CN106271199A - A kind of corrosion-resistant welding wire of low-temperature storage tank - Google Patents

A kind of corrosion-resistant welding wire of low-temperature storage tank Download PDF

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Publication number
CN106271199A
CN106271199A CN201610634842.1A CN201610634842A CN106271199A CN 106271199 A CN106271199 A CN 106271199A CN 201610634842 A CN201610634842 A CN 201610634842A CN 106271199 A CN106271199 A CN 106271199A
Authority
CN
China
Prior art keywords
corrosion
low
storage tank
welding wire
temperature storage
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610634842.1A
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Chinese (zh)
Inventor
卢齐元
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Tianchang Tonglian Welding Industry Co Ltd
Original Assignee
Tianchang Tonglian Welding Industry Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Tianchang Tonglian Welding Industry Co Ltd filed Critical Tianchang Tonglian Welding Industry Co Ltd
Priority to CN201610634842.1A priority Critical patent/CN106271199A/en
Publication of CN106271199A publication Critical patent/CN106271199A/en
Pending legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K35/00Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
    • B23K35/22Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by the composition or nature of the material
    • B23K35/24Selection of soldering or welding materials proper
    • B23K35/30Selection of soldering or welding materials proper with the principal constituent melting at less than 1550 degrees C
    • B23K35/3053Fe as the principal constituent
    • B23K35/308Fe as the principal constituent with Cr as next major constituent
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K35/00Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
    • B23K35/22Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by the composition or nature of the material
    • B23K35/24Selection of soldering or welding materials proper
    • B23K35/30Selection of soldering or welding materials proper with the principal constituent melting at less than 1550 degrees C
    • B23K35/3053Fe as the principal constituent
    • B23K35/308Fe as the principal constituent with Cr as next major constituent
    • B23K35/3086Fe as the principal constituent with Cr as next major constituent containing Ni or Mn
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K35/00Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
    • B23K35/22Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by the composition or nature of the material
    • B23K35/36Selection of non-metallic compositions, e.g. coatings, fluxes; Selection of soldering or welding materials, conjoint with selection of non-metallic compositions, both selections being of interest
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K35/00Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
    • B23K35/22Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by the composition or nature of the material
    • B23K35/36Selection of non-metallic compositions, e.g. coatings, fluxes; Selection of soldering or welding materials, conjoint with selection of non-metallic compositions, both selections being of interest
    • B23K35/3601Selection of non-metallic compositions, e.g. coatings, fluxes; Selection of soldering or welding materials, conjoint with selection of non-metallic compositions, both selections being of interest with inorganic compounds as principal constituents
    • B23K35/3607Silica or silicates

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Nonmetallic Welding Materials (AREA)
  • Arc Welding In General (AREA)

Abstract

The invention discloses a kind of corrosion-resistant welding wire of low-temperature storage tank, its component includes by weight percentage: Ni 10 13%, Cr 25 29%, Mn 1.21 1.85%, Si 0.2 0.4%, C≤0.018%, Co≤0.12%, Nb≤0.015%, V≤0.021%, B≤0.012%, P≤0.015%, S≤0.015%, surplus be Fe and other be inevitably mingled with.Drawing property of the present invention is good, corrosion-resistant and tenacity excellent.

Description

A kind of corrosion-resistant welding wire of low-temperature storage tank
Technical field
The present invention relates to welding wire technology field, particularly relate to a kind of corrosion-resistant welding wire of low-temperature storage tank.
Background technology
Along with developing rapidly of gas industry, transportable pressure vessel i.e. truck tank, railway tank and tank container Manufacture increasingly paid close attention to by people, these hazardous materials transportation and equipment industry emerge rapidly.Low temperature movable type pressure holds The inner canister temperature of device is the lowest, and outer tank is under room temperature, and for whole container, its thermograde is big, process bad easily Producing the biggest thermal stress in weld seam lap-joint, commissure drawing property is poor, and corrosion-resistant and toughness does not reaches demand, easily produces and splits Stricture of vagina and seepage, at present in the low-temperature storage tank of particular/special requirement, drawing, corrosion-resistant and toughness wlding performance are in urgent need to be improved.
Summary of the invention
The technical problem existed based on background technology, the present invention proposes a kind of corrosion-resistant welding wire of low-temperature storage tank, drawing Performance is good, corrosion-resistant and tenacity excellent.
The corrosion-resistant welding wire of a kind of low-temperature storage tank that the present invention proposes, its component includes by weight percentage:
Surplus be Fe and other be inevitably mingled with.
Preferably, the content of C, Mn and Si meets functional relation: YMn=2.85 × ZSi+1.46×XC+0.006;XC、 YMn、ZSiRepresent C, Mn, Si shared percentage by weight in component respectively.
Preferably, Ni Yu Cr weight ratio is 12-12.5:24-26.
Preferably, the weight ratio of Mn, Si and C is 1.4-1.6:0.25-0.35:0.012-0.014.
Preferably, the weight ratio of Co, Nb, V, B is 0.08-0.1:0.01-0.012:0.01-0.016:0.01-0.014.
Preferably, Ni Yu Mn weight ratio is 12-12.5:1.4-1.6.
Preferably, the corrosion-resistant welding wire of described low-temperature storage tank, its component includes by weight percentage:
Surplus be Fe and other be inevitably mingled with.
Low-temperature storage tank of the present invention is identical with prior art preparation method by the preparation method of corrosion-resistant welding wire.
In the present invention, C, Si, Mn, P, S, Ni, Cr element mating reaction, can effectively promote to produce in a large number in weld metal The fine acicular ferritic structure of high density dislocation, low-temperature flexibility is good, and wherein C, Mn, Si mating reaction can be effectively improved weld metal Quenching degree, suppression pro-eutectoid ferrite generation, promote acicular ferrite formation, further with Ni, Cr, Cu mating reaction Goods drawing property can be effectively improved, can meet that weld seam lap-joint is corrosion-resistant, the solder technology requirement of high intensity, high tenacity.
Wherein, chromium essentially consists in raising goods decay resistance, and the underlying cause is to add chromium in steel as alloy unit After element, promote its internally paradoxical movement to be conducive to opposing corrosion failure aspect development.Concrete principle: chromium makes iron-based solid The electrode potential of solution improves;Chromium absorbs the electronics of ferrum makes ferrum be passivated.Passivation is to cause metal owing to anode reaction is prevented from The phenomenon being enhanced with alloy corrosion resistance.Constitute the theoretical a lot of of Metal and Alloy passivation, mainly have thin film opinion, adsorption theory And electronic configuration opinion.I.e. chromium can form one layer of chromium oxide protecting film at stainless steel surfaces after oxidation, can effectively hinder The entrance of the most extraneous soda acid factor and continuation corrosion.
The effect of nickel is just brought into play after coordinating with chromium, and nickel is the element forming austenite in steel, and nickel is same with chromium Time when being present in rustless steel, nickel coordinates with chromium makes tissue change, so that the decay resistance of goods and processing performance Improve, improve stainless mechanical performance, increase stainless ductility, create good condition for its deep-draw and shaping.
Carbon in rustless steel on tissue impact be mainly manifested in two aspects, on the one hand carbon is the element of stable austenite, And the degree acted on is very big, on the other hand very big due to the affinity of carbon and chromium, with the carbide that chromium forms series of complex. Affect stainless decay resistance.When additionally carbon amounts is higher, welding seam toughness declines, and weld seam medium pearlite ratio increases, and controls The intercrystalline corrosion of chromium nickel stainless steel be can largely overcome at certain content, and welding and cold deformation are prone to.
The effect of manganese is that it reduces the critical quenching rate of steel, increases the stability of austenite, suppression Austria when cooling The decomposition of family name's body, makes the austenite formed under high temperature be maintained room temperature, is the effective element of weld seam Strengthening and Toughening, in weld seam Be conducive to deoxidation, prevent from causing the formation of the iron sulfide of fire check.
Silicon plays deoxidation and strengthening weld seam effect when welding, and it also forms ferritic element, at general rustless steel In for often depositing impurity element, and stainless processing performance is also had a major impact by a certain amount of silicon, good to ensure when welding Good mobility and molding.
Detailed description of the invention
Below, by specific embodiment, technical scheme is described in detail.
Embodiment 1
A kind of corrosion-resistant welding wire of low-temperature storage tank, its component includes by weight percentage:
Surplus be Fe and other be inevitably mingled with.
Embodiment 2
A kind of corrosion-resistant welding wire of low-temperature storage tank, its component includes by weight percentage:
Surplus be Fe and other be inevitably mingled with.
Embodiment 3
A kind of corrosion-resistant welding wire of low-temperature storage tank, its component includes by weight percentage:
Surplus be Fe and other be inevitably mingled with.
Embodiment 4
A kind of corrosion-resistant welding wire of low-temperature storage tank, its component includes by weight percentage:
Surplus be Fe and other be inevitably mingled with.
Embodiment 5
A kind of corrosion-resistant welding wire of low-temperature storage tank, its component includes by weight percentage:
Surplus be Fe and other be inevitably mingled with.
The above, the only present invention preferably detailed description of the invention, but protection scope of the present invention is not limited thereto, Any those familiar with the art in the technical scope that the invention discloses, according to technical scheme and Inventive concept equivalent or change in addition, all should contain within protection scope of the present invention.

Claims (7)

1. the corrosion-resistant welding wire of low-temperature storage tank, it is characterised in that its component includes by weight percentage:
The corrosion-resistant welding wire of low-temperature storage tank the most according to claim 1, it is characterised in that the content of C, Mn and Si meets letter Number relational expression: YMn=2.85 × ZSi+1.46×XC+0.006;XC、YMn、ZSiRepresent C, Mn, Si shared weight in component respectively Percentage ratio.
The corrosion-resistant welding wire of low-temperature storage tank the most according to claim 1 and 2, it is characterised in that Ni Yu Cr weight ratio is 12- 12.5:24-26.
4. according to the corrosion-resistant welding wire of low-temperature storage tank described in any one of claim 1-3, it is characterised in that the weight of Mn, Si and C Amount ratio is 1.4-1.6:0.25-0.35:0.012-0.014.
5. according to the corrosion-resistant welding wire of low-temperature storage tank described in any one of claim 1-4, it is characterised in that Co, Nb, V, B's Weight ratio is 0.08-0.1:0.01-0.012:0.01-0.016:0.01-0.014.
6. according to the corrosion-resistant welding wire of low-temperature storage tank described in any one of claim 1-5, it is characterised in that Ni Yu Mn weight ratio For 12-12.5:1.4-1.6.
7. according to the corrosion-resistant welding wire of low-temperature storage tank described in any one of claim 1-6, it is characterised in that its component is by weight Percentage ratio includes:
CN201610634842.1A 2016-08-05 2016-08-05 A kind of corrosion-resistant welding wire of low-temperature storage tank Pending CN106271199A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610634842.1A CN106271199A (en) 2016-08-05 2016-08-05 A kind of corrosion-resistant welding wire of low-temperature storage tank

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610634842.1A CN106271199A (en) 2016-08-05 2016-08-05 A kind of corrosion-resistant welding wire of low-temperature storage tank

Publications (1)

Publication Number Publication Date
CN106271199A true CN106271199A (en) 2017-01-04

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Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5677095A (en) * 1979-11-30 1981-06-25 Daido Steel Co Ltd Stainless steel welding wire
CN101100021A (en) * 2007-07-20 2008-01-09 常州华通焊丝有限公司 Austenitic stainless steel gas shield welding wire for vehicle
CN101244494A (en) * 2008-03-28 2008-08-20 常州华通焊丝有限公司 Austenitic stainless steel buried arc welding wire for low-temperature equipment
CN101352786A (en) * 2008-09-27 2009-01-28 北京金威焊材有限公司 Submerged arc welding wire for stainless steel
CN102019517A (en) * 2010-12-10 2011-04-20 哈尔滨威尔焊接有限责任公司 Novel stainless steel submerged-arc welding wire for improving tensile strength after heat treatment
CN103042316A (en) * 2012-12-21 2013-04-17 武汉市润之达石化设备有限公司 Ultra-low temperature austenite stainless steel solid core welding wire
CN105057917A (en) * 2015-08-14 2015-11-18 中国科学院金属研究所 Austenitic stainless steel welding wire having antibacterial function
CN105643140A (en) * 2016-03-30 2016-06-08 内蒙古第机械集团有限公司 Welding wire special for high-nitrogen austenitic stainless steel

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5677095A (en) * 1979-11-30 1981-06-25 Daido Steel Co Ltd Stainless steel welding wire
CN101100021A (en) * 2007-07-20 2008-01-09 常州华通焊丝有限公司 Austenitic stainless steel gas shield welding wire for vehicle
CN101244494A (en) * 2008-03-28 2008-08-20 常州华通焊丝有限公司 Austenitic stainless steel buried arc welding wire for low-temperature equipment
CN101352786A (en) * 2008-09-27 2009-01-28 北京金威焊材有限公司 Submerged arc welding wire for stainless steel
CN102019517A (en) * 2010-12-10 2011-04-20 哈尔滨威尔焊接有限责任公司 Novel stainless steel submerged-arc welding wire for improving tensile strength after heat treatment
CN103042316A (en) * 2012-12-21 2013-04-17 武汉市润之达石化设备有限公司 Ultra-low temperature austenite stainless steel solid core welding wire
CN105057917A (en) * 2015-08-14 2015-11-18 中国科学院金属研究所 Austenitic stainless steel welding wire having antibacterial function
CN105643140A (en) * 2016-03-30 2016-06-08 内蒙古第机械集团有限公司 Welding wire special for high-nitrogen austenitic stainless steel

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Application publication date: 20170104

RJ01 Rejection of invention patent application after publication