CN106244030A - Photocurable adhesive compositions for cold transfer and preparation method thereof - Google Patents
Photocurable adhesive compositions for cold transfer and preparation method thereof Download PDFInfo
- Publication number
- CN106244030A CN106244030A CN201610609544.7A CN201610609544A CN106244030A CN 106244030 A CN106244030 A CN 106244030A CN 201610609544 A CN201610609544 A CN 201610609544A CN 106244030 A CN106244030 A CN 106244030A
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- Prior art keywords
- photocurable adhesive
- adhesive compositions
- acrylate
- resin
- oligomer
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J4/00—Adhesives based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; adhesives, based on monomers of macromolecular compounds of groups C09J183/00 - C09J183/16
- C09J4/06—Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09J159/00 - C09J187/00
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/08—Macromolecular additives
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
The invention provides a kind of Photocurable adhesive compositions for cold transfer and preparation method thereof, this binding agent includes following component: oligomer resin, thermoplastic resin, reactive diluent, light trigger, aided initiating, adhesion promoter, leveling auxiliary agent.This preparation method comprises the steps: to be divided into reactive diluent two parts, and oligomer resin is dissolved by a part, obtains oligomer resin solution, and thermoplastic resin is dissolved by another part, obtains thermoplastic resin solution；Described oligomer resin solution and thermoplastic resin solution are mixed, after addition light trigger and aided initiating stir, adds leveling auxiliary agent and adhesion promoter, after mixing, obtain described Photocurable adhesive.The present invention has following beneficial effect: cold wave gold speed is fast, and applicable surface is relatively wide, and after thermoprint, VOC residual is few, without harmful VOC residual.
Description
Technical field
The present invention relates to a kind of Photocurable adhesive compositions for cold transfer and preparation method thereof, belong to binding agent skill
Art field.
Background technology
Anodized aluminium for thermoprint word, pattern is widely used in packaging, printing industry, and anodized aluminium is multiple film layer structure,
Typically it is made up of the basement membrane sequentially arranged, release layer, chromatograph, sprayed-on Al layer and heat sensitive adhesive layer.Existing electrochemical aluminium thermoprinting is divided into heat
Thermoprint and cold-hot stamping, the anodized aluminium back side that conventional thermal gilding technology uses is pre-coated with PUR, time gold stamping, relies on the pressure of hot cylinder
Power makes adhesive melts realize aluminium foil transfer.Cold wave technology for gold shifts electrification as a kind of brand-new general cold press technique
Paper tinsel.The anodized aluminium that cold wave gold is used is a kind of extraordinary anodized aluminium, and being coated directly on during the printing of its back side not gluing needs decoration
On position, during transfer, anodized aluminium contacts with binding agent, and under bonding, anodized aluminium is also attached on printed matter surface.
Cold wave gold obvious advantage is that and not only solves many insoluble technological problemses of printing industry, more provides
A kind of saving source, it is to avoid cause the solution of environmental pollution during making metallic plate.And along with anticipating along with environmental protection
Strengthening and the most harsh environmental regulation of knowledge, the solvent based coating that conventional thermal thermoprint uses can discharge a large amount of solvent, this and painting
The trend of material environmental protection deviates from.When cold wave technology for gold is used on narrow rotary press printing adhesive material, only need
At a little device of existing equipment.The High-Tech result of American-European printing industry over Nian, instead of traditional gold stamping dependence hot pressing transfer
The technique of anodized aluminium.
Photocureable coating for cold transfer is the core content of cold wave solution, and the performance of photocureable coating is determined the most greatly
Having determined cold wave gold, existing photocureable coating is most of pure poor in pliability, and VOC remains height, is difficult to food medicated cigarette etc. to VOC
Remaining the packaging of strict restriction, trimming performance is bad, and the fine difficulty of gold stamping pattern reaches requirement, and adhesive force is poor, it is impossible to will
Chromatograph coating is completely transferred on base material.
Summary of the invention
For defect of the prior art, it is an object of the invention to provide a kind of Photocurable adhesive group for cold transfer
Compound and preparation method thereof.
The present invention is achieved by the following technical solutions:
First aspect, the invention provides a kind of Photocurable adhesive compositions for cold transfer, and it includes by weight
The following component of number meter:
This scope is to come according to concrete formula and technique, by adjusting oligomer thermoplastic resin and activity dilution
Agent can regulate the viscosity of formula so that being coated with (roller coat), and the amount by regulation initiator and aided initiating can be with client's
UV light source coordinates makes coating be fully cured；Adhesion promoter has been added and coating can be made to be bonded on moulded board, has lacked and has not then had
Improve the effect of adhesive force；Levelling agent promotes levelling, has lacked and has not improved levelling, many can cause other disadvantage of coating, such as profit
Wet, foaming etc..
Preferably, described oligomer resin is selected from polyurethane acrylic resin, epoxy acrylic resin, polyester third
One or more in olefin(e) acid resin, pure acrylic resin, special functional group's acrylate oligomer.
Preferably, described special functional group's acrylate oligomer includes organic silicon acrylic ester oligomer and molten
One or both in dosage form modification acrylate.
Preferably, described thermoplastic resin selects high acid value acrylic resin, vinyl chloride-vinyl acetate resin, maleic anhydride-benzene second
At least one in alkene copolymer, the acid number of described high acid value acrylic resin is not less than 15.
Preferably, described reactive diluent is selected from 1,6-hexanediyl ester, tripropylene glycol diacrylate
Ester, polyethyleneglycol diacrylate, trimethylolpropane trimethacrylate, trimethylol-propane trimethacrylate, ethoxy
Change trimethylolpropane trimethacrylate, the third oxidation trimethylolpropane trimethacrylate, pentaerythritol triacrylate, season penta
Tetra-acrylate, ethoxyquin tetramethylol methane tetraacrylate, the third oxidation tetramethylol methane tetraacrylate, dipentaerythritol six
One or more in acrylate.
Preferably, described light trigger selected from 2,2 '-(2,5-thiophene diyl) double (5-tert-butyl group benzothiazole),
1-hydroxycyclohexyl phenyl ketone, 2,2-dimethoxy-2-phenyl acetophenone, ton ketone, Fluorenone, anthraquinone, 3-methyl acetophenone,
4-chlorobenzophenone, 4,4 '-dimethoxy-benzophenone, 4,4 '-diaminobenzophenone, Michler's keton, benzophenone, benzoin
Propyl ether, benzoin ethyl ether, benzyl dimethyl ketal, 1-(4-cumenyl) 2-hydroxy-2-methyl acrylate-1-ketone, 2-hydroxyl-2-
Methyl isophthalic acid-phenyl acrylate-1-ketone, methylbenzoyl formate thiaxanthone, diethyl thioxanthone, ITX, 2-chlorine
Thiaxanthone, 2-methyl isophthalic acid-(4-(methyl mercapto) phenyl)-2-morpholine acrylate-1-ketone and 2,4,6-trimethyl benzoyl diphenyl base oxygen
Change one or more in phosphine.
Preferably, described aided initiating is the acrylate of band tertiary amine.Containing carbon carbon in the molecule of aided initiating
Double bond, participates in reaction, can improve Light-Curing Efficiency, improve surface cure effect.
Preferably, described adhesion promoter is selected from silane coupler, chlorinated polyolefin hydro carbons adhesion promoter
In one or two kinds of.
Preferably, described levelling agent is selected from acrylic acid levelling agent, organosilicon levelling agent, fluorocarbons class levelling
One or more in agent.
Second aspect, present invention also offers the preparation method of a kind of Photocurable adhesive compositions as the aforementioned, its bag
Include following steps:
Reactive diluent is divided into two parts, and oligomer resin is dissolved by a part, obtains oligomer resin solution,
Thermoplastic resin is dissolved by another part, obtains thermoplastic resin solution；
Described oligomer resin solution and thermoplastic resin solution are mixed, adds light trigger and aided initiating stirring is equal
After even, add leveling auxiliary agent and adhesion promoter, after mixing, obtain described Photocurable adhesive
Compared with prior art, the present invention has a following beneficial effect:
1, cold wave gold speed is fast, prestissimo up to 50～60m/min, and general rotary-cutting hot stamping speed only have 20～
30m/min；
2, the material applicable surface of cold wave gold is relatively wide, can carry out cold wave gold on temperature-sensitive class paper and a part of thin-film material；
3, owing to using general flexible print plate to replace expensive metallograph cylinder, save the energy, reduce consumption, so greatly
Reduce greatly gold stamping cost of manufacture；
4, compared with burn, glue-line coating solvent-free discharge, extremely environmental protection；
5, after thermoprint, VOC residual is few, without harmful VOC residual；
6, solidification is quickly, less energy just energy completion of cure, and has extraordinary adhesive force on all kinds of base materials；
7, high-flexibility is good, can apply on all kinds of soft or hard base materials.
Detailed description of the invention
Below in conjunction with specific embodiment, the present invention is described in detail.Following example will assist in the technology of this area
Personnel are further appreciated by the present invention, but limit the present invention the most in any form.It should be pointed out that, the ordinary skill to this area
For personnel, without departing from the inventive concept of the premise, it is also possible to make some deformation and improvement.These broadly fall into the present invention
Protection domain.
Oligomer resin in the present invention can be selected for: Changxing 6164, Changxing 6240, Changxing 6372, Sartomer CN9007, sand
Many agates CN2303, Sartomer CN115NS；
Special functional group's acrylate in the present invention can be selected for: Changxing 6063, Changxing 6077, Changxing DR-M451.
Embodiment 1
Each component proportion that the present embodiment relates to the low VOC of a kind of high-flexibility cold transfer Photocurable adhesive is as follows:
| Component | Weight |
| Urethane acrylate | 40 |
| Vinyl chloride-vinyl acetate resin | 5 |
| Reactive diluent HDDA | 20 |
| Reactive diluent TMTPA | 15 |
| 2,2-dimethoxy-2-phenyl acetophenone | 5 |
| Aided initiating CN731 | 10 |
| Adhesion promoter SR9008 | 5 |
| Polyether-type modified organic silicon levelling agent | 0.1 |
The preparation method of the photocuring adhesive of the present embodiment comprises the following steps that:
One, it is dissolved in TMTPA after above-mentioned urethane acrylate being dried 1h at 60～70 DEG C, is evenly stirred until the most molten
Solve；
Two, above-mentioned vinyl chloride-vinyl acetate resin is dissolved in HDDA reactive diluent, stirs to fully dissolving；
Three, step 2 gained mixture is uniformly mixed with step one gained mixture；
Four, in step 3 gained mixture, appeal initiator and aided initiating, high-speed stirred mix homogeneously are added；
Five, in step 4 gained mixture, above-mentioned polyether-type modified organic silicon levelling agent is added, adhesion promoter is high
Speed is uniformly mixed.
Embodiment 2
Each component proportion that the present embodiment relates to the low VOC of a kind of high-flexibility cold transfer Photocurable adhesive is as follows:
The preparation method of the photocuring adhesive of the present embodiment comprises the following steps that:
One, it is dissolved in TMTPA after above-mentioned urethane acrylate and epoxy acrylate being dried 1h at 60～70 DEG C, stirs
Mix uniformly to fully dissolving；
Two, above-mentioned high acid value acrylate is dissolved in HDDA reactive diluent, stirs to fully dissolving；
Three, step 2 gained mixture is uniformly mixed with step one gained mixture；
Four, in step 3 gained mixture, add appeal initiator and aided initiating, tell and be uniformly mixed；
Five, in step 4 gained mixture, appeal polyether-type modified organic silicon levelling agent is added, adhesion promoter is high
Speed is uniformly mixed.
Embodiment 3
Each component proportion that the present embodiment relates to the low VOC of a kind of high-flexibility cold transfer Photocurable adhesive is as follows:
| Component | Weight |
| Urethane acrylate | 40 |
| Pure acrylate | 10 |
| Styrene-maleic anhydride copolymer | 7 |
| Reactive diluent HDDA | 20 |
| Reactive diluent TMTPA | 5 |
| 2,2-dimethoxy-2-phenyl acetophenone | 5 |
| Aided initiating CN731 | 10 |
| Adhesion promoter SR9008 | 3 |
| Polyether-type modified organic silicon levelling agent | 0.1 |
The preparation method of the photocuring adhesive of the present embodiment comprises the following steps that:
One, it is dissolved in TMTPA after above-mentioned urethane acrylate and pure acrylate being dried 1h at 60～70 DEG C, stirring
Uniformly to fully dissolving；
Two, appeal phenylacetic acid maleic anhydride is dissolved in HDDA reactive diluent, stirs to fully dissolving；
Three, step 2 gained mixture is uniformly mixed with step one gained mixture；
Four, in step 3 gained mixture, add appeal initiator and aided initiating, tell and be uniformly mixed；
Five, in step 4 gained mixture, appeal polyether-type modified organic silicon levelling agent is added, adhesion promoter is high
Speed is uniformly mixed.
Table 1 embodiment and the performance comparison of comparative example
Above the specific embodiment of the present invention is described.It is to be appreciated that the invention is not limited in above-mentioned
Particular implementation, those skilled in the art can make various deformation or amendment within the scope of the claims, this not shadow
Ring the flesh and blood of the present invention.
Claims (10)
1. the Photocurable adhesive compositions for cold transfer, it is characterised in that include following group counted by weight
Point:
2. Photocurable adhesive compositions as claimed in claim 1, it is characterised in that described oligomer resin is selected from polyurethane
Acrylic resin, epoxy acrylic resin, polyester acrylate resin, pure acrylic resin, special functional group's acrylate oligomers
One or more in thing.
3. Photocurable adhesive compositions as claimed in claim 2, it is characterised in that described special functional group's acrylate is low
Polymers includes one or both in organic silicon acrylic ester oligomer and solvent-borne type modification acrylate.
4. Photocurable adhesive compositions as claimed in claim 1, it is characterised in that described thermoplastic resin selects high acid value third
At least one in olefin(e) acid resin, vinyl chloride-vinyl acetate resin, maleic anhydride-styrene copolymers, the acid of described high acid value acrylic resin
Value is not less than 15.
5. Photocurable adhesive compositions as claimed in claim 1, it is characterised in that described reactive diluent is selected from 1, and 6-is own
Omega-diol diacrylate, tripropylene glycol diacrylate, polyethyleneglycol diacrylate, trimethylolpropane trimethacrylate,
Trimethylol-propane trimethacrylate, ethoxyquin trimethylolpropane trimethacrylate, the third oxidation trimethylolpropane tris
Acrylate, pentaerythritol triacrylate, tetramethylol methane tetraacrylate, ethoxyquin tetramethylol methane tetraacrylate, the third oxygen
Change one or more in tetramethylol methane tetraacrylate, dipentaerythritol acrylate.
6. Photocurable adhesive compositions as claimed in claim 1, it is characterised in that described light trigger selected from 2,2 '-(2,
5-thiophene diyl) double (5-tert-butyl group benzothiazoles), 1-hydroxycyclohexyl phenyl ketone, 2,2-dimethoxy-2-phenyl benzene second
Ketone, ton ketone, Fluorenone, anthraquinone, 3-methyl acetophenone, 4-chlorobenzophenone, 4,4 '-dimethoxy-benzophenone, 4,4 '-diamino
Base benzophenone, Michler's keton, benzophenone, benzoin propyl ether, benzoin ethyl ether, benzyl dimethyl ketal, 1-(4-isopropylbenzene
Base) 2-hydroxy-2-methyl acrylate-1-ketone, 2-hydroxy-2-methyl-1-phenyl acrylate-1-ketone, methylbenzoyl formate thiaxanthone,
Diethyl thioxanthone, ITX, CTX, 2-methyl isophthalic acid-(4-(methyl mercapto) phenyl)-2-morpholine acrylate-1-
One or more in ketone and TMDPO.
7. Photocurable adhesive compositions as claimed in claim 1, it is characterised in that described aided initiating is the third of band tertiary amine
Olefin(e) acid ester.
8. Photocurable adhesive compositions as claimed in claim 1, it is characterised in that described adhesion promoter is selected from silane
One or two kinds of in coupling agent, chlorinated polyolefin hydro carbons adhesion promoter.
9. Photocurable adhesive compositions as claimed in claim 1, it is characterised in that described levelling agent is selected from acrylic acid levelling
One or more in agent, organosilicon levelling agent, fluorocarbons class levelling agent.
10. a preparation method for the Photocurable adhesive compositions as described in any one in claim 1～9, its feature
It is, comprises the steps:
Reactive diluent is divided into two parts, and oligomer resin is dissolved by a part, obtains oligomer resin solution, another
Thermoplastic resin is dissolved by part, obtains thermoplastic resin solution；
Described oligomer resin solution and thermoplastic resin solution are mixed, adds light trigger and aided initiating stirs
After, add leveling auxiliary agent and adhesion promoter, after mixing, obtain described Photocurable adhesive.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610609544.7A CN106244030A (en) | 2016-07-28 | 2016-07-28 | Photocurable adhesive compositions for cold transfer and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610609544.7A CN106244030A (en) | 2016-07-28 | 2016-07-28 | Photocurable adhesive compositions for cold transfer and preparation method thereof |
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| Publication Number | Publication Date |
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| CN106244030A true CN106244030A (en) | 2016-12-21 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610609544.7A Pending CN106244030A (en) | 2016-07-28 | 2016-07-28 | Photocurable adhesive compositions for cold transfer and preparation method thereof |
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Cited By (7)
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|---|---|---|---|---|
| CN107325760A (en) * | 2017-07-20 | 2017-11-07 | 上海乘鹰新材料有限公司 | A kind of alcohol-soluble and water-soluble flexo cold wave gum and preparation method thereof |
| CN107353866A (en) * | 2017-08-09 | 2017-11-17 | 深圳市中联讯科技有限公司 | A kind of UV optic-solidified adhesives |
| CN108045120A (en) * | 2017-10-30 | 2018-05-18 | 虎彩印艺股份有限公司 | A kind of offset printing line cold foil technology and equipment |
| CN109294511A (en) * | 2018-09-03 | 2019-02-01 | 佛山艾仕仑科技有限公司 | A kind of UV curing adhesive suitable for flexible parent metal bonding |
| CN115477922A (en) * | 2022-09-22 | 2022-12-16 | 惠州巨润科技有限公司 | UV cold-ironing glue applying improved rosin resin and preparation method thereof |
| CN115537164A (en) * | 2022-10-08 | 2022-12-30 | 国网河南省电力公司镇平县供电公司 | Full-lamination liquid optical cement for capacitive touch screen and application |
| CN117264551A (en) * | 2023-11-22 | 2023-12-22 | 汕头市恒顺包装材料有限公司 | Multifunctional cold transfer gold stamping film and manufacturing method thereof |
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| CN117264551A (en) * | 2023-11-22 | 2023-12-22 | 汕头市恒顺包装材料有限公司 | Multifunctional cold transfer gold stamping film and manufacturing method thereof |
| CN117264551B (en) * | 2023-11-22 | 2024-02-06 | 汕头市恒顺包装材料有限公司 | Multifunctional cold transfer gold stamping film and manufacturing method thereof |
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Application publication date: 20161221 |
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| RJ01 | Rejection of invention patent application after publication |