CN106271201A - A kind of for welding the tensile strength structural alloy steel submerged arc flux-cored wire more than 800MPa - Google Patents

A kind of for welding the tensile strength structural alloy steel submerged arc flux-cored wire more than 800MPa Download PDF

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Publication number
CN106271201A
CN106271201A CN201610782244.9A CN201610782244A CN106271201A CN 106271201 A CN106271201 A CN 106271201A CN 201610782244 A CN201610782244 A CN 201610782244A CN 106271201 A CN106271201 A CN 106271201A
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CN
China
Prior art keywords
welding
tensile strength
800mpa
flux
component
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CN201610782244.9A
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Chinese (zh)
Inventor
杨佰超
邹付兵
杨鸿熙
任勇
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Beijing Wisdom Technology Development Co Ltd
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Beijing Wisdom Technology Development Co Ltd
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Application filed by Beijing Wisdom Technology Development Co Ltd filed Critical Beijing Wisdom Technology Development Co Ltd
Priority to CN201610782244.9A priority Critical patent/CN106271201A/en
Publication of CN106271201A publication Critical patent/CN106271201A/en
Pending legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K35/00Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
    • B23K35/22Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by the composition or nature of the material
    • B23K35/24Selection of soldering or welding materials proper
    • B23K35/30Selection of soldering or welding materials proper with the principal constituent melting at less than 1550 degrees C
    • B23K35/3053Fe as the principal constituent
    • B23K35/3066Fe as the principal constituent with Ni as next major constituent
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K9/00Arc welding or cutting
    • B23K9/18Submerged-arc welding

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Plasma & Fusion (AREA)
  • Nonmetallic Welding Materials (AREA)
  • Arc Welding In General (AREA)

Abstract

A kind of for welding the tensile strength structural alloy steel submerged arc flux-cored wire more than 800MPa, belong to materials processing field of welding material.The component of its powder body medicated core and the weight/mass percentage composition of each component be: ferrotianium: 12, molybdenum-iron: 23, electrolytic manganese: 68, metal nickel powder: 9 11, ferrosilicon: 23, iron powder: surplus;Flux-cored wire crust band is SPCC steel band;Powder body medicated core filling rate in cored solder wire is 28 32%.Using submerged-arc welding to prepare welding alloy technique, welding condition is: voltage 28 35V;Electric current 450 550A;Interlayer temperature 120 160 DEG C;Welding wire stretches out the distance of ignition tip: 40 50mm.There is the tensile strength more than 800MPa, excellent low-temperature impact resistance toughness, it is possible to be applicable to the lifting spud leg etc. of the structure member of top load, such as drilling platform.

Description

A kind of for welding the tensile strength structural alloy steel submerged arc medicated core more than 800MPa Welding wire
Technical field
The invention belongs to materials processing field of welding material, relate to a kind of for welding the tensile strength conjunction more than 800MPa Gold structural steel submerged arc welding flux-cored wire, uses in the heavy structures such as sea oil drilling and production platform leg.
Background technology
Tensile strength is the most up to standard with low-temperature impact toughness is the one of the main reasons causing petroleum drilling and mining platform leg to lose efficacy, Huge risk and material consumption is brought to petroleum drilling and mining.In modern industry and technology develop, petroleum drilling and mining carrying structure exists In the face of increasingly rugged environment in using, Tensile strength and low-temperature impact-resistant performance are required more and more higher.
High-intensity welding alloy tensile property under the effect of certain impact power depends on several factors, depends mainly on Its alloy is constituted and substrate microstructure.In order to tackle the complex work environment of big load and low-temperature impact, it is desired to welding metal is existing The tensile strength mated with mother metal has again preferable low-temperature impact toughness.
Summary of the invention
It is an object of the invention to provide a kind of for welding the tensile strength structural alloy steel submerged-arc welding more than 800MPa Connect flux-cored wire.
For achieving the above object, the present invention adopts the technical scheme that: add to improve the tensile strength of welding alloy Certain nickel and molybdenum element;In order to improve toughness and the crack resistance of welding alloy, reduce the content of carbon, and add Mn element conduct Austenizer makes in the matrix of welding alloy thing predominantly ferrite and austenite mutually, simultaneously because the addition of Mn, welding Alloy also has oneself's hardening capacity under the conditions of impact, it is even more important that the addition of a small amount of Ti element, has refined group greatly Knit crystal grain, the crystal boundary encryption that crystal grain refinement brings, further increase tensile strength.
Based on above-mentioned technical though, the present invention's is a kind of for welding the tensile strength structural alloy steel use more than 800MPa Submerged arc welding flux-cored wire, it is characterised in that the component of its powder body medicated core and the weight/mass percentage composition (%) of each component be: titanium Ferrum: 1-2, molybdenum-iron: 2-3, electrolytic manganese: 6-8, metal nickel powder: 9-11, ferrosilicon: 2-3, iron powder: surplus;Flux-cored wire crust band For SPCC steel band;Powder body medicated core filling rate in cored solder wire i.e. crust band is 30-35%.The component of described ferrotianium and each Component percentages is Ti30-40%, Fe surplus;The component of molybdenum-iron and each component percentages are Mo 55-60%, C≤0.1%, Fe Surplus;The component of electrolytic manganese is Mn99.5%, C≤0.08%, surplus impurity;The component of metal nickel powder is Ni 99.8%, surplus Impurity;The component of ferrosilicon is Si 40-45%, Fe surplus.
The above-mentioned flux-cored wire of the present invention is used to prepare a kind of for welding the tensile strength structural alloy steel more than 800MPa Method with submerged arc welding flux-cored wire, it is characterised in that comprise the steps:
Step 1, rolls welding wire according to above-mentioned powder core proportioning medicated core, obtains the powder cored filament material of diameter 4.0mm;Step 2, uses Welding alloy technique is prepared in submerged-arc welding, and welding condition is: voltage 28-35V;Electric current 450-550A;Interlayer temperature 120-160 ℃;Welding wire stretches out the distance of ignition tip: 40-50mm.
Described in step 2, welding procedure is optimized, and welding condition is set as: voltage 30-32V;Electric current 480- 520A;Interlayer temperature 140-150 DEG C;Welding wire stretches out the distance of ignition tip: 42-45mm.
The most described flux-cored wire, each compositional range of welding wire is preferably as follows: ferrotianium 1.2%, molybdenum-iron 2.8%, electrolytic manganese 6%, metal nickel powder 10%, ferrosilicon 2.5%, iron powder surplus.
The content of the alloying element formed in welding alloy is in the range of following: Mo:0.6-0.7wt.%;Mn:1.4~ 2wt.%;Ti:0.05~0.2wt.%;Ni:2-2.5wt.%;C:0.05~0.1wt.%;Fe: surplus;
In flux-cored wire, main component effect is as follows:
Titanium: crystal grain thinning, can improve the tensile strength of deposited metal.
Manganese: austenizer, makes the metallic matrix thing after welding be mainly ferrite and austenite mutually, does not produce geneva Body, and under shock environment, produce shock peening.
Molybdenum: improve the tensile strength of deposited metal, reduces the temper brittleness of deposited metal.Solid solution molybdenum in the base Atomic energy strengthens the intensity of matrix, improves the tensile strength of deposited metal.
Carbon: make matrix obtain certain intensity.
Welding alloy prepared by the flux-cored wire developed by the present invention contains the tensile strength more than 800MPa, and higher is low Temperature impact flexibility.Result shows that welding usability is good, and after welding, metal is under the conditions of certain impact, tensile property and shock resistance Function admirable, it is achieved that goal of the invention.
Accompanying drawing explanation
Fig. 1 is the scene photograph of example welding.
Detailed description of the invention
The welding wire of the present invention is realized by the following method:
Select the SPCC steel band of 16 × 0.8 (width is 16mm, and thickness is 0.8mm).First rolled into U-shaped.According to medicated core Proportion design is made into medicated powder, adds powder rolling and tube reducing becomes the welding wire of diameter 4.0mm.
Embodiment 1, ZS80M
A kind of for welding the tensile strength structural alloy steel submerged arc welding flux-cored wire more than 800MPa, described powder body The proportioning of medicated core is: ferrotianium 1.2%, molybdenum-iron 2.8%, electrolytic manganese 6%, metal nickel powder 10%, ferrosilicon 2.5%, and iron powder surplus is filled out Powder rate is 31%.Welding condition is set as: voltage 32V;Electric current 490A;Interlayer temperature 145 DEG C;Welding wire stretches out ignition tip Distance: 45mm.Select high alkalinity submerged arc welding flux ZSHJ801.Welding alloy composition prepared by above-mentioned technique is shown in Table 1, site welding Meeting Fig. 1, weld properties is shown in Table 2.
Welding alloy prepared by example is carried out chemical composition test and Mechanics Performance Testing.Chemical composition is shown in Table 1, mechanics Results of property is shown in Table 2, and welding condition is shown in Table 3.
In the above-described embodiments, component and each component percentages of described ferrotianium is Ti30-40%, Fe surplus;Molybdenum-iron Component and each component percentages are Mo 55-60%, C≤0.1%, Fe surplus;The component of electrolytic manganese be Mn99.5%, C≤ 0.08%, surplus impurity;The component of metal nickel powder is Ni 99.8%, surplus impurity;The component of ferrosilicon is Si 40-45%, Fe Surplus.
Table 1 is the chemical component table of deposited metal
Table 2 is the mechanical property table of deposited metal
Table 2
Table 3 is welding parameter
Gage of wire (mm) Welding current (A) Weldingvoltage (V) Interlayer temperature (DEG C)
4.0 490 32 145
The welding wire of the present invention is not limited by examples detailed above, any scope claimed in claims of the present invention Interior improvement and change are all within protection scope of the present invention.

Claims (9)

1., for welding a tensile strength structural alloy steel submerged arc welding flux-cored wire more than 800MPa, its feature exists In, the component of its powder body medicated core and the weight/mass percentage composition (%) of each component be: ferrotianium: 1-2, molybdenum-iron: 2-3, electrolytic manganese: 6-8, Metal nickel powder: 9-11, ferrosilicon: 2-3, iron powder: surplus;Flux-cored wire crust band is SPCC steel band;Powder body medicated core is in hollow weldering Filling rate in silk i.e. crust band is 30-35%.
2. according to a kind of structural alloy steel submerged arc welding being more than 800MPa for welding tensile strength described in claim 1 Flux-cored wire, it is characterised in that ferrotianium 1.2%, molybdenum-iron 2.8%, electrolytic manganese 6%, metal nickel powder 10%, ferrosilicon 2.5%, iron powder Surplus.
3. according to a kind of structural alloy steel submerged arc welding being more than 800MPa for welding tensile strength described in claim 1 Flux-cored wire, it is characterised in that the component of described ferrotianium and each component percentages are Ti30-40%, Fe surplus.
4. according to a kind of structural alloy steel submerged arc welding being more than 800MPa for welding tensile strength described in claim 1 Flux-cored wire, it is characterised in that the component of molybdenum-iron and each component percentages are Mo 55-60%, C≤0.1%, Fe surplus.
5. according to a kind of structural alloy steel submerged arc welding being more than 800MPa for welding tensile strength described in claim 1 Flux-cored wire, it is characterised in that the component of electrolytic manganese is Mn99.5%, C≤0.08%, surplus impurity.
6. according to a kind of structural alloy steel submerged arc welding being more than 800MPa for welding tensile strength described in claim 1 Flux-cored wire, it is characterised in that the component of metal nickel powder is Ni 99.8%, surplus impurity.
7. according to a kind of structural alloy steel submerged arc welding being more than 800MPa for welding tensile strength described in claim 1 Flux-cored wire, it is characterised in that the component of ferrosilicon is Si 40-45%, Fe surplus.
8. use the flux-cored wire described in any one of claim 1-7 for welding the tensile strength alloy structure more than 800MPa The method of steel, it is characterised in that comprise the following steps: step 1, rolls welding wire according to above-mentioned powder core proportioning medicated core, obtains diameter The powder cored filament material of 4.0mm;
Step 2, uses submerged-arc welding to prepare welding alloy technique, and welding condition is: voltage 28-35V;Electric current 450-550A; Interlayer temperature 120-160 DEG C;Welding wire stretches out the distance of ignition tip: 40-50mm.
The most in accordance with the method for claim 8, it is characterised in that described in step 2, welding procedure is optimized, by welding procedure Parameter is set as: voltage 30-32V;Electric current 480-520A;Interlayer temperature 140-150 DEG C;Welding wire stretches out the distance of ignition tip: 42- 45mm。
CN201610782244.9A 2016-08-30 2016-08-30 A kind of for welding the tensile strength structural alloy steel submerged arc flux-cored wire more than 800MPa Pending CN106271201A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108340091A (en) * 2018-05-14 2018-07-31 北京智双科技发展有限公司 A kind of ultra-fine diameter X80 pipe line steel flux-cored wire used for welding
CN111360449A (en) * 2020-03-31 2020-07-03 西安理工大学 Flux-cored wire for additive manufacturing and preparation method of low-alloy high-strength steel
CN113649675A (en) * 2021-08-26 2021-11-16 武汉钢铁有限公司 Double-wire submerged arc welding method for engineering mechanical steel with tensile strength of 800MPa

Citations (8)

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Publication number Priority date Publication date Assignee Title
GB1162473A (en) * 1967-02-09 1969-08-27 Murex Welding Processes Ltd Improvements in Arc Welding.
CN1433869A (en) * 2003-02-21 2003-08-06 安泰科技股份有限公司 Low-alloy high-strength high-toughness electric welding rod
CN1528555A (en) * 2003-10-17 2004-09-15 安泰科技股份有限公司 High-strength welding electrode
CN1857849A (en) * 2006-05-29 2006-11-08 中国船舶重工集团公司第七二五研究所 High strength and high toughness welding rod
CN101549442A (en) * 2008-03-31 2009-10-07 鞍钢股份有限公司 High-toughness metal core gas shielded welding wire and manufacturing method thereof
CN101733580A (en) * 2008-11-18 2010-06-16 山东索力得焊材有限公司 800MPa-grade high-strength high-tenacity gas shielded welding wire
CN103028864A (en) * 2012-12-14 2013-04-10 中国船舶重工集团公司第七二五研究所 High-strength and high-toughness metal powder type flux-cored wire with no need of being pre-heated before welded
CN104942475A (en) * 2015-07-10 2015-09-30 北京工业大学 High-strength metal core submerged arc welding wire for X90/X100 pipeline steel and preparation method of high-strength metal core submerged arc welding wire

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1162473A (en) * 1967-02-09 1969-08-27 Murex Welding Processes Ltd Improvements in Arc Welding.
CN1433869A (en) * 2003-02-21 2003-08-06 安泰科技股份有限公司 Low-alloy high-strength high-toughness electric welding rod
CN1528555A (en) * 2003-10-17 2004-09-15 安泰科技股份有限公司 High-strength welding electrode
CN1857849A (en) * 2006-05-29 2006-11-08 中国船舶重工集团公司第七二五研究所 High strength and high toughness welding rod
CN101549442A (en) * 2008-03-31 2009-10-07 鞍钢股份有限公司 High-toughness metal core gas shielded welding wire and manufacturing method thereof
CN101733580A (en) * 2008-11-18 2010-06-16 山东索力得焊材有限公司 800MPa-grade high-strength high-tenacity gas shielded welding wire
CN103028864A (en) * 2012-12-14 2013-04-10 中国船舶重工集团公司第七二五研究所 High-strength and high-toughness metal powder type flux-cored wire with no need of being pre-heated before welded
CN104942475A (en) * 2015-07-10 2015-09-30 北京工业大学 High-strength metal core submerged arc welding wire for X90/X100 pipeline steel and preparation method of high-strength metal core submerged arc welding wire

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108340091A (en) * 2018-05-14 2018-07-31 北京智双科技发展有限公司 A kind of ultra-fine diameter X80 pipe line steel flux-cored wire used for welding
CN108340091B (en) * 2018-05-14 2020-07-31 北京智双科技发展有限公司 Flux-cored wire for welding superfine X80 pipeline steel
CN111360449A (en) * 2020-03-31 2020-07-03 西安理工大学 Flux-cored wire for additive manufacturing and preparation method of low-alloy high-strength steel
CN111360449B (en) * 2020-03-31 2022-04-01 西安理工大学 Flux-cored wire for additive manufacturing and preparation method of low-alloy high-strength steel
CN113649675A (en) * 2021-08-26 2021-11-16 武汉钢铁有限公司 Double-wire submerged arc welding method for engineering mechanical steel with tensile strength of 800MPa

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