CN106268212A - A kind of papermaking solid waste burning flying dust is for the technique of thermoelectricity flue gas desulfurization - Google Patents
A kind of papermaking solid waste burning flying dust is for the technique of thermoelectricity flue gas desulfurization Download PDFInfo
- Publication number
- CN106268212A CN106268212A CN201610654381.4A CN201610654381A CN106268212A CN 106268212 A CN106268212 A CN 106268212A CN 201610654381 A CN201610654381 A CN 201610654381A CN 106268212 A CN106268212 A CN 106268212A
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- China
- Prior art keywords
- flue gas
- flying dust
- solid waste
- desulfurization
- technique
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000428 dust Substances 0.000 title claims abstract description 30
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 title claims abstract description 25
- 239000003546 flue gas Substances 0.000 title claims abstract description 25
- 238000006477 desulfuration reaction Methods 0.000 title claims abstract description 24
- 230000023556 desulfurization Effects 0.000 title claims abstract description 22
- 238000000034 method Methods 0.000 title claims abstract description 20
- 239000002910 solid waste Substances 0.000 title claims abstract description 15
- 230000005619 thermoelectricity Effects 0.000 title claims abstract description 9
- 229910001385 heavy metal Inorganic materials 0.000 claims abstract description 5
- 238000006243 chemical reaction Methods 0.000 claims description 22
- 238000010521 absorption reaction Methods 0.000 claims description 17
- 239000002956 ash Substances 0.000 claims description 16
- 239000007789 gas Substances 0.000 claims description 9
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 claims description 8
- 239000000920 calcium hydroxide Substances 0.000 claims description 8
- 229910001861 calcium hydroxide Inorganic materials 0.000 claims description 8
- 230000003134 recirculating effect Effects 0.000 claims description 7
- 239000007787 solid Substances 0.000 claims description 7
- 235000011116 calcium hydroxide Nutrition 0.000 claims description 6
- 235000019504 cigarettes Nutrition 0.000 claims description 6
- 230000029087 digestion Effects 0.000 claims description 6
- 239000002245 particle Substances 0.000 claims description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 6
- 239000002738 chelating agent Substances 0.000 claims description 4
- 150000002500 ions Chemical class 0.000 claims description 4
- 239000000463 material Substances 0.000 claims description 4
- 230000001133 acceleration Effects 0.000 claims description 3
- 239000010883 coal ash Substances 0.000 claims description 3
- 230000003009 desulfurizing effect Effects 0.000 claims description 3
- 230000001079 digestive effect Effects 0.000 claims description 3
- 210000002249 digestive system Anatomy 0.000 claims description 3
- 230000009977 dual effect Effects 0.000 claims description 3
- 230000000694 effects Effects 0.000 claims description 3
- 230000005684 electric field Effects 0.000 claims description 3
- 239000000843 powder Substances 0.000 claims description 3
- 230000000630 rising effect Effects 0.000 claims description 3
- 239000000203 mixture Substances 0.000 claims description 2
- 239000007921 spray Substances 0.000 claims 1
- 230000007613 environmental effect Effects 0.000 abstract description 2
- 239000013522 chelant Substances 0.000 abstract 1
- XLYOFNOQVPJJNP-ZSJDYOACSA-N heavy water Substances [2H]O[2H] XLYOFNOQVPJJNP-ZSJDYOACSA-N 0.000 description 6
- 239000006227 byproduct Substances 0.000 description 5
- 239000002250 absorbent Substances 0.000 description 3
- 230000002745 absorbent Effects 0.000 description 3
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 2
- 229910052925 anhydrite Inorganic materials 0.000 description 2
- 239000001110 calcium chloride Substances 0.000 description 2
- 229910001628 calcium chloride Inorganic materials 0.000 description 2
- WUKWITHWXAAZEY-UHFFFAOYSA-L calcium difluoride Chemical compound [F-].[F-].[Ca+2] WUKWITHWXAAZEY-UHFFFAOYSA-L 0.000 description 2
- 229910001634 calcium fluoride Inorganic materials 0.000 description 2
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000013505 freshwater Substances 0.000 description 2
- 239000008187 granular material Substances 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- 239000002699 waste material Substances 0.000 description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 239000010893 paper waste Substances 0.000 description 1
- 238000004537 pulping Methods 0.000 description 1
- 239000010802 sludge Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/75—Multi-step processes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/48—Sulfur compounds
- B01D53/50—Sulfur oxides
- B01D53/508—Sulfur oxides by treating the gases with solids
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/68—Halogens or halogen compounds
- B01D53/685—Halogens or halogen compounds by treating the gases with solids
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/81—Solid phase processes
- B01D53/83—Solid phase processes with moving reactants
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B09—DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
- B09B—DISPOSAL OF SOLID WASTE NOT OTHERWISE PROVIDED FOR
- B09B3/00—Destroying solid waste or transforming solid waste into something useful or harmless
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2251/00—Reactants
- B01D2251/40—Alkaline earth metal or magnesium compounds
- B01D2251/404—Alkaline earth metal or magnesium compounds of calcium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2251/00—Reactants
- B01D2251/60—Inorganic bases or salts
- B01D2251/604—Hydroxides
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- Health & Medical Sciences (AREA)
- Biomedical Technology (AREA)
- Analytical Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Treating Waste Gases (AREA)
Abstract
The present invention relates to environmental conservation and technical field of resource utilization, be specifically related to a kind of papermaking solid waste burning flying dust technique for thermoelectricity flue gas desulfurization.First flying dust is digested by the present invention with heavy metal chelant, reacts with the flue gas through pre-dedusting the most again.Use technique of the present invention, it is achieved that the utilization of papermaking solid waste burning flying dust, and desulfuration efficiency is up to 93%, not only protects environment but also achieve the components utilising of resource, can be widely popularized and use.
Description
Technical field
The present invention relates to environmental conservation and technical field of resource utilization, be specifically related to a kind of papermaking solid waste burning flying dust for
The technique of thermoelectricity flue gas desulfurization.
Background technology
Deinked sludge during wastepaper pulping and papermaking, rotary drum waste residue typically take the method burned to process, and process
Process achieves the minimizing of papermaking solid waste.But still creating substantial amounts of flying dust in processing procedure, these flying dusts are to fill out at present
It is main for burying processing mode, had both caused the pollution of environment, and had caused again the waste of resource.Through analyzing, the main component of this flying dust
For CaO, can be used for flue gas semi-dry desulphurization.
Summary of the invention
Technological process of the present invention is:
(1) papermaking solid waste burning flying dust sends into storage silo storage in being transported to field by closed tank truck, by the electron helical at the bottom of storehouse
Claim to be delivered to digestive system.The mixing of the heavy metal ion chelating agent of mass fraction 99.95% flying dust and mass fraction 0.05%
Thing completes digestion process in digestive appartus, is dried simultaneously.The Ca (OH) that digestion is made2Carried by bucket and be delivered to slaked lime storage
Storehouse, the slaked lime powder under Sal Nitri ash silo carries out desulphurization reaction in spraying into desulfurizing tower by air conveying form.
(2) flue gas (temperature 139 DEG C, flow 687364m3/ h) first pass around the pre-dedusting of dual chamber electric field, its efficiency of dust collection is
85%, institute's gumming coal ash is delivered in ash storehouse by air-transport system, then is taken out by tank car or two-stage conveying equipment.
(3) from pre-duster half clean flue gas (temperature 70 C, humidity 70%) out from entrance absorption tower, bottom, at this
Place's high-temperature flue gas and the flying ash of addition, circulation desulfurization ash fully premixing, carry out preliminary desulphurization reaction, in this region
Mainly complete the reaction of absorbent and HCl, HF.
(4) flue gas is by the acceleration of the Venturi tube of bottom, absorption tower, enters recirculating fluidized bed bed body;Material is in recycle stream
Changing in bed, gas-particle two-phase, due to the effect of air-flow, produces fierce turbulence and mixes, and is fully contacted, during rising, no
The disconnected floccule that formed returns downwards, and floccule constantly disintegrates again by gas lift in fierce turbulence so that between gas-solid
Slip velocity be up to 22 times of individual particle slip velocity;Absorption tower top structure further enhances the return of floccule, enters
One step improves the endocorpuscular bed density of tower so that the Ca/S ratio up to 62, SO in bed2Fully reaction.
(5) the outlet expander section at venturi is provided with water injector, and the atomized water sprayed into is in order to reduce in desulfurization reactor
Cigarette temperature, make cigarette temperature drop to 75 DEG C so that SO2With Ca (OH)2Reaction to be converted into the ion-type that can complete moment anti-
Should.
Flying ash, circulation desulfurization ash carries out the abundant reaction of second step in the tower more than venturi section, generate by-product
Thing CaSO3·1/2H2O, in addition with SO3, HF and HCl reaction generate corresponding by-product CaSO4·1/2H2O、CaF2、
CaCl2·Ca(OH)2·2H2O etc..
(6) ash-laden gas after purifying laterally is discharged from top, absorption tower, and after then turning to enter desulfurization, cleaner unit is carried out
Gas solid separation, makes dust concentration reach 50mg/Nm3Hereinafter, then by air-introduced machine chimney is entered.What removing dust device trapped consolidates
Body granule, by the Desulphurization recirculating system under cleaner unit, returns to absorption tower and continues to participate in reaction, so circulate.
The present invention uses corresponding system to carry out sulfur removal technology.System is prepared by pre-duster, absorbent, absorption tower, thing
The composition such as cleaner unit and blind controller system after material circulation, fresh water (FW) system, desulfurization.
Use technique of the present invention, it is achieved that the utilization of papermaking solid waste burning flying dust, and desulfuration efficiency is up to
93%, not only protect environment but also achieve the components utilising of resource, can be widely popularized and use.
Accompanying drawing explanation
Fig. 1 is present configuration schematic diagram;
In figure: 1, absorption tower, 2, dirt pocket, 3, side-product ash silo.
Detailed description of the invention
A kind of papermaking solid waste burning flying dust is for the technique of thermoelectricity flue gas desulfurization, and it concretely comprises the following steps:
(1) papermaking solid waste burning flying dust sends into storage silo storage in being transported to field by closed tank truck, by the electron helical at the bottom of storehouse
Claim to be delivered to digestive system.The mixing of the heavy metal ion chelating agent of mass fraction 99.95% flying dust and mass fraction 0.05%
Thing completes digestion process in digestive appartus, is dried simultaneously.The Ca (OH) that digestion is made2Carried by bucket and be delivered to slaked lime storage
Storehouse, the slaked lime powder under Sal Nitri ash silo carries out desulphurization reaction in spraying into desulfurizing tower by air conveying form.
(2) flue gas (temperature 139 DEG C, flow 687364m3/ h) first pass around the pre-dedusting of dual chamber electric field, its efficiency of dust collection is
85%, institute's gumming coal ash is delivered in ash storehouse by air-transport system, then is taken out by tank car or two-stage conveying equipment.
(3) from pre-duster half clean flue gas (temperature 70 C, humidity 70%) out from entrance absorption tower, bottom, at this
Place's high-temperature flue gas and the flying ash of addition, circulation desulfurization ash fully premixing, carry out preliminary desulphurization reaction, in this region
Mainly complete the reaction of absorbent and HCl, HF.
(4) flue gas is by the acceleration of the Venturi tube of bottom, absorption tower, enters recirculating fluidized bed bed body;Material is in recycle stream
Changing in bed, gas-particle two-phase, due to the effect of air-flow, produces fierce turbulence and mixes, and is fully contacted, during rising, no
The disconnected floccule that formed returns downwards, and floccule constantly disintegrates again by gas lift in fierce turbulence so that between gas-solid
Slip velocity be up to 22 times of individual particle slip velocity;Absorption tower top structure further enhances the return of floccule, enters
One step improves the endocorpuscular bed density of tower so that the Ca/S ratio up to 62, SO in bed2Fully reaction.
(5) the outlet expander section at venturi is provided with water injector, and the atomized water sprayed into is in order to reduce in desulfurization reactor
Cigarette temperature, make cigarette temperature drop to 75 DEG C so that SO2With Ca (OH)2Reaction to be converted into the ion-type that can complete moment anti-
Should.
Flying ash, circulation desulfurization ash carries out the abundant reaction of second step in the tower more than venturi section, generate by-product
Thing CaSO3·1/2H2O, in addition with SO3, HF and HCl reaction generate corresponding by-product CaSO4·1/2H2O、CaF2、
CaCl2·Ca(OH)2·2H2O etc..
(6) ash-laden gas after purifying laterally is discharged from top, absorption tower, and after then turning to enter desulfurization, cleaner unit is carried out
Gas solid separation, makes dust concentration reach 50mg/Nm3Hereinafter, then by air-introduced machine chimney is entered.What removing dust device trapped consolidates
Body granule, by the Desulphurization recirculating system under cleaner unit, returns to absorption tower and continues to participate in reaction, so circulate.
Inventive desulfurization Design of Dust-removing System gas cleaning efficiency and actual efficiency
Project | Design efficiency (%) | Design discharge value (mg/Nm3) | Actual efficiency (%) | Discharge value (mg/Nm3) |
SO2 | 91 | 400 | 93 | 120 |
Claims (4)
1. the technique that a papermaking solid waste burning flying dust is used for thermoelectricity flue gas desulfurization, it is characterised in that: it concretely comprises the following steps:
(1) papermaking solid waste burning flying dust sends into storage silo storage in being transported to field by closed tank truck, the electron helical at the bottom of storehouse claim defeated
Deliver to digestive system;Flying dust completes digestion process with the mixture of heavy metal ion chelating agent in digestive appartus, is dried simultaneously;
The Ca (OH) that digestion is made2Being carried by bucket and be delivered to slaked lime storage storehouse, the slaked lime powder under Sal Nitri ash silo is by air conveying
Form spray into desulfurizing tower in carry out desulphurization reaction;
(2) flue gas first passes around the pre-dedusting of dual chamber electric field, and institute's gumming coal ash is delivered in ash storehouse by air-transport system, then passes through
Tank car or two-stage conveying equipment are taken out;
(3) from pre-duster half clean flue gas out from entrance absorption tower, bottom, in the burning of high-temperature flue gas herein Yu addition
The ash fully premixing of flying dust, circulation desulfurization, carries out preliminary desulphurization reaction;
(4) flue gas is by the acceleration of the Venturi tube of bottom, absorption tower, enters recirculating fluidized bed bed body;Material is at recirculating fluidized bed
In, gas-particle two-phase, due to the effect of air-flow, produces fierce turbulence and mixes, and is fully contacted, during rising, and continuous shape
Become floccule to return downwards, and floccule constantly disintegrates again by gas lift in fierce turbulence so that the cunning between gas-solid
Terminal-velocity degree is up to 22 times of individual particle slip velocity;Absorption tower top structure further enhances the return of floccule, further
Improve the endocorpuscular bed density of tower so that the Ca/S ratio up to 62, SO in bed2Fully reaction.
(5) the outlet expander section at venturi is provided with water injector, and the atomized water sprayed into is in order to reduce the cigarette in desulfurization reactor
Temperature, make cigarette temperature drop to 75 DEG C so that SO2With Ca (OH)2Reaction be converted into the reaction of ionic type that can complete moment;
(6) ash-laden gas after purifying laterally is discharged from top, absorption tower, and after then turning to enter desulfurization, cleaner unit carries out gas-solid
Separate, make dust concentration reach 50mg/Nm3Hereinafter, then by air-introduced machine chimney is entered;The solid that removing dust device traps
Grain, by the Desulphurization recirculating system under cleaner unit, returns to absorption tower and continues to participate in reaction, so circulate.
A kind of papermaking solid waste burning flying dust the most according to claim 1 is for the technique of thermoelectricity flue gas desulfurization, and its feature exists
In: in step (1), flying dust is 99.95:0.05 with the weight ratio of heavy metal ion chelating agent.
A kind of papermaking solid waste burning flying dust the most according to claim 1 is for the technique of thermoelectricity flue gas desulfurization, and its feature exists
In: in step (2), flue-gas temperature is 139 DEG C, flow 687364m3/h。
A kind of papermaking solid waste burning flying dust the most according to claim 1 is for the technique of thermoelectricity flue gas desulfurization, and its feature exists
In: in step (3), half clean flue gas temperature is 70 DEG C, and humidity is 70%.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CN201610654381.4A CN106268212A (en) | 2016-08-11 | 2016-08-11 | A kind of papermaking solid waste burning flying dust is for the technique of thermoelectricity flue gas desulfurization |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201610654381.4A CN106268212A (en) | 2016-08-11 | 2016-08-11 | A kind of papermaking solid waste burning flying dust is for the technique of thermoelectricity flue gas desulfurization |
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Publication Number | Publication Date |
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CN106268212A true CN106268212A (en) | 2017-01-04 |
Family
ID=57668915
Family Applications (1)
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CN201610654381.4A Pending CN106268212A (en) | 2016-08-11 | 2016-08-11 | A kind of papermaking solid waste burning flying dust is for the technique of thermoelectricity flue gas desulfurization |
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CN (1) | CN106268212A (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108579356A (en) * | 2018-04-02 | 2018-09-28 | 安徽蓝天盈丰环保科技有限公司 | A kind of smoke desulfurizing dust-remover for boiler and method |
CN108687115A (en) * | 2018-05-16 | 2018-10-23 | 西安交通大学 | A kind of cooperative processing method of incineration of refuse flyash and desulfurization wastewater |
CN112844002A (en) * | 2021-02-03 | 2021-05-28 | 江西新金叶实业有限公司 | Dense-phase semi-dry flue gas desulfurization device and method thereof |
Citations (4)
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---|---|---|---|---|
JPH10180221A (en) * | 1996-12-26 | 1998-07-07 | Nkk Corp | Treatment of waste incineration fly ash |
CN101474468A (en) * | 2008-01-03 | 2009-07-08 | 上海日技环境技术咨询有限公司 | Method for treating burning flyash using chelant |
CN103551004A (en) * | 2013-10-27 | 2014-02-05 | 黑龙江宏宇电站设备有限公司 | Desulfurization method of dry desulfurization system of coal gangue circulating fluidized bed |
CN105251325A (en) * | 2014-07-16 | 2016-01-20 | 鞍钢股份有限公司 | Sintering flue gas circulating fluidized bed desulfurization and denitrification system and method |
-
2016
- 2016-08-11 CN CN201610654381.4A patent/CN106268212A/en active Pending
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH10180221A (en) * | 1996-12-26 | 1998-07-07 | Nkk Corp | Treatment of waste incineration fly ash |
CN101474468A (en) * | 2008-01-03 | 2009-07-08 | 上海日技环境技术咨询有限公司 | Method for treating burning flyash using chelant |
CN103551004A (en) * | 2013-10-27 | 2014-02-05 | 黑龙江宏宇电站设备有限公司 | Desulfurization method of dry desulfurization system of coal gangue circulating fluidized bed |
CN105251325A (en) * | 2014-07-16 | 2016-01-20 | 鞍钢股份有限公司 | Sintering flue gas circulating fluidized bed desulfurization and denitrification system and method |
Non-Patent Citations (1)
Title |
---|
中国硅酸盐学会房建材料分会主编: "《房建材料与绿色建筑》", 31 August 2009, 北京:中国建材工业出版社 * |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108579356A (en) * | 2018-04-02 | 2018-09-28 | 安徽蓝天盈丰环保科技有限公司 | A kind of smoke desulfurizing dust-remover for boiler and method |
CN108687115A (en) * | 2018-05-16 | 2018-10-23 | 西安交通大学 | A kind of cooperative processing method of incineration of refuse flyash and desulfurization wastewater |
CN112844002A (en) * | 2021-02-03 | 2021-05-28 | 江西新金叶实业有限公司 | Dense-phase semi-dry flue gas desulfurization device and method thereof |
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