CN106244064A - A kind of wrapping paper adhesive and preparation method thereof - Google Patents
A kind of wrapping paper adhesive and preparation method thereof Download PDFInfo
- Publication number
- CN106244064A CN106244064A CN201610741437.XA CN201610741437A CN106244064A CN 106244064 A CN106244064 A CN 106244064A CN 201610741437 A CN201610741437 A CN 201610741437A CN 106244064 A CN106244064 A CN 106244064A
- Authority
- CN
- China
- Prior art keywords
- parts
- wrapping paper
- resin
- phenol
- paper adhesive
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J161/00—Adhesives based on condensation polymers of aldehydes or ketones; Adhesives based on derivatives of such polymers
- C09J161/04—Condensation polymers of aldehydes or ketones with phenols only
- C09J161/06—Condensation polymers of aldehydes or ketones with phenols only of aldehydes with phenols
- C09J161/14—Modified phenol-aldehyde condensates
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Abstract
The invention discloses a kind of wrapping paper adhesive and preparation method thereof, it forms according to the parts by weight of following raw material: starch 2 10 parts, cellulose 35 parts, nylon 4 15 parts, acrylic resin 5 10 parts, phenol-formaldehyde resin modified 10 20 parts, 13 parts of benzidine, ditridecyl phthalate 25 parts, 15 parts of potter's clay, carboxy terminated nitrile rubber 2 10 parts, silane coupler 13 parts, phosphorous vinegar 13 parts, aqueous tackifier resin 13 parts, remaining is 50 100 parts of water.The wrapping paper adhesive cementability of the present invention is good, uses multiple thermoplastic composition workable.
Description
Technical field
The present invention relates to a kind of wrapping paper adhesive and preparation method thereof.
Background technology
Along with the economic development of China, material flow industry have also been obtained quickly development.Owing to needing the article of circulation more to come
The most, the demand for packaging carton is the most increasing.Therefore, the demand for the adhesive used by wrapping paper material is also got over
Come the biggest.
Some multi-functional wrapping paper adhesives also arise at the historic moment, and are currently used for carton adhesive kind a lot, have three
Aldehyde glue and white glue with vinyl etc..Some adhesive are producing and can discharge free state formaldehyde in application process, endanger human body and environment
Evil is serious；Some adhesive, resistance to water and moisture-proof are poor, easily moisture absorption in humid air, and adhesive strength is the highest；At high temperature
Use can produce creep, makes glue-joint strength decline, and stores easy freezing below-5 DEG C, makes emulsion be destroyed, therefore leads
Cause its application the most limited.
Therefore a kind of cementability is good, and good stability, workable, the wrapping paper adhesive adapting to adverse circumstances is
Urgently by demand.
Summary of the invention
The purpose of the present invention is that provides a kind of cementability good to solve the problems referred to above, and good stability is operable
Property strong, adapt to the wrapping paper adhesive of adverse circumstances.
To achieve these goals, the present invention is achieved by the following technical solutions: a kind of wrapping paper adhesive, its
Form according to the parts by weight of following raw material: starch 2-10 part, cellulose 3-5 part, nylon 4-15 part, acrylic resin 5-10
Part, phenol-formaldehyde resin modified 10-20 part, benzidine 1-3 part, ditridecyl phthalate 2-5 part, potter's clay 1-5 part, carboxy terminated nitrile rubber
2-10 part, silane coupler 1-3 part, phosphorous vinegar 1-3 part, aqueous tackifier resin 1-3 part, remaining is water 50-100 part.
Further, a kind of wrapping paper adhesive, it is according to the parts by weight composition of following raw material: starch 3-8 part, fibre
Dimension element 3-5 part, nylon 8-10 parts, acrylic resin 6-8 part, phenol-formaldehyde resin modified 12-18 part, benzidine 1-3 part, O-phthalic
Acid diesters 2-5 part, potter's clay 2-4 part, carboxy terminated nitrile rubber 3-8 part, silane coupler 1-3 part, phosphorous vinegar 1-3 part, aqueous increase
Viscosity resin 1-3 part, remaining is water 50-100 part.
Further, a kind of wrapping paper adhesive, it is according to the parts by weight composition of following raw material: starch 5 parts, fibre
Dimension element 4 parts, nylon 9 part, acrylic resin 7 parts, phenol-formaldehyde resin modified 14 parts, 2 parts of benzidine, ditridecyl phthalate 3 parts, pottery
3 parts of soil, carboxy terminated nitrile rubber 5 parts, silane coupler 2 parts, phosphorous vinegar 2 parts, aqueous tackifier resin 2 parts, remaining is 75 parts of water.
Especially, described phenol-formaldehyde resin modified be by epoxy modified phenolic resin, Pioloform, polyvinyl acetal phenol-formaldehyde resin modified,
One in polyamide modified phenolic resin or many group mixing compositions.
The present invention discloses the preparation method of a kind of wrapping paper adhesive, comprises the following steps: by acrylic resin, modification
Phenolic resin is added to the water and joins 90-100 DEG C, after adding starch, cellulose stirring and dissolving 10-20 minute, adds adjacent benzene two
Formic acid diester, potter's clay and aqueous tackifier resin, after stirring 30-40 minute, add nylon and stir 5-10 minute, be eventually adding connection
Aniline, silane coupler and phosphorous vinegar are heated to 100-150 DEG C, stir 10-50 minute and have both obtained the present invention.
The method have the advantages that the wrapping paper adhesive cementability of the present invention is good in sum, stability
Good, use multiple thermoplastic composition workable, adapt to the adverse circumstances of different condition.
Detailed description of the invention
Specific embodiment 1: a kind of wrapping paper adhesive, it is according to the parts by weight composition of following raw material: starch 2 parts,
Cellulose 3 parts, nylon 4 parts, acrylic resin 5 parts, phenol-formaldehyde resin modified 10 parts, 1 part of benzidine, ditridecyl phthalate 2 parts,
1 part of potter's clay, carboxy terminated nitrile rubber 2 parts, silane coupler 1 part, phosphorous vinegar 1 part, aqueous tackifier resin 1 part, remaining is water 50
Part.
The preparation method of a kind of wrapping paper adhesive, comprises the following steps: by acrylic resin 5 parts, modified phenolic resin
10 parts of fat is added to the water and joins 90 DEG C, adds starch 2 parts, 3 parts of stirring and dissolving of cellulose after 10 minutes, adds phthalic acid
Diester 2 parts, 1 part of potter's clay and aqueous tackifier resin 1 part, after stirring 30 minutes, add nylon 4 parts and stir 5 minutes, be eventually adding
1 part of benzidine, silane coupler 1 part and phosphorous vinegar 1 part are heated to 100 DEG C, stir and have both obtained the present invention in 10 minutes.
Specific embodiment 2: a kind of wrapping paper adhesive, it is according to the parts by weight composition of following raw material: starch 5 parts,
Cellulose 4 parts, nylon 9 part, acrylic resin 7 parts, phenol-formaldehyde resin modified 14 parts, 2 parts of benzidine, ditridecyl phthalate 3 parts,
3 parts of potter's clay, carboxy terminated nitrile rubber 5 parts, silane coupler 2 parts, phosphorous vinegar 2 parts, aqueous tackifier resin 2 parts, remaining is water 75
Part.
The preparation method of a kind of wrapping paper adhesive, comprises the following steps: by acrylic resin 7 parts, modified phenolic resin
14 parts of fat is added to the water and joins 95 DEG C, adds starch 5 parts, 4 parts of stirring and dissolving of cellulose after 15 minutes, adds phthalic acid
Diester 3 parts, 3 parts of potter's clay and aqueous tackifier resin 2 parts, after stirring 35 minutes, add nylon 9 part and stir 8 minutes, be eventually adding
2 parts of benzidine, silane coupler 2 parts and phosphorous vinegar 2 parts are heated to 120 DEG C, stir and have both obtained the present invention in 30 minutes.
Specific embodiment 3: a kind of wrapping paper adhesive, it is according to the parts by weight composition of following raw material: starch 10 parts,
Cellulose 5 parts, nylon 15 parts, acrylic resin 10 parts, phenol-formaldehyde resin modified 20 parts, 3 parts of benzidine, ditridecyl phthalate 5
Part, 5 parts of potter's clay, carboxy terminated nitrile rubber 10 parts, silane coupler 3 parts, phosphorous vinegar 3 parts, aqueous tackifier resin 3 parts, remaining is
100 parts of water.
The preparation method of a kind of wrapping paper adhesive, comprises the following steps: by acrylic resin 10 parts, modified phenolic resin
20 parts of fat is added to the water and joins 100 DEG C, adds starch 10 parts, 5 parts of stirring and dissolving of cellulose after 20 minutes, adds O-phthalic
Acid diesters 5 parts, 5 parts of potter's clay and aqueous tackifier resin 3 parts, after stirring 40 minutes, add nylon 15 parts stirring 10 minutes, finally
Add 3 parts of benzidine, silane coupler 3 parts and phosphorous vinegar 3 parts and be heated to 150 DEG C, stir and both obtained the present invention in 50 minutes.
Embodiment provided above is the better embodiment of the present invention, is only used for the convenient explanation present invention, not to this
Bright make any pro forma restriction, any art has usually intellectual, if without departing from the carried skill of the present invention
In the range of art feature, utilize the Equivalent embodiments that the done local of disclosed technology contents is changed or modified, and
Without departing from the technical characteristic content of the present invention, all still fall within the range of the technology of the present invention feature.
Claims (5)
1. a wrapping paper adhesive, it is characterised in that: form according to the parts by weight of following raw material: starch 2-10 part, fibre
Dimension element 3-5 part, nylon 4-15 part, acrylic resin 5-10 part, phenol-formaldehyde resin modified 10-20 part, benzidine 1-3 part, adjacent benzene two
Formic acid diester 2-5 part, potter's clay 1-5 part, carboxy terminated nitrile rubber 2-10 part, silane coupler 1-3 part, phosphorous vinegar 1-3 part, aqueous
Tackifying resin 1-3 part, remaining is water 50-100 part.
2. a wrapping paper adhesive, it is characterised in that: form according to the parts by weight of following raw material: starch 3-8 part, fiber
Element 3-5 part, nylon 8-10 parts, acrylic resin 6-8 part, phenol-formaldehyde resin modified 12-18 part, benzidine 1-3 part, phthalic acid
Diester 2-5 part, potter's clay 2-4 part, carboxy terminated nitrile rubber 3-8 part, silane coupler 1-3 part, phosphorous vinegar 1-3 part, aqueous tackifier
Resin 1-3 part, remaining is water 50-100 part.
3. a wrapping paper adhesive, it is characterised in that: form according to the parts by weight of following raw material: starch 5 parts, cellulose
4 parts, nylon 9 part, acrylic resin 7 parts, phenol-formaldehyde resin modified 14 parts, 2 parts of benzidine, ditridecyl phthalate 3 parts, potter's clay 3
Part, carboxy terminated nitrile rubber 5 parts, silane coupler 2 parts, phosphorous vinegar 2 parts, aqueous tackifier resin 2 parts, remaining is 75 parts of water.
4. according to a kind of wrapping paper adhesive described in claim 1 or 2 or 3, it is characterised in that: described phenol-formaldehyde resin modified
It is by the one or many in epoxy modified phenolic resin, Pioloform, polyvinyl acetal phenol-formaldehyde resin modified, polyamide modified phenolic resin
Group mixing composition.
5. according to the preparation method of a kind of wrapping paper adhesive described in claim 1 or 2 or 3, it is characterised in that: include with
Lower step: acrylic resin, phenol-formaldehyde resin modified be added to the water and join 90-100 DEG C, adds starch, cellulose stirring molten
After solving 10-20 minute, add ditridecyl phthalate, potter's clay and aqueous tackifier resin, after stirring 30-40 minute, add Buddhist nun
Dragon stirring 5-10 minute, is eventually adding benzidine, silane coupler and phosphorous vinegar and is heated to 100-150 DEG C, stirs 10-50
Minute both obtained the present invention.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610741437.XA CN106244064A (en) | 2016-08-29 | 2016-08-29 | A kind of wrapping paper adhesive and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610741437.XA CN106244064A (en) | 2016-08-29 | 2016-08-29 | A kind of wrapping paper adhesive and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106244064A true CN106244064A (en) | 2016-12-21 |
Family
ID=57597136
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610741437.XA Pending CN106244064A (en) | 2016-08-29 | 2016-08-29 | A kind of wrapping paper adhesive and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106244064A (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107974220A (en) * | 2017-12-12 | 2018-05-01 | 徐发昌 | A kind of environmentally protective resin binder and preparation method thereof |
| CN109251719A (en) * | 2018-09-06 | 2019-01-22 | 安徽英美达新材料科技有限公司 | A kind of EPE pearl wool special bonding agent |
| CN110872792A (en) * | 2018-08-30 | 2020-03-10 | 维美德技术有限公司 | Method for treating a fiber web and treatment system for treating a fiber web |
| CN111690189A (en) * | 2020-06-12 | 2020-09-22 | 华南理工大学 | Carboxyl nitrile rubber/carboxyl starch composite material and preparation method and application thereof |
| CN111978899A (en) * | 2020-08-13 | 2020-11-24 | 安徽镜铭建筑装饰工程有限公司 | High-performance adhesive for stone heat-insulation integrated plate |
| CN114395925A (en) * | 2021-11-12 | 2022-04-26 | 北京航天雷特机电工程有限公司 | Preparation method of novel stab-resistant material |
Citations (5)
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|---|---|---|---|---|
| CN102134466A (en) * | 2011-04-25 | 2011-07-27 | 大连市轻化工研究所 | Reactive water-borne adhesive and preparation method thereof |
| CN104119826A (en) * | 2014-06-26 | 2014-10-29 | 安徽图强文具股份有限公司 | Environment-friendly hot-melt adhesive for notebook adhesion |
| CN104371621A (en) * | 2014-10-30 | 2015-02-25 | 田琳琳 | Low-toxicity environment-friendly adhesive |
| CN105199642A (en) * | 2015-10-26 | 2015-12-30 | 马国才 | Electronic chip glue |
| CN105273672A (en) * | 2015-11-25 | 2016-01-27 | 杨挺 | Adhesive for automotive trims |
-
2016
- 2016-08-29 CN CN201610741437.XA patent/CN106244064A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102134466A (en) * | 2011-04-25 | 2011-07-27 | 大连市轻化工研究所 | Reactive water-borne adhesive and preparation method thereof |
| CN104119826A (en) * | 2014-06-26 | 2014-10-29 | 安徽图强文具股份有限公司 | Environment-friendly hot-melt adhesive for notebook adhesion |
| CN104371621A (en) * | 2014-10-30 | 2015-02-25 | 田琳琳 | Low-toxicity environment-friendly adhesive |
| CN105199642A (en) * | 2015-10-26 | 2015-12-30 | 马国才 | Electronic chip glue |
| CN105273672A (en) * | 2015-11-25 | 2016-01-27 | 杨挺 | Adhesive for automotive trims |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107974220A (en) * | 2017-12-12 | 2018-05-01 | 徐发昌 | A kind of environmentally protective resin binder and preparation method thereof |
| CN110872792A (en) * | 2018-08-30 | 2020-03-10 | 维美德技术有限公司 | Method for treating a fiber web and treatment system for treating a fiber web |
| CN109251719A (en) * | 2018-09-06 | 2019-01-22 | 安徽英美达新材料科技有限公司 | A kind of EPE pearl wool special bonding agent |
| CN111690189A (en) * | 2020-06-12 | 2020-09-22 | 华南理工大学 | Carboxyl nitrile rubber/carboxyl starch composite material and preparation method and application thereof |
| CN111978899A (en) * | 2020-08-13 | 2020-11-24 | 安徽镜铭建筑装饰工程有限公司 | High-performance adhesive for stone heat-insulation integrated plate |
| CN114395925A (en) * | 2021-11-12 | 2022-04-26 | 北京航天雷特机电工程有限公司 | Preparation method of novel stab-resistant material |
| CN114395925B (en) * | 2021-11-12 | 2024-04-26 | 北京航天雷特机电工程有限公司 | Preparation method of stab-resistant material |
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| PB01 | Publication | ||
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| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20161221 |
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| WD01 | Invention patent application deemed withdrawn after publication |