CN106117655A - A kind of anti-slippery butadiene rubber material - Google Patents
A kind of anti-slippery butadiene rubber material Download PDFInfo
- Publication number
- CN106117655A CN106117655A CN201610620191.0A CN201610620191A CN106117655A CN 106117655 A CN106117655 A CN 106117655A CN 201610620191 A CN201610620191 A CN 201610620191A CN 106117655 A CN106117655 A CN 106117655A
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- Prior art keywords
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- butadiene rubber
- slippery
- rubber
- rubber material
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2207/00—Properties characterising the ingredient of the composition
- C08L2207/06—Properties of polyethylene
- C08L2207/062—HDPE
Abstract
The invention discloses a kind of anti-slippery butadiene rubber material, including the raw material of following weight portion: high density polyethylene (HDPE) 50 55 parts, CSM 20 25 parts, polyvinyl butyral resin 59 parts, alkylphenol polyoxyethylene 24 parts, polyvinyl alcohol 15 20 parts, pelopon A 48 parts, potassium peroxydisulfate 26 parts, carbon tetrachloride 12 parts, pentachlorophenol 25 parts, butadiene rubber 100 120 parts.The made product of anti-slippery butadiene rubber material that the present invention provides has higher anti-slippery, safety and environmental protection, has excellent mechanical property simultaneously, and wear-resisting, service life is long.
Description
Technical field
The invention belongs to polymeric material field, be specifically related to a kind of anti-slippery butadiene rubber material.
Background technology
Rubber is that the institutes such as manufacture aircraft, warship, automobile, tractor, harvester, the water conservancy mechanical facilities of irrigation and drainage, medical apparatus and instruments are required
Material.According to source difference, rubber can be divided into natural rubber and synthetic rubber.Synthetic rubber has the performance of minority kind
Similar to natural rubber, great majority are different from natural rubber, but the most elastomeric macromolecular material, be typically both needed to through
After sulfuration and processing, just there is practicality and use value.Synthetic rubber started to produce in 20 beginnings of the century, from the forties
Arrive rapid development.Synthetic rubber is typically comprehensive not as natural rubber in performance, but it has high resiliency, insulating properties, gas
The performances such as close property, oil resistant, high temperature resistant or low temperature, thus be widely used in industrial or agricultural, national defence, traffic and daily life.Rubber
Industry is one of important foundation industry of national economy.It not only provides daily life indispensable daily, medical for people
Deng light industry rubber product, and provide various rubber systems to the heavy industry such as digging, traffic, building, machinery, electronics and new industry
Production equipment or rubber components.Visible, the product category of rubber industry is various, and backward industry is the most wide.Asia accounts for this moment
The half of the country that whole world synthetic rubber produces, Ge great synthetic rubber enterprise falls over each other to invest countries in Asia, and unit scale more comes
The biggest, add that American-European synthetic rubber production capacity substantially shifts to Asia, the elastomeric production in Asia from now on will gradually occupy entirely
Ball leading position.
In recent years, the developing state of synthetic rubber industry made people joyful.Along with production-scale continuous expansion, synthesize rubber
Glue industry will will occupy more importantly status in CHINESE INDUSTRIES economy.Logical development in a few years, Domestic Synthetic Rubber industry
Achieve significant progress.Either annual production and consumption figure, has clamp-oned prostatitis, the world.
Butadiene rubber is the abbreviation of cis-1,4-polybutadiene rubber, and its molecular formula is (C4H6) n.Butadiene rubber be by
The synthetic rubber of the compound with regular structure of polymerizing butadiene, its cis-structure content is more than 95%.According to the difference of catalyst,
It is divided into nickel system, cobalt system, titanium system and Rare Earth (neodymium series) butadiene rubber.Butadiene rubber is the second largest conjunction being only second to butadiene-styrene rubber
Become rubber.Compared with natural rubber and butadiene-styrene rubber, after sulfuration, its tolerance to cold, wearability and elasticity are the most excellent, under dynamic load
Heating is few, and resistance to ag(e)ing is fair, easily with natural rubber, neoprene or nitrile rubber use.Butadiene rubber is particularly well-suited to manufacture
Automobile tire and cold-resistant goods, it is also possible to manufacture padded coaming and various rubber overshoes, adhesive plaster, adhesive tape and sandwich rubber etc..But at present
The domestic butadiene rubber great majority that produce have the shortcoming that wet-sliding resistant performance is bad.
The most how overcoming the deficiencies in the prior art is the problem that current those skilled in the art need solution badly.
Summary of the invention
It is an object of the invention to provide a kind of anti-slippery butadiene rubber material.
To achieve these goals, the invention provides a kind of anti-slippery butadiene rubber material, former by following weight portion
Material prepares: high density polyethylene (HDPE) 50-55 part, CSM 20-25 part, polyvinyl butyral resin 5-9 part, alkyl phenol
Polyoxyethylene ether 2-4 part, polyvinyl alcohol 15-20 part, pelopon A 4-8 part, potassium peroxydisulfate 2-6 part, four chlorinations
Carbon 1-2 part, pentachlorophenol 2-5 part, butadiene rubber 100-120 part.
Preferred version is to be prepared by the raw material of following weight portion: high density polyethylene (HDPE) 50 parts, CSM 20
Part, polyvinyl butyral resin 5 parts, alkylphenol polyoxyethylene 2 parts, polyvinyl alcohol 15 parts, pelopon A 4 parts,
Potassium peroxydisulfate 2 parts, carbon tetrachloride 1 part, pentachlorophenol 2 parts, butadiene rubber 100 parts.
Preferred version is to be prepared by the raw material of following weight portion: high density polyethylene (HDPE) 55 parts, CSM 25
Part, polyvinyl butyral resin 9 parts, alkylphenol polyoxyethylene 4 parts, polyvinyl alcohol 20 parts, pelopon A 8 parts,
Potassium peroxydisulfate 6 parts, carbon tetrachloride 2 parts, pentachlorophenol 5 parts, butadiene rubber 120 parts.
Preferred version is to be prepared by the raw material of following weight portion: high density polyethylene (HDPE) 52 parts, CSM 22
Part, polyvinyl butyral resin 6 parts, alkylphenol polyoxyethylene 3 parts, polyvinyl alcohol 16 parts, pelopon A 5 parts,
Potassium peroxydisulfate 3 parts, carbon tetrachloride 1 part, pentachlorophenol 3 parts, butadiene rubber 105 parts.
Preferred version is to be prepared by the raw material of following weight portion: high density polyethylene (HDPE) 54 parts, CSM 24
Part, polyvinyl butyral resin 8 parts, alkylphenol polyoxyethylene 3 parts, polyvinyl alcohol 18 parts, pelopon A 7 parts,
Potassium peroxydisulfate 5 parts, carbon tetrachloride 2 parts, pentachlorophenol 4 parts, butadiene rubber 110 parts.
Its preparation method is: first each component is joined in vacuum kneader or banbury after mix homogeneously, then passes through
Synthetic rubber molding, the mould finally put in vulcanizer by molded rubber are vulcanized by mill.
The method have the advantages that the made product of anti-slippery butadiene rubber material that the present invention provides has relatively
High anti-slippery, safety and environmental protection, have excellent mechanical property simultaneously, and wear-resisting, service life is long.
Detailed description of the invention
Embodiment 1
The one anti-slippery butadiene rubber material of the present embodiment, is prepared by the raw material of following weight portion: high density polyethylene (HDPE)
50 parts, CSM 20 parts, polyvinyl butyral resin 5 parts, alkylphenol polyoxyethylene 2 parts, polyvinyl alcohol 15 parts,
Pelopon A 4 parts, potassium peroxydisulfate 2 parts, carbon tetrachloride 1 part, pentachlorophenol 2 parts, butadiene rubber 100 parts.
Preparation method is: first join in vacuum kneader or banbury after mix homogeneously by each component, then by opening
Synthetic rubber molding, the mould finally put in vulcanizer by molded rubber are vulcanized by refining machine.
Embodiment 2
The one anti-slippery butadiene rubber material of the present embodiment, is prepared by the raw material of following weight portion: high density polyethylene (HDPE)
55 parts, CSM 25 parts, polyvinyl butyral resin 9 parts, alkylphenol polyoxyethylene 4 parts, polyvinyl alcohol 20 parts,
Pelopon A 8 parts, potassium peroxydisulfate 6 parts, carbon tetrachloride 2 parts, pentachlorophenol 5 parts, butadiene rubber 120 parts.
Preparation method is: first join in vacuum kneader or banbury after mix homogeneously by each component, then by opening
Synthetic rubber molding, the mould finally put in vulcanizer by molded rubber are vulcanized by refining machine.
Embodiment 3
The one anti-slippery butadiene rubber material of the present embodiment, is prepared by the raw material of following weight portion: high density polyethylene (HDPE)
52 parts, CSM 22 parts, polyvinyl butyral resin 6 parts, alkylphenol polyoxyethylene 3 parts, polyvinyl alcohol 16 parts,
Pelopon A 5 parts, potassium peroxydisulfate 3 parts, carbon tetrachloride 1 part, pentachlorophenol 3 parts, butadiene rubber 105 parts.
Preparation method is: first join in vacuum kneader or banbury after mix homogeneously by each component, then by opening
Synthetic rubber molding, the mould finally put in vulcanizer by molded rubber are vulcanized by refining machine.
Embodiment 4
The one anti-slippery butadiene rubber material of the present embodiment, is prepared by the raw material of following weight portion: high density polyethylene (HDPE)
54 parts, CSM 24 parts, polyvinyl butyral resin 8 parts, alkylphenol polyoxyethylene 3 parts, polyvinyl alcohol 18 parts,
Pelopon A 7 parts, potassium peroxydisulfate 5 parts, carbon tetrachloride 2 parts, pentachlorophenol 4 parts, butadiene rubber 110 parts.
Preparation method is: first join in vacuum kneader or banbury after mix homogeneously by each component, then by opening
Synthetic rubber molding, the mould finally put in vulcanizer by molded rubber are vulcanized by refining machine.
Claims (5)
1. an anti-slippery butadiene rubber material, it is characterised in that include the raw material of following weight portion: high density polyethylene (HDPE) 50-55
Part, CSM 20-25 part, polyvinyl butyral resin 5-9 part, alkylphenol polyoxyethylene 2-4 part, polyvinyl alcohol
15-20 part, pelopon A 4-8 part, potassium peroxydisulfate 2-6 part, carbon tetrachloride 1-2 part, pentachlorophenol 2-5 part, suitable
Buna 100-120 part.
One the most according to claim 1 anti-slippery butadiene rubber material, it is characterised in that by the raw material of following weight portion
Prepare: high density polyethylene (HDPE) 50 parts, CSM 20 parts, polyvinyl butyral resin 5 parts, alkylphenol polyoxyethylene
2 parts, polyvinyl alcohol 15 parts, pelopon A 4 parts, potassium peroxydisulfate 2 parts, carbon tetrachloride 1 part, pentachlorophenol 2 parts, suitable
Buna 100 parts.
One the most according to claim 1 anti-slippery butadiene rubber material, it is characterised in that by the raw material of following weight portion
Prepare: high density polyethylene (HDPE) 55 parts, CSM 25 parts, polyvinyl butyral resin 9 parts, alkylphenol polyoxyethylene
4 parts, polyvinyl alcohol 20 parts, pelopon A 8 parts, potassium peroxydisulfate 6 parts, carbon tetrachloride 2 parts, pentachlorophenol 5 parts, suitable
Buna 120 parts.
One the most according to claim 1 anti-slippery butadiene rubber material, it is characterised in that by the raw material of following weight portion
Prepare: high density polyethylene (HDPE) 52 parts, CSM 22 parts, polyvinyl butyral resin 6 parts, alkylphenol polyoxyethylene
3 parts, polyvinyl alcohol 16 parts, pelopon A 5 parts, potassium peroxydisulfate 3 parts, carbon tetrachloride 1 part, pentachlorophenol 3 parts, suitable
Buna 105 parts.
One the most according to claim 1 anti-slippery butadiene rubber material, it is characterised in that by the raw material of following weight portion
Prepare: high density polyethylene (HDPE) 54 parts, CSM 24 parts, polyvinyl butyral resin 8 parts, alkylphenol polyoxyethylene
3 parts, polyvinyl alcohol 18 parts, pelopon A 7 parts, potassium peroxydisulfate 5 parts, carbon tetrachloride 2 parts, pentachlorophenol 4 parts, suitable
Buna 110 parts.
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CN201610620191.0A CN106117655A (en) | 2016-07-29 | 2016-07-29 | A kind of anti-slippery butadiene rubber material |
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Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102311588A (en) * | 2011-07-20 | 2012-01-11 | 中国皮革和制鞋工业研究院 | Lightweight, flame retardant and rubber foaming sole material and manufacturing method thereof |
CN105440350A (en) * | 2015-12-16 | 2016-03-30 | 合肥杰明新材料科技有限公司 | Ageing resistant butadiene rubber material and preparation method thereof |
CN105622999A (en) * | 2016-03-18 | 2016-06-01 | 安徽三联泵业股份有限公司 | Production technology of pump-used cushion rubber |
-
2016
- 2016-07-29 CN CN201610620191.0A patent/CN106117655A/en active Pending
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102311588A (en) * | 2011-07-20 | 2012-01-11 | 中国皮革和制鞋工业研究院 | Lightweight, flame retardant and rubber foaming sole material and manufacturing method thereof |
CN105440350A (en) * | 2015-12-16 | 2016-03-30 | 合肥杰明新材料科技有限公司 | Ageing resistant butadiene rubber material and preparation method thereof |
CN105622999A (en) * | 2016-03-18 | 2016-06-01 | 安徽三联泵业股份有限公司 | Production technology of pump-used cushion rubber |
Non-Patent Citations (1)
Title |
---|
赖逸云等: "BR/HDPE动态硫化共混体系橡塑并用材料的研究", 《弹性体》 * |
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Application publication date: 20161116 |