CN106245320A - A kind of acrylate antistatic fibre spreading mass - Google Patents

A kind of acrylate antistatic fibre spreading mass Download PDF

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Publication number
CN106245320A
CN106245320A CN201610614774.2A CN201610614774A CN106245320A CN 106245320 A CN106245320 A CN 106245320A CN 201610614774 A CN201610614774 A CN 201610614774A CN 106245320 A CN106245320 A CN 106245320A
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CN
China
Prior art keywords
acrylate
added
acrylic ester
ester monomer
antistatic fibre
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610614774.2A
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Chinese (zh)
Inventor
曹英杰
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Yixing Detai Textile Co Ltd Slurry
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Yixing Detai Textile Co Ltd Slurry
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Priority to CN201610614774.2A priority Critical patent/CN106245320A/en
Publication of CN106245320A publication Critical patent/CN106245320A/en
Pending legal-status Critical Current

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    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/73—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof
    • D06M11/74—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof with carbon or graphite; with carbides; with graphitic acids or their salts
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F212/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F212/02—Monomers containing only one unsaturated aliphatic radical
    • C08F212/04—Monomers containing only one unsaturated aliphatic radical containing one ring
    • C08F212/06—Hydrocarbons
    • C08F212/08—Styrene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/14—Methyl esters, e.g. methyl (meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/26—Esters containing oxygen in addition to the carboxy oxygen
    • C08F220/28—Esters containing oxygen in addition to the carboxy oxygen containing no aromatic rings in the alcohol moiety
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/42—Nitriles
    • C08F220/44—Acrylonitrile
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/263—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C08F220/1804—C4-(meth)acrylate, e.g. butyl (meth)acrylate, isobutyl (meth)acrylate or tert-butyl (meth)acrylate

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Carbon And Carbon Compounds (AREA)
  • Graft Or Block Polymers (AREA)

Abstract

The present invention relates to a kind of acrylate antistatic fibre spreading mass, by mass percentage, it includes graphene oxide 1 10% and acrylic ester monomer 90 99%, and its preparation method includes prepared by pre-emulsion preparation and acrylate antistatic fibre spreading mass.

Description

A kind of acrylate antistatic fibre spreading mass
Technical field
The present invention relates to a kind of fiber spreading mass, be specifically related to a kind of antistatic fibre spreading mass.
Background technology
Imitative wool product is popular in market, but goods antistatic effect is the key of product quality.At present, imitative sheep The antistatic effect of woolen is general.
Summary of the invention
Goal of the invention: the invention aims to overcome deficiency of the prior art, it is provided that one has good anti-quiet Electricity and the acrylate antistatic fibre spreading mass of electromagnetic protection performance.
Technical scheme: in order to solve above-mentioned technical problem, a kind of acrylate antistatic fibre starching of the present invention Material, by mass percentage, it includes,
Graphene oxide 1-10%；
Acrylic ester monomer 90-99%；
Described acrylic ester monomer include butyl acrylate, 2-Isooctyl acrylate monomer, ethyl acrylate, 2-(Acryloyloxy)ethanol, Methyl methacrylate, styrene, acrylonitrile, hydroxyethyl methylacrylate, Hydroxypropyl methacrylate；
Its preparation method includes,
(1) prepared by pre-emulsion；
(2) prepared by acrylate antistatic fibre spreading mass；
Wherein, step (1) includes,
A, deionized water, emulsifying agent are added in pre-emulsification still and stir；
B, acrylic ester monomer is added in pre-emulsification still, stir 10-60min；
Wherein, step (2) includes,
A, deionized water, emulsifying agent are added in reactor and stirs, open condensation reflux unit, be warming up to 78-80 DEG C；
B, initiator is added in reactor, be warming up to 80-85 DEG C；
C, by esters of acrylic acid pre-emulsion dropping add reactor, react 60-180min；
D, insulation 30-60min.
Antistatic fibre spreading mass pass through graphene oxide modified aqueous acrylic acid ester, described fiber including but not limited to Terylene, polypropylene, spandex, acrylon, cotton etc..
Beneficial effect: compared with prior art, its remarkable advantage is the present invention: the present invention uses the material of graphene oxide Modification acrylate class slurry so that the antistatic property of slurry promotes, and after being coated into thin film, antistatic film surface resistivity can Reach 106Ω, has good antistatic and electromagnetic protection performance so that imitative wool product antistatic effect significantly promotes.
Detailed description of the invention
Below in conjunction with embodiment, the present invention is further illustrated.
Embodiment 1:
A kind of acrylate antistatic fibre spreading mass of the present invention, by mass percentage, it includes,
Graphene oxide 4%；
Acrylic ester monomer 96%；
Described acrylic ester monomer include butyl acrylate, 2-Isooctyl acrylate monomer, ethyl acrylate, 2-(Acryloyloxy)ethanol, Methyl methacrylate, styrene, acrylonitrile, hydroxyethyl methylacrylate, Hydroxypropyl methacrylate；
Its preparation method includes,
(1) prepared by pre-emulsion；
(2) prepared by acrylate antistatic fibre spreading mass；
Wherein, step (1) includes,
A, deionized water, emulsifying agent SC-09 are added in pre-emulsification still and stir；
B, acrylic ester monomer is added in pre-emulsification still, stir 20min；
Wherein, step (2) includes,
A, deionized water, emulsifying agent SC-09 are added in reactor and stirs, open condensation reflux unit, be warming up to 78 DEG C；
B, initiator ammonium persulfate is added in reactor, be warming up to 81 DEG C；
C, by esters of acrylic acid pre-emulsion dropping add reactor, react 80min；
D, insulation 35min.
Embodiment 2:
A kind of acrylate antistatic fibre spreading mass of the present invention, by mass percentage, it includes,
Graphene oxide 6%；
Acrylic ester monomer 94%；
Described acrylic ester monomer include butyl acrylate, 2-Isooctyl acrylate monomer, ethyl acrylate, 2-(Acryloyloxy)ethanol, Methyl methacrylate, styrene, acrylonitrile, hydroxyethyl methylacrylate, Hydroxypropyl methacrylate；
Its preparation method includes,
(1) prepared by pre-emulsion；
(2) prepared by acrylate antistatic fibre spreading mass；
Wherein, step (1) includes,
A, deionized water, emulsifying agent SC-09 are added in pre-emulsification still and stir；
B, acrylic ester monomer is added in pre-emulsification still, stir 40min；
Wherein, step (2) includes,
A, deionized water, emulsifying agent SC-09 are added in reactor and stirs, open condensation reflux unit, be warming up to 79 DEG C；
B, initiator ammonium persulfate is added in reactor, be warming up to 82 DEG C；
C, by esters of acrylic acid pre-emulsion dropping add reactor, react 120min；
D, insulation 45min.
Embodiment 3:
A kind of acrylate antistatic fibre spreading mass of the present invention, by mass percentage, it includes,
Graphene oxide 8%；
Acrylic ester monomer 92%；
Described acrylic ester monomer include butyl acrylate, 2-Isooctyl acrylate monomer, ethyl acrylate, 2-(Acryloyloxy)ethanol, Methyl methacrylate, styrene, acrylonitrile, hydroxyethyl methylacrylate, Hydroxypropyl methacrylate；
Its preparation method includes,
(1) prepared by pre-emulsion；
(2) prepared by acrylate antistatic fibre spreading mass；
Wherein, step (1) includes,
A, deionized water, emulsifying agent SC-09 are added in pre-emulsification still and stir；
B, acrylic ester monomer is added in pre-emulsification still, stir 50min；
Wherein, step (2) includes,
A, deionized water, emulsifying agent SC-09 are added in reactor and stirs, open condensation reflux unit, be warming up to 80 DEG C；
B, initiator ammonium persulfate is added in reactor, be warming up to 84 DEG C；
C, by esters of acrylic acid pre-emulsion dropping add reactor, react 160min；
D, insulation 55min.
The present invention uses the material modification esters of acrylic acid slurry of graphene oxide so that the antistatic property of slurry carries Rising, after being coated into thin film, antistatic film surface resistivity is up to 106Ω, has good antistatic and electromagnetic protection performance, makes Wool product antistatic effect must be imitated significantly promote.
The invention provides a kind of thinking and method, the method and the approach that implement this technical scheme are a lot, above institute State is only the preferred embodiment of the present invention, it is noted that for those skilled in the art, without departing from On the premise of the principle of the invention, it is also possible to make some improvements and modifications, these improvements and modifications also should be regarded as the guarantor of the present invention Protecting scope, each ingredient the clearest and the most definite in the present embodiment all can use prior art to be realized.

Claims (1)

1. an acrylate antistatic fibre spreading mass, it is characterised in that: by mass percentage, it includes,
Graphene oxide 1-10%；
Acrylic ester monomer 90-99%；
Described acrylic ester monomer include butyl acrylate, 2-Isooctyl acrylate monomer, ethyl acrylate, 2-(Acryloyloxy)ethanol, Methyl methacrylate, styrene, acrylonitrile, hydroxyethyl methylacrylate, Hydroxypropyl methacrylate；
Its preparation method includes,
(1) prepared by pre-emulsion；
(2) prepared by acrylate antistatic fibre spreading mass；
Wherein, step (1) includes,
A, deionized water, emulsifying agent are added in pre-emulsification still and stir；
B, acrylic ester monomer is added in pre-emulsification still, stir 10-60min；
Wherein, step (2) includes,
A, deionized water, emulsifying agent are added in reactor and stirs, open condensation reflux unit, be warming up to 78-80 DEG C；
B, initiator is added in reactor, be warming up to 80-85 DEG C；
C, by esters of acrylic acid pre-emulsion dropping add reactor, react 60-180min；
D, insulation 30-60min.
CN201610614774.2A 2016-08-01 2016-08-01 A kind of acrylate antistatic fibre spreading mass Pending CN106245320A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610614774.2A CN106245320A (en) 2016-08-01 2016-08-01 A kind of acrylate antistatic fibre spreading mass

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610614774.2A CN106245320A (en) 2016-08-01 2016-08-01 A kind of acrylate antistatic fibre spreading mass

Publications (1)

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CN106245320A true CN106245320A (en) 2016-12-21

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109135144A (en) * 2018-07-11 2019-01-04 四川羽玺新材料股份有限公司 A kind of graphene/acrylic resin laminated film and preparation method thereof

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2007204333A (en) * 2006-02-03 2007-08-16 Showa Highpolymer Co Ltd Emulsion for cement mortar and cement mortar composition blended therewith
CN101768895A (en) * 2009-01-07 2010-07-07 湖北大学 Styrene-acrylate emulsion type high effective surface sizing agent and preparation method thereof
CN101974851A (en) * 2010-11-12 2011-02-16 吴江福华织造有限公司 Environmental protection pulp for fine denier filament pulp yarn
CN102603958A (en) * 2012-01-13 2012-07-25 陕西科技大学 Preparation method of acrylic resin/graphene oxide nanometer composite leather finishing agent
CN104005234A (en) * 2014-06-10 2014-08-27 中国科学院山西煤炭化学研究所 Emulsion type carbon fiber sizing agent containing nano material and preparation method of sizing agent
CN105567050A (en) * 2016-03-08 2016-05-11 武汉理工大学 Preparation method for graphene oxide modified polyurea acrylate emulsion

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2007204333A (en) * 2006-02-03 2007-08-16 Showa Highpolymer Co Ltd Emulsion for cement mortar and cement mortar composition blended therewith
CN101768895A (en) * 2009-01-07 2010-07-07 湖北大学 Styrene-acrylate emulsion type high effective surface sizing agent and preparation method thereof
CN101974851A (en) * 2010-11-12 2011-02-16 吴江福华织造有限公司 Environmental protection pulp for fine denier filament pulp yarn
CN102603958A (en) * 2012-01-13 2012-07-25 陕西科技大学 Preparation method of acrylic resin/graphene oxide nanometer composite leather finishing agent
CN104005234A (en) * 2014-06-10 2014-08-27 中国科学院山西煤炭化学研究所 Emulsion type carbon fiber sizing agent containing nano material and preparation method of sizing agent
CN105567050A (en) * 2016-03-08 2016-05-11 武汉理工大学 Preparation method for graphene oxide modified polyurea acrylate emulsion

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109135144A (en) * 2018-07-11 2019-01-04 四川羽玺新材料股份有限公司 A kind of graphene/acrylic resin laminated film and preparation method thereof
CN109135144B (en) * 2018-07-11 2021-07-20 四川羽玺新材料股份有限公司 Graphene/acrylic resin composite film and preparation method thereof

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