CN106277790A - Novel strong acidproof coloured glaze modelled after an antique - Google Patents
Novel strong acidproof coloured glaze modelled after an antique Download PDFInfo
- Publication number
- CN106277790A CN106277790A CN201610641208.0A CN201610641208A CN106277790A CN 106277790 A CN106277790 A CN 106277790A CN 201610641208 A CN201610641208 A CN 201610641208A CN 106277790 A CN106277790 A CN 106277790A
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- CN
- China
- Prior art keywords
- coloured glaze
- accounts
- overall component
- antique
- modelled
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/14—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
- B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C1/00—Ingredients generally applicable to manufacture of glasses, glazes, or vitreous enamels
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C1/00—Ingredients generally applicable to manufacture of glasses, glazes, or vitreous enamels
- C03C1/04—Opacifiers, e.g. fluorides or phosphates; Pigments
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Glass Compositions (AREA)
Abstract
The open a kind of novel strong acidproof coloured glaze modelled after an antique of the present invention, described novel strong acidproof coloured glaze modelled after an antique includes anticorrosive coat and coloured glaze body, described coloured glaze body includes Lead oxide brown, ceria, ferrum oxide color material, fire retardant and brium carbonate combine, described Lead oxide brown accounts for 24% the 29% of the overall component of coloured glaze body, described ceria accounts for 16% the 20% of the overall component of coloured glaze body, described ferrum oxide colorant accounts for 4% the 9% of the overall component of coloured glaze body, described fire retardant accounts for 21% the 23% of the overall component of coloured glaze body, described brium carbonate accounts for 24% the 30% of the overall component of coloured glaze body, the present invention provides a kind of novel strong acidproof coloured glaze modelled after an antique, there is service life long, low cost, cleanliness factor is good, non-friable advantage.
Description
Technical field
The present invention relates to a kind of novel strong acidproof coloured glaze modelled after an antique.
Background technology
Coloured glaze is a kind of silicate product, has a long history, and its quality is glittering and translucent, bright and glittering, changes irregularly magnificent,
Fully demonstrate the exquisiteness of Asians, fine and smooth and implicit, be a kind of important decoration element.Coloured glaze composition is low with softening point, material
Property a length of have good characteristic, be so easy to technique manufacture, being suitable for coloured glaze shapes, and the quality of colored glaze product is embodied in good luster, gas
Bubble, striped, calculus are few.The softening point of coloured glaze, material property depend primarily on kind and the ratio thereof of composition in coloured glaze formula, and
Adding clarifier in coloured glaze basic ingredient can make the reduction of coloured glaze fusion temperature, refining quality be improved, it is to avoid produce gas
The defects such as bubble, striped, calculus.Clarifier can release decomposition gas, or self gasification in coloured glaze production process, produces big
The bubble of amount, receives the minute bubbles of periphery, rises with blub and promotes that coloured glaze is clarified.The most conventional clarifier has titanium dioxide
Cerium, arsenicum sablimatum etc., but arsenicum sablimatum is extremely toxic substance, threatens operator's health serious environment pollution；The clarification effect of ceria
Fruit the most still can, but settling time is longer, and cerium is rare earth element, and cost is costly.Therefore need that a kind of softening point is low, material property badly
The coloured glaze formula long, clarifying effect is good, settling time is short, product property is excellent.
Summary of the invention
The present invention provide a kind of have length in service life, low cost, advantage that cleanliness factor is good, non-friable novel the most acidproof
Coloured glaze modelled after an antique.
The technical scheme is that a kind of novel strong acidproof coloured glaze modelled after an antique, described novel strong acidproof coloured glaze bag modelled after an antique
Including anticorrosive coat and coloured glaze body, described coloured glaze body includes Lead oxide brown, ceria, ferrum oxide colorant, fire retardant and carbonic acid
Barium combines, and described Lead oxide brown accounts for the 24%-29% of the overall component of coloured glaze body, and described ceria accounts for coloured glaze body
The 16%-20% of overall component, described ferrum oxide colorant accounts for the 4%-9% of the overall component of coloured glaze body, and described fire retardant accounts for coloured glaze
The 21%-23% of the overall component of glass body, described brium carbonate accounts for the 24%-30% of the overall component of coloured glaze body.
In a preferred embodiment of the present invention, the thickness of described anticorrosive coat is 1.4-2.2mm.
In a preferred embodiment of the present invention, described Lead oxide brown accounts for the 25% of the overall component of coloured glaze body, described
Ceria accounts for the 19% of the overall component of coloured glaze body, and described ferrum oxide colorant accounts for the 9% of the overall component of coloured glaze body, described
Fire retardant accounts for the 22% of the overall component of coloured glaze body, and described brium carbonate accounts for the 25% of the overall component of coloured glaze body.
The novel strong acidproof coloured glaze modelled after an antique of one of the present invention, has length in service life, low cost, cleanliness factor good, non-friable
Advantage.
Detailed description of the invention
Below presently preferred embodiments of the present invention is described in detail so that advantages and features of the invention can be easier to by
It will be appreciated by those skilled in the art that thus protection scope of the present invention is made apparent clear and definite defining.
Wherein, described novel strong acidproof coloured glaze modelled after an antique includes that anticorrosive coat and coloured glaze body, described coloured glaze body include two
Lead oxide, ceria, ferrum oxide colorant, fire retardant and brium carbonate combine, and it is total that described Lead oxide brown accounts for coloured glaze body
The 24%-29% of body component, described ceria accounts for the 16%-20% of the overall component of coloured glaze body, and described ferrum oxide colorant accounts for
The 4%-9% of the overall component of coloured glaze body, described fire retardant accounts for the 21%-23% of the overall component of coloured glaze body, described brium carbonate
Account for the 24%-30% of the overall component of coloured glaze body.
Further illustrating, the thickness of described anticorrosive coat is 1.4-2.2mm, and it is overall that described Lead oxide brown accounts for coloured glaze body
The 25% of component, described ceria accounts for the 19% of the overall component of coloured glaze body, and it is total that described ferrum oxide colorant accounts for coloured glaze body
The 9% of body component, described fire retardant accounts for the 22% of the overall component of coloured glaze body, and described brium carbonate accounts for the overall component of coloured glaze body
25%.
Further illustrating, fire retardant, giving the functional aid of combustible polymers flame retardancy, be primarily directed to macromolecule
The Principle And Method of Flame Retardation Design of material；Fire retardant has polytype, is divided into additive flame retardant and reactive flame retardant by using method.Add
Adding type fire retardant is to join in polymer by mechanical mix techniques, makes polymer have anti-flammability, current additive flame
Combustion agent mainly has organic fire-retardant and inorganic combustion inhibitor, halogenated flame retardant (organic chloride and organic bromide) and non-halogen.Have
Machine is with bromine system, phosphorus nitrogen system, nitrogen system and red phosphorus and compound some fire retardants as representative, inorganic mainly antimony oxide,
Magnesium hydroxide, aluminium hydroxide, the flame-retardant system such as silicon system.Fire retardant is to make polymer make it burn after being not easy to catch fire and catch fire
Slack-off a kind of commercial auxiliaries.In numerous fire retardant kinds, halogen flame with its good flame retardation effect, do not affect material thing
Change performance and be widely used.But, the polymer amount of being fuming when burning adding halogen flame greatly, easily releases corrosion
Property gas (such as HCl, HBr etc.) and harmful gas, easily cause secondary harm.Therefore, court studied by the fire retardant of the world today
Non-halogen direction to develop.Aluminium hydroxide, flame retardant of magnesium hydroxide are dependent on chemolysis heat absorption and release when application
Water outlet and play fire retardation, have avirulence, do not corrode processing equipment, decompose after generate aluminium oxide, magnesium oxide chemistry
Stable in properties, does not the most produce secondary harm.Along with fire incident the great personnel frequently occurring and thus bringing and
The loss of property, China is it has been specified that the electric wire used when building the important building such as subway must be halogen-free flameproof electricity
Line cable, and along with improving constantly that people's environmental conservation and inherently safe are realized, the halogen-free flameproof of polymeric material necessarily claims
For developing direction from now on.In recent years, aluminium hydroxide (ATH) fire retardant be in inorganic combustion inhibitor most widely used general, consumption is maximum
One, flame retardant of magnesium hydroxide is then one with fastest developing speed.Compared with aluminium hydroxide, the decomposition temperature of magnesium hydroxide is more
Higher (aluminium hydroxide is about 220 DEG C, and magnesium hydroxide is then at 350 ~ 400 DEG C), is more suitable for the processing request of some polymer,
And also have the effect promoting polymer carbonization.Research to flame retardant of magnesium hydroxide is more the most in recent years, and application is also
Constantly expand.
Further illustrate, brium carbonate, chemical formula BaCO3, molecular weight 197.35.Hexagon micro crystal or white powder.
It is insoluble in water, density 4.43 grams per cubic centimter, fusing point 1740 DEG C (8820 kPa of-90 atmospheric pressure).1450 DEG C of decomposition, release titanium dioxide
Carbon.It is slightly soluble in the water containing carbon dioxide, also is soluble in ammonium chloride or ammonium nitrate solution and generates complex, be dissolved in hydrochloric acid, nitric acid is put
Go out carbon dioxide.Poisonous.For electronics, instrument, metallurgical industry.Preparation fireworks, signal flare processed, ceramic coating, optical glass processed
Adjuvant.Also serve as raticide, clarification of water agent and filler.For ceramic coating and optical glass adjuvant for electronic ceramics,
The manufacture of the multiple electronic devices and components such as PTC thermistor, capacitor.Analyze the ferrum in calcium, magnesium, manganese and zinc.Calibrating and mensuration have
Halogen in machine compound.For barium salt processed, pigment, fireworks, raticide pottery, and it is used as filler and clarification of water agent etc..For
Catalyst.Produce electronic ceramics and purify water, producing pigment, coating or other barium salt and be used for optical glass processed, barium magnetic material
Etc. being to produce picture tube glass bulb, magnetic material and the important industrial chemicals of high optics glass.Process excess in plating chromic electrolyte
Sulfate radical, be also used in zinc coat white chromating solution, it is also possible to for processing containing waste water.The present invention provides one novel by force
Acidproof coloured glaze modelled after an antique, has length in service life, low cost, advantage that cleanliness factor is good, non-friable.
The detailed description of the invention of the present invention, but protection scope of the present invention is not limited thereto, any is familiar with this area
Technical staff in the technical scope that disclosed herein, the change can expected without creative work or replacement, all should contain
Cover within protection scope of the present invention.Therefore, the protection model that protection scope of the present invention should be limited with claims
Enclose and be as the criterion.
Claims (3)
1. a novel strong acidproof coloured glaze modelled after an antique, it is characterised in that: described novel strong acidproof coloured glaze modelled after an antique include anticorrosive coat and
Coloured glaze body, described coloured glaze body includes that Lead oxide brown, ceria, ferrum oxide colorant, fire retardant and brium carbonate combine,
Described Lead oxide brown accounts for the 24%-29% of the overall component of coloured glaze body, and described ceria accounts for the overall component of coloured glaze body
16%-20%, described ferrum oxide colorant accounts for the 4%-9% of the overall component of coloured glaze body, and it is overall that described fire retardant accounts for coloured glaze body
The 21%-23% of component, described brium carbonate accounts for the 24%-30% of the overall component of coloured glaze body.
Novel strong acidproof coloured glaze modelled after an antique the most according to claim 1, it is characterised in that: the thickness of described anticorrosive coat is
1.4-2.2mm。
Novel strong acidproof coloured glaze modelled after an antique the most according to claim 1, it is characterised in that: described Lead oxide brown accounts for coloured glaze originally
The 25% of the overall component of body, described ceria accounts for the 19% of the overall component of coloured glaze body, and described ferrum oxide colorant accounts for coloured glaze
The 9% of the overall component of body, described fire retardant accounts for the 22% of the overall component of coloured glaze body, and it is total that described brium carbonate accounts for coloured glaze body
The 25% of body component.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610641208.0A CN106277790A (en) | 2016-08-08 | 2016-08-08 | Novel strong acidproof coloured glaze modelled after an antique |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610641208.0A CN106277790A (en) | 2016-08-08 | 2016-08-08 | Novel strong acidproof coloured glaze modelled after an antique |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106277790A true CN106277790A (en) | 2017-01-04 |
Family
ID=57665874
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610641208.0A Pending CN106277790A (en) | 2016-08-08 | 2016-08-08 | Novel strong acidproof coloured glaze modelled after an antique |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106277790A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107739154A (en) * | 2017-09-27 | 2018-02-27 | 太仓经济开发区坚毅工艺美术品工作室 | Corrosion-resistant high transparency azure stone handicraft |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102786202A (en) * | 2012-07-26 | 2012-11-21 | 淄博市宝泉社会福利玻璃制品厂 | Manufacturing method for colored fluorine-free imitation ceramic glaze |
| CN103466945A (en) * | 2013-09-06 | 2013-12-25 | 太仓市科教新城琉璃艺术策划中心 | Formula of colored glaze |
| CN104044392A (en) * | 2014-06-27 | 2014-09-17 | 张柔佑 | Technical method of colorful glaze body |
-
2016
- 2016-08-08 CN CN201610641208.0A patent/CN106277790A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102786202A (en) * | 2012-07-26 | 2012-11-21 | 淄博市宝泉社会福利玻璃制品厂 | Manufacturing method for colored fluorine-free imitation ceramic glaze |
| CN103466945A (en) * | 2013-09-06 | 2013-12-25 | 太仓市科教新城琉璃艺术策划中心 | Formula of colored glaze |
| CN104044392A (en) * | 2014-06-27 | 2014-09-17 | 张柔佑 | Technical method of colorful glaze body |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107739154A (en) * | 2017-09-27 | 2018-02-27 | 太仓经济开发区坚毅工艺美术品工作室 | Corrosion-resistant high transparency azure stone handicraft |
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| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20170104 |