CN106263263A - A kind of shoe pad with bacteriostatic deodorizing effect - Google Patents
A kind of shoe pad with bacteriostatic deodorizing effect Download PDFInfo
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- CN106263263A CN106263263A CN201610660416.5A CN201610660416A CN106263263A CN 106263263 A CN106263263 A CN 106263263A CN 201610660416 A CN201610660416 A CN 201610660416A CN 106263263 A CN106263263 A CN 106263263A
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- Prior art keywords
- shoe pad
- microcapsule
- fiber
- quintessence oil
- folium granati
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- A—HUMAN NECESSITIES
- A43—FOOTWEAR
- A43B—CHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
- A43B17/00—Insoles for insertion, e.g. footbeds or inlays, for attachment to the shoe after the upper has been joined
- A43B17/003—Insoles for insertion, e.g. footbeds or inlays, for attachment to the shoe after the upper has been joined characterised by the material
- A43B17/006—Insoles for insertion, e.g. footbeds or inlays, for attachment to the shoe after the upper has been joined characterised by the material multilayered
-
- A—HUMAN NECESSITIES
- A43—FOOTWEAR
- A43B—CHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
- A43B17/00—Insoles for insertion, e.g. footbeds or inlays, for attachment to the shoe after the upper has been joined
- A43B17/08—Insoles for insertion, e.g. footbeds or inlays, for attachment to the shoe after the upper has been joined ventilated
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
- D06M13/188—Monocarboxylic acids; Anhydrides, halides or salts thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/224—Esters of carboxylic acids; Esters of carbonic acid
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
- D06M13/248—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing sulfur
- D06M13/256—Sulfonated compounds esters thereof, e.g. sultones
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/564—Polyureas, polyurethanes or other polymers having ureide or urethane links; Precondensation products forming them
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M23/00—Treatment of fibres, threads, yarns, fabrics or fibrous goods made from such materials, characterised by the process
- D06M23/12—Processes in which the treating agent is incorporated in microcapsules
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/16—Synthetic fibres, other than mineral fibres
- D06M2101/18—Synthetic fibres consisting of macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M2101/20—Polyalkenes, polymers or copolymers of compounds with alkenyl groups bonded to aromatic groups
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/16—Synthetic fibres, other than mineral fibres
- D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M2101/32—Polyesters
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- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Footwear And Its Accessory, Manufacturing Method And Apparatuses (AREA)
Abstract
A kind of shoe pad with bacteriostatic deodorizing effect and preparation method thereof, implant by 80～the polyster fibre of 40%, 20～the functional fiber composition of 60%.Its described functional fiber is the functional fiber containing Folium Granati quintessence oil.The hollow performance of polyethylene hollow fiber and microcapsule technology enable the fiber containing Folium Granati quintessence oil to discharge Folium Granati quintessence oil for a long time, slowly, and the shoe pad for making plays antibacterial, deodorant, ventilative effect.
Description
Technical field
The present invention relates to a kind of shoe pad with bacteriostatic deodorizing effect and processing technique thereof.
Background technology
Under modern science and technology, if the function of shoe pad is more than one piece of comfortable cushion, it is promoted to auxiliary shoes subfunction
An assembly.The function that modern high-quality shoe pad can provide has following: 1. prevent sole from sliding in footwear.Footwear bed in footwear is
Flat, but your sole is not, and therefore when walking, sole will slide in footwear, and just during walking, each step will take one more
Point strength, long-distance walking is easier to increase various wounds.The shoe pad using solid figure can be filled with the room between sole and footwear bed,
Lower sole slip in footwear.2. improving support, improve stablizing of paces, the shoe pad added with heel support cup can lower step
Swing when heel lands during row, thus lower fatigue and lower the chance of wound.3. shock-absorbing.Shock absorption shoe-pad has two kinds, a kind of
It is to use rigid cup-shaped heel torr, because the plump muscle of mankind's heel is exactly a natural shock-absorbing function, as long as coordinating
The ebonite torr of one suitable radian, just can give play to good vibration-absorbing function, it is adaptable to the work that some paces are stable and lasting
Dynamic, as sword hit, strength step, pleasure trip on foot etc..And another kind of be help other flexible material, when absorbing heel contact such as Gel, air cushion
Impulsive force, it is adaptable to run, work is beated in the contour race of basketball.4. correct walking and stance.Sound and seem the most magical, but
This function that orthopedic insoles can play just, has many people because of born and other factors, and when standing, vertebra is with thigh bone not
Can be very vertical, or right pendulum is shaken on a stride left side when walking, long-term under cause the wound in various skeleton and joint, by rectifying
Posture when shape shoe pad can be corrected walking and stand, thus lower wound.The most alternative shoe pad has: 1) EVA sends out
It is derived from the shoe pad of sport shoes to steep rubber overshoes pad, simply casts the arc bottom sole with EVA foamed glue, except price is
Substantially free of what performance can say outside cheap, most hiking boots is original-pack is all to use this kind of shoe pad.2) Codium fragile (Sur.) Har. shoe pad.As far back as number
Before century-old, European just has been found that Codium fragile (Sur.) Har. is one of good material making shoe pad.The advantage of Codium fragile (Sur.) Har. is light, soft and comfortable, and has sky
Right breathability, and the advantage of maximum is to be automatically adjusted to most suitable shape according to the radian of your sole, it is ensured that docile.Tradition
Codium fragile (Sur.) Har. shoe pad be the arc that natural Codium fragile (Sur.) Har. cutter is whittled into sole, but the modern times have converted, the mode of casting forming makes.But
Codium fragile (Sur.) Har. also because the most too soft, can not provide the function of support or other side in addition to comfortable；Additionally, Codium fragile (Sur.) Har. shoe pad is the most not
Calculate cheap.3) medium supporting insole.This is also the shoe pad that some senior hiking boots is original-pack, and it is at heel by common EVA shoe pad
Part, plus the ebonite torr of arc, makes to have in terms of support and stability more preferably to show.4) highly supporting insole.It is to be situated between symbol commonly
Product between shoe pad and orthopedic insoles, it is the heel torr on EVA shoe pad plus accurate radian, and support scope stretches
To middle metacarpus part, in support and stablize aspect and have and more preferably show, for evaluation soprano in the most independent shoe pad sold.5) shock-absorbing
Shoe pad.It is plus the vibration absorptive material of Gel or air cushion etc in the heel of common EVA shoe pad and half sole part, is best suitable for running
Or other similar strenuous exercise.Shock absorption shoe-pad be to set for excursionist in fact, because of the impact of each step of pleasure trip on foot paces
Power is the strongest, and stable on the contrary and support is only the function that hiking boots needs most.6) orthopedic insoles.If your foot the most unfortunate
The palm is to be subject to wound, and during walking, pain is unbearable, and that is just wanted the sole degree body that foot doctor is you to order and makes a pair of orthopedic insoles.All kinds of
In shoe pad, orthopedic insoles is optimal because he is to order for your biped to make, though in terms of radian or soft or hard all and you
A pair of sole coincide.Simply taken the most high, typically by diagnosis connect making have to take thousands of unit can not.But,
Generally there is the problems such as poor air permeability in main flow shoe pad in the market, and particularly within summer, footwear, heat is relatively large, if not
Can dispel the heat timely and effectively, easily produce the problem such as tinea pedis and foot odor, grow a large amount of bacteria effect foot healthy simultaneously.
Polyethylene or PET Hollow hollowness of fibre are high, have after arranging good holding finishing agent and relative to
The effect that other chemical fibres are ventilative.Punica granatum L. is machaka or arbor, high generally 3-5m, dilute reaches 10m.Branch top often becomes sharp-pointed point
Lunge, sprout has corner angle, and without hair, old branch is the most cylindrical.Folium Granati is the leaf of Punica granatum L., has antibacterial, astringing to arrest diarrhea, angle poisoning
Worm, main have loose bowels, the effect such as variolar carbuncle, impetigo, traumatic injury.The present invention utilizes the extraction of essential oil technique of improvement, microcapsule technology
And polyethylene or the characteristic of PET Hollow fiber hollow, it is used for fiber finishing after finishing agent is made microcapsule, it is possible to
Inside hollow fibre obtain good finishing agent keeping quality can, useful life longevity is good.
Summary of the invention
The present invention, by the experimental selection to multiple fiber, utilizes extraction of essential oil technique, the hollow of doughnut improved
Performance and microcapsule technology enable the fiber containing Folium Granati quintessence oil to discharge Folium Granati quintessence oil for a long time, slowly, and rise
To ventilative, antibacterial, the effect of deodorant.
For reaching above-mentioned purpose, the present invention provides a kind of functional innersole, it is characterised in that implant is by 80～40%
Polyster fibre, 20～the functional fiber composition of 60%.Its described functional fiber is the functional fibre containing Folium Granati quintessence oil
Dimension.The polyster fibre of preferably 78% and the functional fiber of 22%, the polyster fibre of more preferably 60% and the functional fiber of 40%, hundred
Proportion by subtraction is weight percentage.
The preparation method of described shoe pad, it is characterised in that include that following methods prepares:
The first step: extract Folium Granati quintessence oil.Folium Granati was pulverized 40-50 mesh sieve, weighed 10-20g, in 250mL boiling flask
In, add normal hexane or normal butane 150-200mL by solid-liquid ratio 1:15-1:20, be placed in shaking table interior at 50-60 DEG C, 100-150
Secondary/min vibration extraction 3-5h, then carries out heating and refluxing extraction in water-bath, and Extracting temperature is 30-50 DEG C, extraction time
For 25min.Taking-up is cooled to room temperature, sucking filtration, leaches extracting solution and is placed in 500mL round-bottomed flask ,-0.80Mpa and 40 DEG C～
Carry out rotary evaporation under the conditions of 45 DEG C and be concentrated to small size, recycling design, wave most solvent, obtain Folium Granati quintessence oil；
Second step: under conditions of water bath with thermostatic control, by Folium Granati quintessence oil, 3-4g pyrethrin, 0.1-1g zinc acetate, 0.8-1.5g
Xylene monosulfonic acid potassium, 3-5g polyurethanes, put into 10 ~ 13%(weight) in microcapsule solution, it is heated to stirring, depends on
Secondary addition 2 5g lavandula angustifolia extracting solution, dispersant and binding agent, stirring, make microcapsule dressing agent；
3rd step, after microcapsule dressing agent is applied to fiber surface by the means of atomization by ultrasonic atomization equipment, at its table
Layer covers a microcapsule finishing agent film, completes pretreatment；
4th step, puts into pretreated polyethylene or PET Hollow fiber in microcapsule dressing agent the most again and impregnates, band liquid
Rate is 90-100%；It is dehydrated 2 minutes at 30-45 DEG C the most again, 60-70 DEG C of low temperature preliminary drying subsequently, finally naturally dries, prepared merit
Can property fiber；
5th step, makes shoe pad by functional fiber and polyster fibre, and concrete steps mode is that described shoe pad is distinguished from top to bottom
Aftershaping is extruded through hot-rolling by ground floor terylene warp knit screen cloth, second layer composite, third layer terylene warp knit screen cloth, described
The weight ratio of two layers of composite be the terylene of 1:2 1:1.5 and functional fiber through shredding, mixing, combing, staggered lapping,
The aftershapings such as acupuncture, hot light reinforcing, the mesh of described ground floor warp knit screen cloth and second layer warp knit screen cloth is fusiformis, thus obtains
Shoe pad bidirectional stretch ability strong, good permeability.Hot pressure condition be upper and lower surface roller be rubber smooth roll, pressure is 3 kilograms, temperature
It it is 100 120 DEG C.
The preparation method of described shoe pad, it is characterised in that: the frequency of oscillation that ultrasonic atomization processes is 1.7MHz
2.4MHz。
Doughnut can also is that viscose doughnut, dry strong the 22 of fiber～24cN/tex, stem elongation rate 14%～
15%.Wet strong 10～12cN/tex, wet expansion 15%～22%.Water absorption rate 120%～130%.Use viscose doughnut
The moisture-penetrable ventilated property of rear shoe pad is more preferable, is more suitable for using summer.
Microcapsule solution is gelatin or instant arabic gum.Dispersant is the conventional disperse such as glyceryl tristearate, paraffin
Agent, binding agent is starch, dextrin, polyvinyl alcohol, carboxymethyl cellulose, vinyl acetate resin, acrylic resin or chlorinated rubber
Deng；Microcapsule solution is gelatin or instant arabic gum.
Folium Granati extraction of essential oil can be carried out by following two mode:
One, the organic solvent way of distillation:
40 mesh sieves pulverized by Folium Granati, weighed 10g, in 250mL boiling flask, added n-hexane 150mL by solid-liquid ratio 1:15,
It is placed in shaking table interior at 50 DEG C, 100 times/min vibration extraction 4h.Then in water-bath, carry out heating and refluxing extraction.Extracting temperature
Being 55 DEG C, extraction time is 30min.Taking-up is cooled to room temperature, sucking filtration, leaches extracting solution and is placed in (the rotation steaming of 500mL round-bottomed flask
Send out the flask used on instrument, and to weigh up weight in advance be W1) in, rotate under the conditions of-0.80Mpa and 40 DEG C～45 DEG C
Evaporation and concentration, to small size, recycling design, waves most solvent, and weigh W2.It is calculated as follows and smokes clothing oil extraction ratio:
Folium Granati extraction of essential oil rate=(weight g) × 100% of (W2-W1) g/ dry flower
Two, microwave-assisted extraction
40 mesh sieves pulverized by Folium Granati, weighed 5g, in 250ml triangular flask, added n-hexane 150mL by solid-liquid ratio 1:15, filled
Sub-dip profit is placed in microwave oven, microwave treatment conditions: microwave power is middle-grade (484W), radiated time 5min, fixed frequency
2450MHz.After certain time, take out and be cooled to room temperature, sucking filtration, leach extracting solution and be placed in 500mL round-bottomed flask (Rotary Evaporators
The flask of upper use, and to weigh up weight in advance be W1) in, under the conditions of-0.80Mpa and 40 DEG C～45 DEG C, carry out rotary evaporation
Being concentrated to small size, recycling design, wave most solvent, weigh W2.Calculate by above formula and smoke clothing oil extraction ratio.
Compared with prior art, the application has the advantages that
(1) microcapsule technology of the present invention, forms the particle diameter microcapsule at 0.1 0.9 micrometer ranges, and mode of appearance is good, point
Dissipating property good, and polyethylene hollow fiber degree of hollowness is high, therefore under both cooperations, microcapsule can be efficiently entering and adsorb
On fiber；
(2) present invention is before impregnation, first doughnut is carried out pretreatment, is arranged by microcapsule with ultrasonic atomization equipment
After agent is applied to fiber surface by the means of atomization, one microcapsule finishing agent film at its Surface mulch, this means
Employing makes in addition to fibrous inside can be coated with functional material, additionally it is possible to adheres in outside, is effectively increased function
The adhesive rate of property finishing agent and releasing effect；
(3) various process parameters of Folium Granati extraction of essential oil of the present invention is that test is repeated, the quintessence oil purity finally obtained
Height, had good sustained release effect.Pyrethrin, zinc acetate, three kinds of materials of xylene monosulfonic acid potassium are added when manufacturing microcapsule solution, they
With Folium Granati quintessence oil generation synergism, there is the effects such as antibacterial, anti-relieving itching, additionally, the addition of lavandula angustifolia extracting solution also makes
The shoe pad that must make has the abnormal smells from the patient that fragrance is pleasant.
(4) present invention passes through many kinds of substance and the cooperation of technique, and the shoe pad of manufacture has air-permeable anti-bacterial and good simultaneously
The characteristic of hot strength, other method is difficult to realize simultaneously.
Detailed description of the invention
Below in conjunction with embodiment, the present invention is further elaborated.
Embodiment 1
The first step: extract Folium Granati quintessence oil.Folium Granati was pulverized 48 mesh sieves, weighed 15g, in 250mL boiling flask, by material
Liquor ratio 1:16 adds normal hexane 180mL, is placed in shaking table interior at 55 DEG C, 130 times/min vibration extraction 4h, then enters in water-bath
Row heating and refluxing extraction, Extracting temperature is 35 DEG C, and extraction time is 25min.Taking-up is cooled to room temperature, sucking filtration, leaches extracting solution
It is placed in 500mL round-bottomed flask, under the conditions of-0.80Mpa and 44 DEG C, carries out rotary evaporation be concentrated to small size, recycling design,
Wave most solvent, obtain Folium Granati quintessence oil；
Second step: under conditions of water bath with thermostatic control, by Folium Granati quintessence oil, 3.4g pyrethrin, 0.11g zinc acetate, 0.85g diformazan
Benzenesulfonic acid potassium, 3.5g polyurethanes, put in 11% gelatin solution, is heated to stirring, and is sequentially added into 3g lavandula angustifolia and carries
Take liquid, dispersant and binding agent, stirring, make microcapsule dressing agent；
3rd step, after microcapsule dressing agent is applied to fiber surface by the means of atomization by ultrasonic atomization equipment, at its table
Layer covers a microcapsule finishing agent film, completes pretreatment；The frequency of oscillation that ultrasonic atomization processes is 2.2MHz
4th step, puts into pretreated polyethylene hollow fiber in microcapsule dressing agent the most again and impregnates, and liquid carrying rate is 90-
100%；It is dehydrated 2 minutes at 34 DEG C the most again, 67 DEG C of low temperature preliminary dryings subsequently, finally naturally dries, prepared functional fiber；
5th step, makes shoe pad by functional fiber and polyster fibre, and concrete steps mode is that described shoe pad is distinguished from top to bottom
It is that composite, third layer terylene warp knit screen cloth extrude aftershaping through hot-rolling by ground floor terylene warp knit screen cloth, the second layer, described
The weight ratio of second layer composite be the terylene of 1:2 and functional fiber through shredding, mixing, combing, staggered lapping, acupuncture,
The aftershapings such as hot light reinforcing, the mesh of described ground floor warp knit screen cloth and second layer warp knit screen cloth is fusiformis.
Embodiment 2
Take Folium Granati quintessence oil.Folium Granati was pulverized 49 mesh sieves, weighed 18g, in 250mL boiling flask, by solid-liquid ratio 1:19
Add normal butane 180mL, be placed in shaking table interior at 45 DEG C, 130 times/min vibration extraction 4h, then heat back in water-bath
Stream extracts, and Extracting temperature is 35 DEG C, and extraction time is 25min.Taking-up is cooled to room temperature, sucking filtration, leaches extracting solution and is placed in 500mL
In round-bottomed flask, under the conditions of-0.80Mpa and 44 DEG C, carry out rotary evaporation be concentrated to small size, recycling design, wave most solvent,
Obtain Folium Granati quintessence oil；
Second step: under conditions of water bath with thermostatic control, by Folium Granati quintessence oil, 3-4g pyrethrin, 0.1-1g zinc acetate, 0.8-1.5g
Xylene monosulfonic acid potassium, 3-5g polyurethanes, put in 12% gumwater, is heated to stirring, is sequentially added into 4g
Lavandula angustifolia extracting solution, dispersant and binding agent, stirring, make microcapsule dressing agent；
3rd step, after microcapsule dressing agent is applied to fiber surface by the means of atomization by ultrasonic atomization equipment, at its table
Layer covers a microcapsule finishing agent film, completes pretreatment；The frequency of oscillation that ultrasonic atomization processes is 2MHz
4th step, puts into pretreated polyethylene hollow fiber in microcapsule dressing agent the most again and impregnates, and liquid carrying rate is
100%；It is dehydrated 2 minutes at 38 DEG C the most again, 69 DEG C of low temperature preliminary dryings subsequently, finally naturally dries, prepared functional fiber；
5th step, makes shoe pad by functional fiber and polyster fibre, and concrete steps mode is that described shoe pad is distinguished from top to bottom
It is that composite, third layer terylene warp knit screen cloth extrude aftershaping through hot-rolling by ground floor terylene warp knit screen cloth, the second layer, described
The weight ratio of second layer composite is that the terylene of 1:1.5 and functional fiber are through shredding, mixing, combing, staggered lapping, pin
The aftershapings such as thorn, hot light reinforcing, the mesh of described ground floor warp knit screen cloth and second layer warp knit screen cloth is fusiformis,
Embodiment 3
Take Folium Granati quintessence oil.Folium Granati was pulverized 50 mesh sieves, weighed 15g, in 250mL boiling flask, by solid-liquid ratio 1:20
Add normal hexane 180mL, be placed in shaking table interior at 45 DEG C, 130 times/min vibration extraction 4h, then heat back in water-bath
Stream extracts, and Extracting temperature is 35 DEG C, and extraction time is 25min.Taking-up is cooled to room temperature, sucking filtration, leaches extracting solution and is placed in 500mL
In round-bottomed flask, under the conditions of-0.80Mpa and 44 DEG C, carry out rotary evaporation be concentrated to small size, recycling design, wave most solvent,
Obtain Folium Granati quintessence oil；
Second step: under conditions of water bath with thermostatic control, by Folium Granati quintessence oil, 4g pyrethrin, 0.8g zinc acetate, 0.9g dimethylbenzene sulphur
Acid potassium, 3.5g polyurethanes, put in 15% gumwater, be heated to stirring, be sequentially added into 3.3g lavandula angustifolia
Extracting solution, dispersant and binding agent, stirring, make microcapsule dressing agent；
3rd step, after microcapsule dressing agent is applied to PET fiber surface by the means of atomization by ultrasonic atomization equipment,
Its Surface mulch one microcapsule finishing agent film, completes pretreatment；The frequency of oscillation that ultrasonic atomization processes is 1.8MHz
4th step, puts into pretreated PET Hollow fiber in microcapsule dressing agent the most again and impregnates, and liquid carrying rate is 100%；
It is dehydrated 2 minutes at 38 DEG C the most again, 69 DEG C of low temperature preliminary dryings subsequently, finally naturally dries, prepared functional fiber；
5th step, makes shoe pad by functional fiber and polyster fibre, and concrete steps mode is that described shoe pad is distinguished from top to bottom
It is that composite, third layer terylene warp knit screen cloth extrude aftershaping through hot-rolling by ground floor terylene warp knit screen cloth, the second layer, described
The weight ratio of second layer composite is that the terylene of 1:2 1:1.5 and functional fiber are through shredding, mixing, combing, staggered paving
The aftershapings such as net, acupuncture, hot light reinforcing, the mesh of described ground floor warp knit screen cloth and second layer warp knit screen cloth is fusiformis.
Comparative example 1
Polyethylene hollow fiber in embodiment 1 is replaced to polyurethane fiber.
Comparative example 2
Other is same as in Example 2, but is not added with pyrethrin, zinc acetate, three kinds of materials of xylene monosulfonic acid potassium.
Comparative example 3
Being provided without ultrasonic atomization pretreatment, other is same as in Example 3.
Comparative example 4
The mesh of described ground floor warp knit screen cloth and second layer warp knit screen cloth is arbitrary shape, and other is same with embodiment 3.
After testing, the insole function result that prepared by embodiment is as follows:
| Embodiment 1 | Embodiment 2 | Embodiment 3 | Comparative example 1 | Comparative example 2 | Comparative example 3 | Comparative example 4 | |
| Antibiotic property (%) | 98 | 98.5 | 99.99 | 85 | 86 | 83 | 97 |
| 100 days release rates (%) | 64 | 66.6 | 63 | 41 | 42.5 | 41 | 60 |
| 100 days antibiotic rates (%) | 97 | 97.98 | 99 | 91 | 83.2 | 86 | 99 |
| After washing 10 times | 91 | 89 | 92 | 77 | 72 | 63 | 91 |
| Antibacterial ring (mm) | 8 | 7.5 | 8.9 | 6 | 6.5 | 5 | 8.5 |
| Hot strength (mpa) | 10 | 8 | 9 | 7 | 8 | 8 | 4 |
Claims (7)
1. a shoe pad with bacteriostatic deodorizing effect, it is characterised in that by 80～the polyster fibre of 40%, 20～the merit of 60%
Can make by property fiber.
2. shoe pad as claimed in claim 1, its described functional fiber is the functional fiber containing Folium Granati quintessence oil.
3. the preparation method of a shoe pad as claimed in claim 1 or 2, it is characterised in that comprise the steps:
The first step: extract Folium Granati quintessence oil.
4. Folium Granati was pulverized 40-50 mesh sieve, weighed 10-20g, in 250mL boiling flask, by solid-liquid ratio 1:15-1:20
Add normal hexane 150-200mL, be placed in shaking table interior at 50-60 DEG C, 100-150 time/min vibration extraction 3-5h, then in water-bath
Carrying out heating and refluxing extraction in Guo, Extracting temperature is 30-50 DEG C, and extraction time is 25min.
5. take out and be cooled to room temperature, sucking filtration, leach extracting solution and be placed in 500mL round-bottomed flask ,-0.80Mpa and 40 DEG C～45
Carry out rotary evaporation under the conditions of DEG C and be concentrated to small size, recycling design, wave most solvent, obtain Folium Granati quintessence oil；
Second step: under conditions of water bath with thermostatic control, by Folium Granati quintessence oil, 3-4g pyrethrin, 0.1-1g zinc acetate, 0.8-1.5g
Xylene monosulfonic acid potassium, 3-5g polyurethanes, put in microcapsule solution, is heated to stirring, is sequentially added into lavandula angustifolia
Extracting solution, dispersant and binding agent, stirring, make microcapsule dressing agent；
3rd step, microcapsule dressing agent is applied to polyethylene hollow fiber surface by the means of atomization by ultrasonic atomization equipment
After, one microcapsule finishing agent film at its Surface mulch, complete pretreatment；
4th step, puts into pretreated polyethylene hollow fiber in microcapsule dressing agent the most again and impregnates, and liquid carrying rate is 90-
100%；It is dehydrated 2 minutes at 30-45 DEG C the most again, 60-70 DEG C of low temperature preliminary drying subsequently, finally naturally dries, prepared functional fibre
Dimension；
5th step, makes shoe pad by functional fiber and polyster fibre, and concrete mode is that described shoe pad is the most respectively by the
One layer of terylene warp knit screen cloth, second layer composite, third layer terylene warp knit screen cloth extrude aftershaping, the described second layer through hot-rolling
Composite is 1:2 1:1.5(weight ratio) terylene and the functional fiber that obtains after treatment through shredding, mixing, combing,
Staggered lapping, acupuncture, hot light reinforce aftershaping, and the mesh of described ground floor warp knit screen cloth and second layer warp knit screen cloth is fusiformis,
Hot pressure condition be upper and lower surface roller be rubber smooth roll, pressure is 3 kilograms, and temperature is 100 120 DEG C.
6. method as claimed in claim 3, it is characterised in that: the frequency of oscillation that ultrasonic atomization processes be 1.7MHz ~
2.4MHz。
7. the method as described in claim 3 or 4, it is characterised in that: microcapsule solution is gelatin or instant arabic gum.
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| CN201610660416.5A CN106263263A (en) | 2016-08-12 | 2016-08-12 | A kind of shoe pad with bacteriostatic deodorizing effect |
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| CN201610660416.5A CN106263263A (en) | 2016-08-12 | 2016-08-12 | A kind of shoe pad with bacteriostatic deodorizing effect |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107326660A (en) * | 2017-06-26 | 2017-11-07 | 苏州威尔德工贸有限公司 | A kind of preparation method of anti-bacterial textile finishing agent |
| CN108741408A (en) * | 2018-04-19 | 2018-11-06 | 金华市博益飞科技有限公司 | Insole and preparation method thereof with health-care efficacy |
| CN108894050A (en) * | 2018-05-04 | 2018-11-27 | 河南工程学院 | The preparation method and application of high efficiency filter hollow-fibre membrane non-woven material |
| CN109090765A (en) * | 2018-10-30 | 2018-12-28 | 温州薪然鞋业有限公司 | A kind of deodorizing sole and preparation method thereof |
| CN116695332A (en) * | 2023-08-04 | 2023-09-05 | 常州赛凡寝具科技有限公司 | Preparation method of plant extract modified polyester fiber mat |
Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1250827A (en) * | 1998-10-14 | 2000-04-19 | 河南省科学院化学研究所 | Application of function fibres containing organic amine and imidazoline heterocycle in sanitation and health-care field |
| CN101081110A (en) * | 2006-05-29 | 2007-12-05 | 陈威利 | Wave-energy-massaging biology antibiotic type deodorant polyurethane insole |
| CN101530248A (en) * | 2008-03-11 | 2009-09-16 | 中国人民解放军总后勤部军需装备研究所 | Stacked composite anti-transpierce shoe midsole and method for manufacturing same |
| CN101560733A (en) * | 2008-04-18 | 2009-10-21 | 中国人民解放军总后勤部军需装备研究所 | Fabric and non-weaving cloth composite material and preparation method thereof |
| CN201528727U (en) * | 2009-09-17 | 2010-07-21 | 际华三五一五皮革皮鞋有限公司 | Hemp insole |
| CN101838933A (en) * | 2009-03-20 | 2010-09-22 | 李江陵 | Sleeping-aided fabric and manufacturing method thereof |
| CN204541023U (en) * | 2015-03-19 | 2015-08-12 | 胡莲慧 | A kind of wormwood health insoles |
| CN104997237A (en) * | 2015-08-21 | 2015-10-28 | 梁修剑 | Ultra-thin fragrant insole |
-
2016
- 2016-08-12 CN CN201610660416.5A patent/CN106263263A/en active Pending
Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1250827A (en) * | 1998-10-14 | 2000-04-19 | 河南省科学院化学研究所 | Application of function fibres containing organic amine and imidazoline heterocycle in sanitation and health-care field |
| CN101081110A (en) * | 2006-05-29 | 2007-12-05 | 陈威利 | Wave-energy-massaging biology antibiotic type deodorant polyurethane insole |
| CN101530248A (en) * | 2008-03-11 | 2009-09-16 | 中国人民解放军总后勤部军需装备研究所 | Stacked composite anti-transpierce shoe midsole and method for manufacturing same |
| CN101560733A (en) * | 2008-04-18 | 2009-10-21 | 中国人民解放军总后勤部军需装备研究所 | Fabric and non-weaving cloth composite material and preparation method thereof |
| CN101838933A (en) * | 2009-03-20 | 2010-09-22 | 李江陵 | Sleeping-aided fabric and manufacturing method thereof |
| CN201528727U (en) * | 2009-09-17 | 2010-07-21 | 际华三五一五皮革皮鞋有限公司 | Hemp insole |
| CN204541023U (en) * | 2015-03-19 | 2015-08-12 | 胡莲慧 | A kind of wormwood health insoles |
| CN104997237A (en) * | 2015-08-21 | 2015-10-28 | 梁修剑 | Ultra-thin fragrant insole |
Non-Patent Citations (1)
| Title |
|---|
| 张云: "熏衣草精油的提取、分离、抗氧化性及微胶囊化研究", 《中国优秀硕士学位论文 工程科技 I辑》 * |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107326660A (en) * | 2017-06-26 | 2017-11-07 | 苏州威尔德工贸有限公司 | A kind of preparation method of anti-bacterial textile finishing agent |
| CN108741408A (en) * | 2018-04-19 | 2018-11-06 | 金华市博益飞科技有限公司 | Insole and preparation method thereof with health-care efficacy |
| CN108894050A (en) * | 2018-05-04 | 2018-11-27 | 河南工程学院 | The preparation method and application of high efficiency filter hollow-fibre membrane non-woven material |
| CN109090765A (en) * | 2018-10-30 | 2018-12-28 | 温州薪然鞋业有限公司 | A kind of deodorizing sole and preparation method thereof |
| CN116695332A (en) * | 2023-08-04 | 2023-09-05 | 常州赛凡寝具科技有限公司 | Preparation method of plant extract modified polyester fiber mat |
| CN116695332B (en) * | 2023-08-04 | 2023-10-13 | 常州赛凡寝具科技有限公司 | Preparation method of plant extract modified polyester fiber mat |
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Application publication date: 20170104 |