel wall flame-proof thermal insulation material the most according to claim 2, it is characterised in that in described light calcined magnesia
The content of magnesium oxide is more than 85%.
A kind of novel wall flame-proof thermal insulation material the most according to claim 1, it is characterised in that described light thermal-insulation aggregate
For glass bead, granularity is 0.5 ~ 1.5mm.
A kind of novel wall flame-proof thermal insulation material the most according to claim 1, it is characterised in that described foaming agent is dioxygen
Water.
A kind of novel wall flame-proof thermal insulation material the most according to claim 1, it is characterised in that described hydrophober is powder body
Type waterproofing agent of organosilicon.
A kind of novel wall flame-proof thermal insulation material the most according to claim 1, it is characterised in that described anti-crack fiber is poly-
Propylene chopped fiber, a length of 9mm.
8. according to the preparation method of a kind of novel wall flame-proof thermal insulation material described in any one of claim 1 ~ 7, including following
Concrete steps:
(1) it is first according to above-mentioned quality proportioning and weighs each component, citric acid and anti-crack fiber C are added to the water stirring 30 seconds, make
Fiber is completely dispersed, and citric acid is dissolved completely in water;
(2) then Magnesium sulfate heptahydrate crystal addition aqueous solution is stirred into uniform magnesium sulfate solution, low rate mixing sulfur
Acid magnesium solution, while adding light calcined magnesia, is treated that light calcined magnesia the most quickly stirs 5 minutes after adding, is stirred into uniform
Sulfur lemon magnesium cement paste;
(3) glass bead is finally added, hydrophober A and hydrogen peroxide, stir 30 seconds;
Being injected in time in wallboard by the slurry mixed and stirred, under the conditions of 25 DEG C, sealed maintenance is to 28d age.
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CN201610634510.3A CN106278123A (en) | 2016-08-05 | 2016-08-05 | A kind of novel wall flame-proof thermal insulation material and preparation method thereof |
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CN201610634510.3A CN106278123A (en) | 2016-08-05 | 2016-08-05 | A kind of novel wall flame-proof thermal insulation material and preparation method thereof |
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Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN110372318A (en) * | 2019-07-18 | 2019-10-25 | 深圳工建科技有限公司 | A kind of heat insulating mortar and preparation method thereof |
CN111635212A (en) * | 2020-06-22 | 2020-09-08 | 黑龙江省天彩新型材料研发有限责任公司 | Inorganic fireproof heat-insulation decorative integrated board |
CN111689754A (en) * | 2019-12-06 | 2020-09-22 | 江苏中砼新材料科技有限公司 | Fireproof heat-insulating lightweight concrete for roof pouring |
CN115405025A (en) * | 2022-09-06 | 2022-11-29 | 江苏望沛建材科技有限公司 | Magnesium oxysulfate light partition plate |
-
2016
- 2016-08-05 CN CN201610634510.3A patent/CN106278123A/en active Pending
Non-Patent Citations (1)
Title |
---|
杨华峰: "耐火轻质保温板的研制与性能", 《中国优秀硕士学位论文全文数据库 工程科技Ⅱ辑》 * |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN110372318A (en) * | 2019-07-18 | 2019-10-25 | 深圳工建科技有限公司 | A kind of heat insulating mortar and preparation method thereof |
CN111689754A (en) * | 2019-12-06 | 2020-09-22 | 江苏中砼新材料科技有限公司 | Fireproof heat-insulating lightweight concrete for roof pouring |
CN111689754B (en) * | 2019-12-06 | 2022-03-25 | 江苏中砼新材料科技有限公司 | Fireproof heat-insulating lightweight concrete for roof pouring |
CN111635212A (en) * | 2020-06-22 | 2020-09-08 | 黑龙江省天彩新型材料研发有限责任公司 | Inorganic fireproof heat-insulation decorative integrated board |
CN115405025A (en) * | 2022-09-06 | 2022-11-29 | 江苏望沛建材科技有限公司 | Magnesium oxysulfate light partition plate |
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Application publication date: 20170104 |