CN106268212A - A kind of papermaking solid waste burning flying dust is for the technique of thermoelectricity flue gas desulfurization - Google Patents

A kind of papermaking solid waste burning flying dust is for the technique of thermoelectricity flue gas desulfurization Download PDF

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Publication number
CN106268212A
CN106268212A CN201610654381.4A CN201610654381A CN106268212A CN 106268212 A CN106268212 A CN 106268212A CN 201610654381 A CN201610654381 A CN 201610654381A CN 106268212 A CN106268212 A CN 106268212A
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China
Prior art keywords
flue gas
flying dust
solid waste
desulfurization
technique
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CN201610654381.4A
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Chinese (zh)
Inventor
张凤山
周景蓬
刘燕韶
李晓亮
魏文光
冯好伟
李红艳
郭启程
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SHANDONG HUATAI PAPER CO Ltd
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SHANDONG HUATAI PAPER CO Ltd
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Priority to CN201610654381.4A priority Critical patent/CN106268212A/en
Publication of CN106268212A publication Critical patent/CN106268212A/en
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/75Multi-step processes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/46Removing components of defined structure
    • B01D53/48Sulfur compounds
    • B01D53/50Sulfur oxides
    • B01D53/508Sulfur oxides by treating the gases with solids
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/46Removing components of defined structure
    • B01D53/68Halogens or halogen compounds
    • B01D53/685Halogens or halogen compounds by treating the gases with solids
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/81Solid phase processes
    • B01D53/83Solid phase processes with moving reactants
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B09DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
    • B09BDISPOSAL OF SOLID WASTE NOT OTHERWISE PROVIDED FOR
    • B09B3/00Destroying solid waste or transforming solid waste into something useful or harmless
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2251/00Reactants
    • B01D2251/40Alkaline earth metal or magnesium compounds
    • B01D2251/404Alkaline earth metal or magnesium compounds of calcium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2251/00Reactants
    • B01D2251/60Inorganic bases or salts
    • B01D2251/604Hydroxides

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Biomedical Technology (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Treating Waste Gases (AREA)

Abstract

The present invention relates to environmental conservation and technical field of resource utilization, be specifically related to a kind of papermaking solid waste burning flying dust technique for thermoelectricity flue gas desulfurization.First flying dust is digested by the present invention with heavy metal chelant, reacts with the flue gas through pre-dedusting the most again.Use technique of the present invention, it is achieved that the utilization of papermaking solid waste burning flying dust, and desulfuration efficiency is up to 93%, not only protects environment but also achieve the components utilising of resource, can be widely popularized and use.

Description

A kind of papermaking solid waste burning flying dust is for the technique of thermoelectricity flue gas desulfurization
Technical field
The present invention relates to environmental conservation and technical field of resource utilization, be specifically related to a kind of papermaking solid waste burning flying dust for The technique of thermoelectricity flue gas desulfurization.
Background technology
Deinked sludge during wastepaper pulping and papermaking, rotary drum waste residue typically take the method burned to process, and process Process achieves the minimizing of papermaking solid waste.But still creating substantial amounts of flying dust in processing procedure, these flying dusts are to fill out at present It is main for burying processing mode, had both caused the pollution of environment, and had caused again the waste of resource.Through analyzing, the main component of this flying dust For CaO, can be used for flue gas semi-dry desulphurization.
Summary of the invention
Technological process of the present invention is:
(1) papermaking solid waste burning flying dust sends into storage silo storage in being transported to field by closed tank truck, by the electron helical at the bottom of storehouse Claim to be delivered to digestive system.The mixing of the heavy metal ion chelating agent of mass fraction 99.95% flying dust and mass fraction 0.05% Thing completes digestion process in digestive appartus, is dried simultaneously.The Ca (OH) that digestion is made2Carried by bucket and be delivered to slaked lime storage Storehouse, the slaked lime powder under Sal Nitri ash silo carries out desulphurization reaction in spraying into desulfurizing tower by air conveying form.
(2) flue gas (temperature 139 DEG C, flow 687364m3/ h) first pass around the pre-dedusting of dual chamber electric field, its efficiency of dust collection is 85%, institute's gumming coal ash is delivered in ash storehouse by air-transport system, then is taken out by tank car or two-stage conveying equipment.
(3) from pre-duster half clean flue gas (temperature 70 C, humidity 70%) out from entrance absorption tower, bottom, at this Place's high-temperature flue gas and the flying ash of addition, circulation desulfurization ash fully premixing, carry out preliminary desulphurization reaction, in this region Mainly complete the reaction of absorbent and HCl, HF.
(4) flue gas is by the acceleration of the Venturi tube of bottom, absorption tower, enters recirculating fluidized bed bed body;Material is in recycle stream Changing in bed, gas-particle two-phase, due to the effect of air-flow, produces fierce turbulence and mixes, and is fully contacted, during rising, no The disconnected floccule that formed returns downwards, and floccule constantly disintegrates again by gas lift in fierce turbulence so that between gas-solid Slip velocity be up to 22 times of individual particle slip velocity;Absorption tower top structure further enhances the return of floccule, enters One step improves the endocorpuscular bed density of tower so that the Ca/S ratio up to 62, SO in bed2Fully reaction.
(5) the outlet expander section at venturi is provided with water injector, and the atomized water sprayed into is in order to reduce in desulfurization reactor Cigarette temperature, make cigarette temperature drop to 75 DEG C so that SO2With Ca (OH)2Reaction to be converted into the ion-type that can complete moment anti- Should.
Flying ash, circulation desulfurization ash carries out the abundant reaction of second step in the tower more than venturi section, generate by-product Thing CaSO3·1/2H2O, in addition with SO3, HF and HCl reaction generate corresponding by-product CaSO4·1/2H2O、CaF2、 CaCl2·Ca(OH)2·2H2O etc..
(6) ash-laden gas after purifying laterally is discharged from top, absorption tower, and after then turning to enter desulfurization, cleaner unit is carried out Gas solid separation, makes dust concentration reach 50mg/Nm3Hereinafter, then by air-introduced machine chimney is entered.What removing dust device trapped consolidates Body granule, by the Desulphurization recirculating system under cleaner unit, returns to absorption tower and continues to participate in reaction, so circulate.
The present invention uses corresponding system to carry out sulfur removal technology.System is prepared by pre-duster, absorbent, absorption tower, thing The composition such as cleaner unit and blind controller system after material circulation, fresh water (FW) system, desulfurization.
Use technique of the present invention, it is achieved that the utilization of papermaking solid waste burning flying dust, and desulfuration efficiency is up to 93%, not only protect environment but also achieve the components utilising of resource, can be widely popularized and use.
Accompanying drawing explanation
Fig. 1 is present configuration schematic diagram;
In figure: 1, absorption tower, 2, dirt pocket, 3, side-product ash silo.
Detailed description of the invention
A kind of papermaking solid waste burning flying dust is for the technique of thermoelectricity flue gas desulfurization, and it concretely comprises the following steps:
(1) papermaking solid waste burning flying dust sends into storage silo storage in being transported to field by closed tank truck, by the electron helical at the bottom of storehouse Claim to be delivered to digestive system.The mixing of the heavy metal ion chelating agent of mass fraction 99.95% flying dust and mass fraction 0.05% Thing completes digestion process in digestive appartus, is dried simultaneously.The Ca (OH) that digestion is made2Carried by bucket and be delivered to slaked lime storage Storehouse, the slaked lime powder under Sal Nitri ash silo carries out desulphurization reaction in spraying into desulfurizing tower by air conveying form.
(2) flue gas (temperature 139 DEG C, flow 687364m3/ h) first pass around the pre-dedusting of dual chamber electric field, its efficiency of dust collection is 85%, institute's gumming coal ash is delivered in ash storehouse by air-transport system, then is taken out by tank car or two-stage conveying equipment.
(3) from pre-duster half clean flue gas (temperature 70 C, humidity 70%) out from entrance absorption tower, bottom, at this Place's high-temperature flue gas and the flying ash of addition, circulation desulfurization ash fully premixing, carry out preliminary desulphurization reaction, in this region Mainly complete the reaction of absorbent and HCl, HF.
(4) flue gas is by the acceleration of the Venturi tube of bottom, absorption tower, enters recirculating fluidized bed bed body;Material is in recycle stream Changing in bed, gas-particle two-phase, due to the effect of air-flow, produces fierce turbulence and mixes, and is fully contacted, during rising, no The disconnected floccule that formed returns downwards, and floccule constantly disintegrates again by gas lift in fierce turbulence so that between gas-solid Slip velocity be up to 22 times of individual particle slip velocity;Absorption tower top structure further enhances the return of floccule, enters One step improves the endocorpuscular bed density of tower so that the Ca/S ratio up to 62, SO in bed2Fully reaction.
(5) the outlet expander section at venturi is provided with water injector, and the atomized water sprayed into is in order to reduce in desulfurization reactor Cigarette temperature, make cigarette temperature drop to 75 DEG C so that SO2With Ca (OH)2Reaction to be converted into the ion-type that can complete moment anti- Should.
Flying ash, circulation desulfurization ash carries out the abundant reaction of second step in the tower more than venturi section, generate by-product Thing CaSO3·1/2H2O, in addition with SO3, HF and HCl reaction generate corresponding by-product CaSO4·1/2H2O、CaF2、 CaCl2·Ca(OH)2·2H2O etc..
(6) ash-laden gas after purifying laterally is discharged from top, absorption tower, and after then turning to enter desulfurization, cleaner unit is carried out Gas solid separation, makes dust concentration reach 50mg/Nm3Hereinafter, then by air-introduced machine chimney is entered.What removing dust device trapped consolidates Body granule, by the Desulphurization recirculating system under cleaner unit, returns to absorption tower and continues to participate in reaction, so circulate.
Inventive desulfurization Design of Dust-removing System gas cleaning efficiency and actual efficiency
Project Design efficiency (%) Design discharge value (mg/Nm3) Actual efficiency (%) Discharge value (mg/Nm3)
SO2 91 400 93 120

Claims (4)

1. the technique that a papermaking solid waste burning flying dust is used for thermoelectricity flue gas desulfurization, it is characterised in that: it concretely comprises the following steps:
(1) papermaking solid waste burning flying dust sends into storage silo storage in being transported to field by closed tank truck, the electron helical at the bottom of storehouse claim defeated Deliver to digestive system;Flying dust completes digestion process with the mixture of heavy metal ion chelating agent in digestive appartus, is dried simultaneously; The Ca (OH) that digestion is made2Being carried by bucket and be delivered to slaked lime storage storehouse, the slaked lime powder under Sal Nitri ash silo is by air conveying Form spray into desulfurizing tower in carry out desulphurization reaction;
(2) flue gas first passes around the pre-dedusting of dual chamber electric field, and institute's gumming coal ash is delivered in ash storehouse by air-transport system, then passes through Tank car or two-stage conveying equipment are taken out;
(3) from pre-duster half clean flue gas out from entrance absorption tower, bottom, in the burning of high-temperature flue gas herein Yu addition The ash fully premixing of flying dust, circulation desulfurization, carries out preliminary desulphurization reaction;
(4) flue gas is by the acceleration of the Venturi tube of bottom, absorption tower, enters recirculating fluidized bed bed body;Material is at recirculating fluidized bed In, gas-particle two-phase, due to the effect of air-flow, produces fierce turbulence and mixes, and is fully contacted, during rising, and continuous shape Become floccule to return downwards, and floccule constantly disintegrates again by gas lift in fierce turbulence so that the cunning between gas-solid Terminal-velocity degree is up to 22 times of individual particle slip velocity;Absorption tower top structure further enhances the return of floccule, further Improve the endocorpuscular bed density of tower so that the Ca/S ratio up to 62, SO in bed2Fully reaction.
(5) the outlet expander section at venturi is provided with water injector, and the atomized water sprayed into is in order to reduce the cigarette in desulfurization reactor Temperature, make cigarette temperature drop to 75 DEG C so that SO2With Ca (OH)2Reaction be converted into the reaction of ionic type that can complete moment;
(6) ash-laden gas after purifying laterally is discharged from top, absorption tower, and after then turning to enter desulfurization, cleaner unit carries out gas-solid Separate, make dust concentration reach 50mg/Nm3Hereinafter, then by air-introduced machine chimney is entered;The solid that removing dust device traps Grain, by the Desulphurization recirculating system under cleaner unit, returns to absorption tower and continues to participate in reaction, so circulate.
A kind of papermaking solid waste burning flying dust the most according to claim 1 is for the technique of thermoelectricity flue gas desulfurization, and its feature exists In: in step (1), flying dust is 99.95:0.05 with the weight ratio of heavy metal ion chelating agent.
A kind of papermaking solid waste burning flying dust the most according to claim 1 is for the technique of thermoelectricity flue gas desulfurization, and its feature exists In: in step (2), flue-gas temperature is 139 DEG C, flow 687364m3/h。
A kind of papermaking solid waste burning flying dust the most according to claim 1 is for the technique of thermoelectricity flue gas desulfurization, and its feature exists In: in step (3), half clean flue gas temperature is 70 DEG C, and humidity is 70%.
CN201610654381.4A 2016-08-11 2016-08-11 A kind of papermaking solid waste burning flying dust is for the technique of thermoelectricity flue gas desulfurization Pending CN106268212A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108579356A (en) * 2018-04-02 2018-09-28 安徽蓝天盈丰环保科技有限公司 A kind of smoke desulfurizing dust-remover for boiler and method
CN108687115A (en) * 2018-05-16 2018-10-23 西安交通大学 A kind of cooperative processing method of incineration of refuse flyash and desulfurization wastewater
CN112844002A (en) * 2021-02-03 2021-05-28 江西新金叶实业有限公司 Dense-phase semi-dry flue gas desulfurization device and method thereof

Citations (4)

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Publication number Priority date Publication date Assignee Title
JPH10180221A (en) * 1996-12-26 1998-07-07 Nkk Corp Treatment of waste incineration fly ash
CN101474468A (en) * 2008-01-03 2009-07-08 上海日技环境技术咨询有限公司 Method for treating burning flyash using chelant
CN103551004A (en) * 2013-10-27 2014-02-05 黑龙江宏宇电站设备有限公司 Desulfurization method of dry desulfurization system of coal gangue circulating fluidized bed
CN105251325A (en) * 2014-07-16 2016-01-20 鞍钢股份有限公司 Sintering flue gas circulating fluidized bed desulfurization and denitrification system and method

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH10180221A (en) * 1996-12-26 1998-07-07 Nkk Corp Treatment of waste incineration fly ash
CN101474468A (en) * 2008-01-03 2009-07-08 上海日技环境技术咨询有限公司 Method for treating burning flyash using chelant
CN103551004A (en) * 2013-10-27 2014-02-05 黑龙江宏宇电站设备有限公司 Desulfurization method of dry desulfurization system of coal gangue circulating fluidized bed
CN105251325A (en) * 2014-07-16 2016-01-20 鞍钢股份有限公司 Sintering flue gas circulating fluidized bed desulfurization and denitrification system and method

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中国硅酸盐学会房建材料分会主编: "《房建材料与绿色建筑》", 31 August 2009, 北京:中国建材工业出版社 *

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108579356A (en) * 2018-04-02 2018-09-28 安徽蓝天盈丰环保科技有限公司 A kind of smoke desulfurizing dust-remover for boiler and method
CN108687115A (en) * 2018-05-16 2018-10-23 西安交通大学 A kind of cooperative processing method of incineration of refuse flyash and desulfurization wastewater
CN112844002A (en) * 2021-02-03 2021-05-28 江西新金叶实业有限公司 Dense-phase semi-dry flue gas desulfurization device and method thereof

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