CN106239772A - A kind of method of squash type separation blending medicated clothing composition - Google Patents

A kind of method of squash type separation blending medicated clothing composition Download PDF

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Publication number
CN106239772A
CN106239772A CN201610627508.3A CN201610627508A CN106239772A CN 106239772 A CN106239772 A CN 106239772A CN 201610627508 A CN201610627508 A CN 201610627508A CN 106239772 A CN106239772 A CN 106239772A
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Prior art keywords
heating roller
composite fibre
roller
medicated clothing
roll
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Application number
CN201610627508.3A
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Chinese (zh)
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CN106239772B (en
Inventor
尚诚德
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Anhui Yuze Plastic Technology Co.,Ltd.
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Jieshou City Yu Zesu Industry Co Ltd
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Priority to CN201610627508.3A priority Critical patent/CN106239772B/en
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29BPREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B17/00Recovery of plastics or other constituents of waste material containing plastics
    • B29B17/02Separating plastics from other materials
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01GPRELIMINARY TREATMENT OF FIBRES, e.g. FOR SPINNING
    • D01G11/00Disintegrating fibre-containing articles to obtain fibres for re-use
    • D01G11/04Opening rags to obtain fibres for re-use
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29BPREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B17/00Recovery of plastics or other constituents of waste material containing plastics
    • B29B17/02Separating plastics from other materials
    • B29B2017/0213Specific separating techniques
    • B29B2017/0255Specific separating techniques using different melting or softening temperatures of the materials to be separated
    • B29B2017/0258Specific separating techniques using different melting or softening temperatures of the materials to be separated using heated surfaces for selective softening or melting of at least one plastic ingredient
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/52Mechanical processing of waste for the recovery of materials, e.g. crushing, shredding, separation or disassembly
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/62Plastics recycling; Rubber recycling
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/66Disintegrating fibre-containing textile articles to obtain fibres for re-use

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Environmental & Geological Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Treatment Of Fiber Materials (AREA)

Abstract

A kind of method that the present invention relates to squash type separation blending medicated clothing composition, process for different blending compositions, process first by different solution, then carry out heating and carry out roller process, cotton is made to separate with Chemical fiber component, in the waste and old medicated clothing that the present invention provides, defibration method step is simple, after treatment, can effectively reduce the resolution ratio of fiber in processing procedure, keep the response rate as much as possible, the structure of fiber is not destroyed after recovery, avoid decomposing, promote the recovery utilization rate of waste and old medicated clothing, simultaneously, in removal process, first pass through solution process, the resolution ratio in processing procedure can either be reduced, in the application processing procedure, resolution ratio is within 2%, the speed separated can promote more than 20% relative to conventional method.

Description

A kind of method of squash type separation blending medicated clothing composition
Technical field
The invention belongs to waste reclaimation field, a kind of method being specifically related to squash type separation blending medicated clothing composition.
Background technology
Containing substantial amounts of chemical fibre in waste and old medicated clothing, but often use the side of directly burning in present processing method Formula processes, and can not effectively be recycled by composition therein not to the utmost, and can cause serious in burning process Environmental pollution, existing waste and old medicated clothing recoverying and utilizing method can only carry out simple classification process, then manufacture the article such as mop, Can not fundamentally solve waste and old medicated clothing to recycle.
Summary of the invention
It is an object of the invention to provide a kind of method being carried out by kind by fiber in waste and old medicated clothing and separating, fibre can be improved The separation accuracy of dimension and speed.
The present invention is achieved through the following technical solutions:
A kind of method of squash type separation blending medicated clothing composition, comprises the following steps:
Process for the cotton medicated clothing with blend polyester:
Medicated clothing is carried out by a, removes dirt and the oil stain of clothing surface, medicated clothing is broken into the diameter chip at 3-5cm, Chip is used mixed solution immersion treatment 45-50min, then cleans, remove unnecessary mixed solution, dry;Mixed solution It is made up of following raw material by weight: the Fluohydric acid. of mass fraction 0.5% 10 parts, 80 parts of the sulphuric acid of mass fraction 0.5%, terpenic oil 6 parts, dodecyl sodium sulfate 4.2 parts, sodium hexameta phosphate 2.5 parts, diformazan 18-amine. 1 part, stearmide 3.2 parts;
B, medicated clothing is ground into the composite fibre that particle diameter is 3mm, composite fibre uses lapping machine be processed into composite fibre net, Nitrogen protection is lower uses Electromechanic heating roller to carry out a roller process, and Electromechanic heating roller surface is smooth mirror roller, a roller Temperature when pressure processes is 180 DEG C, and composite fibre is processed into the composite fibre net that thickness is 1.3-1.5mm;
C, composite fibre net step b handled well use Electromechanic heating roller to carry out secondary roller process under nitrogen protection, electricity The roll body surface of magnetic heating roller, with bellmouth, is provided with cavity in roll body, bellmouth connects with cavity, the temperature of secondary roller process Degree is 248 DEG C, isolates fused mass and solids;
D, step c is processed after the solids that obtains use Electromechanic heating roller to carry out at three roll-ins under inert gas shielding Reason, the roll body surface of Electromechanic heating roller, with bellmouth, is provided with cavity in roll body, bellmouth connects with cavity, at three roll-ins The temperature of reason is 255 DEG C, fractional melting thing and solids;Collecting all fused mass, described fused mass is terylene, and solids is Cotton;
As follows with the process step of spandex blending medicated clothing for cotton:
A, medicated clothing is ground into the composite fibre that particle diameter is 2.2mm, composite fibre is used treatment fluid A immersion treatment 80- 90min, treatment fluid A are made up of following raw material by weight: 15 parts of the sulphuric acid of mass fraction 1%, 4.2 parts of glacial acetic acid, hexa metaphosphoric acid 0.5 part of sodium, ethyl acetate 4 parts;Composite fibre after being processed by treatment fluid A uses water rinsing, then uses at treatment fluid B immersion Reason 15min, described treatment fluid B are made up of following raw material by weight: 1.2 parts of carbamide, 2-amino-3-hydroxyl azophenlyene 0.2 part, water 20 parts;Wash after process, dry;
B, by step a process after composite fibre use lapping machine to be processed into composite fibre net composite fibre, nitrogen protect Lower use Electromechanic heating roller carries out a roller process, and Electromechanic heating roller surface is smooth mirror roller, during a roller process Temperature be 193 DEG C, composite fibre is processed into the composite fibre net that thickness is 1.2-1.5mm;
B, composite fibre net step a handled well use Electromechanic heating roller to carry out secondary roller process under nitrogen protection, electricity The roll body surface of magnetic heating roller, with bellmouth, is provided with cavity in roll body, bellmouth connects with cavity, the temperature of secondary roller process Degree is 245 DEG C, isolates fused mass and solids;
C, step b is processed after the solids that obtains use Electromechanic heating roller to carry out at three roll-ins under inert gas shielding Reason, the roll body surface of Electromechanic heating roller, with bellmouth, is provided with cavity in roll body, bellmouth connects with cavity, at three roll-ins The temperature of reason is 251 DEG C, fractional melting thing and solids;Collecting all fused mass, described fused mass is spandex, and solids is Cotton.
Described bellmouth connects with internal cavities, and the bellmouth diameter near side, roll body surface is less than internal diameter, Roll body side is provided with the connector that cavity is in communication with the outside.
Being provided with scraper discontiguous with Electromechanic heating roller by Electromechanic heating roller, scraper is axially arranged along Electromechanic heating roller, For preventing fiber at Electromechanic heating roller surfaces stick.
Described Electromechanic heating roller is divided into home roll and secondary roller, and the diameter of home roll is provided with therewith more than secondary rod, the cooperation of each home roll Match multiple secondary rod, and composite fibre net feeds from home roll, and home roll surface is mirror roller, secondary rod roll body surface with bellmouth, Being provided with cavity in roll body, the bellmouth diameter near conical surface side, less than internal diameter, sets by Electromechanic heating roller pair rod Have and the discontiguous scraper in secondary rod surface, be used for preventing fiber at Electromechanic heating roller surfaces stick.
Beneficial effects of the present invention: in the waste and old medicated clothing that the present invention provides, defibration method step is simple, through processing After, it is possible to effectively reduce the resolution ratio of fiber in processing procedure, keep the response rate as much as possible, after recovery, do not destroy fiber Structure, it is to avoid decompose, promotes the recovery utilization rate of waste and old medicated clothing, meanwhile, first passes through solution and process in removal process, can either Reducing the resolution ratio in processing procedure, in the application processing procedure, resolution ratio is within 2%, and the speed of separation is relative to routine side Method can promote more than 20%.
Detailed description of the invention
A kind of method of squash type separation blending medicated clothing composition, comprises the following steps:
Process for the cotton medicated clothing with blend polyester:
Medicated clothing is carried out by a, removes dirt and the oil stain of clothing surface, medicated clothing is broken into the diameter chip at 3-5cm, Chip is used mixed solution immersion treatment 45-50min, then cleans, remove unnecessary mixed solution, dry;Mixed solution It is made up of following raw material by weight: the Fluohydric acid. of mass fraction 0.5% 10 parts, 80 parts of the sulphuric acid of mass fraction 0.5%, terpenic oil 6 parts, dodecyl sodium sulfate 4.2 parts, sodium hexameta phosphate 2.5 parts, diformazan 18-amine. 1 part, stearmide 3.2 parts;
B, medicated clothing is ground into the composite fibre that particle diameter is 3mm, composite fibre uses lapping machine be processed into composite fibre net, Nitrogen protection is lower uses Electromechanic heating roller to carry out a roller process, and Electromechanic heating roller surface is smooth mirror roller, a roller Temperature when pressure processes is 180 DEG C, and composite fibre is processed into the composite fibre net that thickness is 1.3-1.5mm;
C, composite fibre net step b handled well use Electromechanic heating roller to carry out secondary roller process under nitrogen protection, electricity The roll body surface of magnetic heating roller, with bellmouth, is provided with cavity in roll body, bellmouth connects with cavity, the temperature of secondary roller process Degree is 248 DEG C, isolates fused mass and solids;
D, step c is processed after the solids that obtains use Electromechanic heating roller to carry out at three roll-ins under inert gas shielding Reason, the roll body surface of Electromechanic heating roller, with bellmouth, is provided with cavity in roll body, bellmouth connects with cavity, at three roll-ins The temperature of reason is 255 DEG C, fractional melting thing and solids;Collecting all fused mass, described fused mass is terylene, and solids is Cotton;
As follows with the process step of spandex blending medicated clothing for cotton:
A, medicated clothing is ground into the composite fibre that particle diameter is 2.2mm, composite fibre is used treatment fluid A immersion treatment 80- 90min, treatment fluid A are made up of following raw material by weight: 15 parts of the sulphuric acid of mass fraction 1%, 4.2 parts of glacial acetic acid, hexa metaphosphoric acid 0.5 part of sodium, ethyl acetate 4 parts;Composite fibre after being processed by treatment fluid A uses water rinsing, then uses at treatment fluid B immersion Reason 15min, described treatment fluid B are made up of following raw material by weight: 1.2 parts of carbamide, 2-amino-3-hydroxyl azophenlyene 0.2 part, water 20 parts;Wash after process, dry;
B, by step a process after composite fibre use lapping machine to be processed into composite fibre net composite fibre, nitrogen protect Lower use Electromechanic heating roller carries out a roller process, and Electromechanic heating roller surface is smooth mirror roller, during a roller process Temperature be 193 DEG C, composite fibre is processed into the composite fibre net that thickness is 1.2-1.5mm;
B, composite fibre net step a handled well use Electromechanic heating roller to carry out secondary roller process under nitrogen protection, electricity The roll body surface of magnetic heating roller, with bellmouth, is provided with cavity in roll body, bellmouth connects with cavity, the temperature of secondary roller process Degree is 245 DEG C, isolates fused mass and solids;
C, step b is processed after the solids that obtains use Electromechanic heating roller to carry out at three roll-ins under inert gas shielding Reason, the roll body surface of Electromechanic heating roller, with bellmouth, is provided with cavity in roll body, bellmouth connects with cavity, at three roll-ins The temperature of reason is 251 DEG C, fractional melting thing and solids;Collecting all fused mass, described fused mass is spandex, and solids is Cotton.
Described bellmouth connects with internal cavities, and the bellmouth diameter near side, roll body surface is less than internal diameter, Roll body side is provided with the connector that cavity is in communication with the outside.
Being provided with scraper discontiguous with Electromechanic heating roller by Electromechanic heating roller, scraper is axially arranged along Electromechanic heating roller, For preventing fiber at Electromechanic heating roller surfaces stick.
Described Electromechanic heating roller is divided into home roll and secondary roller, and the diameter of home roll is provided with therewith more than secondary rod, the cooperation of each home roll Match multiple secondary rod, and composite fibre net feeds from home roll, and home roll surface is mirror roller, secondary rod roll body surface with bellmouth, Being provided with cavity in roll body, the bellmouth diameter near conical surface side, less than internal diameter, sets by Electromechanic heating roller pair rod Have and the discontiguous scraper in secondary rod surface, be used for preventing fiber at Electromechanic heating roller surfaces stick.
Through cotton and the medicated clothing of blend polyester of this method process, after process, rate of weight loss is less than 3.5%, washs after separation The purity of synthetic fibre reaches 98.5%.Through cotton and the spandex blending medicated clothing of this method process, after process, rate of weight loss is less than 3.2%, After separation, the purity of terylene reaches 98.4%.More existing processing method, purity is obviously improved, and the temperature fall processed Low, decrease resolution ratio.The cotton of isolated of the present invention can be used for the modification of Colophonium, and chemical fibre can be used for the processing of other products.
The method and apparatus using the present invention can also separate the waste and old medicated clothing with other fibre compositions.

Claims (4)

1. the method for a squash type separation blending medicated clothing composition, it is characterised in that comprise the following steps:
Process for the cotton medicated clothing with blend polyester:
Medicated clothing is carried out by a, removes dirt and the oil stain of clothing surface, medicated clothing is broken into the diameter chip at 3-5cm, Chip is used mixed solution immersion treatment 45-50min, then cleans, remove unnecessary mixed solution, dry;Mixed solution It is made up of following raw material by weight: the Fluohydric acid. of mass fraction 0.5% 10 parts, 80 parts of the sulphuric acid of mass fraction 0.5%, terpenic oil 6 parts, dodecyl sodium sulfate 4.2 parts, sodium hexameta phosphate 2.5 parts, diformazan 18-amine. 1 part, stearmide 3.2 parts;
B, medicated clothing is ground into the composite fibre that particle diameter is 3mm, composite fibre uses lapping machine be processed into composite fibre net, Nitrogen protection is lower uses Electromechanic heating roller to carry out a roller process, and Electromechanic heating roller surface is smooth mirror roller, a roller Temperature when pressure processes is 180 DEG C, and composite fibre is processed into the composite fibre net that thickness is 1.3-1.5mm;
C, composite fibre net step b handled well use Electromechanic heating roller to carry out secondary roller process under nitrogen protection, electricity The roll body surface of magnetic heating roller, with bellmouth, is provided with cavity in roll body, bellmouth connects with cavity, the temperature of secondary roller process Degree is 248 DEG C, isolates fused mass and solids;
D, step c is processed after the solids that obtains use Electromechanic heating roller to carry out at three roll-ins under inert gas shielding Reason, the roll body surface of Electromechanic heating roller, with bellmouth, is provided with cavity in roll body, bellmouth connects with cavity, at three roll-ins The temperature of reason is 255 DEG C, fractional melting thing and solids;Collecting all fused mass, described fused mass is terylene, and solids is Cotton;
As follows with the process step of spandex blending medicated clothing for cotton:
A, medicated clothing is ground into the composite fibre that particle diameter is 2.2mm, composite fibre is used treatment fluid A immersion treatment 80- 90min, treatment fluid A are made up of following raw material by weight: 15 parts of the sulphuric acid of mass fraction 1%, 4.2 parts of glacial acetic acid, hexa metaphosphoric acid 0.5 part of sodium, ethyl acetate 4 parts;Composite fibre after being processed by treatment fluid A uses water rinsing, then uses at treatment fluid B immersion Reason 15min, described treatment fluid B are made up of following raw material by weight: 1.2 parts of carbamide, 2-amino-3-hydroxyl azophenlyene 0.2 part, water 20 parts;Wash after process, dry;
B, by step a process after composite fibre use lapping machine to be processed into composite fibre net composite fibre, nitrogen protect Lower use Electromechanic heating roller carries out a roller process, and Electromechanic heating roller surface is smooth mirror roller, during a roller process Temperature be 193 DEG C, composite fibre is processed into the composite fibre net that thickness is 1.2-1.5mm;
B, composite fibre net step a handled well use Electromechanic heating roller to carry out secondary roller process under nitrogen protection, electricity The roll body surface of magnetic heating roller, with bellmouth, is provided with cavity in roll body, bellmouth connects with cavity, the temperature of secondary roller process Degree is 245 DEG C, isolates fused mass and solids;
C, step b is processed after the solids that obtains use Electromechanic heating roller to carry out at three roll-ins under inert gas shielding Reason, the roll body surface of Electromechanic heating roller, with bellmouth, is provided with cavity in roll body, bellmouth connects with cavity, at three roll-ins The temperature of reason is 251 DEG C, fractional melting thing and solids;Collecting all fused mass, described fused mass is spandex, and solids is Cotton.
The method of a kind of squash type separation blending medicated clothing composition the most according to claim 1, it is characterised in that described taper Hole connects with internal cavities, and the bellmouth diameter near side, roll body surface is less than internal diameter, and roll body side is provided with cavity The connector being in communication with the outside.
The method of a kind of squash type separation blending medicated clothing composition the most according to claim 2, it is characterised in that add at electromagnetism Being provided with scraper discontiguous with Electromechanic heating roller by hot-rolling, scraper is axially arranged along Electromechanic heating roller, is used for preventing fiber at electricity Magnetic heating roller surface adhesion.
The method of a kind of squash type separation blending medicated clothing composition the most according to claim 3, it is characterised in that described electromagnetism Heating roller is divided into home roll and secondary roller, and the diameter of home roll is more than secondary rod, and the cooperation of each home roll is provided with cooperating therewith multiple secondary rod, mixed Condensating fiber net feeds from home roll, and home roll surface is mirror roller, and secondary rod roll body surface, with bellmouth, is provided with cavity in roll body, cone The shape hole diameter near conical surface side, less than internal diameter, is provided with by Electromechanic heating roller pair rod and does not contacts with secondary rod surface Scraper, be used for preventing fiber at Electromechanic heating roller surfaces stick.
CN201610627508.3A 2016-08-03 2016-08-03 A kind of method that squash type separates blended clothing component Active CN106239772B (en)

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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1527863A1 (en) * 2002-08-06 2005-05-04 Matsushita Refrigeration Company Method for recycling treatment of thermal insulating material, recycled article and refrigerator
CN101121289A (en) * 2007-09-21 2008-02-13 北京工业大学 Method for recovering and treating waste flexible circuit board
CN102264519A (en) * 2008-12-23 2011-11-30 大众汽车有限公司 Method for processing a textile fraction generated when processing used tires, and system for performing the method
CN102717451A (en) * 2012-07-04 2012-10-10 汨罗万容电子废弃物处理有限公司 Recycling treatment method and equipment of waste plastic
JP5162819B2 (en) * 2004-12-10 2013-03-13 東京電力株式会社 Material recycling method for waste optical fiber cable

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1527863A1 (en) * 2002-08-06 2005-05-04 Matsushita Refrigeration Company Method for recycling treatment of thermal insulating material, recycled article and refrigerator
JP5162819B2 (en) * 2004-12-10 2013-03-13 東京電力株式会社 Material recycling method for waste optical fiber cable
CN101121289A (en) * 2007-09-21 2008-02-13 北京工业大学 Method for recovering and treating waste flexible circuit board
CN102264519A (en) * 2008-12-23 2011-11-30 大众汽车有限公司 Method for processing a textile fraction generated when processing used tires, and system for performing the method
CN102717451A (en) * 2012-07-04 2012-10-10 汨罗万容电子废弃物处理有限公司 Recycling treatment method and equipment of waste plastic

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Address after: 236500 No. B16 Fanxing Fourth Road, Guangwu Industrial Zone, Jieshou City, Anhui Province

Patentee after: Anhui Yu Ze plastic industry Polytron Technologies Inc

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Denomination of invention: A method for extrusion separation of blended clothing components

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