CN106243894A - A kind of anion formaldehyde scavenger for sheet material - Google Patents
A kind of anion formaldehyde scavenger for sheet material Download PDFInfo
- Publication number
- CN106243894A CN106243894A CN201610623553.1A CN201610623553A CN106243894A CN 106243894 A CN106243894 A CN 106243894A CN 201610623553 A CN201610623553 A CN 201610623553A CN 106243894 A CN106243894 A CN 106243894A
- Authority
- CN
- China
- Prior art keywords
- parts
- sheet material
- nano
- anion
- formaldehyde scavenger
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/24—Homopolymers or copolymers of amides or imides
- C09D133/26—Homopolymers or copolymers of acrylamide or methacrylamide
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
Abstract
The present invention relates to environmental friendly indoor field, a kind of anion formaldehyde scavenger for sheet material, its raw material is calculated as by weight: nano antibacterial agent 15 parts, fatty alcohol-polyoxyethylene ether 12 parts, nanometer anion powder 7 parts, Folium Camelliae sinensis extract 5 parts, modified polyacrylamide solution 10 parts, 5 parts of carbamide, thiourea 3 parts, defoamer 1.5 parts, deionized water 200 parts.Product can directly apply to ornament materials or polymerization sheet surface, effectively reduces the content of the poisonous and harmful substances such as formaldehyde in family, promotes home air quality.
Description
Technical field
The present invention relates to environmental friendly indoor field, a kind of anion formaldehyde scavenger for sheet material.
Background technology
In room air pollution, formaldehyde pollution is typically the most universal the most intractable, during decorating house, by
In many artificial board, binding agent, coating, paint, all contain formaldehyde, the dusty gas based on formaldehyde can be volatilized for a long time,
Human body is damaged.Formaldehyde is defined as carcinogenic and teratogenecity material by World Health Organization (WHO), and Long Term Contact formaldehyde can draw
Play the diseases such as chronic respiratory tract disease, pregnancy syndrome, leukemia, it is also possible to cause neonatal chromosome disorder and teenager note
Recall power to go down, mental retardation etc..Wherein artificial board becomes with huge formaldehyde volatile quantity with up to volatilization cycle of ten several years
High harm polluter the most obstinate in indoor pollutant.The most conventional air purifying process, mainly physical absorption, such as
Plant absorption and activated carbon adsorption；When wherein using activated carbon adsorption, mainly activated carbon is prevented the dress in certain structure
Put, rely on the natural flow of air or the effect of blower fan to adsorb.But owing to formaldehyde is long-time slowly release, in room
In can not place formaldehyde plant, so human body still can constantly be damaged by formaldehyde always.
Wanting really to solve the pollution problem of indoor formaldehyde, starting with from polluter is the quickest and permanently effective hands
Section.The volatile source that indoor formaldehyde is the most serious and the cycle is the longest is various ornament materials or polymerization sheet.Through testing discovery in a large number, often
The rarest formaldehyde to artificial board etc. of formaldehyde removing method seen volatilizees and has long-term remarkable result, and exploitation one has long-term effect
The formaldehyde scavenger of fruit is the most urgent to solving Formaldehyde Pollution of Indoor Air problem.
Summary of the invention
The present invention is directed to the problems referred to above and propose a kind of formaldehyde removing product, it is possible to permanently effective suppression wood-based plate etc. are stupid
Gu the formaldehyde volatilization of polluter, reduce indoor formaldehyde concentration, ensure that home environment is healthy.
To achieve these goals, the used technical scheme of the present invention is, a kind of anion formaldehyde removing for sheet material
Its raw material of agent is calculated as by weight: nano antibacterial agent 15 parts, fatty alcohol-polyoxyethylene ether 12 parts, nanometer anion powder 7 parts, Folium Camelliae sinensis
Extract 5 parts, modified polyacrylamide solution 10 parts, 5 parts of carbamide, thiourea 3 parts, defoamer 1.5 parts, deionized water 200 parts.
Described nano antibacterial agent is nano TiO 2, nano-ZnO and the mixture of nanometer Ag, nano TiO 2, nano-ZnO
Being 30～50 nanometers with the granularity of nanometer silver, the ratio of three is TiO2:ZnO:Ag=(1～2): 1:0.5.
The preparation method of described modified polyacrylamide is, ratio 1:1 chooses mass fraction by weight is 18～22%
The polyacrylamide solution of mean molecule quantity 40000 and mass fraction are the hydrazine hydrate solution mixing of 75～85%, at 50-60
Stirring reaction 16～21h under DEG C environment, by the product obtained through precipitation, be dried, obtain modified polyacrylamide.
As preferably, in the preparation process improving polyacrylamide, the mass fraction of described polyacrylamide solution
Being 20%, the mass fraction of described hydrazine hydrate solution is 80%.
As preferably, the described stirring response time is 19h.
By scavenger brushing or be sprayed on plate surface during use.
Nano antibacterial agent, Folium Camelliae sinensis extract and the nanometer anion powder contained in the present invention, can capture board fast and effectively
Free formaldehyde PARA FORMALDEHYDE PRILLS(91,95) in material decompose, simultaneously nano antibacterial agent can effective bacteriostasis antibiosis, long action time,
Organic amine group can generate the stable compounds such as hexamethylenetetramine in formaldehyde reaction for a long time, penetrates into plate while eliminating formaldehyde
Material mechanism forms resin polymers, stops the continuation volatilization of formaldehyde, and fatty alcohol-polyoxyethylene ether is as penetrating agent, it is possible to help
All kinds of materials enter material internal, remove formaldehyde from inside.Nanometer anion powder not only has elimination foreign flavor indoors and harmful gas
The function of body, also has health care.Product finally can effectively reduce the content of the poisonous and harmful substance such as formaldehyde in family, carries
Rise home air quality.
Detailed description of the invention
Below by specific embodiment, the present invention is described in further detail.
Embodiment 1: a kind of its raw material of anion formaldehyde scavenger for sheet material is calculated as by weight: nano antibacterial agent 15
Part, fatty alcohol-polyoxyethylene ether 12 parts, nanometer anion powder 7 parts, Folium Camelliae sinensis extract 5 parts, modified polyacrylamide solution 10 parts,
5 parts of carbamide, thiourea 3 parts, defoamer 1.5 parts, deionized water 200 parts.
Described nano antibacterial agent is nano TiO 2, nano-ZnO and the mixture of nanometer Ag, nano TiO 2, nano-ZnO
Being 30～50 nanometers with the granularity of nanometer silver, the ratio of three is TiO2:ZnO:Ag=1.5:1:0.5.
The preparation method of described modified polyacrylamide is, by weight ratio 1:1 choose mass fraction be 20% average
The polyacrylamide solution of molecular weight 40000 and the hydrazine hydrate solution mixing that mass fraction is 80%, under 50-60 DEG C of environment
Stirring reaction 19h, by the product obtained through precipitating, being dried, obtains modified polyacrylamide.
Embodiment 2: a kind of its raw material of anion formaldehyde scavenger for sheet material is calculated as by weight: nano antibacterial agent 15
Part, fatty alcohol-polyoxyethylene ether 12 parts, nanometer anion powder 7 parts, Folium Camelliae sinensis extract 5 parts, modified polyacrylamide solution 10 parts,
5 parts of carbamide, thiourea 3 parts, defoamer 1.5 parts, deionized water 200 parts.
Described nano antibacterial agent is nano TiO 2, nano-ZnO and the mixture of nanometer Ag, nano TiO 2, nano-ZnO
Being 30～50 nanometers with the granularity of nanometer silver, the ratio of three is TiO2:ZnO:Ag=1.5:1:0.5.
The preparation method of described modified polyacrylamide is, by weight ratio 1:1 choose mass fraction be 18% average
The polyacrylamide solution of molecular weight 40000 and the hydrazine hydrate solution mixing that mass fraction is 75%, under 50-60 DEG C of environment
Stirring reaction 16h, by the product obtained through precipitating, being dried, obtains modified polyacrylamide.
Embodiment 3: a kind of its raw material of anion formaldehyde scavenger for sheet material is calculated as by weight: nano antibacterial agent 15
Part, fatty alcohol-polyoxyethylene ether 12 parts, nanometer anion powder 7 parts, Folium Camelliae sinensis extract 5 parts, modified polyacrylamide solution 10 parts,
5 parts of carbamide, thiourea 3 parts, defoamer 1.5 parts, deionized water 200 parts.
Described nano antibacterial agent is nano TiO 2, nano-ZnO and the mixture of nanometer Ag, nano TiO 2, nano-ZnO
Being 30～50 nanometers with the granularity of nanometer silver, the ratio of three is TiO2:ZnO:Ag=1.5:1:0.5.
The preparation method of described modified polyacrylamide is, by weight ratio 1:1 choose mass fraction be 22% average
The polyacrylamide solution of molecular weight 40000 and the hydrazine hydrate solution mixing that mass fraction is 85%, under 50-60 DEG C of environment
Stirring reaction 21h, by the product obtained through precipitating, being dried, obtains modified polyacrylamide.
The foregoing is only the preferred embodiments of the present invention, be not limited to the present invention, for the skill of this area
For art personnel, can there be various modifications and variations in the spirit and principles in the present invention, the modification of these equivalents or replacement etc.,
Within being all contained in protection scope of the present invention.
Claims (5)
1. the anion formaldehyde scavenger for sheet material, it is characterised in that its raw material is calculated as by weight: nano antibacterial agent
15 parts, fatty alcohol-polyoxyethylene ether 12 parts, nanometer anion powder 7 parts, Folium Camelliae sinensis extract 5 parts, modified polyacrylamide solution 10
Part, 5 parts of carbamide, thiourea 3 parts, defoamer 1.5 parts, deionized water 200 parts.
A kind of anion formaldehyde scavenger for sheet material the most according to claim 1, it is characterised in that described modification gathers
The preparation method of acrylamide is: ratio 1:1 by weight chooses the mean molecule quantity 40000 that mass fraction is 18～22%
Polyacrylamide solution and mass fraction are the hydrazine hydrate solution mixing of 75～85%, stir reaction 16 under 50-60 DEG C of environment
～21h, by the product obtained through precipitating, being dried, obtain modified polyacrylamide.
A kind of anion formaldehyde scavenger for sheet material the most according to claim 2, it is characterised in that: improving poly-third
In the preparation process of acrylamide, the mass fraction of described polyacrylamide solution is 20%, and the quality of described hydrazine hydrate solution is divided
Number is 80%.
A kind of anion formaldehyde scavenger for sheet material the most according to claim 2, it is characterised in that: described stirring is anti-
It is 19h between Ying Shi.
A kind of anion formaldehyde scavenger for sheet material the most according to claim 1, it is characterised in that: described nanometer
Antibacterial is nano TiO 2, nano-ZnO and the mixture of nanometer Ag, and nano TiO 2, nano-ZnO are with the granularity of nanometer silver
30～50 nanometers, the ratio of three is TiO2:ZnO:Ag=(1～2): 1:0.5.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610623553.1A CN106243894A (en) | 2016-08-02 | 2016-08-02 | A kind of anion formaldehyde scavenger for sheet material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610623553.1A CN106243894A (en) | 2016-08-02 | 2016-08-02 | A kind of anion formaldehyde scavenger for sheet material |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106243894A true CN106243894A (en) | 2016-12-21 |
Family
ID=57606150
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610623553.1A Pending CN106243894A (en) | 2016-08-02 | 2016-08-02 | A kind of anion formaldehyde scavenger for sheet material |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106243894A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107349762A (en) * | 2017-09-15 | 2017-11-17 | 广州欧派集成家居有限公司 | Except net taste composition of aldehyde and its preparation method and application |
| CN108392969A (en) * | 2018-03-09 | 2018-08-14 | 太原氦舶新材料有限责任公司 | A kind of formaldehyde removal purification spray |
| CN109289507A (en) * | 2018-10-23 | 2019-02-01 | 南京海洛阿姆生物科技有限公司 | A kind of formaldehyde scavenger and preparation method thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1743032A (en) * | 2005-09-09 | 2006-03-08 | 罗文圣 | Floor-board with low free formaldehyde release and furniture production method |
| CN1918999A (en) * | 2006-08-30 | 2007-02-28 | 吴金龙 | Preparation process of nano antibacterial agent |
| CN101474419A (en) * | 2008-01-03 | 2009-07-08 | 欧阳林 | Compound catalytic material for purifying harmful gas |
| CN103360108A (en) * | 2013-06-17 | 2013-10-23 | 浙江日盛建设有限公司 | Novel organic silicon waterproof agent and preparation method thereof |
| CN105727494A (en) * | 2014-12-12 | 2016-07-06 | 上海美世环保科技有限公司 | Formaldehyde scavenging agent |
-
2016
- 2016-08-02 CN CN201610623553.1A patent/CN106243894A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1743032A (en) * | 2005-09-09 | 2006-03-08 | 罗文圣 | Floor-board with low free formaldehyde release and furniture production method |
| CN1918999A (en) * | 2006-08-30 | 2007-02-28 | 吴金龙 | Preparation process of nano antibacterial agent |
| CN101474419A (en) * | 2008-01-03 | 2009-07-08 | 欧阳林 | Compound catalytic material for purifying harmful gas |
| CN103360108A (en) * | 2013-06-17 | 2013-10-23 | 浙江日盛建设有限公司 | Novel organic silicon waterproof agent and preparation method thereof |
| CN105727494A (en) * | 2014-12-12 | 2016-07-06 | 上海美世环保科技有限公司 | Formaldehyde scavenging agent |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107349762A (en) * | 2017-09-15 | 2017-11-17 | 广州欧派集成家居有限公司 | Except net taste composition of aldehyde and its preparation method and application |
| CN108392969A (en) * | 2018-03-09 | 2018-08-14 | 太原氦舶新材料有限责任公司 | A kind of formaldehyde removal purification spray |
| CN109289507A (en) * | 2018-10-23 | 2019-02-01 | 南京海洛阿姆生物科技有限公司 | A kind of formaldehyde scavenger and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN109847527A (en) | A kind of wet tissue and preparation method thereof with except aldehyde function | |
| CN106110856A (en) | A kind of except formaldehyde purifying agent | |
| CN103691314A (en) | Deodorizing composition and application thereof | |
| CN106634362A (en) | Building coating capable of adsorbing formaldehyde | |
| CN105174859A (en) | Diatomite micropowder-based interior wall paint capable of removing formaldehyde and peculiar smell in indoor air and preparation method thereof | |
| CN106243894A (en) | A kind of anion formaldehyde scavenger for sheet material | |
| CN103551028A (en) | Reaction type formaldehyde scavenger with aminopolyol as active matter and preparation method thereof | |
| CN104910866A (en) | Novel spraying agent for reducing indoor haze, and application thereof | |
| CN110951303A (en) | Plant antibacterial water paint capable of decomposing formaldehyde and releasing negative ions | |
| CN105038559A (en) | Formaldehyde removing paint | |
| CN106540665A (en) | A kind of formaldehyde adsorbent | |
| CN108159591A (en) | A kind of photocatalyst antiseptic mask and preparation method thereof | |
| CN105964133A (en) | Method for eliminating formaldehyde with biological protease | |
| CN106345287A (en) | Anion formaldehyde purifying agent | |
| CN105131799A (en) | Ultraviolet curable coating for removing formaldehyde | |
| CN106994334A (en) | A kind of adsorbent being used in air purifier | |
| CN105038366A (en) | Air-purification internal wall putty | |
| CN106178384A (en) | A kind of formaldehyde scavenger | |
| CN105478075B (en) | The modified nano composite material of water-based system purification air | |
| CN107603294B (en) | A kind of shell magma coating and preparation method thereof that can remove formaldehyde | |
| CN103555108A (en) | Applying method for interior wall paint capable of absorbing and decomposing formaldehyde | |
| CN103555110B (en) | A kind of interior wall coating absorbing also decomposing formaldehyde | |
| CN105218017A (en) | Based on diatomite ultrafine powder except formaldehyde in indoor air diatom ooze and preparation method thereof | |
| CN203043841U (en) | Formaldehyde removing device and formaldehyde removing fan | |
| CN106215364A (en) | A kind of formaldehyde scavenger for sheet material |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20161221 |
|
| RJ01 | Rejection of invention patent application after publication |