CN106262665A - A kind of direct employing film processes the method for equivalent dialysis - Google Patents
A kind of direct employing film processes the method for equivalent dialysis Download PDFInfo
- Publication number
- CN106262665A CN106262665A CN201610662083.XA CN201610662083A CN106262665A CN 106262665 A CN106262665 A CN 106262665A CN 201610662083 A CN201610662083 A CN 201610662083A CN 106262665 A CN106262665 A CN 106262665A
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- Prior art keywords
- film
- filtrate
- dialysis
- clear liquid
- processes
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- 238000000034 method Methods 0.000 title claims abstract description 59
- 238000000502 dialysis Methods 0.000 title claims abstract description 16
- 239000000706 filtrate Substances 0.000 claims abstract description 65
- 239000007788 liquid Substances 0.000 claims abstract description 51
- WBZFUFAFFUEMEI-UHFFFAOYSA-M Acesulfame k Chemical compound [K+].CC1=CC(=O)[N-]S(=O)(=O)O1 WBZFUFAFFUEMEI-UHFFFAOYSA-M 0.000 claims abstract description 39
- 229960004998 acesulfame potassium Drugs 0.000 claims abstract description 39
- 235000010358 acesulfame potassium Nutrition 0.000 claims abstract description 39
- 239000000619 acesulfame-K Substances 0.000 claims abstract description 39
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 34
- 239000011550 stock solution Substances 0.000 claims abstract description 24
- 239000012528 membrane Substances 0.000 claims abstract description 17
- 239000010808 liquid waste Substances 0.000 claims abstract description 16
- 230000004907 flux Effects 0.000 claims abstract description 8
- 239000000047 product Substances 0.000 abstract description 8
- 239000000463 material Substances 0.000 abstract description 4
- 150000003839 salts Chemical class 0.000 abstract description 4
- 230000008719 thickening Effects 0.000 abstract 1
- 230000000694 effects Effects 0.000 description 5
- 238000005516 engineering process Methods 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 3
- 238000005265 energy consumption Methods 0.000 description 2
- 235000013305 food Nutrition 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- 239000002253 acid Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 235000013373 food additive Nutrition 0.000 description 1
- 239000002778 food additive Substances 0.000 description 1
- 235000003599 food sweetener Nutrition 0.000 description 1
- 230000004060 metabolic process Effects 0.000 description 1
- 230000000149 penetrating effect Effects 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 235000019605 sweet taste sensations Nutrition 0.000 description 1
- 239000003765 sweetening agent Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D61/00—Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
- B01D61/58—Multistep processes
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23V—INDEXING SCHEME RELATING TO FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES AND LACTIC OR PROPIONIC ACID BACTERIA USED IN FOODSTUFFS OR FOOD PREPARATION
- A23V2002/00—Food compositions, function of food ingredients or processes for food or foodstuffs
Landscapes
- Engineering & Computer Science (AREA)
- Water Supply & Treatment (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Separation Using Semi-Permeable Membranes (AREA)
Abstract
The invention discloses a kind of method that direct employing film processes equivalent dialysis, comprise the following steps: S1: the filtrate of acesulfame potassium is stored in filtrate tanks, is stock solution；S2: use hot water cyclesystem, make filtrate tanks stock solution heat up, arranges into film simultaneously and goes out film pressure, and through organic membrane through concentrating, film clear liquid flows to clear liquid storage tank and recycles；S3: when the film clear liquid flux in film clear liquid storage tank drops to 20～60L/PM, dialyses with the water of isodose, is given by acesulfame potassium and recycle；S4: in circulating tank, remaining residual liquid is directly discharged to liquid waste processing center and carries out liquid waste processing；S5: film device is carried out and detects.The present invention uses hot water cyclesystem to heat, and saves concentration removal process, energy efficient, thickening temperature is low, and material is not easily decomposed, it is achieved liquid decoloration and the processing intent of organic salt, products obtained therefrom can directly recycle, and equipment is simple, and processing cost is low.
Description
Technical field
The present invention relates to chemical technology field, particularly relate to a kind of method that direct employing film processes equivalent dialysis.
Background technology
Acesulfame potassium is a kind of food additive, has the function increasing food sweet taste, in good taste, empty calory, and at human body
Inside not metabolism, do not absorb, good to heat and absolute acid stability, it is forth generation synthetic sweetener on our times.The production work of acesulfame potassium
Skill is simple, and cheap, superior performance, it is considered to be one of the most promising sweeting agent, is widely used in various food
In production.Along with the increase of acesulfame potassium usage amount, the intractability of its filtrate is consequently increased.At present, both at home and abroad to acesulfame potassium
Processing of filtrate mainly uses two traditional effect concentration method and MVR enrichment facility new techniques.And two traditional effects are dense
Contracting processing method needs to carry out being concentrated to by filtrate crystallization, then processes through the mode of decrease temperature crystalline and separation, profit
Reclaiming acesulfame potassium by the method, steam consumption is big, and in the acesulfame potassium of recovery, impurity content is high, often needs to carry out at secondary refining
Reason.Two effect concentration methods often evaporate 1 ton of water, take around consumption steam about 0.8 ton, and energy resource consumption is relatively big, Er Qienong
During contracting temperature required higher, easily cause material decompose.And MVR enrichment facility new technique is a kind of emerging technology, this technology pair
The high treating effect of acesulfame potassium filtrate, but in this technology, the device of application is expensive, and then make being processed into of acesulfame potassium filtrate
Originally dramatically increase.
Summary of the invention
The invention aims to solve shortcoming present in prior art, and a kind of directly employing film proposed processes
The method of equivalent dialysis.
A kind of direct employing film processes the method for equivalent dialysis, comprises the following steps:
S1: the filtrate of acesulfame potassium is stored in filtrate tanks, is stock solution；
S2: the temperature presetting filtrate tanks is 20～50 DEG C, opens the hot water cyclesystem outside filtrate tanks, makes filtrate store up
The temperature of tank stock solution rises to preset temperature, and arrange entering film and going out film pressure in film device is 15～30kg simultaneously, treats stock solution temperature
Degree opens the outlet valve of filtrate tanks and the imported valve of film device after reaching preset temperature, makes stock solution enter film device,
Being carried out through concentrating by the membranous system in film device, the passing through of organic membrane in membranous system, film clear liquid flows to clear liquid storage tank again
Recycle；
S3: when the film clear liquid flux in film clear liquid storage tank drops to 20～60L/PM, to the circulating tank filling film dope
The water of interior addition isodose is dialysed, and acesulfame potassium is dialyzed out and flows to collecting tank and recycles；
S4: in circulating tank, remaining residual liquid is directly discharged to liquid waste processing center and carries out liquid waste processing；
S5: be carried out film device and detect, i.e. completes whole acesulfame potassium filtrate and processes operation after having detected.
Preferably, the hot water circulation heated that the hot water cyclesystem in described S2 step uses temperature to be 60～90 DEG C.
Preferably, the organic membrane that the organic membrane in described S2 step uses molecular weight to be 800～1200.
Preferably, the organic membrane in described S2 step uses molecular weight to be the organic membrane of 1000.
Preferably, in described S2 step, the temperature of filtrate tanks is 25～40 DEG C.
Preferably, entering film in described S2 step and going out film pressure is 20～25kg.
The method that the present invention proposes, uses the hot water cyclesystem of 60～90 DEG C to heat acesulfame potassium filtrate, with regard to energy
Meet the production needs that acesulfame potassium filtrate processes, save concentration removal process, save substantial amounts of steam energy consumption, and concentrate
Temperature is relatively low, and material is not easily decomposed, and selects organic membrane to process, and under high pressure acesulfame potassium can be gone out by film surface penetration, and
Organic impurities and pigment can be rejected by, and reach the feature of penetrating fluid free from admixture and pigment, it is achieved liquid decoloration and organic salt
Processing intent, makes finished product color transparent, and organic salt clearance is high, and the film clear liquid of gained and acesulfame potassium all can directly reclaim
Utilizing, and the equipment used in the method processing procedure is simple, general, processing cost is relatively low.
Detailed description of the invention
Below in conjunction with specific embodiment, the present invention is explained orally further.
Embodiment one
A kind of direct employing film that the present invention proposes processes the method for equivalent dialysis, comprises the following steps:
S1: the filtrate of acesulfame potassium is stored in filtrate tanks, is stock solution；
S2: the temperature presetting filtrate tanks is 38 DEG C, opens the hot water cyclesystem outside filtrate tanks, makes filtrate tanks former
The temperature of liquid rises to preset temperature, and the film pressure of entering simultaneously arranged in film device is 23.5kg, and going out film pressure is 23kg, treats stock solution
Temperature opens the outlet valve of filtrate tanks and the imported valve of film device after reaching preset temperature, make stock solution enter film and set
Standby, then carry out, through concentrating, passing through through the organic membrane that membranous system middle-molecular-weihydroxyethyl is 1000 by the membranous system in film device,
Film clear liquid flows to clear liquid storage tank and recycles；
S3: when the film clear liquid flux in film clear liquid storage tank drops to 30L/PM, add in the circulating tank filling film dope
The water entering isodose is dialysed, and acesulfame potassium is dialyzed out and flows to collecting tank and recycles；
S4: in circulating tank, remaining residual liquid is directly discharged to liquid waste processing center and carries out liquid waste processing；
S5: be carried out film device and detect, i.e. completes whole acesulfame potassium filtrate and processes operation after having detected.
In the present invention, the hot water circulation heated that the hot water cyclesystem in S2 step uses temperature to be 70 DEG C.
Embodiment two
A kind of direct employing film that the present invention proposes processes the method for equivalent dialysis, comprises the following steps:
S1: the filtrate of acesulfame potassium is stored in filtrate tanks, is stock solution；
S2: the temperature presetting filtrate tanks is 37 DEG C, opens the hot water cyclesystem outside filtrate tanks, makes filtrate tanks former
The temperature of liquid rises to preset temperature, arranges entering film and going out film pressure and be 24kg in film device simultaneously, treats that stock solution temperature reaches
Open the outlet valve of filtrate tanks and the imported valve of film device after preset temperature, make stock solution enter film device, then pass through
Membranous system in film device carries out, through concentrating, passing through through the organic membrane that membranous system middle-molecular-weihydroxyethyl is 800, and film clear liquid flows to
Clear liquid storage tank recycles；
S3: when the film clear liquid flux in film clear liquid storage tank drops to 45L/PM, add in the circulating tank filling film dope
The water entering isodose is dialysed, and acesulfame potassium is dialyzed out and flows to collecting tank and recycles；
S4: in circulating tank, remaining residual liquid is directly discharged to liquid waste processing center and carries out liquid waste processing；
S5: be carried out film device and detect, i.e. completes whole acesulfame potassium filtrate and processes operation after having detected.
In the present invention, the hot water circulation heated that the hot water cyclesystem in S2 step uses temperature to be 60 DEG C.
Embodiment three
A kind of direct employing film that the present invention proposes processes the method for equivalent dialysis, comprises the following steps:
S1: the filtrate of acesulfame potassium is stored in filtrate tanks, is stock solution；
S2: the temperature presetting filtrate tanks is 32 DEG C, opens the hot water cyclesystem outside filtrate tanks, makes filtrate tanks former
The temperature of liquid rises to preset temperature, arranges entering film and going out film pressure and be 23.5kg in film device simultaneously, treats that stock solution temperature reaches
After preset temperature, open the outlet valve of filtrate tanks and the imported valve of film device, make stock solution enter film device, then lead to
Cross the membranous system in film device to carry out, through concentrating, passing through through the organic membrane that membranous system middle-molecular-weihydroxyethyl is 1200, film clear liquid
Flow to clear liquid storage tank recycle；
S3: when the film clear liquid flux in film clear liquid storage tank drops to 50L/PM, add in the circulating tank filling film dope
The water entering isodose is dialysed, and acesulfame potassium is dialyzed out and flows to collecting tank and recycles；
S4: in circulating tank, remaining residual liquid is directly discharged to liquid waste processing center and carries out liquid waste processing；
S5: be carried out film device and detect, i.e. completes whole acesulfame potassium filtrate and processes operation after having detected.
In the present invention, the hot water circulation heated that the hot water cyclesystem in S2 step uses temperature to be 90 DEG C.
Embodiment four
S1: the filtrate of acesulfame potassium is stored in filtrate tanks, is stock solution；
S2: the temperature presetting filtrate tanks is 40 DEG C, opens the hot water cyclesystem outside filtrate tanks, makes filtrate tanks former
The temperature of liquid rises to preset temperature, arranges entering film and going out film pressure and be 23.5kg in film device simultaneously, treats that stock solution temperature reaches
After preset temperature, open the outlet valve of filtrate tanks and the imported valve of film device, make stock solution enter film device, then lead to
Cross the membranous system in film device to carry out, through concentrating, passing through through the organic membrane that membranous system middle-molecular-weihydroxyethyl is 1000, film clear liquid
Flow to clear liquid storage tank recycle；
S3: when the film clear liquid flux in film clear liquid storage tank drops to 35L/PM, add in the circulating tank filling film dope
The water entering isodose is dialysed, and acesulfame potassium is dialyzed out and flows to collecting tank and recycles；
S4: in circulating tank, remaining residual liquid is directly discharged to liquid waste processing center and carries out liquid waste processing；
S5: be carried out film device and detect, i.e. completes whole acesulfame potassium filtrate and processes operation after having detected.
In the present invention, the hot water circulation heated that the hot water cyclesystem in S2 step uses temperature to be 80 DEG C.
Embodiment five
S1: the filtrate of acesulfame potassium is stored in filtrate tanks, is stock solution；
S2: the temperature presetting filtrate tanks is 34 DEG C, opens the hot water cyclesystem outside filtrate tanks, makes filtrate tanks former
The temperature of liquid rises to preset temperature, arranges entering film and going out film pressure and be 24kg in film device simultaneously, treats that stock solution temperature reaches
Open the outlet valve of filtrate tanks and the imported valve of film device after preset temperature, make stock solution enter film device, then pass through
Membranous system in film device carries out, through concentrating, passing through through the organic membrane that membranous system middle-molecular-weihydroxyethyl is 1000, film clear liquid stream
Recycle to clear liquid storage tank；
S3: when the film clear liquid flux in film clear liquid storage tank drops to 35L/PM, add in the circulating tank filling film dope
The water entering isodose is dialysed, and acesulfame potassium is dialyzed out and flows to collecting tank and recycles；
S4: in circulating tank, remaining residual liquid is directly discharged to liquid waste processing center and carries out liquid waste processing；
S5: be carried out film device and detect, i.e. completes whole acesulfame potassium filtrate and processes operation after having detected.
In the present invention, the hot water circulation heated that the hot water cyclesystem in S2 step uses temperature to be 80 DEG C.
Take the acesulfame potassium filtrate of same batch to be respectively adopted the method for above-described embodiment one～five and carry out filtrate process, and to filter
The processing procedure of liquid and parameter carry out itemized record, and record result is as follows:
The record of embodiment one:
The final products obtained therefrom color of embodiment one is transparent.
The record of embodiment two:
The final products obtained therefrom color of embodiment two is transparent.
The record of embodiment three:
The final products obtained therefrom color of embodiment three is transparent.
The record of embodiment four:
The final products obtained therefrom color of embodiment four is transparent.
The record of embodiment five:
The final products obtained therefrom color of embodiment five is transparent.
Showing according to above-mentioned process record, the film that the present invention proposes processes the method for equivalent dialysis and processes acesulfame potassium filtrate
High treating effect, can meet the demand for heat of acesulfame potassium filtrate under conditions of the hot water circulation heated of 60～90 DEG C, save
Concentration removal process, saves substantial amounts of steam energy consumption, and material is not easily decomposed, the product face after embodiment one～five process
Color is the most transparent, and the clearance of organic salt is high, and the film clear liquid of gained and acesulfame potassium all can directly recycle.
The above, the only present invention preferably detailed description of the invention, but protection scope of the present invention is not limited thereto,
Any those familiar with the art in the technical scope that the invention discloses, according to technical scheme and
Inventive concept equivalent or change in addition, all should contain within protection scope of the present invention.
Claims (6)
1. the method that a direct employing film processes equivalent dialysis, it is characterised in that comprise the following steps:
S1: the filtrate of acesulfame potassium is stored in filtrate tanks, is stock solution；
S2: the temperature presetting filtrate tanks is 20～50 DEG C, opens the hot water cyclesystem outside filtrate tanks, makes filtrate tanks former
The temperature of liquid rises to preset temperature, and arrange entering film and going out film pressure in film device is 15～30kg simultaneously, treats that stock solution temperature reaches
After preset temperature, open the outlet valve of filtrate tanks and the imported valve of film device, make stock solution enter film device, then lead to
Crossing the membranous system in film device to carry out through concentrating, the passing through of organic membrane in membranous system, film clear liquid flows to clear liquid storage tank to be carried out
Recycle；
S3: when the film clear liquid flux in film clear liquid storage tank drops to 20～60L/PM, add in the circulating tank filling film dope
The water entering isodose is dialysed, and acesulfame potassium is dialyzed out and flows to collecting tank and recycles；
S4: in circulating tank, remaining residual liquid is directly discharged to liquid waste processing center and carries out liquid waste processing；
S5: be carried out film device and detect, i.e. completes whole acesulfame potassium filtrate and processes operation after having detected.
A kind of direct employing film the most according to claim 1 processes the method for equivalent dialysis, it is characterised in that described S2 walks
The hot water circulation heated that hot water cyclesystem in Zhou uses temperature to be 60～90 DEG C.
A kind of direct employing film the most according to claim 1 processes the method for equivalent dialysis, it is characterised in that described S2 walks
The organic membrane that organic membrane in Zhou uses molecular weight to be 800～1200.
A kind of direct employing film the most according to claim 1 processes the method for equivalent dialysis, it is characterised in that described S2 walks
Organic membrane in Zhou uses molecular weight to be the organic membrane of 1000.
A kind of direct employing film the most according to claim 1 processes the method for equivalent dialysis, it is characterised in that described S2 walks
In rapid, the temperature of filtrate tanks is 25～40 DEG C.
A kind of direct employing film the most according to claim 1 processes the method for equivalent dialysis, it is characterised in that described S2 walks
Entering film in Zhou and going out film pressure is 20～25kg.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610662083.XA CN106262665A (en) | 2016-08-12 | 2016-08-12 | A kind of direct employing film processes the method for equivalent dialysis |
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| CN201610662083.XA CN106262665A (en) | 2016-08-12 | 2016-08-12 | A kind of direct employing film processes the method for equivalent dialysis |
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Cited By (5)
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|---|---|---|---|---|
| US10023546B2 (en) | 2016-09-21 | 2018-07-17 | Celanese International Corporation | Acesulfame potassium compositions and processes for producing same |
| US10030000B2 (en) | 2016-09-21 | 2018-07-24 | Celanese International Corporation | Acesulfame potassium compositions and processes for producing same |
| US10029998B2 (en) | 2016-09-21 | 2018-07-24 | Celanese International Corporation | Acesulfame potassium compositions and processes for producing same |
| US10029999B2 (en) | 2016-09-21 | 2018-07-24 | Celanese International Corporation | Acesulfame potassium compositions and processes for producing same |
| USRE48464E1 (en) | 2012-06-08 | 2021-03-16 | Celanese Sales Germany Gmbh | Process for producing acesulfame potassium |
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|---|---|---|---|---|
| USRE48464E1 (en) | 2012-06-08 | 2021-03-16 | Celanese Sales Germany Gmbh | Process for producing acesulfame potassium |
| US10759771B2 (en) | 2016-09-21 | 2020-09-01 | Celanese International Corporation | Acesulfame potassium compositions and processes for producing same |
| US11724994B2 (en) | 2016-09-21 | 2023-08-15 | Celanese International Corporation | Acesulfame potassium compositions and processes for producing same |
| US10029999B2 (en) | 2016-09-21 | 2018-07-24 | Celanese International Corporation | Acesulfame potassium compositions and processes for producing same |
| US10208004B2 (en) | 2016-09-21 | 2019-02-19 | Celanese International Corporation | Acesulfame potassium compositions and processes for producing same |
| US10227316B2 (en) | 2016-09-21 | 2019-03-12 | Celanese International Corporation | Acesulfame potassium compositions and processes for producing same |
| US10233163B2 (en) | 2016-09-21 | 2019-03-19 | Celanese International Corporation | Acesulfame potassium compositions and processes for producing same |
| US10233164B2 (en) | 2016-09-21 | 2019-03-19 | Celanese International Corporation | Acesulfame potassium compositions and processes for producing same |
| US10590096B2 (en) | 2016-09-21 | 2020-03-17 | Celenese International Corporation | Acesulfame potassium compositions and processes for producing same |
| US10590098B2 (en) | 2016-09-21 | 2020-03-17 | Celanese International Corporation | Acesulfame potassium compositions and processes for producing same |
| US10590097B2 (en) | 2016-09-21 | 2020-03-17 | Celanese International Corporation | Acesulfame potassium compositions and processes for producing same |
| US11731948B2 (en) | 2016-09-21 | 2023-08-22 | Celanese International Corporation | Acesulfame potassium compositions and processes for producing same |
| US10029998B2 (en) | 2016-09-21 | 2018-07-24 | Celanese International Corporation | Acesulfame potassium compositions and processes for producing same |
| US10781191B2 (en) | 2016-09-21 | 2020-09-22 | Celanese International Corporation | Acesulfame potassium compositions and processes for producing same |
| US10781190B2 (en) | 2016-09-21 | 2020-09-22 | Celanese International Corporation | Acesulfame potassium compositions and processes for producing same |
| US10759770B2 (en) | 2016-09-21 | 2020-09-01 | Celanese International Corporation | Acesulfame potassium compositions and processes for producing same |
| US10030000B2 (en) | 2016-09-21 | 2018-07-24 | Celanese International Corporation | Acesulfame potassium compositions and processes for producing same |
| US10954203B2 (en) | 2016-09-21 | 2021-03-23 | Celanese International Corporation | Acesulfame potassium compositions and processes for producing same |
| US10954204B2 (en) | 2016-09-21 | 2021-03-23 | Celanese International Corporation | Acesulfame potassium compositions and processes for producing same |
| US10961207B2 (en) | 2016-09-21 | 2021-03-30 | Celanese International Corporation | Acesulfame potassium compositions and processes for producing same |
| US10975047B2 (en) | 2016-09-21 | 2021-04-13 | Celanese International Corporation | Acesulfame potassium compositions and processes for producing same |
| US11718594B2 (en) | 2016-09-21 | 2023-08-08 | Celanese International Corporation | Acesulfame potassium compositions and processes for producing same |
| US10023546B2 (en) | 2016-09-21 | 2018-07-17 | Celanese International Corporation | Acesulfame potassium compositions and processes for producing same |
| US11724993B2 (en) | 2016-09-21 | 2023-08-15 | Celanese International Corporation | Acesulfame potassium compositions and processes for producing same |
| US10590095B2 (en) | 2016-09-21 | 2020-03-17 | Celanese International Corporation | Acesulfame potassium compositions and processes for producing same |
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Application publication date: 20170104 |