CN106263960B - A kind of abnormity football cup - Google Patents

A kind of abnormity football cup Download PDF

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Publication number
CN106263960B
CN106263960B CN201610764904.0A CN201610764904A CN106263960B CN 106263960 B CN106263960 B CN 106263960B CN 201610764904 A CN201610764904 A CN 201610764904A CN 106263960 B CN106263960 B CN 106263960B
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Prior art keywords
cup
additive
abnormity
main body
football
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CN106263960A (en
Inventor
孙柯达
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NINGBO HAISHU KELI PLASTIC INDUSTRY Co.,Ltd.
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Yin Zhou Kelisu Industry Co Ltd Of Ningbo City
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    • AHUMAN NECESSITIES
    • A47FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
    • A47GHOUSEHOLD OR TABLE EQUIPMENT
    • A47G19/00Table service
    • A47G19/22Drinking vessels or saucers used for table service
    • A47G19/2205Drinking glasses or vessels
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24Acids; Salts thereof
    • C08K3/26Carbonates; Bicarbonates
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/28Nitrogen-containing compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K7/00Use of ingredients characterised by shape
    • C08K7/02Fibres or whiskers
    • C08K7/04Fibres or whiskers inorganic
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K7/00Use of ingredients characterised by shape
    • C08K7/02Fibres or whiskers
    • C08K7/04Fibres or whiskers inorganic
    • C08K7/06Elements
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10Homopolymers or copolymers of propene
    • C08L23/12Polypropene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24Acids; Salts thereof
    • C08K3/26Carbonates; Bicarbonates
    • C08K2003/265Calcium, strontium or barium carbonate

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Oxide Ceramics (AREA)

Abstract

Abnormity football cup disclosed by the invention, cup body and cup lid including bottom of a cup, with water containing chamber, cup body is spherical, and cup body outer surface has multiple hexagons and multiple pentagonal assorted figures, each of which hexagon is complete or local, each pentagon is complete or local, and cup body is enhancing PP materials, also has protective layer on cup body inner wall.The silastic-layer and rubber thin-bed with lower opening that the present invention passes through setting, pass through the suction-operated of the silastic-layer of bottom end opening, make its placement property more preferable, it is not easily susceptible to slight vibration or touches and topple over, there is more preferable safety in utilization, and the protective layer structure for passing through setting, effective insulating effect can be played, and prevent that the easy composition that leaches in plastics is leached in use, and be ingested in vivo, so as to improve the safety in utilization of plastic cup.

Description

A kind of abnormity football cup
Technical field
The present invention relates to a kind of plastic cup, particularly a kind of special-shaped football cup.
Background technology
Plastic products bring great convenience to our life, and but then, its appearance allows peace of the people to it again Full property is half believing, half doubting.Plastic cup is used for the disposable container of dixie cup and tea.Disposal plastic cup usage amount it is maximum be usually Liquor store, hot cold drink shop, milk tea shop, hotel, dining room and cafe, there is provided the tyre drink of various plastics cups and scene make With.
Plastic cup belongs to nondegradable product, and many people conveniently just throw away cup after beverage is finished off, and also causes This disposal plastic cup becomes the main source of " white pollution ".And the common soya-bean milk bottle of pp plastic cups, Yogurt bottle, fruit juice Beverage bottle, micro-wave oven cutlery box, hot water cup etc..Fusing point is up to 167 DEG C, is the plastic casing that can uniquely put micro-wave oven into, can be small Reused after heart cleaning.It is noted that some micro-wave oven cutlery boxs, box body is manufactured with No. 5 pp, but box lid is manufactured with No. 1 PE, Since PE cannot be supported by high temperature, therefore micro-wave oven cannot be put into the lump with box body.
Pp plastic cups are using polypropylene, it has good heat resistance, and product can be carried out in 100 DEG C of temperatures above Sterilization, under conditions of from external force, 150 DEG C also indeformable.Brittle temperature be -35 DEG C, can occur less than -35 DEG C it is crisp Change, cold resistance is not so good as polyethylene.Polyacrylic melting temperature about improves 40 one 50%, about 164 1 170 DEG C than polyethylene, 100% grade polypropylene.
Although be by materials such as PE, PP of food-grade usually it is nontoxic, its as synthesis high molecular material, modeling In material can there are various auxiliary agents and the polymer of oligomeric form, in routine use, as hot-water soak, oil, milk, Wine, acid, fruit juice etc. can leach the material of these in plastics, and as usage time is longer and leaching effect is better, from And be ingested in human body, health is influenced whether by long-term accumulation.Meanwhile easily because small collision in routine use Or rock and topple over, content outflow, influences daily life, the safety and efficiency of work.
The content of the invention
To solve the above problems, abnormity football cup disclosed by the invention, passes through the silicon rubber with lower opening of setting Glue-line and rubber thin-bed, by the suction-operated of the silastic-layer of bottom end opening, make its placement property more preferable, are not easily susceptible to slightly shake Move or touch and topple over, there is more preferable safety in utilization, and by the protective layer structure of setting, can play effective Insulating effect, and prevent that the easy composition that leaches in plastics is leached in use, and be ingested in vivo, so as to improve plastic cup Safety in utilization.
Abnormity football cup disclosed by the invention, including bottom of a cup, the cup body and cup lid with water containing chamber, cup body be it is spherical, And cup body outer surface has multiple hexagons and a multiple pentagonal assorted figures, each of which hexagon to be complete or Local, each pentagon is complete or local, and cup body is enhancing PP materials, also has protection on cup body inner wall Layer.The protective layer that this programme is set can carry out isolated protection to PP materials, reduce the small molecule in plastics in a state of use The leaching probability of material, so as to lift the security used.
The a kind of of abnormity football cup disclosed by the invention improves, two neighboring pentagon and/or six sides in assorted figure The junction of shape has groove structure and/or projective structure.
A kind of improvement of abnormity football cup disclosed by the invention, when junction has projective structure, it includes silicon rubber The main body of material.The main body of silicone rubber material causes the bulge-structure that there is good elasticity and buffering to recover energy in this programme Power, so that it is when being held or being collided, there is provided good flexible buffer.
The a kind of of abnormity football cup disclosed by the invention improves, and is additionally provided with hard cap in main body, hard cap is arranged on Body end and it is engaged with body end.
The hard cap set in this programme, while providing protection for the main body of silicone rubber material, makes it be not easy using In be destroyed, while wearability can be improved again, prevent from wearing.Hard cap can be ceramic cap, which can be ceramics Sheet type, it has good compatibility with silicon rubber main body, while has the characteristic light, rigidity is good, wearability is strong again, makes It provides bulge-structure sufficiently protection.The hard cap of ceramic sheet type, using ceramic high intensity high rigidity characteristic and With reference to its relatively thin thickness, and when cup is subject to greater impact, the preferential rigidity that occurs is broken, and stress then is delivered to master again Body and cup body, so as to implement rigid-flexible double protection, so as to lift the ability of protecting against shock damage.Ceramics can in the program Think, its raw material composition includes, in terms of parts by weight:00 part of silica 1;Alumina particle and magnesium oxide particle 0.3-1.2 Part;3-10 parts of boric acid.Preferably, the granularity of silica is D50≤0.5 micron.It is furthermore preferred that alumina particle and oxidation The granularity of magnesium granules is D50≤3.0 micron.It is highly preferred that raw material is prepared through water base ball milling, wherein addition accounts for original during water base ball milling Expect the PVA aqueous solutions of gross mass percentage 16-20%, the concentration of PVA aqueous solutions is 10wt.%.It is highly preferred that during water base ball milling Also addition accounts for the dispersant of raw material gross mass percentage 0.05-0.5%.
The a kind of of abnormity football cup disclosed by the invention improves, and silastic-layer is additionally provided with bottom of a cup, silastic-layer Lower end is provided with least one groove, and groove only has at least one opening in lower section.
The silastic-layer is set by being arranged on position of the bottom outside i.e. outside vial bottom in this programme, it is by setting The groove put and opening thereunder is set --- the setting causes opening in the bottom of groove and towards down-set, Coordinate the softer silica gel material of quality at the same time, so as to place in use, it can be oppressed, so that by the air in groove Emptied from bottom and form negative pressure, suction-operated is produced to cup, and adsorbed on the table, so as to be not easy because touching vibration And topple over, occur damaged.
The a kind of of abnormity football cup disclosed by the invention improves, and is provided with folded slot in the groove of silastic-layer, folds Groove is parallel with bottom lower surface.This programme is arranged on the folded slot on groove inner wall so that cup is when placing, the silicon of its bottom Rubber layer is more easy to be folded, and oppresses groove, so as to be more easy to fully exclude the air in groove, and maximally forms negative-pressure adsorption Power, so as to lift the stability and security of placement.
A kind of improvement of abnormity football cup disclosed by the invention, enhancing PP be the main body of PP materials outer skin with Additive is doped, and additive is at least one of carbon fiber, ceramic fibre, titanium nitride, calcium carbonate, and additive accounts for main body The 0.1-0.3wt% of gross mass.PP materials are molded PP raw materials for common food level cup in this programme.This programme passes through addition Additive part, the enhancing tissue of protective layer and mechanical performance, wear-resisting property as PP materials, to change from microscopic pattern Its abrasiveness and mechanical performance, and achieve the purpose that enhancing and improve service life.Specific by additive uses, and overcomes The harmful effect in terms of structure and intensity such as impurity element and crystal defect.
A kind of improvement of abnormity football cup disclosed by the invention, additive doping depth in main body are not more than 0.5mm.
A kind of improvement of abnormity football cup disclosed by the invention, additive be uniformly distributed in main body top layer or by table and In successively decrease (i.e. with the increase of doping depth, the content of additive is reduced in same depth).
In the present invention program, the appearance Rotating fields of the cup of PP materials are only entrained in using the additive of low-doped amount, The surface enhanced of the cup under low-doped amount is realized, while reduces the content in material internal additive, and is reduced internal The content of " impurity " form material of institutional framework is influenced, reduces the influence to microstructures such as crystallizations, reduces boundary stress, from And reduce the influence to Fine Texture of Material stability and uniformity.
A kind of improvement of abnormity football cup disclosed by the invention, protective layer for glass protecting layer or ceramic protection layer or Person's stainless steel protective cover.
A kind of improvement of abnormity football cup disclosed by the invention, protective layer have loose structure.
Cup disclosed by the invention, has simple in structure, and production and application is convenient, has more preferable safety in utilization and gripping Convenience, while material has good wear resistance and stability, in use since the negative-pressure adsorption of bottom acts on, It is not susceptible to topple over, and is not susceptible to small-molecule substance leaching, so that with more good safety in utilization.
Brief description of the drawings
Fig. 1, special-shaped football cup disclosed by the invention a kind of embodiment structure diagram.
Reference numerals list:1st, cup lid;2nd, cup body;3rd, bottom of a cup.
Embodiment
With reference to the accompanying drawings and detailed description, the present invention is furture elucidated, it should be understood that following embodiments are only For illustrating the present invention rather than limiting the scope of the invention.It should be noted that word " preceding " used in the following description, " rear ", "left", "right", "up" and "down" refer to the direction in attached drawing, and word " interior " and " outer " refer respectively to direction or remote From the direction of particular elements geometric center.
Embodiment 1
As shown in Figure 1, special-shaped football cup in the present embodiment, including bottom of a cup 3, the cup body 2 and cup lid 1 with water containing chamber, Cup body 2 is spherical, and 2 outer surface of cup body has multiple hexagons and multiple pentagonal assorted figures, six side of each of which Shape is that each complete either local pentagon is complete or local, and cup body is to strengthen PP materials, cup body inner wall On be provided with protective layer.
Embodiment 2
Special-shaped football cup in the present embodiment, including bottom of a cup, the cup body and cup lid with water containing chamber, cup body are spherical, and Cup body outer surface has multiple hexagons and multiple pentagonal assorted figures, and each of which hexagon is complete or office Portion, each pentagon is complete or local, and cup body is enhancing PP materials, and protective layer is provided with cup body inner wall, The junction of two neighboring pentagon and/or hexagon has groove structure in assorted figure.
Embodiment 3
Special-shaped football cup in the present embodiment, including bottom of a cup, the cup body and cup lid with water containing chamber, cup body are spherical, and Cup body outer surface has multiple hexagons and multiple pentagonal assorted figures, and each of which hexagon is complete or office Portion, each pentagon is complete or local, and cup body is enhancing PP materials, and protective layer is provided with cup body inner wall, The junction of two neighboring pentagon and/or hexagon has projective structure in assorted figure.
Embodiment 4
Special-shaped football cup in the present embodiment, including bottom of a cup, the cup body and cup lid with water containing chamber, cup body are spherical, and Cup body outer surface has multiple hexagons and multiple pentagonal assorted figures, and each of which hexagon is complete or office Portion, each pentagon is complete or local, and cup body is enhancing PP materials, and protective layer is provided with cup body inner wall, The junction of two neighboring pentagon and/or hexagon has groove structure and/or projective structure, assorted figure in assorted figure In two neighboring pentagon and/or hexagon junction have groove structure (projective structure can into disperse with projective structure Point section shape distribution).
Distinguished with including but not limited to above-described embodiment, when junction has projective structure, it includes silicon rubber material The main body of matter.
Distinguished with including but not limited to above-described embodiment, hard cap is additionally provided with main body, the hard cap is set It is engaged in body end and with body end.
Distinguished with including but not limited to above-described embodiment, hard cap is ceramic sheet type.
Distinguished with including but not limited to above-described embodiment, ceramic hard cap can be as follows by including but not limited to The preparation embodiment obtains:
Prepare embodiment 1
In this preparation embodiment, ceramic raw material composition is 00 part of silica 1;Alumina particle and magnesium oxide particle 0.3 part;5 parts of boric acid, it is hard that above-mentioned raw materials obtain sintering ceramics after the technique such as batch mixing ball milling, spray drying, dry-pressing formed, sintering Matter cap,
Wherein it is sintered to and is sintered in vacuum high temperature furnace under argon gas protection, sintering temperature is 1875 DEG C, and in-furnace temperature reaches The heat preservation sintering time is 1.3h after sintering temperature, and argon gas is filled with when vacuum high temperature furnace is preheated to 1500 DEG C.
This preparation embodiment prepares ceramics sample 100, and sintering finished qualification rate 99%, sample is by detection, average densification > 98% is spent, fracture toughness is less than 4.5MPA.
Prepare embodiment 2
In this preparation embodiment, ceramic raw material composition is 00 part of silica 1;Alumina particle and magnesium oxide particle 0.7 part;3 parts of boric acid, it is hard that above-mentioned raw materials obtain sintering ceramics after the technique such as batch mixing ball milling, spray drying, dry-pressing formed, sintering Matter cap,
Wherein it is sintered to and is sintered in vacuum high temperature furnace under argon gas protection, sintering temperature is 1860 DEG C, and in-furnace temperature reaches The heat preservation sintering time is 1.8h after sintering temperature, and argon gas is filled with when vacuum high temperature furnace is preheated to 1500 DEG C.
This preparation embodiment prepares ceramics sample 100, and sintering finished qualification rate 99%, sample is by detection, average densification > 98% is spent, fracture toughness is less than 4.5MPA.
Prepare embodiment 3
In this preparation embodiment, ceramic raw material composition is 00 part of silica 1;Alumina particle and magnesium oxide particle 1.0 part;10 parts of boric acid, above-mentioned raw materials obtain sintering ceramics after the technique such as batch mixing ball milling, spray drying, dry-pressing formed, sintering Hard cap,
Wherein it is sintered to and is sintered in vacuum high temperature furnace under argon gas protection, sintering temperature is 1870 DEG C, and in-furnace temperature reaches The heat preservation sintering time is 1.3h after sintering temperature, and argon gas is filled with when vacuum high temperature furnace is preheated to 1500 DEG C.
This preparation embodiment prepares ceramics sample 100, and sintering finished qualification rate 99%, sample is by detection, average densification > 98% is spent, fracture toughness is less than 4.5MPA.
Prepare embodiment 4
In this preparation embodiment, ceramic raw material composition is 00 part of silica 1;Alumina particle and magnesium oxide particle 1.2 part;7 parts of boric acid, it is hard that above-mentioned raw materials obtain sintering ceramics after the technique such as batch mixing ball milling, spray drying, dry-pressing formed, sintering Matter cap,
Wherein it is sintered to and is sintered in vacuum high temperature furnace under argon gas protection, sintering temperature is 1900 DEG C, and in-furnace temperature reaches The heat preservation sintering time is 2h after sintering temperature, and argon gas is filled with when vacuum high temperature furnace is preheated to 1500 DEG C.
This preparation embodiment prepares ceramics sample 100, and sintering finished qualification rate 99%, sample is by detection, average densification > 98% is spent, fracture toughness is less than 4.5MPA.
Prepare embodiment 5
In this preparation embodiment, ceramic raw material composition is 00 part of silica 1;Alumina particle and magnesium oxide particle 0.8 part;9 parts of boric acid, it is hard that above-mentioned raw materials obtain sintering ceramics after the technique such as batch mixing ball milling, spray drying, dry-pressing formed, sintering Matter cap,
Wherein it is sintered to and is sintered in vacuum high temperature furnace under argon gas protection, sintering temperature is 1890 DEG C, and in-furnace temperature reaches The heat preservation sintering time is 1.5h after sintering temperature, and argon gas is filled with when vacuum high temperature furnace is preheated to 1500 DEG C.
This preparation embodiment prepares ceramics sample 100, and sintering finished qualification rate 99%, sample is by detection, average densification > 98% is spent, fracture toughness is less than 4.5MPA.
Prepare embodiment 6
In this preparation embodiment, ceramic raw material composition is 00 part of silica 1;Alumina particle and magnesium oxide particle 0.5 part;8 parts of boric acid, it is hard that above-mentioned raw materials obtain sintering ceramics after the technique such as batch mixing ball milling, spray drying, dry-pressing formed, sintering Matter cap,
Wherein it is sintered to and is sintered in vacuum high temperature furnace under argon gas protection, sintering temperature is 1850 DEG C, and in-furnace temperature reaches The heat preservation sintering time is 1.2h after sintering temperature, and argon gas is filled with when vacuum high temperature furnace is preheated to 1500 DEG C.
This preparation embodiment prepares ceramics sample 100, and sintering finished qualification rate 99%, sample is by detection, average densification > 98% is spent, fracture toughness is less than 4.5MPA.
Embodiment 7-12 is prepared with preparing differing only in for embodiment 1-6, the granularity of silica is micro- for D50≤0.5 Rice (this place value can also for less than or equal to 0.3 micron, less than or equal to 0.15 micron, less than or equal to 0.4 micron, be less than or equal to 0.25 micron, less than or equal to 0.37 micron, less than or equal to 0.13 micron).Each embodiment for preparing in this place prepares ceramics sample 100, Sintering finished qualification rate 99%, sample is by detection, average density > 98.5%, fracture toughness 4.3-5.0MPA.
Embodiment 13-24 and preparation embodiment 1-12 is prepared to differ only in, alumina particle and magnesium oxide particle Granularity be D50≤3.0 micron (this place value can also be less than or equal to 2.3 microns, less than or equal to 1.5 microns, be less than or equal to 1.4 microns, less than or equal to 2.25 microns, less than or equal to 2.7 microns, less than or equal to 1.13 microns).This place is each to prepare embodiment system Standby ceramics sample 100, sintering finished qualification rate 99%, sample is by detection, and average density > 98.5%, fracture toughness (takes Average value ranges, similarly hereinafter) 4.8-5.3MPA.
Embodiment 25-48 is prepared with preparing differing only in for embodiment 1-24, raw material is prepared through water base ball milling, wherein water Addition accounts for the PVA aqueous solutions of raw material gross mass percentage 16% during base ball milling, and the concentration of PVA aqueous solutions is 10wt.%.This place is each Prepare embodiment and prepare ceramics sample 100, sintering finished qualification rate 99%, by detection, average density > 98%, breaks sample Split toughness and be more than 7.4MPA.Here during water base ball milling PVA aqueous solutions addition account for raw material gross mass percentage can also be 17%, 17.5%th, 18%, 18.5%, 19%, 19.5%, 20%, 18.3%, 17.2%, 16.7%, 19.4%, 16.1%, 18.8% And other arbitrary values in the range of 16-20%, and product quality is satisfied by the sintering finished qualification rate 99% of aforementioned claim, sample Product are by detection, average density > 98%, fracture toughness 5.3-5.8MPA.
Embodiment 47-96 is prepared with preparing differing only in for embodiment 1-48, when carrying out water base ball milling, ball milling slurry is dense Spend for (in terms of solid quality percentage) 45%, Ball-milling Time 3h.This place ball milling slurry concentration can also be 46%, 47%, 48%th, any other value in the range of 49%, 50% or 45-50%;Ball-milling Time can also be 1h, 2h, 1.5h or 1-3h In the range of other arbitrary values.Each embodiment product quality for preparing in this place is satisfied by the sintering finished qualification rate 99% of aforementioned claim, sample Product are by detection, average density > 98%, fracture toughness 5.5-6.2MPA.
Embodiment 47-96 is prepared with preparing differing only in for embodiment 1-48, obtains spray drying when dry-pressing formed Granularity D50 be 0.10mm granulation material, it is dry-pressing formed in 150MPA pressure.The granularity D50 that this place is dried to obtain can also be 0.15th, any other value in the range of 0.2,0.17,0.12,0.14 or 0.10-0.20mm;Dry-pressing formed pressure can also be 170th, other arbitrary values in the range of 200,175 or 150-200MPA.Each preparation embodiment product quality in this place is satisfied by foregoing It is required that sintering finished qualification rate 99%, sample is by detection, average density > 98%, fracture toughness 6.3-6.5MPA.
Distinguished with including but not limited to above-described embodiment, be additionally provided with silastic-layer under bottom of a cup, under silastic-layer End be provided with least one groove, groove only has at least one opening in lower section, be specifically as follows include but not limited to it is as follows It is any:The lower end of silastic-layer is provided with a groove, and groove only has an opening in lower section;The lower end of silastic-layer is set There is a groove, groove only has two mutually independent openings in lower section;The lower end of silastic-layer is provided with a groove, recessed Groove only has three mutually independent openings in lower section;The lower end of silastic-layer is provided with two mutually independent grooves, wherein One groove only has an opening in lower section, and another groove only has two mutually independent openings in lower section;Silicon rubber The lower end of glue-line is provided with three mutual grooves, and one of groove only has an opening in lower section, and another groove is only There are two mutually opening, the 3rd grooves only to have three mutually independent openings in lower section in lower section;Under silastic-layer End is provided with three mutual grooves, and two of which groove only all has an opening in lower section, and another groove is only in lower section With two mutually independent openings;The lower end of silastic-layer is provided with three mutual grooves, and two of which groove is only in lower section With two mutually independent openings, and another groove only has three mutually independent openings in lower section.
Distinguished with including but not limited to above-described embodiment, folded slot, folded slot are provided with the groove of silastic-layer It is parallel with bottom lower surface.
Distinguished with including but not limited to above-described embodiment, strengthen PP to add in the outer skin of the main body of PP materials Agent is added to be doped, additive is at least one of carbon fiber, ceramic fibre, titanium nitride, calcium carbonate, and it is total that additive accounts for main body The 0.1-0.3wt% of quality.
Include but not limited to the following specific embodiment for enhancing PP and be satisfied by the scope limit of technical solution of the present invention It is fixed.
Strengthen PP embodiments 1
The main part of the enhancing PP of the present embodiment is injection food-grade PP particulate materials, its top layer is mixed with additive Miscellaneous, additive carbon fiber content in main body is 0.13wt%.
Strengthen PP embodiments 2
The main part of the enhancing PP of the present embodiment is injection food-grade PP particulate materials, its top layer is mixed with additive Miscellaneous, additive ceramic fibre content in main body is 0.3wt%.
Strengthen PP embodiments 3
The main part of the enhancing PP of the present embodiment is injection food-grade PP particulate materials, its top layer is mixed with additive Miscellaneous, additive titanium nitride content in main body is 0.2wt%.
Strengthen PP embodiments 4
The main part of the enhancing PP of the present embodiment is injection food-grade PP particulate materials, its top layer is mixed with additive Miscellaneous, additive calcium carbonate content in main body is 0.1wt%.
Strengthen PP embodiments 5
The main part of the enhancing PP of the present embodiment is injection food-grade PP particulate materials, its top layer is mixed with additive Miscellaneous, additive carbon fiber, the ceramic fibre content in main body are respectively 0.1wt%, 0.13wt%.
Strengthen PP embodiments 6
The main part of the enhancing PP of the present embodiment is injection food-grade PP particulate materials, its top layer is mixed with additive Miscellaneous, additive carbon fiber, the calcium carbonate content in main body are respectively 0.01wt%, 0.16wt%wt%.
Strengthen PP embodiments 7
The main part of the enhancing PP of the present embodiment is injection food-grade PP particulate materials, its top layer is mixed with additive Miscellaneous, additive carbon fiber, the titanium nitride content in main body are respectively 0.15wt%, 0.13wt%.
Strengthen PP embodiments 8
The main part of the enhancing PP of the present embodiment is injection food-grade PP particulate materials, its top layer is mixed with additive Miscellaneous, additive ceramic fibre, the titanium nitride content in main body are respectively 0.1wt%, 0.18wt%.
Strengthen PP embodiments 9
The main part of the enhancing PP of the present embodiment is injection food-grade PP particulate materials, its top layer is mixed with additive Miscellaneous, additive ceramic fibre, the calcium carbonate content in main body are respectively 0.05wt%, 0.05wt%.
Strengthen PP embodiments 10
The main part of the enhancing PP of the present embodiment is injection food-grade PP particulate materials, its top layer is mixed with additive Miscellaneous, additive titanium nitride, the calcium carbonate content in main body are respectively 0.01wt%, 0.23wt%.
Strengthen PP embodiments 11
The main part of the enhancing PP of the present embodiment is injection food-grade PP particulate materials, its top layer is mixed with additive Miscellaneous, additive carbon fiber, ceramic fibre, the titanium nitride content in main body are respectively 0.1wt%, 0.03wt%, 0.13wt%.
Strengthen PP embodiments 12
The main part of the enhancing PP of the present embodiment is injection food-grade PP particulate materials, its top layer is mixed with additive Miscellaneous, additive carbon fiber, ceramic fibre, the calcium carbonate content in main body are respectively 0.04wt%, 0.08wt%, 0.12wt%.
Strengthen PP embodiments 13
The main part of the enhancing PP of the present embodiment is injection food-grade PP particulate materials, its top layer is mixed with additive Miscellaneous, additive carbon fiber, titanium nitride, the calcium carbonate content in main body are respectively 0.15wt%, 0.07wt%, 0.04wt%.
Strengthen PP embodiments 14
The main part of the enhancing PP of the present embodiment is injection food-grade PP particulate materials, its top layer is mixed with additive Miscellaneous, additive ceramic fibre, titanium nitride, the calcium carbonate content in main body are respectively 0.01wt%, 0.23wt%, 0.03wt%.
Strengthen PP embodiments 15
The main part of the enhancing PP of the present embodiment is injection food-grade PP particulate materials, its top layer is mixed with additive It is miscellaneous, additive carbon fiber, ceramic fibre, titanium nitride, the calcium carbonate content in main body be respectively 0.11wt%, 0.03wt%, 0.05wt%, 0.11wt%.
Strengthen PP embodiments 16
The main part of the enhancing PP of the present embodiment is injection food-grade PP particulate materials, its top layer is mixed with additive Miscellaneous, additive carbon fiber, the calcium carbonate content in main body are respectively 0.08wt%, 0.03wt%.
Strengthen PP embodiments 17
The main part of the enhancing PP of the present embodiment is injection food-grade PP particulate materials, its top layer is mixed with additive It is miscellaneous, additive carbon fiber, ceramic fibre, titanium nitride, the calcium carbonate content in main body be respectively 0.08wt%, 0.03wt%, 0.05wt%, 0.10wt%.
Distinguished with above-described embodiment, additive in main body for 0.5mm, (mix doping depth in main body by additive Miscellaneous depth can also be 0.17mm, 0.29mm, 0.36mm, 0.48mm, 0.32mm, 0.4mm, 0.24mm, 0.25mm, 0.21mm, 0.18mm、0.30mm、0.33mm、0.14mm、0.22mm、0.103mm、0.02mm、0.05mm、0.07mm、0.08mm、0.1mm、 0.2mm, 0.15mm, 0.25mm, 0.35mm, 0.45mm and other values no more than 0.5mm).It is very small when being agglomerated into one Thickness be that material surface forms one and mainly forms shell using PP as bonding agent by additive, have at this time good Wearability and mechanical performance.At this time, additive can be uniformly distributed in the top layer in main body in doping depth;Can also content From outward appearance to inner essence successively decrease, i.e., with the increase of doping depth, the content of additive is reduced in same depth.
Distinguished with above-described embodiment, protective layer is glass protecting layer.The thickness of glass protecting layer is 0.5mm (glass The thickness of glass protective layer can also be 0.17mm, 0.29mm, 0.36mm, 0.48mm, 0.32mm, 0.4mm, 0.24mm, 0.25mm, 0.21mm、0.18mm、0.30mm、0.33mm、0.14mm、0.22mm、0.103mm、0.02mm、0.05mm、0.07mm、 0.08mm, 0.1mm, 0.2mm, 0.15mm, 0.25mm, 0.35mm, 0.45mm and other values no more than 0.5mm).
Distinguished with above-described embodiment, protective layer is ceramic protection layer.The thickness of ceramic protection layer is 0.5mm (potteries The thickness of porcelain protective layer can also be 0.17mm, 0.29mm, 0.36mm, 0.48mm, 0.32mm, 0.4mm, 0.24mm, 0.25mm, 0.21mm、0.18mm、0.30mm、0.33mm、0.14mm、0.22mm、0.103mm、0.02mm、0.05mm、0.07mm、 0.08mm, 0.1mm, 0.2mm, 0.15mm, 0.25mm, 0.35mm, 0.45mm and other values no more than 0.5mm).
Distinguished with above-described embodiment, protective layer is stainless steel protective cover, is food-grade stainless steel.Stainless steel protects Layer thickness be 0.5mm (thickness of stainless steel protective cover can also be 0.17mm, 0.29mm, 0.36mm, 0.48mm, 0.32mm, 0.4mm、0.24mm、0.25mm、0.21mm、0.18mm、0.30mm、0.33mm、0.14mm、0.22mm、0.103mm、0.02mm、 0.05mm, 0.07mm, 0.08mm, 0.1mm, 0.2mm, 0.15mm, 0.25mm, 0.35mm, 0.45mm and other it is not more than The value of 0.5mm).
Distinguished with above-described embodiment, protective layer has loose structure.The average pore size of loose structure is (more for 10 μm The average pore size of pore structure can also be 10.5 μm, 20 μm, 25.4 μm, 30 μm, 33.7 μm, 40 μm, 49.9 μm, 50 μm, 56.2 μ M, its in 60 μm, 66.4 μm, 70 μm, 78.3 μm, 80 μm, 88.1 μm, 90 μm, 92.9 μm, 100 μm and 10-100 μ ms Its arbitrary value).Preferably, it is that (hole of loose structure is evenly distributed 80/square inch that the hole of loose structure, which is evenly distributed density, Density can also be 82/square inch, 90/square inch, 93/square inch, 100/square inch, 101/flat Square inch, 110/square inch, 115/square inch, 120/square inch, 124/square inch, 130/square Inch, 137/square inch, 140/square inch, 146/square inch, 150/square inch, 159/square English Very little, 160/square inch, 168/square inch, 170/square inch, 177/square inch, 180/square English Very little, 189/square inch, 290/square inch, 196/square inch, 200/square inch and 80-200/flat Other arbitrary values in square inch range).Preferably, the depth in the hole of loose structure is 1/5 (loose structure of overcoat thickness Hole depth can also be overcoat thickness 1/4,1/3,1/2,0.3,0.35,0.4,0.45 and 1/5-1/2 in the range of Other arbitrary values).
This place embodiment is in place of the claimed non-limit of technical scope midrange and in embodiment technology The new technical solution formed is replaced on an equal basis to single or multiple technical characteristics in scheme, equally all in application claims In the range of protection;At the same time the present invention program it is all enumerate or unrequited embodiment in, in the same embodiment each Parameter is merely representative of an example (i.e. a kind of feasible scheme) for its technical solution, and between parameters and is not present stringent Cooperation and qualified relation, wherein each parameter can be replaced mutually when stating and asking without prejudice to axiom and the present invention, special declaration Except.
Technological means disclosed in the present invention program is not limited only to the technological means disclosed in above-mentioned technological means, further includes Formed technical solution is combined by above technical characteristic.The above is the embodiment of the present invention, should be referred to Go out, for those skilled in the art, without departing from the principle of the present invention, can also make some Improvements and modifications, these improvements and modifications are also considered as protection scope of the present invention.

Claims (6)

1. a kind of abnormity football cup, including bottom of a cup, the cup body and cup lid with water containing chamber, it is characterised in that the cup body is It is spherical, and cup body outer surface has multiple hexagons and multiple pentagonal assorted figures, each of which hexagon is complete Each either local pentagon to be complete or local, the cup body is enhancing PP materials, the cup body inner wall On also there is protective layer;
Wherein, the enhancing PP is to be doped in the outer skins of main body of PP materials with additive, additive is carbon fiber, At least one of ceramic fibre, titanium nitride, calcium carbonate, additive account for the 0.1-0.3wt% of main body gross mass, the additive Doping depth is not more than 0.5mm in main body, and the additive is uniformly distributed in main body top layer or from outward appearance to inner essence successively decreases.
2. abnormity football cup according to claim 1, it is characterised in that two neighboring pentagon in the assorted figure And/or the junction of hexagon has groove structure and/or projective structure.
3. abnormity football cup according to claim 2, it is characterised in that when the junction has projective structure, its Main body including silicone rubber material.
4. abnormity football cup according to claim 3, it is characterised in that hard cap, institute are additionally provided with the main body Hard cap is stated to be arranged on body end and be engaged with body end.
5. abnormity football cup according to claim 1, it is characterised in that silastic-layer is additionally provided with the bottom of a cup, The lower end of the silastic-layer is provided with least one groove, and the groove only has at least one opening in lower section.
6. abnormity football cup according to claim 5, it is characterised in that folding is provided with the groove of the silastic-layer Folded groove, the folded slot are parallel with bottom lower surface.
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RU2677152C2 (en) * 2017-03-01 2019-01-15 Евгений Александрович Вавилов Bottle
CN109463955A (en) * 2018-10-24 2019-03-15 李春红 One kind building water purple pottery pot and its manufacture craft

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CN100420408C (en) * 2006-08-11 2008-09-24 陆焕炯 Ball-shaped cup
CN200980529Y (en) * 2006-10-11 2007-11-28 张柏荣 Handicraft teapot
CN201317477Y (en) * 2008-10-07 2009-09-30 林智勇 Football beverage bottle
CN201365761Y (en) * 2009-02-13 2009-12-23 何焯辉 Single reticular teapot
DE202010002253U1 (en) * 2010-02-16 2010-05-06 Dangelmayer, Markus bottle
CN204500234U (en) * 2015-04-09 2015-07-29 汤铭源 A kind of massage type water tumbler

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Address after: 315156 Dongbei No. 38, Dongqiao Town, Haishu District, Ningbo, Zhejiang

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