CN106243805A - A kind of heat insulation type exterior coating - Google Patents
A kind of heat insulation type exterior coating Download PDFInfo
- Publication number
- CN106243805A CN106243805A CN201610610880.3A CN201610610880A CN106243805A CN 106243805 A CN106243805 A CN 106243805A CN 201610610880 A CN201610610880 A CN 201610610880A CN 106243805 A CN106243805 A CN 106243805A
- Authority
- CN
- China
- Prior art keywords
- parts
- heat insulation
- weight portion
- insulation type
- exterior coating
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D4/00—Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
- C09D4/06—Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09D159/00 - C09D187/00
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/70—Additives characterised by shape, e.g. fibres, flakes or microspheres
Abstract
The present invention relates to technical field of coatings, specifically about a kind of heat insulation type exterior coating, the component including following mass ratio is prepared from: the mass ratio of fluorine-carbon modified acrylic acid ester emulsion, acrylate reactive amine and fatty acid amide is 9 12:1 3.5:0.7 2.Multicomponent Synergistic of the present invention makes paint adhesion strong, non-scale, has quick solidifying, the feature that brightness is high, smear rear surface highly polished, later stage exterior wall robot cleaning is convenient, can prevent the later stage from rough causing robot suction to drop not, and it has the strongest self-cleaning ability simultaneously, and oxidation resistance, durable persistently coating has good translucidus, and heat absorption capacity is weak.
Description
Technical field
The present invention relates to technical field of coatings, specifically about a kind of heat insulation type exterior coating.
Background technology
Optical curing of UV coating products is applicable to multiple substrate surface: paper, woodenware, stone material, leather, pottery, metal, glass
Glass, plastics, concrete etc., especially suitable to some thermo-responsive materials especially.Photocuring technology be a kind of efficiently, environment, energy-conservation,
The surface treatment technology of material of high-quality, it is to utilize ultraviolet light to cause to have the crosslinking of chemism liquid material rapid polymerization, wink
Between be solidified into solid material, it is substantially free of volatile solvent (VOC), thus without causing air pollution and the harm to human body
And the danger of fire.
Summary of the invention
It is an object of the invention to provide a kind of fast setting, aging resistance, well-insulated exterior coating.
In order to realize foregoing invention purpose, technical scheme is specific as follows:
A kind of heat insulation type exterior coating, it is characterised in that include that the component of following mass ratio is prepared from: fluorine-carbon modified acrylic acid
The mass ratio of ester emulsion, acrylate reactive amine and fatty acid amide is 9-12:1-3.5:0.7-2.
Preferably, described heat insulation type exterior coating, the component including following weight portion is prepared from: fluorine-carbon modified acrylic acid
Ester emulsion 90-120 part, acrylate reactive amine 10-35 part, light trigger 2-5 part, itaconic acid 5-9 part, HBCD 4-
9 parts, glass microballoon 9-16 part, maleic anhydride 3-9 part, calcium stearate 4-9 part, sodium carboxymethyl cellulose 7-9 part, fatty acid amide
7-20 part, POLYPROPYLENE GLYCOL 11-13 part, antioxidant 1-5 part.
Preferably, described heat insulation type exterior coating, the component including following weight portion is prepared from: fluorine-carbon modified acrylic acid
Ester emulsion 110 parts, acrylate reactive amine 28 parts, light trigger 4 parts, 7 parts of itaconic acid, HBCD 6 parts, glass microballoon
12 parts, maleic anhydride 7 parts, calcium stearate 6 parts, sodium carboxymethyl cellulose 8 parts, fatty acid amide 11 parts, POLYPROPYLENE GLYCOL 12 parts, anti-
Oxygen agent 3.5 parts.
Preferably, described fluorine-carbon modified acrylic acid ester emulsion is by methyl methacrylate 7-20 weight portion, ethylene glycol 4-9
Weight portion, coconut oil fat acyl diethanolamine 0.2-0.5 weight portion, dodecafluoroheptyl methacrylate 5-8 weight portion, nano-sized carbon
After powder 2-6 weight portion and the mixing of deionized water 45-90 weight portion, under 75-85 DEG C of water bath with thermostatic control, with the speed of 300-400r/min
The emulsion that degree dispersed with stirring 4-6h obtains.
Preferably, described light trigger is 2-methyl isophthalic acid-(4-methyl mercapto phenyl)-2-morpholinyl-1-acetone and 2,4,6-
The mixture of trimethyl benzoyl diphenyl base phosphine oxide.
Preferably, described 2-methyl isophthalic acid-(4-methyl mercapto phenyl)-2-morpholinyl-1-acetone and 2,4,6-trimethylbenzene first
The mass ratio of acyl group diphenyl phosphine oxide is 1:2.
Preferably, described antioxidant is three (2,4-di-tert-butyl-phenyl) phosphite ester, N, N-bis--(3-(3,5-bis-uncles
Butyl-4-hydroxy phenyl) propiono) double [β-(the 3-tertiary butyl-4-hydroxy-5-aminomethyl phenyl) of hexamethylene diamine and triethylene-glycol
Propionic ester] in one or more.
Beneficial effect of the present invention, multicomponent Synergistic of the present invention makes paint adhesion strong, and non-scale has quick solidifying,
The feature that brightness is high, it is highly polished to smear rear surface, and later stage exterior wall robot cleaning is convenient, and the later stage can be prevented rough
Causing robot suction to drop not, it has the strongest self-cleaning ability, and an oxidation resistance simultaneously, durable persistently, coating has
Good translucidus, heat absorption capacity is weak.
Detailed description of the invention
Below in conjunction with embodiment, present disclosure is described in further detail.
Embodiment 1
A kind of heat insulation type exterior coating, the component including following weight portion is prepared from: fluorine-carbon modified acrylic acid ester emulsion 90 parts,
Acrylate reactive amine 10 parts, light trigger 2 parts, 5 parts of itaconic acid, HBCD 4 parts, glass microballoon 9-16 part, Malaysia
Anhydride 3-9 part, calcium stearate 4-9 part, sodium carboxymethyl cellulose 7 parts, fatty acid amide 7 parts, POLYPROPYLENE GLYCOL 11 parts, antioxidant 1
Part.
Embodiment 2
A kind of heat insulation type exterior coating, the component including following weight portion is prepared from: fluorine-carbon modified acrylic acid ester emulsion 110
Part, acrylate reactive amine 28 parts, light trigger 4 parts, 7 parts of itaconic acid, HBCD 6 parts, glass microballoon 12 parts, Malaysia
7 parts of anhydride, calcium stearate 6 parts, sodium carboxymethyl cellulose 8 parts, fatty acid amide 11 parts, POLYPROPYLENE GLYCOL 12 parts, antioxidant 3.5
Part.
Embodiment 3
A kind of heat insulation type exterior coating, the component including following weight portion is prepared from: fluorine-carbon modified acrylic acid ester emulsion 120
Part, acrylate reactive amine 35 parts, light trigger 5 parts, 9 parts of itaconic acid, HBCD 9 parts, glass microballoon 16 parts, Malaysia
9 parts of anhydride, calcium stearate 9 parts, sodium carboxymethyl cellulose 9 parts, fatty acid amide 20 parts, POLYPROPYLENE GLYCOL 13 parts, 5 parts of antioxidant.
Although reference be made herein to invention has been described for the explanatory embodiment of the present invention, and above-described embodiment is only this
Bright preferably embodiment, embodiments of the present invention are also not restricted to the described embodiments, it should be appreciated that people in the art
Member can be designed that a lot of other amendments and embodiment, and these amendments and embodiment will fall in principle disclosed in the present application
Within scope and spirit.
Claims (7)
1. a heat insulation type exterior coating, it is characterised in that include that the component of following mass ratio is prepared from: fluorine-carbon modified propylene
The mass ratio of acid esters emulsion, acrylate reactive amine and fatty acid amide is 9-12:1-3.5:0.7-2.
Heat insulation type exterior coating the most according to claim 1, it is characterised in that include following weight portion component preparation and
Become: fluorine-carbon modified acrylic acid ester emulsion 90-120 part, acrylate reactive amine 10-35 part, light trigger 2-5 part, itaconic acid 5-9
Part, HBCD 4-9 part, glass microballoon 9-16 part, maleic anhydride 3-9 part, calcium stearate 4-9 part, carboxymethyl cellulose
Sodium 7-9 part, fatty acid amide 7-20 part, POLYPROPYLENE GLYCOL 11-13 part, antioxidant 1-5 part.
Heat insulation type exterior coating the most according to claim 2, it is characterised in that include following weight portion component preparation and
Become: fluorine-carbon modified acrylic acid ester emulsion 110 parts, acrylate reactive amine 28 parts, light trigger 4 parts, 7 parts of itaconic acid, hexabromo ring
Dodecane 6 parts, glass microballoon 12 parts, maleic anhydride 7 parts, calcium stearate 6 parts, sodium carboxymethyl cellulose 8 parts, fatty acid amide 11
Part, POLYPROPYLENE GLYCOL 12 parts, 3.5 parts of antioxidant.
Heat insulation type exterior coating the most according to claim 1, it is characterised in that described fluorine-carbon modified acrylic acid ester emulsion be by
Methyl methacrylate 7-20 weight portion, ethylene glycol 4-9 weight portion, coconut oil fat acyl diethanolamine 0.2-0.5 weight portion, first
After base dodecafluorhe-ptylacrylate 5-8 weight portion, nano-carbon powder 2-6 weight portion and the mixing of deionized water 45-90 weight portion,
Under 75-85 DEG C of water bath with thermostatic control, the emulsion obtained with speed dispersed with stirring 4-6h of 300-400r/min.
Heat insulation type exterior coating the most according to claim 1, it is characterised in that described light trigger is 2-methyl isophthalic acid-(4-first
Sulfenyl phenyl)-2-morpholinyl-1-acetone and the mixture of TMDPO.
Heat insulation type exterior coating the most according to claim 5, it is characterised in that described 2-methyl isophthalic acid-(4-methyl mercapto phenyl)-
The mass ratio of 2-morpholinyl-1-acetone and TMDPO is 1:2.
Heat insulation type exterior coating the most according to claim 2, it is characterised in that described antioxidant is three (2,4-di-t-butyls
Phenyl) phosphite ester, N, N-bis--(3-(3,5-di-tert-butyl-hydroxy phenyl) propiono) hexamethylene diamine and triethylene-glycol
In double [β-(3-tertiary butyl-4-hydroxy-5-aminomethyl phenyl) propionic esters] one or more.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610610880.3A CN106243805A (en) | 2016-07-29 | 2016-07-29 | A kind of heat insulation type exterior coating |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610610880.3A CN106243805A (en) | 2016-07-29 | 2016-07-29 | A kind of heat insulation type exterior coating |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106243805A true CN106243805A (en) | 2016-12-21 |
Family
ID=57604990
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610610880.3A Withdrawn CN106243805A (en) | 2016-07-29 | 2016-07-29 | A kind of heat insulation type exterior coating |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106243805A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107325711A (en) * | 2017-06-27 | 2017-11-07 | 天长市巨龙车船涂料有限公司 | A kind of automatically cleaning warning sign coating |
-
2016
- 2016-07-29 CN CN201610610880.3A patent/CN106243805A/en not_active Withdrawn
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107325711A (en) * | 2017-06-27 | 2017-11-07 | 天长市巨龙车船涂料有限公司 | A kind of automatically cleaning warning sign coating |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WW01 | Invention patent application withdrawn after publication |
Application publication date: 20161221 |
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| WW01 | Invention patent application withdrawn after publication |