CN106240103A - One is dispersed and is applied drip defogging film and preparation method thereof outside emitting - Google Patents
One is dispersed and is applied drip defogging film and preparation method thereof outside emitting Download PDFInfo
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- CN106240103A CN106240103A CN201610620441.0A CN201610620441A CN106240103A CN 106240103 A CN106240103 A CN 106240103A CN 201610620441 A CN201610620441 A CN 201610620441A CN 106240103 A CN106240103 A CN 106240103A
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- layer
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- thin film
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- 238000002360 preparation method Methods 0.000 title claims abstract description 12
- 239000010408 film Substances 0.000 claims abstract description 56
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 38
- 238000000149 argon plasma sintering Methods 0.000 claims abstract description 35
- 239000011248 coating agent Substances 0.000 claims abstract description 34
- 238000000576 coating method Methods 0.000 claims abstract description 34
- 239000010409 thin film Substances 0.000 claims abstract description 33
- 229920003229 poly(methyl methacrylate) Polymers 0.000 claims abstract description 29
- 239000004926 polymethyl methacrylate Substances 0.000 claims abstract description 29
- 238000009413 insulation Methods 0.000 claims abstract description 23
- 239000000428 dust Substances 0.000 claims abstract description 13
- 229910052599 brucite Inorganic materials 0.000 claims abstract description 3
- 239000003085 diluting agent Substances 0.000 claims abstract description 3
- 239000004594 Masterbatch (MB) Substances 0.000 claims description 21
- 239000002994 raw material Substances 0.000 claims description 16
- 239000004611 light stabiliser Substances 0.000 claims description 14
- 230000002745 absorbent Effects 0.000 claims description 12
- 239000002250 absorbent Substances 0.000 claims description 12
- 239000003963 antioxidant agent Substances 0.000 claims description 10
- 230000003078 antioxidant effect Effects 0.000 claims description 10
- 238000001125 extrusion Methods 0.000 claims description 10
- 229920000092 linear low density polyethylene Polymers 0.000 claims description 10
- 239000004707 linear low-density polyethylene Substances 0.000 claims description 10
- 239000007788 liquid Substances 0.000 claims description 9
- 239000002245 particle Substances 0.000 claims description 9
- 239000000243 solution Substances 0.000 claims description 8
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 6
- 238000003618 dip coating Methods 0.000 claims description 6
- 229910052710 silicon Inorganic materials 0.000 claims description 6
- 239000010703 silicon Substances 0.000 claims description 6
- 238000010438 heat treatment Methods 0.000 claims description 5
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 4
- 239000000654 additive Substances 0.000 claims description 4
- 230000000996 additive effect Effects 0.000 claims description 4
- PEDCQBHIVMGVHV-UHFFFAOYSA-N glycerol group Chemical group OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 4
- 229920001684 low density polyethylene Polymers 0.000 claims description 4
- 239000004702 low-density polyethylene Substances 0.000 claims description 4
- 238000004519 manufacturing process Methods 0.000 claims description 4
- 229920001526 metallocene linear low density polyethylene Polymers 0.000 claims description 4
- 239000003595 mist Substances 0.000 claims description 4
- 239000000203 mixture Substances 0.000 claims description 4
- QUAMTGJKVDWJEQ-UHFFFAOYSA-N octabenzone Chemical group OC1=CC(OCCCCCCCC)=CC=C1C(=O)C1=CC=CC=C1 QUAMTGJKVDWJEQ-UHFFFAOYSA-N 0.000 claims description 4
- 229910052760 oxygen Inorganic materials 0.000 claims description 4
- 239000001301 oxygen Substances 0.000 claims description 4
- 239000003755 preservative agent Substances 0.000 claims description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 4
- 238000003851 corona treatment Methods 0.000 claims description 3
- 239000008367 deionised water Substances 0.000 claims description 3
- 229910021641 deionized water Inorganic materials 0.000 claims description 3
- 239000006185 dispersion Substances 0.000 claims description 3
- 239000000839 emulsion Substances 0.000 claims description 3
- 238000002156 mixing Methods 0.000 claims description 3
- 239000002798 polar solvent Substances 0.000 claims description 3
- -1 stearoyl ester Chemical class 0.000 claims description 3
- 239000011550 stock solution Substances 0.000 claims description 3
- 150000001412 amines Chemical class 0.000 claims description 2
- 238000010422 painting Methods 0.000 claims description 2
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 claims 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 claims 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 claims 1
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 claims 1
- 239000005642 Oleic acid Substances 0.000 claims 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 claims 1
- 238000007788 roughening Methods 0.000 claims 1
- 230000005540 biological transmission Effects 0.000 abstract description 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract description 4
- 239000005995 Aluminium silicate Substances 0.000 abstract description 2
- 235000012211 aluminium silicate Nutrition 0.000 abstract description 2
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 abstract description 2
- 235000012239 silicon dioxide Nutrition 0.000 abstract description 2
- 239000000377 silicon dioxide Substances 0.000 abstract description 2
- 239000005038 ethylene vinyl acetate Substances 0.000 description 5
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 description 5
- 230000035515 penetration Effects 0.000 description 4
- 241000196324 Embryophyta Species 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 238000002834 transmittance Methods 0.000 description 3
- VBICKXHEKHSIBG-UHFFFAOYSA-N 1-monostearoylglycerol Chemical group CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 description 2
- 230000012010 growth Effects 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 244000025254 Cannabis sativa Species 0.000 description 1
- 238000007605 air drying Methods 0.000 description 1
- 201000009310 astigmatism Diseases 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 208000002173 dizziness Diseases 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 229940075507 glyceryl monostearate Drugs 0.000 description 1
- 230000003760 hair shine Effects 0.000 description 1
- 238000003306 harvesting Methods 0.000 description 1
- 210000004276 hyalin Anatomy 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 239000001788 mono and diglycerides of fatty acids Substances 0.000 description 1
- 239000002105 nanoparticle Substances 0.000 description 1
- 229950002083 octabenzone Drugs 0.000 description 1
- FATBGEAMYMYZAF-KTKRTIGZSA-N oleamide Chemical group CCCCCCCC\C=C/CCCCCCCC(N)=O FATBGEAMYMYZAF-KTKRTIGZSA-N 0.000 description 1
- FATBGEAMYMYZAF-UHFFFAOYSA-N oleicacidamide-heptaglycolether Natural products CCCCCCCCC=CCCCCCCCC(N)=O FATBGEAMYMYZAF-UHFFFAOYSA-N 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 230000029553 photosynthesis Effects 0.000 description 1
- 238000010672 photosynthesis Methods 0.000 description 1
- 230000000243 photosynthetic effect Effects 0.000 description 1
- 230000008635 plant growth Effects 0.000 description 1
Classifications
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- B32—LAYERED PRODUCTS
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- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01G—HORTICULTURE; CULTIVATION OF VEGETABLES, FLOWERS, RICE, FRUIT, VINES, HOPS OR SEAWEED; FORESTRY; WATERING
- A01G13/00—Protecting plants
- A01G13/02—Protective coverings for plants; Coverings for the ground; Devices for laying-out or removing coverings
- A01G13/0206—Canopies, i.e. devices providing a roof above the plants
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
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- B29C48/18—Articles comprising two or more components, e.g. co-extruded layers the components being layers
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- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29D—PRODUCING PARTICULAR ARTICLES FROM PLASTICS OR FROM SUBSTANCES IN A PLASTIC STATE
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- B29D7/01—Films or sheets
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- B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
- B32B27/306—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers comprising vinyl acetate or vinyl alcohol (co)polymers
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- B32B27/32—Layered products comprising a layer of synthetic resin comprising polyolefins
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- B32B33/00—Layered products characterised by particular properties or particular surface features, e.g. particular surface coatings; Layered products designed for particular purposes not covered by another single class
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- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/06—Polyethene
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0807—Copolymers of ethene with unsaturated hydrocarbons only containing more than three carbon atoms
- C08L23/0815—Copolymers of ethene with aliphatic 1-olefins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
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- B29K2033/00—Use of polymers of unsaturated acids or derivatives thereof as moulding material
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2223/00—Use of polyalkenes or derivatives thereof as reinforcement
- B29K2223/04—Polymers of ethylene
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- B29K2223/0608—PE, i.e. polyethylene characterised by its density
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- B32B2255/00—Coating on the layer surface
- B32B2255/10—Coating on the layer surface on synthetic resin layer or on natural or synthetic rubber layer
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- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
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- B32B2307/30—Properties of the layers or laminate having particular thermal properties
- B32B2307/304—Insulating
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- B32B2307/40—Properties of the layers or laminate having particular optical properties
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- B32B2410/00—Agriculture-related articles
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/002—Physical properties
- C08K2201/003—Additives being defined by their diameter
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/16—Applications used for films
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- C—CHEMISTRY; METALLURGY
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- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
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- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- General Health & Medical Sciences (AREA)
- Environmental Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Toxicology (AREA)
- Greenhouses (AREA)
- Protection Of Plants (AREA)
Abstract
The present invention relates to one and disperse coating drip defogging film and preparation method thereof outside emitting.This disperses coating drip defogging film outside emitting, by five-layer co-squeezing thin film and be located at the coat of five-layer co-squeezing thin film outer surface and form, described five-layer co-squeezing thin film is followed successively by dust layer, the first heat-insulation layer, the second heat-insulation layer, secondary internal layer, corona layer from outside to inside, and described coat is organosilicon coat.This disperses outside emitting coating drip defogging film, uses the organic light scattering agent of PMMA, prepares through five-layer co-squeezing and disperse emitting agricultural film, have excellence drip, disperse fog, be incubated, light transmission and mechanical property.Use the organic light scattering agent of PMMA type, compare the inorganic scattering diluents such as traditional Kaolin, brucite, silicon dioxide, can greatly strengthen light transmission rate and the compatibility, on the premise of high transmission, some light scattering is fallen, thus realize reducing direct projection at noon peak temperature, do not make blade face of burning, and scattered light can be irradiated to plant middle and lower part blade, strengthens the utilization rate to light.
Description
Technical field
The present invention relates to one and disperse coating drip defogging film and preparation method thereof outside emitting.
Background technology
Why the sky that we have seen that daytime is bright, is because sunlight during arriving ground by air
There occurs atmospheric scattering when running into the particles such as air molecule, grit, water dust, atmospheric scattering is to all the winds launched sunlight, because of
We see that skyward either direction all can have light to enter eyes for this.And there is no air on the moon, so in night sky except
Outside the most luminous celestial body is bright, remaining is entirely black.It is photosynthetic heavy that solar energy is that crops are carried out
Wanting one of factor, be the essential condition of crop growth, growth, result, wherein scattered light can make light be more evenly distributed, and shines
It is mapped to more plant leaf blade, makes the crop number of sheets increase, improve the yield of crop, shorten the crop harvesting phase;And scattered light can
To be irradiated to plant middle and lower part, strengthen the photosynthesis of middle and lower part blade, increase the utilization rate to light, promote the growth of plant.
Additionally, on the premise of light transmittance is constant, if can be by increasing diffused light ratio, moreover it is possible to the peak value of the midday temperatures that disappears, take
Generation tradition uses grass felt etc. to keep the sun off and avoids burning the mode on blade face.The quantity of the direct light and scattered light that arrive ground depends on
In air, when cloud layer is more, only have diffused light, air drying, clear time then produce substantial amounts of direct light.Light scattering type agricultural film
It is by adding filler in agricultural film, makes to occur through the light of agricultural film the agricultural film of scattering.At present, the preparation of light scattering type agricultural film
It is to make agricultural film form the effect of clouded glass by the method adding inorganic nano-particle or micron ion, but so to agricultural film printing opacity
The impact of rate is very big, and matte surface need to carry out bigger change to existing technique, is unsuitable for popularization and application.
Summary of the invention
The present invention is in order to make up the deficiencies in the prior art, it is provided that a kind of good, to light penetration shadow with resin compatible
Sound is little, improve dispersing of light nephelometric turbidity unit applies drip defogging film and preparation method thereof outside emitting, solve in prior art and deposit
Problem.
The present invention is achieved through the following technical solutions:
One disperses outside emitting coating drip defogging film, by five-layer co-squeezing thin film and be located at five-layer co-squeezing thin film outer surface
Coat form, described five-layer co-squeezing thin film be followed successively by from outside to inside dust layer, the first heat-insulation layer, the second heat-insulation layer, secondary internal layer,
Corona layer, described coat is organosilicon coat, described dust layer, the first heat-insulation layer, the second heat-insulation layer, secondary internal layer, corona
The gross thickness of layer is 120 μm, and each layer thickness ratio is 1:1:1:1:1;
Described dust layer is made up of the raw material of following parts by weight: mLLDPE 20-25 part, light stabilizer 0.13-0.16
Part, antioxidant 0.04-0.06 part, UV absorbent 0.02-0.04 part, antistatic additive 0.3-0.4 part, slipping agent 0.08-0.1
Part, light scattering agent master batch 0.75-6 part;
Described first heat-insulation layer is made up of the raw material of following parts by weight: mLLDPE 15-18 part, high VA (vinyl acetate
Ester) EVA (ethylene-vinyl acetate copolymer) 11-15 part of content, heat preserving agent 2-3.0 part, light stabilizer 0.13-0.16 part, anti-
Oxygen agent 0.04-0.06 part, UV absorbent 0.02-0.04 part, light scattering agent master batch 0.75-5.6 part, described high VA content
In EVA, VA content is 14%;
Described second heat-insulation layer is made up of the raw material of following parts by weight: EVA 14-15 part of low VA content, light stabilizer
0.13-0.16 part, antioxidant 0.05-0.06 part, UV absorbent 0.02-0.04 part, light scattering agent master batch 0.25-2.3 part,
In the EVA of described low VA content, VA content is 9%;
Described time internal layer is made up of the raw material of following parts by weight: LDPE 8-10 part, light stabilizer 0.13-0.16 part, anti-
Oxygen agent 0.05-0.06 part, UV absorbent 0.02-0.04 part, light scattering agent master batch 0.25-2.3 part;
Described corona layer is made up of the raw material of following parts by weight: LDPE 7.6-9.7 part, light stabilizer 0.13-0.16
Part, antioxidant 0.04-0.06 part, UV absorbent 0.02-0.04 part, light scattering agent master batch 0.25-2.0 part;
Described light scattering agent master batch is made up of PMMA (polymethyl methacrylate) and LLDPE, the weight of PMMA and LLDPE
Ratio is 1:4-3:7.
Described antioxidant is Hinered phenols antioxidant.
Described light stabilizer is hindered amine light stabilizer.
Described antistatic additive is glyceryl monostearate.
Described slipping agent is oleamide.
Described heat preserving agent is 5000 mesh brucites.
The particle diameter of described PMMA is one or more in 1.5,2,3,5,7,10 μm.
Described UV absorbent is UV-531 (Octabenzone).
This disperses the preparation method applying drip defogging film outside emitting, employing following steps:
(1) organic silicon coating solution and the raw material of five-layer co-squeezing thin film every layer, wherein five-layer co-squeezing thin film are proportionally prepared
In every layer, the preparation method of contained light scattering agent master batch is: use banbury at 130 DEG C of bars after being mixed homogeneously by PMMA with LLDPE
Banburying 20-30min under part, makes PMMA emulsion dispersion use single screw pelletizer extrusion processing the most afterwards, obtains light scattering agent master batch,
Single screw pelletizer extrusion processing uses level Four heating, the barrel zone temperature of four thermals treatment zone be set as successively 148 DEG C, 157 DEG C,
152℃、128℃;
(2) profit after every layer of raw material of five-layer co-squeezing thin film step (1) prepared utilizes mixing equipment mixture respectively uniformly
Be blow molded into five-layer co-squeezing thin film with five-layer co-squeezing machine inflation film manufacturing machine, barrel zone temperature during each layer extrusion be respectively dust layer 210 DEG C, the
One heat-insulation layer 185 DEG C, the second heat-insulation layer 185 DEG C, secondary internal layer 190 DEG C, 190 DEG C of corona layer;
(3) obtain coating liquid with deionized water after first organic silicon coating solution stock solution being mixed homogeneously with the weight ratio of 1:17 to hold
In coating groove, then the surface of five-layer co-squeezing thin film is made to become through sided corona treatment the five-layer co-squeezing thin film that step (2) prepares
Coarse and increase its wettability to polar solvent, then by the coating liquid dip-coating in coating groove, dip-coating complete use scraper will
After unnecessary coating liquid shaves, at 60 DEG C, five-layer co-squeezing thin film is dried 30-40s, obtain described in disperse and outside emitting, apply stream
Drip defogging film.
The invention has the beneficial effects as follows: this disperses coating drip defogging film outside emitting, uses the organic light scattering agent of PMMA, warp
Five-layer co-squeezing, prepares and disperses emitting agricultural film, have excellence drip, disperse fog, be incubated, light transmission and mechanical property.Use
The organic light scattering agent of PMMA type, compares the inorganic scattering diluents such as traditional Kaolin, brucite, silicon dioxide, can greatly strengthen light
Transmitance and the compatibility, fall some light scattering on the premise of high transmission, thus realizes reducing direct projection at noon peak temperature, does not makes
Burn blade face, and scattered light can be irradiated to plant middle and lower part blade, strengthens the utilization rate to light.Can make for difference during application
The thing demand to light, develops the agricultural film of different astigmatism degree, such as 20% (micro-scattering), 35% (middle scattering), 65% (complete
Scattering), middle scattering, entirely disperse emitting agricultural film and be applicable to south and the most regional and northern summer at High aititude sunshine, micro-unrestrained
Scatter-type film can be suitable at northern area.
Accompanying drawing explanation
The present invention is further illustrated below in conjunction with the accompanying drawings.
Fig. 1 be the present invention disperse outside emitting apply drip defogging film in canopy heating rate affect chart.
Detailed description of the invention
For the technical characterstic of this programme can be clearly described, below by detailed description of the invention, and combine its accompanying drawing, to this
Bright it is described in detail.
Embodiment 1:
This disperses outside emitting coating drip defogging film, by five-layer co-squeezing thin film and the painting of being located at five-layer co-squeezing thin film outer surface
Coating forms, and described five-layer co-squeezing thin film is followed successively by dust layer, the first heat-insulation layer, the second heat-insulation layer, secondary internal layer, electricity from outside to inside
Dizzy layer, described coat is organosilicon coat, described dust layer, the first heat-insulation layer, the second heat-insulation layer, secondary internal layer, corona layer
Gross thickness be 120 μm, each layer thickness ratio is 1:1:1:1:1;
In described light scattering agent master batch, the weight ratio of light scattering agent PMMA Yu LLDPE is 1:4;The particle diameter of described PMMA is 5,
7, the weight ratio of two kinds of particle diameters is 6:4.
The content (kilogram) of each component see table:
Wherein, light scattering agent PMMA content in film is 5 ‰, and in five layers, the ratio of PMMA content is 3:3:2:1:1, gained
The scattering degree of coating drip defogging film outside emitting of dispersing is 20%, for micro-scattering film.
This disperses the preparation method applying drip defogging film outside emitting, employing following steps:
(1) organic silicon coating solution and the raw material of five-layer co-squeezing thin film every layer, wherein five-layer co-squeezing thin film are proportionally prepared
In every layer, the preparation method of contained light scattering agent master batch is: use banbury at 130 DEG C of bars after being mixed homogeneously by PMMA with LLDPE
Banburying 20-30min under part, makes PMMA emulsion dispersion use single screw pelletizer extrusion processing the most afterwards, obtains light scattering agent master batch,
Single screw pelletizer extrusion processing uses level Four heating, the barrel zone temperature of four thermals treatment zone be set as successively 148 DEG C, 157 DEG C,
152℃、128℃;
(2) profit after every layer of raw material of five-layer co-squeezing thin film step (1) prepared utilizes mixing equipment mixture respectively uniformly
Be blow molded into five-layer co-squeezing thin film with five-layer co-squeezing machine inflation film manufacturing machine, barrel zone temperature during each layer extrusion be respectively dust layer 210 DEG C, the
One heat-insulation layer 185 DEG C, the second heat-insulation layer 185 DEG C, secondary internal layer 190 DEG C, 190 DEG C of corona layer;
(3) obtain coating liquid with deionized water after first organic silicon coating solution stock solution being mixed homogeneously with the weight ratio of 1:17 to hold
In coating groove, then the surface of five-layer co-squeezing thin film is made to become through sided corona treatment the five-layer co-squeezing thin film that step (2) prepares
Coarse and increase its wettability to polar solvent, then by the coating liquid dip-coating in coating groove, dip-coating complete use scraper will
After unnecessary coating liquid shaves, at 60 DEG C, five-layer co-squeezing thin film is dried 30-40s, obtain described in disperse and outside emitting, apply stream
Drip defogging film.
Embodiment 2:
In described light scattering agent master batch, the weight ratio of light scattering agent PMMA Yu LLDPE is 1:3;The particle diameter of described PMMA is 3,
5 μm, the weight ratio of two kinds of particle diameters is 7:3.
The content (kilogram) of each component see table:
Wherein, light scattering agent PMMA content in film is 1.9%, and in five layers, the ratio of PMMA content is 3:3:2:1:1, institute
The scattering degree of coating drip defogging film outside emitting of must dispersing is 35%, for middle scattering film.
Embodiment 3:
In described light scattering agent master batch, the weight ratio of light scattering agent PMMA Yu LLDPE is 3:7;The particle diameter of described PMMA is
1.5,3 μm, the weight ratio of two kinds of particle diameters is 6:4.
The content (kilogram) of each component see table:
Wherein, light scattering agent PMMA content in film is 6%, and in five layers, the ratio of PMMA content is 3:3:2:1:1, gained
The scattering degree of coating drip defogging film outside emitting of dispersing is 65%, for total scattering film.
As it is shown in figure 1, after testing, the present invention disperses coating drip defogging film outside emitting, the least on light penetration impact,
Not affecting heating rate in canopy, in canopy, temperature relatively transparent film in peak is low 0.5-2 DEG C, on the premise of ensureing light penetration, and will
Some light scatters, and makes light be uniformly distributed in canopy.
The performance of drip defogging film is applied outside emitting, the present inventor's performance to agricultural film in all its bearings in order to verify to disperse
Being detected, result is as follows:
Table 1 present invention disperses the performance applying drip defogging film outside emitting
Project | Thick deg micron | Transmitance | Mist degree % | Hot strength MPa | Transverse and longitudinal percentage elongation % |
Hyaline membrane | 100 | 91.2 | 12 | 35.3/33.7 | 920/700 |
Embodiment 1 | 100 | 90.3 | 20 | 34.5/34.2 | 900/680 |
Embodiment 2 | 100 | 89.3 | 35 | 35.2/33.2 | 930/720 |
Embodiment 3 | 100 | 88.4 | 65 | 33.3/34.9 | 920/690 |
Light penetration, it will be seen that the present invention disperses coating drip defogging film outside emitting, is not had by data from upper table 1
Too much influence, agricultural film mist degree reaches 65%, and light transmittance can reach more than 88%, compares U.S. Agriculture
Solutions light-diffusing film (mist degree 60%, transmitance 83%), improves light transmittance greatly, and is not required to select special resin,
Can be realized as under existing fabrication process condition.
Claims (9)
1. disperse outside emitting a coating drip defogging film, it is characterized in that: by five-layer co-squeezing thin film and be located at five-layer co-squeezing thin film
The coat composition of outer surface, described five-layer co-squeezing thin film is followed successively by dust layer, the first heat-insulation layer, the second insulation from outside to inside
Layer, secondary internal layer, corona layer, described coat is organosilicon coat, described dust layer, the first heat-insulation layer, the second heat-insulation layer, secondary
Internal layer, the gross thickness of corona layer are 120 μm, and each layer thickness ratio is 1:1:1:1:1;
Described dust layer is made up of the raw material of following parts by weight: mLLDPE 20-25 part, light stabilizer 0.13-0.16 part, anti-
Oxygen agent 0.04-0.06 part, UV absorbent 0.02-0.04 part, antistatic additive 0.3-0.4 part, slipping agent 0.08-0.1 part, light
Scattering diluent master batch 0.75-6 part;
Described first heat-insulation layer is made up of the raw material of following parts by weight: mLLDPE 15-18 part, the EVA 11-15 of high VA content
Part, heat preserving agent 2-3.0 part, light stabilizer 0.13-0.16 part, antioxidant 0.04-0.06 part, UV absorbent 0.02-0.04
Part, light scattering agent master batch 0.75-5.6 part, in the EVA of described high VA content, VA content is 14%;
Described second heat-insulation layer is made up of the raw material of following parts by weight: EVA 14-15 part of low VA content, light stabilizer
0.13-0.16 part, antioxidant 0.05-0.06 part, UV absorbent 0.02-0.04 part, light scattering agent master batch 0.25-2.3 part,
In the EVA of described low VA content, VA content is 9%;
Described time internal layer is made up of the raw material of following parts by weight: LDPE 8-10 part, light stabilizer 0.13-0.16 part, antioxidant
0.05-0.06 part, UV absorbent 0.02-0.04 part, light scattering agent master batch 0.25-2.3 part;
Described corona layer is made up of the raw material of following parts by weight: LDPE 7.6-9.7 part, light stabilizer 0.13-0.16 part, anti-
Oxygen agent 0.04-0.06 part, UV absorbent 0.02-0.04 part, light scattering agent master batch 0.25-2.0 part;
Described light scattering agent master batch is made up of PMMA and LLDPE, and the weight ratio of PMMA and LLDPE is 1:4-3:7.
The most according to claim 1 dispersing applies drip defogging film outside emitting, it is characterized in that: described antioxidant is hindered phenol
Kind antioxidant.
The most according to claim 1 dispersing applies drip defogging film outside emitting, it is characterized in that: described light stabilizer is for being obstructed
Amine light stabilizer.
The most according to claim 1 dispersing applies drip defogging film outside emitting, it is characterized in that: described antistatic additive is glycerol
Single stearoyl ester.
The most according to claim 1 dispersing applies drip defogging film outside emitting, it is characterized in that: described slipping agent is oleic acid acyl
Amine.
The most according to claim 1 dispersing applies drip defogging film outside emitting, it is characterized in that: described heat preserving agent is 5000 mesh
Brucite.
The most according to claim 1 dispersing applies drip defogging film outside emitting, it is characterized in that: the particle diameter of described PMMA is
1.5, one or more in 2,3,5,7,10 μm.
The most according to claim 1 dispersing applies drip defogging film outside emitting, it is characterized in that: described UV absorbent is
UV-531。
9. as described in claim 1-8 is arbitrary disperse outside emitting apply drip defogging film a preparation method, it is characterized in that:
Comprise the steps:
(1) organic silicon coating solution and the raw material of five-layer co-squeezing thin film every layer, wherein five-layer co-squeezing thin film every layer are proportionally prepared
Contained by, the preparation method of light scattering agent master batch is: use banbury after being mixed homogeneously by PMMA with LLDPE under the conditions of 130 DEG C
Banburying 20-30min, makes PMMA emulsion dispersion use single screw pelletizer extrusion processing the most afterwards, obtains light scattering agent master batch, single spiral shell
Bar comminutor extrusion processing use level Four heating, the barrel zone temperature of four thermals treatment zone be set as successively 148 DEG C, 157 DEG C, 152 DEG C,
128℃;
(2) every layer of raw material of five-layer co-squeezing thin film step (1) prepared utilizes five after utilizing mixing equipment mixture respectively uniformly
Layer co-extrusion machine inflation film manufacturing machine is blow molded into five-layer co-squeezing thin film, and barrel zone temperature during each layer extrusion is respectively dust layer 210 DEG C, the first guarantor
Temperature 185 DEG C of layer, the second heat-insulation layer 185 DEG C, secondary internal layer 190 DEG C, 190 DEG C of corona layer;
(3) obtain coating liquid after first organic silicon coating solution stock solution being mixed homogeneously with the weight ratio of 1:17 with deionized water and be contained in painting
Cover in groove, then make the surface of five-layer co-squeezing thin film roughening through sided corona treatment the five-layer co-squeezing thin film that step (2) prepares
And increase its wettability to polar solvent, then by the coating liquid dip-coating in coating groove, dip-coating complete use scraper is by unnecessary
Coating liquid shave after, at 60 DEG C by five-layer co-squeezing thin film dry 30-40s, obtain described in disperse outside emitting apply drip disappear
Mist film.
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