CN106243425A - A kind of Environment-friendlywear-resistant wear-resistant styrene-butadiene rubber - Google Patents

A kind of Environment-friendlywear-resistant wear-resistant styrene-butadiene rubber Download PDF

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Publication number
CN106243425A
CN106243425A CN201610618657.3A CN201610618657A CN106243425A CN 106243425 A CN106243425 A CN 106243425A CN 201610618657 A CN201610618657 A CN 201610618657A CN 106243425 A CN106243425 A CN 106243425A
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China
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parts
resistant
rubber
styrene
butadiene
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CN201610618657.3A
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Chinese (zh)
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陈林美
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Individual
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L9/00Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
    • C08L9/06Copolymers with styrene

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The invention discloses a kind of Environment-friendlywear-resistant wear-resistant styrene-butadiene rubber, including the raw material of following weight portion: 50 60 parts of butadiene-styrene rubber, dual-tert-butyl peroxy isopropyl base benzene 26 parts, ethylene bis stearamide 25 parts, aluminium nitride 35 parts, acetic acid 10 15 parts, 14 parts of magnesium chloride, glycerol 37 parts, lime water 40 50 parts, waterglass 30 40 parts, Tissuemat E 10 15 parts.The Environment-friendlywear-resistant wear-resistant styrene-butadiene rubber that the present invention provides has excellent mechanical property, and wear-resisting, and service life is long, and technique is simple, low production cost, environment-protecting asepsis.

Description

A kind of Environment-friendlywear-resistant wear-resistant styrene-butadiene rubber
Technical field
The invention belongs to polymeric material field, be specifically related to a kind of Environment-friendlywear-resistant wear-resistant styrene-butadiene rubber.
Background technology
Rubber is that the institutes such as manufacture aircraft, warship, automobile, tractor, harvester, the water conservancy mechanical facilities of irrigation and drainage, medical apparatus and instruments are required Material.According to source difference, rubber can be divided into natural rubber and synthetic rubber.Synthetic rubber has the performance of minority kind Similar to natural rubber, great majority are different from natural rubber, but the most elastomeric macromolecular material, be typically both needed to through After sulfuration and processing, just there is practicality and use value.Synthetic rubber started to produce in 20 beginnings of the century, from the forties Arrive rapid development.Synthetic rubber is typically comprehensive not as natural rubber in performance, but it has high resiliency, insulating properties, gas The performances such as close property, oil resistant, high temperature resistant or low temperature, thus be widely used in industrial or agricultural, national defence, traffic and daily life.Rubber Industry is one of important foundation industry of national economy.It not only provides daily life indispensable daily, medical for people Deng light industry rubber product, and provide various rubber systems to the heavy industry such as digging, traffic, building, machinery, electronics and new industry Production equipment or rubber components.Visible, the product category of rubber industry is various, and backward industry is the most wide.Asia accounts for this moment The half of the country that whole world synthetic rubber produces, Ge great synthetic rubber enterprise falls over each other to invest countries in Asia, and unit scale more comes The biggest, add that American-European synthetic rubber production capacity substantially shifts to Asia, the elastomeric production in Asia from now on will gradually occupy entirely Ball leading position.
In recent years, the developing state of synthetic rubber industry made people joyful.Along with production-scale continuous expansion, synthesize rubber Glue industry will will occupy more importantly status in CHINESE INDUSTRIES economy.Logical development in a few years, Domestic Synthetic Rubber industry Achieve significant progress.Either annual production and consumption figure, has clamp-oned prostatitis, the world.
Butadiene-styrene rubber (SBR), also known as polystyrenebutadienes copolymer.Its physical mechanism performance, processing characteristics and goods Serviceability close to natural rubber, some performance is the most wear-resisting, heat-resisting, ageing-resistant and curingprocess rate is the most excellent compared with natural rubber Good, can with natural rubber and various synthetic rubber use, be widely used in tire, adhesive tape, sebific duct, electric wire, medical apparatus and The fields such as the production of various rubbers, are maximum general purpose synthetic rubber kinds, are also the rubbers realizing industrialized production the earliest One of glue kind.Shortcoming is that description is few, and anti-wear performance is the poorest, it is impossible to meet the requirement to rubber.
The most how overcoming the deficiencies in the prior art is the problem that current those skilled in the art need solution badly.
Summary of the invention
It is an object of the invention to provide a kind of Environment-friendlywear-resistant wear-resistant styrene-butadiene rubber.
To achieve these goals, the invention provides a kind of Environment-friendlywear-resistant wear-resistant styrene-butadiene rubber, by following weight portion Raw material prepares: butadiene-styrene rubber 50-60 part, dual-tert-butyl peroxy isopropyl base benzene 2-6 part, ethylene bis stearamide 2-5 part, aluminium nitride 3-5 part, acetic acid 10-15 part, magnesium chloride 1-4 part, glycerol 3-7 part, lime water 40-50 part, waterglass 30-40 part, Tissuemat E 10-15 part.
Preferred version is to be prepared by the raw material of following weight portion: 50 parts of butadiene-styrene rubber, dual-tert-butyl peroxy isopropyl base benzene 2 Part, ethylene bis stearamide 2 parts, aluminium nitride 3 parts, acetic acid 10 parts, 1 part of magnesium chloride, glycerol 3 parts, lime water 40 parts, waterglass 30 Part, Tissuemat E 10 parts.
Preferred version is to be prepared by the raw material of following weight portion: 60 parts of butadiene-styrene rubber, dual-tert-butyl peroxy isopropyl base benzene 6 Part, ethylene bis stearamide 5 parts, aluminium nitride 5 parts, acetic acid 15 parts, 4 parts of magnesium chloride, glycerol 7 parts, lime water 50 parts, waterglass 40 Part, Tissuemat E 15 parts.
Preferred version is to be prepared by the raw material of following weight portion: 52 parts of butadiene-styrene rubber, dual-tert-butyl peroxy isopropyl base benzene 3 Part, ethylene bis stearamide 3 parts, aluminium nitride 4 parts, acetic acid 12 parts, 2 parts of magnesium chloride, glycerol 4 parts, lime water 42 parts, waterglass 32 Part, Tissuemat E 12 parts.
Preferred version is to be prepared by the raw material of following weight portion: 58 parts of butadiene-styrene rubber, dual-tert-butyl peroxy isopropyl base benzene 5 Part, ethylene bis stearamide 4 parts, aluminium nitride 4 parts, acetic acid 14 parts, 3 parts of magnesium chloride, glycerol 6 parts, lime water 48 parts, waterglass 38 Part, Tissuemat E 14 parts.
Its preparation method is: first each component is joined in vacuum kneader or banbury after mix homogeneously, then passes through Synthetic rubber molding, the mould finally put in vulcanizer by molded rubber are vulcanized by mill.
The method have the advantages that the Environment-friendlywear-resistant wear-resistant styrene-butadiene rubber that the present invention provides has excellent mechanics Performance, and wear-resisting, service life is long, and technique is simple, low production cost, environment-protecting asepsis.
Detailed description of the invention
Embodiment 1
A kind of Environment-friendlywear-resistant wear-resistant styrene-butadiene rubber of the present embodiment, is prepared by the raw material of following weight portion: butadiene-styrene rubber 50 Part, dual-tert-butyl peroxy isopropyl base benzene 2 parts, ethylene bis stearamide 2 parts, aluminium nitride 3 parts, acetic acid 10 parts, 1 part of magnesium chloride, sweet Oil 3 parts, lime water 40 parts, waterglass 30 parts, Tissuemat E 10 parts.
Preparation method is: first join in vacuum kneader or banbury after mix homogeneously by each component, then by opening Synthetic rubber molding, the mould finally put in vulcanizer by molded rubber are vulcanized by refining machine.
Embodiment 2
A kind of Environment-friendlywear-resistant wear-resistant styrene-butadiene rubber of the present embodiment, is prepared by the raw material of following weight portion: butadiene-styrene rubber 60 Part, dual-tert-butyl peroxy isopropyl base benzene 6 parts, ethylene bis stearamide 5 parts, aluminium nitride 5 parts, acetic acid 15 parts, 4 parts of magnesium chloride, sweet Oil 7 parts, lime water 50 parts, waterglass 40 parts, Tissuemat E 15 parts.
Preparation method is: first join in vacuum kneader or banbury after mix homogeneously by each component, then by opening Synthetic rubber molding, the mould finally put in vulcanizer by molded rubber are vulcanized by refining machine.
Embodiment 3
A kind of Environment-friendlywear-resistant wear-resistant styrene-butadiene rubber of the present embodiment, is prepared by the raw material of following weight portion: butadiene-styrene rubber 52 Part, dual-tert-butyl peroxy isopropyl base benzene 3 parts, ethylene bis stearamide 3 parts, aluminium nitride 4 parts, acetic acid 12 parts, 2 parts of magnesium chloride, sweet Oil 4 parts, lime water 42 parts, waterglass 32 parts, Tissuemat E 12 parts.
Preparation method is: first join in vacuum kneader or banbury after mix homogeneously by each component, then by opening Synthetic rubber molding, the mould finally put in vulcanizer by molded rubber are vulcanized by refining machine.
Embodiment 4
A kind of Environment-friendlywear-resistant wear-resistant styrene-butadiene rubber of the present embodiment, is prepared by the raw material of following weight portion: butadiene-styrene rubber 58 Part, dual-tert-butyl peroxy isopropyl base benzene 5 parts, ethylene bis stearamide 4 parts, aluminium nitride 4 parts, acetic acid 14 parts, 3 parts of magnesium chloride, sweet Oil 6 parts, lime water 48 parts, waterglass 38 parts, Tissuemat E 14 parts.
Preparation method is: first join in vacuum kneader or banbury after mix homogeneously by each component, then by opening Synthetic rubber molding, the mould finally put in vulcanizer by molded rubber are vulcanized by refining machine.

Claims (5)

1. an Environment-friendlywear-resistant wear-resistant styrene-butadiene rubber, it is characterised in that include the raw material of following weight portion: butadiene-styrene rubber 50-60 Part, dual-tert-butyl peroxy isopropyl base benzene 2-6 part, ethylene bis stearamide 2-5 part, aluminium nitride 3-5 part, acetic acid 10-15 part, chlorination Magnesium 1-4 part, glycerol 3-7 part, lime water 40-50 part, waterglass 30-40 part, Tissuemat E 10-15 part.
A kind of Environment-friendlywear-resistant wear-resistant styrene-butadiene rubber the most according to claim 1, it is characterised in that former by following weight portion Material prepares: 50 parts of butadiene-styrene rubber, dual-tert-butyl peroxy isopropyl base benzene 2 parts, ethylene bis stearamide 2 parts, aluminium nitride 3 parts, acetic acid 10 parts, 1 part of magnesium chloride, glycerol 3 parts, lime water 40 parts, waterglass 30 parts, Tissuemat E 10 parts.
A kind of Environment-friendlywear-resistant wear-resistant styrene-butadiene rubber the most according to claim 1, it is characterised in that former by following weight portion Material prepares: 60 parts of butadiene-styrene rubber, dual-tert-butyl peroxy isopropyl base benzene 6 parts, ethylene bis stearamide 5 parts, aluminium nitride 5 parts, acetic acid 15 parts, 4 parts of magnesium chloride, glycerol 7 parts, lime water 50 parts, waterglass 40 parts, Tissuemat E 15 parts.
A kind of Environment-friendlywear-resistant wear-resistant styrene-butadiene rubber the most according to claim 1, it is characterised in that former by following weight portion Material prepares: 52 parts of butadiene-styrene rubber, dual-tert-butyl peroxy isopropyl base benzene 3 parts, ethylene bis stearamide 3 parts, aluminium nitride 4 parts, acetic acid 12 parts, 2 parts of magnesium chloride, glycerol 4 parts, lime water 42 parts, waterglass 32 parts, Tissuemat E 12 parts.
A kind of Environment-friendlywear-resistant wear-resistant styrene-butadiene rubber the most according to claim 1, it is characterised in that former by following weight portion Material prepares: 58 parts of butadiene-styrene rubber, dual-tert-butyl peroxy isopropyl base benzene 5 parts, ethylene bis stearamide 4 parts, aluminium nitride 4 parts, acetic acid 14 parts, 3 parts of magnesium chloride, glycerol 6 parts, lime water 48 parts, waterglass 38 parts, Tissuemat E 14 parts.
CN201610618657.3A 2016-07-28 2016-07-28 A kind of Environment-friendlywear-resistant wear-resistant styrene-butadiene rubber Pending CN106243425A (en)

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CN201610618657.3A CN106243425A (en) 2016-07-28 2016-07-28 A kind of Environment-friendlywear-resistant wear-resistant styrene-butadiene rubber

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Application Number Priority Date Filing Date Title
CN201610618657.3A CN106243425A (en) 2016-07-28 2016-07-28 A kind of Environment-friendlywear-resistant wear-resistant styrene-butadiene rubber

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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1727387A (en) * 2004-07-28 2006-02-01 纳拉化学株式会社 Rubber compsns. for cleaning and stripping mould
CN103059398A (en) * 2012-12-18 2013-04-24 滁州凯凯建筑节能有限公司 Polyethylene/SBR (Styrene Butadiene Rubber) coating coconut husk powder particle blending foaming material and preparation method thereof
CN105111544A (en) * 2015-08-18 2015-12-02 合肥市再德高分子材料有限公司 High-performance modified styrene butadiene rubber composition

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1727387A (en) * 2004-07-28 2006-02-01 纳拉化学株式会社 Rubber compsns. for cleaning and stripping mould
CN103059398A (en) * 2012-12-18 2013-04-24 滁州凯凯建筑节能有限公司 Polyethylene/SBR (Styrene Butadiene Rubber) coating coconut husk powder particle blending foaming material and preparation method thereof
CN105111544A (en) * 2015-08-18 2015-12-02 合肥市再德高分子材料有限公司 High-performance modified styrene butadiene rubber composition

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