CN106117655A - A kind of anti-slippery butadiene rubber material - Google Patents

A kind of anti-slippery butadiene rubber material Download PDF

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Publication number
CN106117655A
CN106117655A CN201610620191.0A CN201610620191A CN106117655A CN 106117655 A CN106117655 A CN 106117655A CN 201610620191 A CN201610620191 A CN 201610620191A CN 106117655 A CN106117655 A CN 106117655A
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CN
China
Prior art keywords
parts
butadiene rubber
slippery
rubber
rubber material
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Pending
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CN201610620191.0A
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Chinese (zh)
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王莹
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Individual
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Individual
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Priority to CN201610620191.0A priority Critical patent/CN106117655A/en
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L9/00Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2207/00Properties characterising the ingredient of the composition
    • C08L2207/06Properties of polyethylene
    • C08L2207/062HDPE

Abstract

The invention discloses a kind of anti-slippery butadiene rubber material, including the raw material of following weight portion: high density polyethylene (HDPE) 50 55 parts, CSM 20 25 parts, polyvinyl butyral resin 59 parts, alkylphenol polyoxyethylene 24 parts, polyvinyl alcohol 15 20 parts, pelopon A 48 parts, potassium peroxydisulfate 26 parts, carbon tetrachloride 12 parts, pentachlorophenol 25 parts, butadiene rubber 100 120 parts.The made product of anti-slippery butadiene rubber material that the present invention provides has higher anti-slippery, safety and environmental protection, has excellent mechanical property simultaneously, and wear-resisting, service life is long.

Description

A kind of anti-slippery butadiene rubber material
Technical field
The invention belongs to polymeric material field, be specifically related to a kind of anti-slippery butadiene rubber material.
Background technology
Rubber is that the institutes such as manufacture aircraft, warship, automobile, tractor, harvester, the water conservancy mechanical facilities of irrigation and drainage, medical apparatus and instruments are required Material.According to source difference, rubber can be divided into natural rubber and synthetic rubber.Synthetic rubber has the performance of minority kind Similar to natural rubber, great majority are different from natural rubber, but the most elastomeric macromolecular material, be typically both needed to through After sulfuration and processing, just there is practicality and use value.Synthetic rubber started to produce in 20 beginnings of the century, from the forties Arrive rapid development.Synthetic rubber is typically comprehensive not as natural rubber in performance, but it has high resiliency, insulating properties, gas The performances such as close property, oil resistant, high temperature resistant or low temperature, thus be widely used in industrial or agricultural, national defence, traffic and daily life.Rubber Industry is one of important foundation industry of national economy.It not only provides daily life indispensable daily, medical for people Deng light industry rubber product, and provide various rubber systems to the heavy industry such as digging, traffic, building, machinery, electronics and new industry Production equipment or rubber components.Visible, the product category of rubber industry is various, and backward industry is the most wide.Asia accounts for this moment The half of the country that whole world synthetic rubber produces, Ge great synthetic rubber enterprise falls over each other to invest countries in Asia, and unit scale more comes The biggest, add that American-European synthetic rubber production capacity substantially shifts to Asia, the elastomeric production in Asia from now on will gradually occupy entirely Ball leading position.
In recent years, the developing state of synthetic rubber industry made people joyful.Along with production-scale continuous expansion, synthesize rubber Glue industry will will occupy more importantly status in CHINESE INDUSTRIES economy.Logical development in a few years, Domestic Synthetic Rubber industry Achieve significant progress.Either annual production and consumption figure, has clamp-oned prostatitis, the world.
Butadiene rubber is the abbreviation of cis-1,4-polybutadiene rubber, and its molecular formula is (C4H6) n.Butadiene rubber be by The synthetic rubber of the compound with regular structure of polymerizing butadiene, its cis-structure content is more than 95%.According to the difference of catalyst, It is divided into nickel system, cobalt system, titanium system and Rare Earth (neodymium series) butadiene rubber.Butadiene rubber is the second largest conjunction being only second to butadiene-styrene rubber Become rubber.Compared with natural rubber and butadiene-styrene rubber, after sulfuration, its tolerance to cold, wearability and elasticity are the most excellent, under dynamic load Heating is few, and resistance to ag(e)ing is fair, easily with natural rubber, neoprene or nitrile rubber use.Butadiene rubber is particularly well-suited to manufacture Automobile tire and cold-resistant goods, it is also possible to manufacture padded coaming and various rubber overshoes, adhesive plaster, adhesive tape and sandwich rubber etc..But at present The domestic butadiene rubber great majority that produce have the shortcoming that wet-sliding resistant performance is bad.
The most how overcoming the deficiencies in the prior art is the problem that current those skilled in the art need solution badly.
Summary of the invention
It is an object of the invention to provide a kind of anti-slippery butadiene rubber material.
To achieve these goals, the invention provides a kind of anti-slippery butadiene rubber material, former by following weight portion Material prepares: high density polyethylene (HDPE) 50-55 part, CSM 20-25 part, polyvinyl butyral resin 5-9 part, alkyl phenol Polyoxyethylene ether 2-4 part, polyvinyl alcohol 15-20 part, pelopon A 4-8 part, potassium peroxydisulfate 2-6 part, four chlorinations Carbon 1-2 part, pentachlorophenol 2-5 part, butadiene rubber 100-120 part.
Preferred version is to be prepared by the raw material of following weight portion: high density polyethylene (HDPE) 50 parts, CSM 20 Part, polyvinyl butyral resin 5 parts, alkylphenol polyoxyethylene 2 parts, polyvinyl alcohol 15 parts, pelopon A 4 parts, Potassium peroxydisulfate 2 parts, carbon tetrachloride 1 part, pentachlorophenol 2 parts, butadiene rubber 100 parts.
Preferred version is to be prepared by the raw material of following weight portion: high density polyethylene (HDPE) 55 parts, CSM 25 Part, polyvinyl butyral resin 9 parts, alkylphenol polyoxyethylene 4 parts, polyvinyl alcohol 20 parts, pelopon A 8 parts, Potassium peroxydisulfate 6 parts, carbon tetrachloride 2 parts, pentachlorophenol 5 parts, butadiene rubber 120 parts.
Preferred version is to be prepared by the raw material of following weight portion: high density polyethylene (HDPE) 52 parts, CSM 22 Part, polyvinyl butyral resin 6 parts, alkylphenol polyoxyethylene 3 parts, polyvinyl alcohol 16 parts, pelopon A 5 parts, Potassium peroxydisulfate 3 parts, carbon tetrachloride 1 part, pentachlorophenol 3 parts, butadiene rubber 105 parts.
Preferred version is to be prepared by the raw material of following weight portion: high density polyethylene (HDPE) 54 parts, CSM 24 Part, polyvinyl butyral resin 8 parts, alkylphenol polyoxyethylene 3 parts, polyvinyl alcohol 18 parts, pelopon A 7 parts, Potassium peroxydisulfate 5 parts, carbon tetrachloride 2 parts, pentachlorophenol 4 parts, butadiene rubber 110 parts.
Its preparation method is: first each component is joined in vacuum kneader or banbury after mix homogeneously, then passes through Synthetic rubber molding, the mould finally put in vulcanizer by molded rubber are vulcanized by mill.
The method have the advantages that the made product of anti-slippery butadiene rubber material that the present invention provides has relatively High anti-slippery, safety and environmental protection, have excellent mechanical property simultaneously, and wear-resisting, service life is long.
Detailed description of the invention
Embodiment 1
The one anti-slippery butadiene rubber material of the present embodiment, is prepared by the raw material of following weight portion: high density polyethylene (HDPE) 50 parts, CSM 20 parts, polyvinyl butyral resin 5 parts, alkylphenol polyoxyethylene 2 parts, polyvinyl alcohol 15 parts, Pelopon A 4 parts, potassium peroxydisulfate 2 parts, carbon tetrachloride 1 part, pentachlorophenol 2 parts, butadiene rubber 100 parts.
Preparation method is: first join in vacuum kneader or banbury after mix homogeneously by each component, then by opening Synthetic rubber molding, the mould finally put in vulcanizer by molded rubber are vulcanized by refining machine.
Embodiment 2
The one anti-slippery butadiene rubber material of the present embodiment, is prepared by the raw material of following weight portion: high density polyethylene (HDPE) 55 parts, CSM 25 parts, polyvinyl butyral resin 9 parts, alkylphenol polyoxyethylene 4 parts, polyvinyl alcohol 20 parts, Pelopon A 8 parts, potassium peroxydisulfate 6 parts, carbon tetrachloride 2 parts, pentachlorophenol 5 parts, butadiene rubber 120 parts.
Preparation method is: first join in vacuum kneader or banbury after mix homogeneously by each component, then by opening Synthetic rubber molding, the mould finally put in vulcanizer by molded rubber are vulcanized by refining machine.
Embodiment 3
The one anti-slippery butadiene rubber material of the present embodiment, is prepared by the raw material of following weight portion: high density polyethylene (HDPE) 52 parts, CSM 22 parts, polyvinyl butyral resin 6 parts, alkylphenol polyoxyethylene 3 parts, polyvinyl alcohol 16 parts, Pelopon A 5 parts, potassium peroxydisulfate 3 parts, carbon tetrachloride 1 part, pentachlorophenol 3 parts, butadiene rubber 105 parts.
Preparation method is: first join in vacuum kneader or banbury after mix homogeneously by each component, then by opening Synthetic rubber molding, the mould finally put in vulcanizer by molded rubber are vulcanized by refining machine.
Embodiment 4
The one anti-slippery butadiene rubber material of the present embodiment, is prepared by the raw material of following weight portion: high density polyethylene (HDPE) 54 parts, CSM 24 parts, polyvinyl butyral resin 8 parts, alkylphenol polyoxyethylene 3 parts, polyvinyl alcohol 18 parts, Pelopon A 7 parts, potassium peroxydisulfate 5 parts, carbon tetrachloride 2 parts, pentachlorophenol 4 parts, butadiene rubber 110 parts.
Preparation method is: first join in vacuum kneader or banbury after mix homogeneously by each component, then by opening Synthetic rubber molding, the mould finally put in vulcanizer by molded rubber are vulcanized by refining machine.

Claims (5)

1. an anti-slippery butadiene rubber material, it is characterised in that include the raw material of following weight portion: high density polyethylene (HDPE) 50-55 Part, CSM 20-25 part, polyvinyl butyral resin 5-9 part, alkylphenol polyoxyethylene 2-4 part, polyvinyl alcohol 15-20 part, pelopon A 4-8 part, potassium peroxydisulfate 2-6 part, carbon tetrachloride 1-2 part, pentachlorophenol 2-5 part, suitable Buna 100-120 part.
One the most according to claim 1 anti-slippery butadiene rubber material, it is characterised in that by the raw material of following weight portion Prepare: high density polyethylene (HDPE) 50 parts, CSM 20 parts, polyvinyl butyral resin 5 parts, alkylphenol polyoxyethylene 2 parts, polyvinyl alcohol 15 parts, pelopon A 4 parts, potassium peroxydisulfate 2 parts, carbon tetrachloride 1 part, pentachlorophenol 2 parts, suitable Buna 100 parts.
One the most according to claim 1 anti-slippery butadiene rubber material, it is characterised in that by the raw material of following weight portion Prepare: high density polyethylene (HDPE) 55 parts, CSM 25 parts, polyvinyl butyral resin 9 parts, alkylphenol polyoxyethylene 4 parts, polyvinyl alcohol 20 parts, pelopon A 8 parts, potassium peroxydisulfate 6 parts, carbon tetrachloride 2 parts, pentachlorophenol 5 parts, suitable Buna 120 parts.
One the most according to claim 1 anti-slippery butadiene rubber material, it is characterised in that by the raw material of following weight portion Prepare: high density polyethylene (HDPE) 52 parts, CSM 22 parts, polyvinyl butyral resin 6 parts, alkylphenol polyoxyethylene 3 parts, polyvinyl alcohol 16 parts, pelopon A 5 parts, potassium peroxydisulfate 3 parts, carbon tetrachloride 1 part, pentachlorophenol 3 parts, suitable Buna 105 parts.
One the most according to claim 1 anti-slippery butadiene rubber material, it is characterised in that by the raw material of following weight portion Prepare: high density polyethylene (HDPE) 54 parts, CSM 24 parts, polyvinyl butyral resin 8 parts, alkylphenol polyoxyethylene 3 parts, polyvinyl alcohol 18 parts, pelopon A 7 parts, potassium peroxydisulfate 5 parts, carbon tetrachloride 2 parts, pentachlorophenol 4 parts, suitable Buna 110 parts.
CN201610620191.0A 2016-07-29 2016-07-29 A kind of anti-slippery butadiene rubber material Pending CN106117655A (en)

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CN201610620191.0A CN106117655A (en) 2016-07-29 2016-07-29 A kind of anti-slippery butadiene rubber material

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Application Number Priority Date Filing Date Title
CN201610620191.0A CN106117655A (en) 2016-07-29 2016-07-29 A kind of anti-slippery butadiene rubber material

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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102311588A (en) * 2011-07-20 2012-01-11 中国皮革和制鞋工业研究院 Lightweight, flame retardant and rubber foaming sole material and manufacturing method thereof
CN105440350A (en) * 2015-12-16 2016-03-30 合肥杰明新材料科技有限公司 Ageing resistant butadiene rubber material and preparation method thereof
CN105622999A (en) * 2016-03-18 2016-06-01 安徽三联泵业股份有限公司 Production technology of pump-used cushion rubber

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102311588A (en) * 2011-07-20 2012-01-11 中国皮革和制鞋工业研究院 Lightweight, flame retardant and rubber foaming sole material and manufacturing method thereof
CN105440350A (en) * 2015-12-16 2016-03-30 合肥杰明新材料科技有限公司 Ageing resistant butadiene rubber material and preparation method thereof
CN105622999A (en) * 2016-03-18 2016-06-01 安徽三联泵业股份有限公司 Production technology of pump-used cushion rubber

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
赖逸云等: "BR/HDPE动态硫化共混体系橡塑并用材料的研究", 《弹性体》 *

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Application publication date: 20161116