CN106242537A - A kind of heavy duty grinding wheel and metal removal alundum abrasive particle and production method - Google Patents

A kind of heavy duty grinding wheel and metal removal alundum abrasive particle and production method Download PDF

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CN106242537A
CN106242537A CN201610727999.9A CN201610727999A CN106242537A CN 106242537 A CN106242537 A CN 106242537A CN 201610727999 A CN201610727999 A CN 201610727999A CN 106242537 A CN106242537 A CN 106242537A
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abrasive particle
alundum abrasive
alundum
lamellar
content
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庞京涛
吴晓冬
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Shanghai Rong Rong New Mstar Technology Ltd
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Shanghai Rong Rong New Mstar Technology Ltd
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    • C04B35/10Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on aluminium oxide
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B24GRINDING; POLISHING
    • B24DTOOLS FOR GRINDING, BUFFING OR SHARPENING
    • B24D18/00Manufacture of grinding tools or other grinding devices, e.g. wheels, not otherwise provided for
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Abstract

The invention discloses a kind of heavy duty grinding wheel and metal removal alundum abrasive particle and production method, its raw material composition percentage by weight is: α Al2O3Content 98 99.5%wt;SiO20.1~0.5%wt;MnO、Fe2O3、MgO、Cr2O3In one or several combination, content 0.3 1.0%wt;Rare earth oxide Eu2O3, La2O3, Y2O3In the combination of one or more, content 0.1~0.5%wt;After adding various raw materials according to raw material composition percentage by weight, add auxiliary agent and mix, utilize the mode molded or extrude to produce biscuit, then 1,550 1700 DEG C of sintering in sintering furnace.α Al is formed after sintering2O3The microstructure of dense uniform.Product has higher density and hardness.Can solve the problem that the problems such as the conventional grains grinding efficiency in heavy load field is low, the most aging.And variously-shaped laminar abrasive particle can be made by the method for extruding or mold pressing, can apply to metal removal field.

Description

A kind of heavy duty grinding wheel and metal removal alundum abrasive particle and production method
Technical field
The present invention relates to a kind of alundum abrasive particle, for heavy load polishing and metal removal field, in particular A kind of heavy load grinding alundum abrasive particle and production method thereof.
Background technology
Actual industrial production has the grinding under various load, the reconditioning of heavy load polishing mainly steel billet, abrades steel ingot Surface defect layer;The processing of heavy castings forging;Cutting sheet, grinding disc cutting or polishing metal are also a kind of on-load mills Cut.
Conventional heavy load polishing uses with the abrasive particle of bauxite sintering, and hardness is inadequate;It is only capable of for grinding The material that rustless steel etc. are softer.And owing in abrasive particle, impurity content is higher, under the high temperature conditions can be the most aging.
Therefore, prior art existing defects, need to improve.
Summary of the invention
A kind of heavy duty grinding wheel and metal removal alundum abrasive particle and producer is provided for the deficiencies in the prior art Method.
The present invention adopts the following technical scheme that
A kind of alundum abrasive particle, its raw material composition percentage by weight is: α-Al2O3Content 98-99.5%wt;SiO20.1 ~0.5%wt;MnO、Fe2O3、MgO、Cr2O3In one or several combination, content 0.3-1.0%wt;Rare earth oxide Eu2O3, La2O3, Y2O3In the combination of one or more, content 0.1~0.5%wt.
Its formula includes α-Al2O3Content 98-99.5%wt, α-Al2O3As principal crystalline phase;SiO2Content 0.1~ 0.5%, SiO2Addition mainly the most at high temperature with α-Al2O3Form mullite phase, increase under the high temperature of whole microstructure Intensity;MnO、Fe2O3、MgO、Cr2O3In one or several combination, adding of the oxide such as content 0.3-1.0%wt, MnO Enter mainly with α-Al2O3Form solid solution, exist with on crystal boundary, suppress α-Al2O3Crystal grain grow up.Rare earth oxide Eu2O3, La2O3, Y2O3In the combination of one or more, content 0.1~0.5%wt, the addition of rare earth oxide is to deposit as bulky grain It is α-Al2O3Crystal boundary on, prevent crystal grain abnormal growth and suppression grain boundary defects extension, increase product toughness, microcosmic Crystal phase structure is as shown in Figure 1.By the effect of above additive, the physical characteristic of product can reach, and density is more than 3.74g/ mm3, hardness HV is more than 1400kg/mm2
Described alundum abrasive particle, its density is more than 3.74g/mm3, hardness HV is more than 1400kg/mm2
Described alundum abrasive particle, wherein α-Al2O3With the addition of powder, diameter of particle 1-5um.
Described alundum abrasive particle, including strip alundum abrasive particle and lamellar alundum abrasive particle, wherein strip burns Knot alumina grain includes column type alundum abrasive particle, trifolium-shaped alundum abrasive particle, annulus stripe shape alundum abrasive particle;Institute The column type alundum abrasive particle stated, its cross section is circular, and the ratio of length and diameter is 1.5 to 5;Described trifolium-shaped Alundum abrasive particle, its cross section is the inner circle that three symmetrical sizes of cylindrical inscribe are identical, and three inner circles are the most circumscribed, length It is 1.5 to 5 with the ratio of diameter;Described annulus stripe shape alundum abrasive particle, its cross section is annulus, its internal diameter and external diameter ratio Value is 1/4 to 3/4, and the ratio of length and diameter is 1.5 to 5;
Lamellar alundum abrasive particle includes triangle lamellar alundum abrasive particle and hexagon lamellar alundum abrasive particle, institute The triangular form lamellar alundum abrasive particle stated, its cross section is equilateral triangle, and its thickness is 1/10 to the 1/2 of the length of side;Described Hexagon lamellar alundum abrasive particle, its cross section is hexagon, and its thickness is 1/10 to the 1/2 of the length of side.
The production method of a kind of arbitrary described alundum abrasive particle, adds various raw materials according to raw material composition percentage by weight After, add auxiliary agent and mix, utilize the mode molded or extrude to produce biscuit, then 1550-1700 in sintering furnace DEG C sintering.
Described production method, wherein auxiliary agent refers to that content accounts for institute in order to improve the organic additive that powder body processability adds The percentage ratio stating raw material weight sum is: liquid paraffin 5-10%wt;Stearic acid 0.5-1.0%wt.
Described production method, wherein mixing is various raw materials and auxiliary agent to be mixed by churned mechanically mode;Its Middle mold pressing is, by roll, the powder body after stirring is clamp-oned die cavity, and wherein extruding is, by screw rod, the powder body after stirring is clamp-oned mould Chamber.
Described production method, the biscuit after wherein sintering is by molding, 1550-1700 DEG C of sintering 60-200 in kiln Minute.
It is low that the present invention solves conventional grains grinding efficiency, the problem that abrasive particle is the most aging.Patent of the present invention is micro-with aluminium oxide Powder is primary raw material, adds MnO, Fe2O3、MgO、Cr2O3In one or several combination, rare earth oxide Eu2O3, La2O3, Y2O3In the combination of one or more, by the abrasive particle made of method of sintering.The effect of the oxide added is fall The sintering temperature of al suboxide, growing up of suppression crystal grain.α-Al is formed after sintering2O3The microstructure of dense uniform.Product has Higher density and hardness.Can solve the problem that the problems such as the conventional grains grinding efficiency in heavy load field is low, the most aging.And lead to The method crossing extruding or mold pressing can make variously-shaped laminar abrasive particle, can apply to metal removal field.
Accompanying drawing explanation
Fig. 1 is abrasive particle crystal phase structure figure of the present invention;1, α-Al2O3Crystal grain, 2, rare earth oxide, 3, MnO2Brilliant in solid solution Boundary;
Fig. 2 is column type abrasive particle schematic diagram (left) and pictorial diagram (right);
Fig. 3 is trifolium-shaped abrasive particle schematic diagram (left) and pictorial diagram (right);
Fig. 4 is annulus stripe shape abrasive particle schematic diagram (left) and pictorial diagram (right);
Fig. 5 is triangular form abrasive particle schematic diagram (left) and pictorial diagram (right);
Fig. 6 is hexangle type abrasive particle schematic diagram (left) and pictorial diagram (right).
Detailed description of the invention
Below in conjunction with specific embodiment, the present invention is described in detail.
Embodiment 1 formula test and the physical characteristic of product
Alundum abrasive particle, its raw material composition percentage by weight is: α-Al2O3Content 98-99.5%wt;SiO20.1~ 0.5%wt;MnO、Fe2O3、MgO、Cr2O3In one or several combination, content 0.3-1.0%wt;Rare earth oxide Eu2O3, La2O3, Y2O3In the combination of one or more, content 0.1~0.5%wt;
Being also added with auxiliary agent, auxiliary agent refers to that content is above-mentioned raw materials in order to improve the organic additive that powder body processability adds The percentage ratio of weight sum: liquid paraffin 5-10%wt;Stearic acid 0.5-1.0%wt.
The shape of described alundum abrasive particle has strip and lamellar two class, and wherein strip is column type (Fig. 2), Herba Trifolii Pratentis Type (Fig. 3), annulus stripe shape (Fig. 4).It is molded into emery wheel after mixing with resinoid bond, is mainly used in heavy load polishing field. The advantage of column type is that intensity is high, the most easy to wear, but little with the contact area of resinoid bond, and adhesion is inadequate, easily takes off Fall.Trifolium-shaped and annulus stripe shape, increase the contact area with resinoid bond, and adhesion is good, and abrasive particle is not easy from emery wheel Come off.And trifolium-shaped and annulus stripe shape, little with grinding workpiece contact area in grinding process, abrasive particle can peel off layer by layer, Self-sharpening is good, and grinding efficiency is high.
The following is the feature description of strip abrasive particle: described column type alundum abrasive particle, its cross section is circular, length It is 1.5 to 5 with the ratio of diameter.Described trifolium-shaped alundum abrasive particle, its cross section is that cylindrical inscribe three is symmetrical The inner circle that size is identical, three inner circles are the most circumscribed, and the ratio of length and diameter is 1.5 to 5.Described annulus stripe shape sintering is just Beautiful abrasive particle, its cross section is annulus, it is characterized by that internal diameter and external diameter ratio are 1/4 to 3/4, and the ratio of length and diameter is 1.5 To 5.
The abrasive particle of lamellar mainly comprises triangle lamellar, and hexagon lamellar, is mainly used in Metal Cutting and polishing neck The resin cutting slice in territory and grinding disc.Owing to abrasive particle ratio itself is relatively thin, it is easy to make relatively thin cutting sheet/grinding disc.And three Angle-style abrasive particle or the seamed edge of hexangle type abrasive particle, wedge angle can be obviously improved stock-removing efficiency.
The following is the feature description of lamellar abrasive particle:
Described triangular form alundum abrasive particle, cross section is equilateral triangle, it is characterized by that thickness is the 1/10 of the length of side To 1/2.Described hexangle type alundum abrasive particle, cross section is hexagon, it is characterized by that thickness is the length of side 1/10 to 1/2.
Specific experiment as shown in table 1 below is carried out according to above-mentioned formula:
Table 1
By α-Al2O3Powder, SiO2The oxide powder such as powder, MnO, Eu2O3Join according to upper table Deng RE oxide powder Side weighs, and mixes 30 minutes in high speed mixer the most again.The powder mixed is put into kneader, and adds by upper table formula Enter liquid paraffin and magnesium stearate, mediate 30 minutes.Kneaded material is put into roller extruder or screw extruder, Join difform mould, squeeze out difform biscuit.Biscuit is stood 12 hours, subsequently into sintering furnace at 1700 DEG C Sinter the abrasive particle that i.e. can obtain needing 100 minutes.The density and hardness of abrasive particle, result after sintering with durometer and densimeter measurement As shown above.
Steel billet of polishing under embodiment 2 abrasive particle heavy load is tested
The strip particle abrasive particle resinoid bond of making of above-mentioned formula is fabricated toThickness 76mm emery wheel, enters Row grinding test.Experimental condition: grinding speed 80m/s, load 1000Kgf.Result of the test is as shown in table 2 below:
Table 2
Emery wheel is numbered Abrasive particle shape Formula number Workpiece stock removal (g) Emery wheel waste (g) Wear resistance ratio
1 Column type 1 2802 400 7.0
2 Trifolium-shaped 1 3695 493 7.5
3 Open circles bar 1 3599 467 7.7
4 Column type 2 2703 398 6.8
5 Trifolium-shaped 2 3254 452 7.2
6 Open circles bar 2 3301 452 7.3
7 Column type 3 2794 405 6.9
8 Trifolium-shaped 3 3255 465 7.0
9 Open circles bar 3 3289 463 7.1
The grinding efficiency of the present invention is relatively good as can be seen from Table 1.
The Metal Cutting test of embodiment 3 lamellar abrasive particle
The triangular form abrasive particle produced in embodiment 1 and hexagon abrasive particle are added resinoid bond and fiberglass reinforced mesh sheet, It is fabricated toThickness 1.0 cuts sheet, carries out cutting test.Cutting speed 80m/s, tests material Φ 16#45 rod iron.
Table 3
In the present invention, cutting efficiency and the life-span of abrasive particle are relatively good as can be seen from Table 3.
The metal polishing test of embodiment 4 lamellar abrasive particle
The triangular form abrasive particle produced in embodiment 1 and hexagon abrasive particle are added resinoid bond and fiberglass reinforced mesh sheet, It is fabricated toThickness 3.0 grinding disc, carries out metal polishing test.Test material #45 steel, polisher power 720W, rotating speed 11000RPM, material #45 steel of polishing, polish 10 minutes time.
Table 4
In the present invention, the grinding efficiency of abrasive particle is relatively good as can be seen from Table 4.
It should be appreciated that for those of ordinary skills, can be improved according to the above description or be converted, And all these modifications and variations all should belong to the protection domain of claims of the present invention.

Claims (8)

1. an alundum abrasive particle, it is characterised in that its raw material composition percentage by weight is: α-Al2O3Content 98-99.5% wt;SiO20.1~0.5%wt;MnO、Fe2O3、MgO、Cr2O3In one or several combination, content 0.3-1.0%wt; Rare earth oxide Eu2O3, La2O3, Y2O3In the combination of one or more, content 0.1~0.5%wt.
Alundum abrasive particle the most according to claim 1, it is characterised in that the density of described alundum abrasive particle is more than 3.74g/mm3, hardness HV is more than 1400kg/mm2
Alundum abrasive particle the most according to claim 1, it is characterised in that wherein α-Al2O3With the addition of powder, Diameter of particle 1-5um.
Alundum abrasive particle the most according to claim 1, it is characterised in that described alundum abrasive particle includes that strip burns Knot alumina grain and lamellar alundum abrasive particle, wherein strip alundum abrasive particle includes column type alundum abrasive particle, SANYE Grass type alundum abrasive particle, annulus stripe shape alundum abrasive particle;Described column type alundum abrasive particle, its cross section is circle The ratio of shape, length and diameter is 1.5 to 5;Described trifolium-shaped alundum abrasive particle, its cross section is cylindrical inscribe three The inner circle that symmetrical size is identical, three inner circles are the most circumscribed, and the ratio of length and diameter is 1.5 to 5;Described annulus stripe shape Alundum abrasive particle, its cross section is annulus, and its internal diameter and external diameter ratio are 1/4 to 3/4, and the ratio of length and diameter is 1.5 To 5;
Lamellar alundum abrasive particle includes triangle lamellar alundum abrasive particle and hexagon lamellar alundum abrasive particle, described Triangular form lamellar alundum abrasive particle, its cross section is equilateral triangle, and its thickness is 1/10 to the 1/2 of the length of side;Described six Dihedral lamellar alundum abrasive particle, its cross section is hexagon, and its thickness is 1/10 to the 1/2 of the length of side.
5. the production method of the arbitrary described alundum abrasive particle of claim 1-4, it is characterised in that according to raw material composition weight After amount percentage ratio adds various raw materials, add auxiliary agent and mix, utilize the mode molded or extrude to produce biscuit, then 1550-1700 DEG C of sintering in sintering furnace.
6. according to the production method described in claim 5, it is characterised in that wherein auxiliary agent refers to as improving powder body processability The organic additive added, content accounts for the percentage ratio of described raw material weight sum and is: liquid paraffin 5-10%wt;Stearic acid 0.5- 1.0%wt.
7. according to the production method described in claim 5, it is characterised in that wherein mixing is various raw materials and auxiliary agent to be led to Cross churned mechanically mode to mix;Wherein molding is, by roll, the powder body after stirring is clamp-oned die cavity, and wherein extruding is to pass through Powder body after stirring is clamp-oned die cavity by screw rod.
8. according to the production method described in claim 5, it is characterised in that the biscuit after wherein sintering is by molding, at kiln In stove, 1550-1700 DEG C sinters 60-200 minute.
CN201610727999.9A 2016-08-25 2016-08-25 A kind of heavy duty grinding wheel and metal removal alundum abrasive particle and production method Pending CN106242537A (en)

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CN111136589A (en) * 2019-12-30 2020-05-12 宁波大学 Abrasive grain boundary bonding and fixing grinding tool and preparation method thereof
CN116477966A (en) * 2023-04-26 2023-07-25 深圳市博迪科技开发有限公司 Preparation method of hydroxyapatite-based porous ceramic without powder falling
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CN107522474A (en) * 2017-08-23 2017-12-29 上海雨荣新材料科技有限公司 Nanocrystalline alundum abrasive particle and preparation method thereof
CN111136589A (en) * 2019-12-30 2020-05-12 宁波大学 Abrasive grain boundary bonding and fixing grinding tool and preparation method thereof
CN116477966A (en) * 2023-04-26 2023-07-25 深圳市博迪科技开发有限公司 Preparation method of hydroxyapatite-based porous ceramic without powder falling
CN116768608A (en) * 2023-07-13 2023-09-19 郑州蚂蚁特材有限公司 Semi-brittle corundum and preparation method thereof

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