CN106243399A - A kind of high resilience polyurethane composite - Google Patents

A kind of high resilience polyurethane composite Download PDF

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Publication number
CN106243399A
CN106243399A CN201610688586.4A CN201610688586A CN106243399A CN 106243399 A CN106243399 A CN 106243399A CN 201610688586 A CN201610688586 A CN 201610688586A CN 106243399 A CN106243399 A CN 106243399A
Authority
CN
China
Prior art keywords
parts
polyurethane composite
high resilience
dimethicone
resilience polyurethane
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610688586.4A
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Chinese (zh)
Inventor
张复光
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Tongcheng City Hong Ye Plastic Co Ltd
Original Assignee
Tongcheng City Hong Ye Plastic Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Tongcheng City Hong Ye Plastic Co Ltd filed Critical Tongcheng City Hong Ye Plastic Co Ltd
Priority to CN201610688586.4A priority Critical patent/CN106243399A/en
Publication of CN106243399A publication Critical patent/CN106243399A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L3/00Compositions of starch, amylose or amylopectin or of their derivatives or degradation products
    • C08L3/02Starch; Degradation products thereof, e.g. dextrin
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L75/00Compositions of polyureas or polyurethanes; Compositions of derivatives of such polymers
    • C08L75/04Polyurethanes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend

Abstract

The open a kind of high resilience polyurethane composite of the present invention, by weight, including following raw material components: corn starch 60 70 parts, isocyanates 15 20 parts, zinc oxide 26 parts, Boehmeria boon 58 parts, melamine cyanurate salt 9 13 parts, carborundum 6 12 parts, ammonium heptamolybdate 37 parts, boron carbide 12 25 parts, glass fibre 23 29 parts, ceramic fibre 12 23 parts, aluminium sesquioxide 23 27 parts, titanium dioxide 13 parts, tetraethylthiuram disulfide 37 parts, N phenyl αnaphthylamine 4 10 parts, 37 parts of barium sulfate, phthalic acid list Octyl Nitrite 37 parts, antimony oxide 0.5 2 parts, deca-BDE 25 parts, dimethicone 15 parts, diethyldithiocar bamic acid 12 parts.Raw materials for production of the present invention are simple and easy to get, with low cost, and elastic properties of materials is high, and fatigue strength is high;Technique is simple, discharges without harmful gas.

Description

A kind of high resilience polyurethane composite
Technical field
The present invention relates to field of material technology, specifically a kind of high resilience polyurethane composite.
Background technology
Polyurethane is a kind of characteristic having rubber and plastics concurrently, and its performance is again adjustable brand-new material, uses polyurethane Manufacture the scope involved by goods widely, including polyurethane foam plastics, elastomer, coating, synthetic fibers etc.. Polyurethane synthetic material has any other commercial rubber and plastics all without the performance of language rival, the most wear-resisting, high intensity, Gao Shen Contracting, high resiliency, be devoted to by the way of adjusting raw material to develop multiple high-tech for many years in polyurethanes technology field always Goods.
Skateboarding substantially makes with wooden plywood's material at present, there is complex process, easily comes unglued, easy fracture, Fatigue strength is low, has solvent to volatilize in the fabrication process, to problems such as environments..
Summary of the invention
It is an object of the invention to provide a kind of high resilience polyurethane composite.
The purpose of the present invention can be achieved through the following technical solutions:
A kind of high resilience polyurethane composite, by weight, including following raw material components: corn starch 60-70 part, Isocyanates 15-20 part, zinc oxide 2-6 part, Boehmeria boon 5-8 part, melamine cyanurate salt 9-13 part, carborundum 6-12 Part, ammonium heptamolybdate 3-7 part, boron carbide 12-25 part, glass fibre 23-29 part, ceramic fibre 12-23 part, aluminium sesquioxide 23- 27 parts, titanium dioxide 1-3 part, tetraethylthiuram disulfide 3-7 part, N-phenyl-a-naphthylamine 4-10 part, barium sulfate 3-7 part, adjacent benzene Diformate mono Octyl Nitrite 3-7 part, antimony oxide 0.5-2 part, deca-BDE 2-5 part, dimethicone 1-5 part, diethyl Base aminodithioformic acid 1-2 part.
Preferably, described a kind of high resilience polyurethane composite, by weight, including following raw material components: beautiful Rice starch 60 parts, isocyanates 15 parts, zinc oxide 2 parts, Boehmeria boon 5 parts, melamine cyanurate salt 9 parts, carborundum 6 parts, Ammonium heptamolybdate 3 parts, boron carbide 12 parts, glass fibre 23 parts, ceramic fibre 12 parts, aluminium sesquioxide 23 parts, titanium dioxide 1 part, two Tetraethylthiuram sulfide 3 parts, N-phenyl-a-naphthylamine 4 parts, 3 parts of barium sulfate, phthalic acid list Octyl Nitrite 3 parts, three oxidations Two 0.5 part of antimony, deca-BDE 2 parts, dimethicone 1 part, diethyldithiocar bamic acid 1 part.
Preferably, described a kind of high resilience polyurethane composite, by weight, including following raw material components: beautiful Rice starch 70 parts, isocyanates 20 parts, zinc oxide 6 parts, Boehmeria boon 8 parts, melamine cyanurate salt 13 parts, carborundum 12 Part, ammonium heptamolybdate 7 parts, boron carbide 25 parts, glass fibre 29 parts, ceramic fibre 23 parts, aluminium sesquioxide 27 parts, titanium dioxide 3 parts, Tetraethylthiuram disulfide 7 parts, N-phenyl-a-naphthylamine 10 parts, 7 parts of barium sulfate, phthalic acid list Octyl Nitrite 7 parts, three Aoxidize 2 parts of two antimony, deca-BDE 5 parts, dimethicone 5 parts, diethyldithiocar bamic acid 2 parts.
Preferably, described a kind of high resilience polyurethane composite, by weight, including following raw material components: beautiful Rice starch 65 parts, isocyanates 18 parts, zinc oxide 5 parts, Boehmeria boon 6 parts, melamine cyanurate salt 10 parts, carborundum 10 Part, ammonium heptamolybdate 5 parts, boron carbide 18 parts, glass fibre 25 parts, ceramic fibre 20 parts, aluminium sesquioxide 25 parts, titanium dioxide 2 parts, Tetraethylthiuram disulfide 5 parts, N-phenyl-a-naphthylamine 5 parts, 4 parts of barium sulfate, phthalic acid list Octyl Nitrite 5 parts, three oxygen Change 1 part of two antimony, deca-BDE 3 parts, dimethicone 2 parts, diethyldithiocar bamic acid 1 part.
Beneficial effects of the present invention: raw materials for production of the present invention are simple and easy to get, with low cost, elastic properties of materials is high, fatigue strength High;Technique is simple, discharges without harmful gas.
Detailed description of the invention
Below in conjunction with specific embodiment, the present invention is described in further detail.
Embodiment 1
A kind of high resilience polyurethane composite, by weight, including following raw material components: corn starch 60 parts, different Cyanate 15 parts, zinc oxide 2 parts, Boehmeria boon 5 parts, melamine cyanurate salt 9 parts, carborundum 6 parts, ammonium heptamolybdate 3 parts, carbon Change boron 12 parts, glass fibre 23 parts, ceramic fibre 12 parts, aluminium sesquioxide 23 parts, titanium dioxide 1 part, tetraethyl base Flos Cymbidii Ensifolii Nurse 3 parts, N-phenyl-a-naphthylamine 4 parts, 3 parts of barium sulfate, phthalic acid list Octyl Nitrite 3 parts, antimony oxide 0.5 part, ten bromines Diphenyl ether 2 parts, dimethicone 1 part, diethyldithiocar bamic acid 1 part.
The preparation method of the present invention is same as the prior art.
Embodiment 2
A kind of high resilience polyurethane composite, by weight, including following raw material components: corn starch 70 parts, different Cyanate 20 parts, zinc oxide 6 parts, Boehmeria boon 8 parts, melamine cyanurate salt 13 parts, carborundum 12 parts, ammonium heptamolybdate 7 parts, Boron carbide 25 parts, glass fibre 29 parts, ceramic fibre 23 parts, aluminium sesquioxide 27 parts, titanium dioxide 3 parts, tetraethyl base autumn Blue nurse 7 parts, N-phenyl-a-naphthylamine 10 parts, 7 parts of barium sulfate, phthalic acid list Octyl Nitrite 7 parts, antimony oxide 2 parts, ten Dibromodiphenyl ether 5 parts, dimethicone 5 parts, diethyldithiocar bamic acid 2 parts.
The preparation method of the present invention is same as the prior art.
Embodiment 3
A kind of high resilience polyurethane composite, by weight, including following raw material components: corn starch 65 parts, different Cyanate 18 parts, zinc oxide 5 parts, Boehmeria boon 6 parts, melamine cyanurate salt 10 parts, carborundum 10 parts, ammonium heptamolybdate 5 parts, Boron carbide 18 parts, glass fibre 25 parts, ceramic fibre 20 parts, aluminium sesquioxide 25 parts, titanium dioxide 2 parts, tetraethyl base autumn Blue nurse 5 parts, N-phenyl-a-naphthylamine 5 parts, 4 parts of barium sulfate, phthalic acid list Octyl Nitrite 5 parts, antimony oxide 1 part, ten bromines Diphenyl ether 3 parts, dimethicone 2 parts, diethyldithiocar bamic acid 1 part.
The preparation method of the present invention is same as the prior art.
Embodiment 4
A kind of high resilience polyurethane composite, by weight, including following raw material components: corn starch 68 parts, different Cyanate 16 parts, zinc oxide 3 parts, Boehmeria boon 7 parts, melamine cyanurate salt 11 parts, carborundum 10 parts, ammonium heptamolybdate 5 parts, Boron carbide 16 parts, glass fibre 26 parts, ceramic fibre 15 parts, aluminium sesquioxide 25 parts, titanium dioxide 2 parts, tetraethyl base autumn Blue nurse 3 parts, N-phenyl-a-naphthylamine 10 parts, 3 parts of barium sulfate, phthalic acid list Octyl Nitrite 7 parts, antimony oxide 2 parts, ten Dibromodiphenyl ether 2 parts, dimethicone 1 part, diethyldithiocar bamic acid 1 part.
The preparation method of the present invention is same as the prior art.
Embodiment 5
A kind of high resilience polyurethane composite, by weight, including following raw material components: corn starch 66 parts, different Cyanate 16 parts, zinc oxide 5 parts, Boehmeria boon 5 parts, melamine cyanurate salt 10 parts, carborundum 10 parts, ammonium heptamolybdate 5 parts, Boron carbide 22 parts, glass fibre 26 parts, ceramic fibre 16 parts, aluminium sesquioxide 25 parts, titanium dioxide 2 parts, tetraethyl base autumn Blue nurse 4 parts, N-phenyl-a-naphthylamine 5 parts, 5 parts of barium sulfate, phthalic acid list Octyl Nitrite 4 parts, antimony oxide 1 part, ten bromines Diphenyl ether 2 parts, dimethicone 2 parts, diethyldithiocar bamic acid 1 part.
The preparation method of the present invention is same as the prior art.

Claims (4)

1. a high resilience polyurethane composite, it is characterised in that by weight, including following raw material components: Semen Maydis forms sediment Powder 60-70 part, isocyanates 15-20 part, zinc oxide 2-6 part, Boehmeria boon 5-8 part, melamine cyanurate salt 9-13 part, carbon SiClx 6-12 part, ammonium heptamolybdate 3-7 part, boron carbide 12-25 part, glass fibre 23-29 part, ceramic fibre 12-23 part, three oxidations Two aluminum 23-27 parts, titanium dioxide 1-3 part, tetraethylthiuram disulfide 3-7 part, N-phenyl-a-naphthylamine 4-10 part, barium sulfate 3-7 Part, phthalic acid list Octyl Nitrite 3-7 part, antimony oxide 0.5-2 part, deca-BDE 2-5 part, dimethicone 1-5 Part, diethyldithiocar bamic acid 1-2 part.
A kind of high resilience polyurethane composite the most according to claim 1, it is characterised in that by weight, including Following raw material components: corn starch 60 parts, isocyanates 15 parts, zinc oxide 2 parts, Boehmeria boon 5 parts, melamine cyanurate salt 9 parts, carborundum 6 parts, ammonium heptamolybdate 3 parts, boron carbide 12 parts, glass fibre 23 parts, ceramic fibre 12 parts, aluminium sesquioxide 23 Part, titanium dioxide 1 part, tetraethylthiuram disulfide 3 parts, N-phenyl-a-naphthylamine 4 parts, 3 parts of barium sulfate, phthalic acid list second The own ester of base 3 parts, antimony oxide 0.5 part, deca-BDE 2 parts, dimethicone 1 part, diethyldithiocar bamic acid 1 Part.
A kind of high resilience polyurethane composite the most according to claim 1, it is characterised in that by weight, including Following raw material components: corn starch 70 parts, isocyanates 20 parts, zinc oxide 6 parts, Boehmeria boon 8 parts, melamine cyanurate salt 13 parts, carborundum 12 parts, ammonium heptamolybdate 7 parts, boron carbide 25 parts, glass fibre 29 parts, ceramic fibre 23 parts, aluminium sesquioxide 27 Part, titanium dioxide 3 parts, tetraethylthiuram disulfide 7 parts, N-phenyl-a-naphthylamine 10 parts, 7 parts of barium sulfate, phthalic acid list second The own ester of base 7 parts, antimony oxide 2 parts, deca-BDE 5 parts, dimethicone 5 parts, diethyldithiocar bamic acid 2 parts.
A kind of high resilience polyurethane composite the most according to claim 1, it is characterised in that by weight, including Following raw material components: corn starch 65 parts, isocyanates 18 parts, zinc oxide 5 parts, Boehmeria boon 6 parts, melamine cyanurate salt 10 parts, carborundum 10 parts, ammonium heptamolybdate 5 parts, boron carbide 18 parts, glass fibre 25 parts, ceramic fibre 20 parts, aluminium sesquioxide 25 Part, titanium dioxide 2 parts, tetraethylthiuram disulfide 5 parts, N-phenyl-a-naphthylamine 5 parts, 4 parts of barium sulfate, phthalic acid list second The own ester of base 5 parts, antimony oxide 1 part, deca-BDE 3 parts, dimethicone 2 parts, diethyldithiocar bamic acid 1 part.
CN201610688586.4A 2016-08-18 2016-08-18 A kind of high resilience polyurethane composite Pending CN106243399A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610688586.4A CN106243399A (en) 2016-08-18 2016-08-18 A kind of high resilience polyurethane composite

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610688586.4A CN106243399A (en) 2016-08-18 2016-08-18 A kind of high resilience polyurethane composite

Publications (1)

Publication Number Publication Date
CN106243399A true CN106243399A (en) 2016-12-21

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Family Applications (1)

Application Number Title Priority Date Filing Date
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Country Status (1)

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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1077725A (en) * 1993-04-20 1993-10-27 王笃伦 Rigid foam glucose polyurethane plastics and production method thereof
CN101426855A (en) * 2006-02-24 2009-05-06 Phb工业有限公司 Composition for preparing a biodegradable polyurethane- based foam and a biodegradable polyurethane foam
CN104292784A (en) * 2014-09-30 2015-01-21 苏州博利迈新材料科技有限公司 Degradable foamed plastic and preparation method thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1077725A (en) * 1993-04-20 1993-10-27 王笃伦 Rigid foam glucose polyurethane plastics and production method thereof
CN101426855A (en) * 2006-02-24 2009-05-06 Phb工业有限公司 Composition for preparing a biodegradable polyurethane- based foam and a biodegradable polyurethane foam
CN104292784A (en) * 2014-09-30 2015-01-21 苏州博利迈新材料科技有限公司 Degradable foamed plastic and preparation method thereof

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Application publication date: 20161221