CN1062751A - A kind of method and device of producing dry distillation gas - Google Patents

A kind of method and device of producing dry distillation gas Download PDF

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Publication number
CN1062751A
CN1062751A CN 92100912 CN92100912A CN1062751A CN 1062751 A CN1062751 A CN 1062751A CN 92100912 CN92100912 CN 92100912 CN 92100912 A CN92100912 A CN 92100912A CN 1062751 A CN1062751 A CN 1062751A
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China
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coal
dry
boiler
gas
ash
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CN 92100912
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CN1025568C (en
Inventor
梁永爱
范季贤
王旌海
沈昌炽
洪邦俊
怀力田
袁春生
于盈生
马庆安
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Beijing Water Conservancy & Power Economy Inst
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Beijing Water Conservancy & Power Economy Inst
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E20/00Combustion technologies with mitigation potential
    • Y02E20/16Combined cycle power plant [CCPP], or combined cycle gas turbine [CCGT]
    • Y02E20/18Integrated gasification combined cycle [IGCC], e.g. combined with carbon capture and storage [CCS]

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  • Vaporization, Distillation, Condensation, Sublimation, And Cold Traps (AREA)
  • Coke Industry (AREA)

Abstract

The present invention relates to a kind of is the method and apparatus that thermal source is produced dry distillation gas with circular fluid bed cycling hot ash.This device mainly comprises circular fluid bed, fluidized bed dryer, dry distiller and material pneumatic conveying system.After coal drying device drying and broken the gluing, the hot ash heating that in dry distiller, is come by the self-circulation fluidized-bed combustion boiler, the generation dry distillation gas, semicoke that destructive distillation produces and the ash after the heat release are sent burner hearth back to, and semicoke is as boiler oil.Processes and apparatus of the present invention is simple, and thermosteresis is little, and gas cost is low, and caloric power of gas is greater than 14630KJ/Nm 3, carbon monoxide content is lower than 10% in the coal gas

Description

A kind of method and device of producing dry distillation gas
The present invention relates to a kind of method and device of producing dry distillation gas, particularly relating to a kind of is that thermal source adds hot coal with circular fluid bed cycling hot ash, produces the method and the device of dry distillation gas.
In the area that Sweet natural gas, liquefied petroleum gas (LPG) lack, resident living and explained hereafter are very urgent to the requirement of high-quality coal gas.The production of domestic gas at present mainly adopts coke oven, upright carbide furnace, blue-gas generator to add methanation device and lurgi gasifier etc., because their ubiquities investment greatly, efficient is low, gas cost is high and coal requires problems such as height, and its application is very limited.
USDOE report DOE/LE/40543-3, DE86 009113(1985.2)-having introduced a kind of among " fundamental research of advanced fluidized bed air well heater technology " (Ge-neric Studies of Advanced Fluid Bed Air Heater Technology) is the pressure fluidized-bed dry distillation gas production method and the device of fluidizing medium with the air.To be that the pressurization in the coal lock of the broken coal of crossing is laggard go into the fluidisation bed dryer to its method.The moisture eliminator working temperature is 370 ℃, and pressure is 17 normal atmosphere.Coal is preheated in moisture eliminator, dehydration and preoxidation broken sticking after, enter pressure fluidized-bed dry distiller, the dry distiller working temperature is 538 ℃, pressure is about 17 normal atmosphere, fugitive constituent in the coal discharges, become coal gas, the fluidized gas of moisture eliminator and dry distiller is pressurized air, and institute's heat requirement provides by part burning of coal in it.The semicoke that dry distiller is discharged is delivered to The normal pressure fluidized bed boiler combustion heat release.Because dry distiller is fluidized gas with the air, the calorific value that produces coal gas is lower, and carbon monoxide content is higher in the coal gas, can not directly be used as domestic gas, because operating pressure is higher, equipment manufacturing cost and running cost are also all higher simultaneously.
In order to overcome the deficiency of above several coal gas production method and device, the method of seeking that a kind of technology and equipment are simple, investment is low and can produce high quality coal gas, the present invention proposes a kind of is thermal source with the circular fluid bed circulating ash, produces the method and apparatus of dry distillation gas.
Production dry distillation gas method of the present invention, comprise coal preheating in fluidized bed dryer, dry, unsticking, in moisture eliminator, heat again, produce dry distillation gas, its principal character is that dry distillation of coal institute heat requirement is that the cycling hot ash of origin self-circulation fluidized-bed combustion boiler provides, and the semicoke that destructive distillation produces is sent the circular fluid bed burning that acts as a fuel back to, its key step is, the broken raw coal of crossing is introduced into the The normal pressure fluidized bed moisture eliminator, carry out preheating, drying and unsticking, the fluidizing agent of moisture eliminator is air or the hot flue gas from boiler, also can be both gas mixtures, and moisture eliminator institute heat requirement is provided by part burning of coal in it and hot obvious heat of smoke.The circulating ash of circular fluid bed separator flows to two places, and a part is directly got back to boiler furnace, and another part then is sent in the dry distiller.The scale of two portions ash amount is by the ash amount adjustment doors control that is located in the separator.The hot ash that dry coal that moisture eliminator ejects and circular fluid bed separator come is introduced in the dry distiller by a certain percentage of the weight simultaneously, coal is by the heating of heat ash, the fugitive constituent that discharges is dry distillation gas, coal becomes semicoke after discharging fugitive constituent, ash after semicoke and the heat release flows out from the dry distiller bottom, enters pneumatic carrier, and the air that is transferred blower fan is delivered to boiler furnace, the fuel of boiler is semicoke or semicoke and makes flameholding, regulates the added raw coal of boiler load.This part coal is directly to add the burner hearth burning that acts as a fuel through coal feeder of boiler.The coal gas that dry distiller comes out is delivered to conventional gas purification operation.
Produce the device that method adopted of dry distillation gas among the present invention, comprise fluidized-bed combustion boiler, fluidized bed dryer, dry distiller and material pneumatic conveying system, be characterized in, fluidized-bed combustion boiler provides the circular fluid bed that adds the required cycling hot ash of hot coal for the semicoke that can the coal combustion destructive distillation produces and for dry distiller, the upper boiler exhanst gas outlet links to each other with boiler separator, and the boiler separator bottom is connected to boiler revert pipe and the hot ash pipe of dry distiller.The hot ash pipe of boiler revert pipe and dry distiller is connected with boiler furnace and dry distiller respectively, be provided with ash amount adjustment doors in the boiler separator, fluidized bed dryer is furnished with coal bunker and feeder, outlet of moisture eliminator top and external moisture eliminator separator are connected, the excessive coal mouth of its separator lower part outlet and moisture eliminator is connected with the dry coal bucket, the grey material returning device outlet of the fuel dropping pipe of dry coal bucket bottom and dry distiller heat is joined or is directly fed dry distiller, one gas pipe is arranged at dry distiller top, there is a drainage conduit its underpart, drainage conduit with semicoke with put ash after the combustion and send the pneumatic carrier of boiler furnace back to and be connected.The used circular fluid bed of the present invention can be steam boiler or hot water boiler.Boiler separator can be cyclonic separator or inertial separator, also can be the separator of other form, and separator can vertically be arranged, also can horizontally arrange.The ash of separator can all or part ofly enter dry distiller.When boiler separator during more than one, can be from any one or send ash from several separators to dry distiller simultaneously, boiler can burn coal or semicoke.
Before raw coal enters moisture eliminator, make its maximum particle size be no more than 8 millimeters through broken.The working temperature of moisture eliminator can specifically be decided on coal between 150 ℃~370 ℃.When coal is inviscid, also can not establish moisture eliminator, directly the coal after the fragmentation is added dry distiller.
One or more separators can be established in dry distiller inside, also can not establish.The dry distiller operating pressure is a normal pressure, working temperature can be between 400 ℃~850 ℃, specifically can measure adjustment doors and control the ash amount that enters dry distiller by ash, the realization temperature is adjusted, ash is 2-20 with the weight ratio of coal in the dry distiller, instant heating ash: coal=2~20: 1, can in dry distiller, establish whipping appts, coal and ash are mixed.
Technology of the present invention is simple, invest low, gas production thermo-efficiency height, coal adaptability is wide, available bituminous coal, brown coal and part meager coal, the gas quality height, calorific value is greater than 14630KJ/Nm 3, carbon monoxide content is lower than 10%, can be directly as domestic gas.Enforcement of the present invention will be opened up an effective way for the development of China's town gas, play and save construction investment, save energy, reduce the urban atmospheric pollution degree, improve the effect of resident living level.The present invention is used for thermoelectric power station, can realize coal gas, electric power and heating power " three coproduction ", can solve the gas that only heats that exists in present cogeneration, the central heating, does not give gas the problem of resident living inconvenience; The present invention is used to transform domestic existing small-sized fuel-burning power plant, realize that coal gas and electric power " two coproduction " can improve it significantly and produce thermo-efficiency and economic benefit, make it have higher existence and competitive capacity, also can be used for transforming more existing arcolas, realize coal gas and heating power " two coproduction ".
To specifically describe the present invention below in conjunction with accompanying drawing.
Accompanying drawing is produced the used device synoptic diagram of dry distillation gas method for the present invention.
Among the figure:
(1) circular fluid bed (14) dry distiller
(2) boiler separator (15) dry distiller built-in splitter
(3) boiler revert pipe (16) gas pipe
(4) the hot ash pipe of dry distiller (17) fuel dropping pipe
(5) ash amount adjustment doors (18) coal bunker
(6) boiler material returning device (19) moisture eliminator separator
(7) dry distiller heat grey material returning device (20) induced draft fan
(8) boiler coal bunker (21) fluidized bed dryer
(9) coal feeder of boiler (22) feeder
(10) boiler primary air fan (23) moisture eliminator coal bunker
(11) boiler slagging pipe (24) blast main
(12) pneumatic carrier (25) smoke extractor
(13) conveying fan (26) drainage conduit
Accompanying drawing is also produced an embodiment of dry distillation gas device for the present invention.As shown in the figure, it mainly is made of with conveying fan (13) and relevant auxiliary facility circular fluid bed (1), fluidized bed dryer (21), dry distiller (14) and pneumatic carrier (12).Coal bunker (8) and feeder (9) are directly to boiler (1) coal supply, and primary air enters boiler (1) through primary air fan (10) from the boiler bottom air compartment.Slag remaining behind the coal combustion is regularly discharged from slagging pipe (11).Flue gas enters boiler separator (2) after burner hearth comes out, isolated ash enters the burner hearth and the dry distiller (14) of boiler (1) respectively through boiler revert pipe (3), boiler material returning device (6) and the hot ash pipe of dry distiller (4), dry distiller material returning device (7).Regulate ash amount adjustment doors (5), the ratio of may command two portions ash amount.Process moisture eliminator coal bunker (23) and feeder (22) are to moisture eliminator (21) coal supply.The fluidized gas of moisture eliminator (21) is from the hot flue gas of smoke extractor (25) with from the Air mixing gas of blast main (24).Moisture eliminator (21) is provided with an external separator (19), and used separator is a cyclonic separator in this device, and the coal grain of carrying secretly in the flue gas of moisture eliminator (21) discharge is separated.Self-separation device (19) expellant gas is through entering atmosphere behind the induced draft fan (20).The dry coal that the coal grain that separator (19) separates, moisture eliminator (21) overflow port come out all enters dry coal bucket (18), enters dry distiller (14) jointly after converging through the fuel dropping pipe (17) of its underpart and the hot ash that comes out from the dry distiller grey material returning device of heat (7).Dry distiller (14) inside is provided with a built-in cyclonic separator (15), and the dry distillation gas of generation causes follow-up cleaning section through separator (15) from gas pipe (16).Semicoke that destructive distillation produces and the ash after the heat release enter pneumatic carrier (12) from dry distiller (14) bottom through drainage conduit (26), pneumatic carrier (12) links to each other with boiler (1) burner hearth, from the air of conveying fan (13) semicoke and ash is sent into burner hearth.
Present embodiment has related parameter as follows:
Circular fluid bed:
Pattern: hot water boiler
Capacity: 7 tons/hour
Add raw coal: 30 kilograms/hour
Leaving water temperature(LWT): 75 ℃
Enter temperature: 20 ℃
Fluidized bed dryer:
Exert oneself: 150 kilograms of coals/hour
Working temperature: 350 ℃
Advance the moisture eliminator flue-gas temperature: 350 ℃
Dry distiller:
Working temperature: 700 ℃
Ash/coal: 5: 1
Gas yield: 30Nm 3/ h
Caloric power of gas: 15460KJ/Nm 3
CO content (volume): 7.5%

Claims (8)

1, a kind ofly comprise coal preheating in fluidized bed dryer, dry, unsticking, in dry distiller, heat again, produce the method for dry distillation gas, be primarily characterized in that the sensible heat of dry distillation of coal heating institute heat requirement from circular fluid bed cycling hot ash, the semicoke that destructive distillation produces in circular fluid bed as fuel combustion, its key step is, the preheating in fluidized bed dryer earlier of the broken coal of crossing, drying and unsticking, the fluidizing agent of moisture eliminator is an air or from the hot flue gas of boiler, also can be both gas mixtures, the dry institute of coal heat requirement is provided by part burning of coal in hot obvious heat of smoke and the moisture eliminator, the cycling hot ash that dry coal that moisture eliminator is discharged and circular fluid bed separator bottom attract is admitted to dry distiller simultaneously, coal is by the heating of heat ash, discharge fugitive constituent wherein, produce dry distillation gas, semicoke that the dry distillation of coal produces and the ash after the heat release are discharged from the dry distiller bottom, be sent to boiler hearth of circulating fluidized bed then, the fuel of boiler is semicoke or semicoke and makes flameholding, regulates the raw coal of boiler load.
2,, it is characterized in that the coal carbonization temperature is between 400~850 ℃ in the dry distiller according to the method for the described production dry distillation gas of claim 1.
3,, it is characterized in that entering the heat ash of dry distiller and the weight specific heat ash of coal according to the method for claim 1 or 2 described production dry distillation gases: coal=(2-20): 1.
4,, it is characterized in that the isolated cycling hot ash of circular fluid bed separator partly or entirely enters dry distiller according to the method for the described production dry distillation gas of claim 1.
5, a kind of used device of method of producing dry distillation gas according to claim 1, comprise fluidized-bed combustion boiler, fluidized bed dryer, dry distiller and material pneumatic conveying system, it is characterized in that fluidized-bed combustion boiler provides the circular fluid bed that adds the required cycling hot ash of hot coal (1) for the semicoke that can the coal combustion destructive distillation be produced and for dry distiller, boiler (1) top exhanst gas outlet links to each other with boiler separator (2), boiler revert pipe (3) and the hot ash pipe of dry distiller (4) that boiler separator (2) bottom is connected to are connected with boiler (1) burner hearth and dry distiller (14) inside respectively, fluidized bed dryer (21) top is connected with moisture eliminator separator (19), the excessive coal mouth of separator (19) lower part outlet and moisture eliminator (21) is connected with coal bunker (18), the dry coal fuel dropping pipe (17) of coal bunker (18) bottom is connected or directly is connected with dry distiller (14) with the dry distiller grey material returning device of heat (7) outlet, one gas pipe (16) is arranged at dry distiller (14) top, there is a drainage conduit (26) its underpart, and drainage conduit (26) is connected with the pneumatic carrier (12) of the ash after semicoke and the heat release being sent back to boiler (1) burner hearth.
6,, it is characterized in that circular fluid bed is steam boiler or is hot water boiler according to the described device of claim 5.
7,, it is characterized in that to establish one or more separators in the dry distiller according to the described device of claim 5.
8,, it is characterized in that to be provided with in the dry distiller whipping appts that coal and hot ash are mixed according to claim 5,6 or 7 described devices.
CN 92100912 1992-02-18 1992-02-18 Producing method and device for dry distilation coal gas Expired - Fee Related CN1025568C (en)

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Application Number Priority Date Filing Date Title
CN 92100912 CN1025568C (en) 1992-02-18 1992-02-18 Producing method and device for dry distilation coal gas

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Application Number Priority Date Filing Date Title
CN 92100912 CN1025568C (en) 1992-02-18 1992-02-18 Producing method and device for dry distilation coal gas

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CN1062751A true CN1062751A (en) 1992-07-15
CN1025568C CN1025568C (en) 1994-08-03

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Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1038765C (en) * 1995-03-02 1998-06-17 孙北斗 Fixed bed atmospheric pressure coal gasifying generating furnace
CN1318796C (en) * 2004-07-26 2007-05-30 中国科学院工程热物理研究所 Method for producing both gas and steam, and boiler of circulating fluid bed with pyrolysis vaporizer
CN101168693B (en) * 2006-10-27 2010-09-08 神华集团有限责任公司 Low water content high heating value coal dust and its preparing method and device
CN102175030A (en) * 2011-02-28 2011-09-07 邹炎 System and method for integrating smoke purification and lignite quality-improvement
CN102175034A (en) * 2011-02-11 2011-09-07 宋文奇 Raw coal recycling process
CN102391892A (en) * 2011-09-21 2012-03-28 首钢总公司 Blast furnace gas enrichment apparatus and method
CN102585913A (en) * 2012-03-12 2012-07-18 浙江大学 Coal gas, tar, semi-coke and steam poly-generation method based on fluidized bed pyrolysis technology
CN102952554A (en) * 2011-08-26 2013-03-06 北京低碳清洁能源研究所 Carbonaceous material dry distillation system
CN109595541A (en) * 2017-12-14 2019-04-09 湘潭锅炉有限责任公司 A kind of lignite circulating fluidized bed boiler

Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1038765C (en) * 1995-03-02 1998-06-17 孙北斗 Fixed bed atmospheric pressure coal gasifying generating furnace
CN1318796C (en) * 2004-07-26 2007-05-30 中国科学院工程热物理研究所 Method for producing both gas and steam, and boiler of circulating fluid bed with pyrolysis vaporizer
CN101168693B (en) * 2006-10-27 2010-09-08 神华集团有限责任公司 Low water content high heating value coal dust and its preparing method and device
CN102175034A (en) * 2011-02-11 2011-09-07 宋文奇 Raw coal recycling process
CN102175030A (en) * 2011-02-28 2011-09-07 邹炎 System and method for integrating smoke purification and lignite quality-improvement
CN102175030B (en) * 2011-02-28 2013-01-23 邹炎 System and method for integrating smoke purification and lignite quality-improvement
CN102952554A (en) * 2011-08-26 2013-03-06 北京低碳清洁能源研究所 Carbonaceous material dry distillation system
CN102952554B (en) * 2011-08-26 2014-05-07 北京低碳清洁能源研究所 Carbonaceous material dry distillation system
CN102391892A (en) * 2011-09-21 2012-03-28 首钢总公司 Blast furnace gas enrichment apparatus and method
CN102585913A (en) * 2012-03-12 2012-07-18 浙江大学 Coal gas, tar, semi-coke and steam poly-generation method based on fluidized bed pyrolysis technology
CN102585913B (en) * 2012-03-12 2013-11-06 浙江大学 Coal gas, tar, semi-coke and steam poly-generation method based on fluidized bed pyrolysis technology
CN109595541A (en) * 2017-12-14 2019-04-09 湘潭锅炉有限责任公司 A kind of lignite circulating fluidized bed boiler

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