CN106245326B - 一种粘胶短纤维纺纱用油剂 - Google Patents

一种粘胶短纤维纺纱用油剂 Download PDF

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CN106245326B
CN106245326B CN201610679368.4A CN201610679368A CN106245326B CN 106245326 B CN106245326 B CN 106245326B CN 201610679368 A CN201610679368 A CN 201610679368A CN 106245326 B CN106245326 B CN 106245326B
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张林雅
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Tangshan Sanyou Group Xingda Chemical Fiber Co., Ltd.
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Hebei University of Science and Technology
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    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
    • D06M13/282—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing phosphorus
    • D06M13/292—Mono-, di- or triesters of phosphoric or phosphorous acids; Salts thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/02—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with hydrocarbons
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    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
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    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/224—Esters of carboxylic acids; Esters of carbonic acid
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    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/224—Esters of carboxylic acids; Esters of carbonic acid
    • D06M13/2246—Esters of unsaturated carboxylic acids
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    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
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    • D06M2101/02—Natural fibres, other than mineral fibres
    • D06M2101/04—Vegetal fibres
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    • D06M2200/40—Reduced friction resistance, lubricant properties; Sizing compositions
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
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    • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/50—Modified hand or grip properties; Softening compositions

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  • Textile Engineering (AREA)
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Abstract

本发明涉及一种粘胶短纤维纺纱用油剂，由下述重量份的组物复配组成：F18～35份，S 65～82份；所述组物F由油酸聚氧乙烯酯、十四醇油酸脂、脂肪酸聚氧乙烯醚、液体石蜡和乙醇组成，所述组物S由脂肪醇醚磷酸酯钾盐、蓖麻油聚氧乙烯醚、失水山梨醇脂肪酸酯、聚氧乙烯失水山梨醇脂肪酸酯和水组分组成，本发明提供的粘胶短纤维纺纱用油剂，可有效调整纤维纺纱加工中的动静摩擦系数，改善纤维的摩擦性能，提高纤维之间的抱合力，赋予纤维良好的平滑性和柔软性，消除或减少丝束松散、起毛、断裂、静电等不良现象，满足纺纱加工的生产所需。

Description

一种粘胶短纤维纺纱用油剂
技术领域
本发明属于化工技术领域，具体涉及一种粘胶短纤维纺纱用油剂。
背景技术
粘胶纤维是一种取自植物的天然纤维，因其服用的舒适性和原料的环保性，应用日渐广泛，粘胶纤维生产也在日新月异快速发展。粘胶纤维在使用中，摩擦系数是一项重要的性能指标，摩擦系数的大小，对纤维的后续加工有影响较大，会直接影响到纤维的抱合力、静电性等性能。
在粘胶纤维的生产过程中，油剂的应用必不可少，主要作用于调整纤维的摩擦系数，在纺织加工过程中，提供给纤维适宜的抱合性和抗静电性。纤维的抱合力,可保证半制品如纤维卷、纤维条、粗纱以及纱线等具有一定的强力，是织物保持良好尺寸稳定性的必要条件。静电性能如控制不当，则会造成纤维缠绕针布、缠罗拉、断头率增加等一系列问题，严重影响加工过程的顺利进行。油剂对生产稳定性、产品质量起着至关重要的作用。
油剂配方可由多种组分组成，主要有平滑剂、抗静电剂、乳化剂以及其它少量助剂。通过不同组分的协同作用，调节纤维的摩擦性，防止或消除静电积聚，赋予纤维平滑、柔软等特性，使纤维顺利通过纺纱、织造等工序，提高纤维的可纺性，同时改善制成品的手感、起毛起球、耐磨等服用性能。
目前国内粘胶纤维生产厂家仍以国外进口油剂居多，应用成本高，技术约束性强，极大制约了国内外粘胶纤维工业的发展。粘胶短纤维纺纱用油剂的自主研发有利于克服约束，降低成本，提高粘胶纤维的应用性能，推动粘胶纤维产品的升级换代。
发明内容
本发明的目的是提供一种粘胶短纤维纺纱用油剂，可有效改善粘胶短纤维纺纱的平滑性和抱合性，调整纤维加工中的动静摩擦系数，保证在有效范围内降低动摩擦系数、提高静摩擦系数，消除加工过程中丝束松散、起毛、断裂、静电等不良现象，保证生产过程和产品质量的稳定性。
本发明提供的粘胶短纤维纺纱用油剂，由组物F和组物S复配组成，其中组物F由非离子型平滑剂、乳化剂、消泡剂等组成，主要用于赋予纤维良好的平滑性和柔软性，纤维经过平滑剂后，使摩擦发生在相互滑动的憎水基之间，获得柔软效果，提高纤维的可纺性；组物S由阴离子型抗静电剂和非离子型乳化剂等组成，通过提高摩擦体间隙中介质的介电常数，降低纤维表面的电阻，以利于电荷的导出，达到消除静电的目的，主要用于提高纤维之间的抱合力。
本发明采用以下技术方案予以实现：
一种粘胶短纤维纺纱用油剂，由下述重量份的组物复配组成为：
F 18～35份，S 65～82份；
所述组物F由下述重量份的组分组成为：
所述组物S由下述重量份的组分组成为：
优选的，所述组物F由下述重量份的组分组成为：
进一步优选的，所述组物F由下述重量份的组分组成：
优选的，所述组物S由下述重量份的组分组成为：
进一步优选的，所述组物S由下述重量份的组分组成为：
最佳方案为：一种粘胶短纤维纺纱用油剂，由下述重量份的组物复配组成：F 28份，S 72份。
其中组物F由下述重量份的组分组成：
其中组物S由下述重量份的组分组成：
本发明与现有技术相比具有的显著效果为：
本发明中的粘胶短纤维纺纱用油剂生产成本低，配制过程简单，以水为溶剂，绿色环保。应用于粘胶纤维生产中，可有效克服纤维在加工过程中摩擦产生的影响，提高纤维之间的抱合力，赋予纤维良好的平滑性和柔软性，消除或减少丝束松散、起毛、断裂、静电等不良现象，满足后加工的生产所需，达到稳定的生产过程和产品质量。
具体实施方式
下面结合实施例对本发明作进一步的说明。
实施例一：
一种粘胶短纤维纺纱用油剂，由下述重量份的组物复配组成：F 18份，S 82份。
其中组物F由下述重量份的组分组成：
其中组物S由下述重量份的组分组成：
实施例二：
一种粘胶短纤维纺纱用油剂，由下述重量份的组物复配组成：F 25份，S 75份。
其中组物F由下述重量份的组分组成：
其中组物S由下述重量份的组分组成：
实施例三：
一种粘胶短纤维纺纱用油剂，由下述重量份的组物复配组成：F 30份，S 70份。
其中组物F由下述重量份的组分组成：
其中组物S由下述重量份的组分组成：
实施例四：
一种粘胶短纤维纺纱用油剂，由下述重量份的组物复配组成：F 35份，S 65份。
其中组物F由下述重量份的组分组成：
其中组物S由下述重量份的组分组成：
实施例五：
一种粘胶短纤维纺纱用油剂，由下述重量份的油剂复配组成：F 28份，S 72份。
其中油剂F由下述重量份的组分组成：
其中组物S由下述重量份的组分组成：
以上述实施例所生产的粘胶短纤维纺纱用油剂，依照生产浓度对纤维进行上油，测试指标如下：
以上述实施例所生产的上油后粘胶短纤维成品，依照成纱生产工序进行清花→梳棉→并条→粗纱→细纱流程，测试成纱指标如下：
根据以上指标，本发明的粘胶短纤维纺纱用油剂，应用后纤维比电阻值低，可有效调整动静摩擦系数，满足纤维生产所需的平滑性和抱合性。上油后的粘胶短纤维用于纺纱，条干均匀度好，具有较低的变异指数和较少的常发性纱疵个数，毛羽指数小，捻度及断裂强度均达到了加工要求。

Claims (6)

1.一种粘胶短纤维纺纱用油剂，其特征是由下述重量份的组物复配组成：
F 18～35份，S 65～82份；
所述组物F由下述重量份的组分组成：
所述组物S由下述重量份的组分组成：
2.如权利要求1所述的一种粘胶短纤维纺纱用油剂，其特征是，所述组物F由下述重量份的组分组成：
3.如权利要求2所述的一种粘胶短纤维纺纱用油剂，其特征是，所述组物F由下述重量份的组分组成：
4.如权利要求1所述的一种粘胶短纤维纺纱用油剂，其特征是，所述组物S由下述重量份的组分组成：
5.如权利要求4所述的一种粘胶短纤维纺纱用油剂，其特征是，所述组物S由下述重量份的组分组成：
6.如权利要求1所述的一种粘胶短纤维纺纱用油剂，其特征是由下述重量份的组物复配组成：F 28份，S 72份；
其中组物F由下述重量份的组分组成：
其中组物S由下述重量份的组分组成：
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CN108611862A (zh) * 2018-05-04 2018-10-02 沈阳浩博实业有限公司 一种连续纺粘胶长丝抗静电高性能油剂
CN108867041A (zh) * 2018-05-18 2018-11-23 浙江皇马科技股份有限公司 一种粘胶短纤油剂及其应用
CN108755141B (zh) * 2018-06-29 2021-03-12 乌鲁木齐市华泰隆化学助剂有限公司 一种粘胶纤维纺丝油剂及其制备方法
CN114351450A (zh) * 2022-01-13 2022-04-15 沈阳浩博实业有限公司 一种半连续纺粘胶长丝用油剂及其制备方法和应用

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