CN106235536A - A kind of preparation method of self-moistening type resin teeth zipper - Google Patents

A kind of preparation method of self-moistening type resin teeth zipper Download PDF

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Publication number
CN106235536A
CN106235536A CN201610711718.0A CN201610711718A CN106235536A CN 106235536 A CN106235536 A CN 106235536A CN 201610711718 A CN201610711718 A CN 201610711718A CN 106235536 A CN106235536 A CN 106235536A
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CN
China
Prior art keywords
preparation
self
chain
type resin
slide fastener
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610711718.0A
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Chinese (zh)
Inventor
贾丙祥
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Sheng Zipper Technology (taicang) Co Ltd
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Sheng Zipper Technology (taicang) Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
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Priority to CN201610711718.0A priority Critical patent/CN106235536A/en
Publication of CN106235536A publication Critical patent/CN106235536A/en
Pending legal-status Critical Current

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Classifications

    • AHUMAN NECESSITIES
    • A44HABERDASHERY; JEWELLERY
    • A44BBUTTONS, PINS, BUCKLES, SLIDE FASTENERS, OR THE LIKE
    • A44B19/00Slide fasteners
    • A44B19/42Making by processes not fully provided for in one other class, e.g. B21D53/50, B21F45/18, B22D17/16, B29D5/00
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K13/00Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
    • C08K13/02Organic and inorganic ingredients
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/02Elements
    • C08K3/04Carbon
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/30Sulfur-, selenium- or tellurium-containing compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/04Oxygen-containing compounds
    • C08K5/06Ethers; Acetals; Ketals; Ortho-esters
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/30Sulfur-, selenium- or tellurium-containing compounds
    • C08K2003/3009Sulfides
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives

Abstract

The invention discloses the preparation method of a kind of self-moistening type resin teeth zipper, this preparation method comprises the steps: that a) selection is got the raw materials ready, b) preparation of raw material, c) injection-molded discharge miaow, d) chain post processing, e) assembling detection.Present invention is disclosed the preparation method of a kind of self-moistening type resin teeth zipper, this preparation method procedure arrangement is reasonable, preparation cost is moderate, the one-tenth assignment system that its chain strip adoption is unique, slide fastener is made in use to possess self-lubricity energy, effectively avoiding slide fastener and in use produce stuck phenomenon with medicated clothing, it is the most convenient to provide for daily life.

Description

A kind of preparation method of self-moistening type resin teeth zipper
Technical field
The present invention relates to the preparation method of a kind of resin teeth zipper, particularly relate to the preparation side of a kind of self-moistening type resin teeth zipper Method, belongs to zipper technology field.
Background technology
Slide fastener is dependent on continuously arranged chain tooth, makes article the connector closing or separating, is widely used in clothes now The fields such as dress, bag and tent.The structure of slide fastener is as follows: mainly include a pair base band, on the opposite side edge of base band respectively Row are provided with a row chain tooth, and chain tooth is fixing with base band to be connected, and is provided with the pull head making they engagements and separating between two row chain teeth, It is respectively arranged with upper stop member and lower stop member in the upper and lower end base band of every row chain tooth.Dividing according to the common used material of slide fastener, slide fastener can divide For nylon zipper, resin teeth zipper and metal zip fastener three major types.
Resin teeth zipper has by force, hardness high, be prone to the advantage such as molding and colouring, preparation technology simplicity, moderate cost, but deposits Higher in chain tooth surface roughness, the shortcomings such as coefficient of friction is bigger.Therefore, during the use of resin teeth zipper, especially clothing Slide fastener on clothes is easy to be stuck in clothes, produces the phenomenon that slide fastener is stuck.Running into this situation, people use brute-force mostly Pull chain, run counter to desire sometimes, make a mess of slide fastener.To this end, people take to smear the mode of paraffin or liquid detergent on slide fastener, profit Sliding slide fastener, to reduce the frictional force between chain tooth, in order to pull-out slide fastener.Although said method can eliminate the phenomenon that slide fastener is stuck, But people must lack convenience by foreign object, bring unnecessary trouble to the orthobiosis of people.
Summary of the invention
For the demand, the invention provides the preparation method of a kind of self-moistening type resin teeth zipper, this preparation method operation Arranging rationally, preparation cost is moderate, the one-tenth assignment system that its chain strip adoption is unique, makes slide fastener in use possess self-lubricity Can, effectively avoid slide fastener and in use produce stuck phenomenon with medicated clothing, provide pole for daily life The most convenient.
The present invention is the preparation method of a kind of self-moistening type resin teeth zipper, and this preparation method comprises the steps: that a) selection is standby Material, b) preparation of raw material, c) injection-molded discharge miaow, d) chain post processing, e) assembling detection.
In a preferred embodiment of the present invention, in described step a), the pull head on slide fastener, base band, upper stop member, lower stop member It is outsourcing piece, the material terylene of base band with latch square;Chain on slide fastener is moulding, its main component: polyformaldehyde tree Fat, self-lubricity filler and auxiliary agent;Self-lubricity filler is Nano graphite powder and the compound of molybdenum bisuphide micropowder, after milled processed Average particle size is 500-600 mesh;Auxiliary agent by dispersant polyethylene glycol 200 or PEG400, heat stabilizer benzoate or Stearate, antioxidant tea polyphenols or Butylated hydroxyanisole, curing agent ethylene diamine or diethylenetriamine and formaldehyde absorption Agent forms.
In a preferred embodiment of the present invention, in described step b), process for preparation is as follows: first, by acetal resin, Heat stabilizer, antioxidant and formaldehyde absorbent add to melt compounding in high temperature batch mixer, and batch mixer barrel temperature controls 180 DEG C-185 DEG C, fully merge;Then, adding self-lubricity filler and dispersant in barrel, barrel temperature is promoted to 5 DEG C-10 DEG C, rotating speed controls at 450-500r/min;Finally, adding firming agent in barrel, constant temperature is standby after stirring 20-25 minute.
In a preferred embodiment of the present invention, in described step c), row microphone machine parameter is provided that screw diameter is selected For 20mm, injection amount controls at 45-50g, and injection Stress control is at 120-130Mpa, and mold clamping force controls at 250-280KN, injection Temperature controls at 190 DEG C-200 DEG C;The injection mo(u)lding time of chain controls at 3-4s, at 60 DEG C of-65 DEG C of baking ovens after chain molding After interior process 30-35 minute, it is cooled to room temperature in atmosphere.
In a preferred embodiment of the present invention, in described step d), aftertreatment technology includes washing and dries, and uses pressure Power is that the deionized water of 0.1-0.12Mpa washes away chain, takes out the drying in oven at 30 DEG C-35 DEG C after unnecessary powder.
In a preferred embodiment of the present invention, in described step e), assembly technology is included in chain upper end and only installs Part and pull head, and stop member and latch square under chain lower end is installed;After assembling, slide fastener is carried out spacing cut-off part Reason;Finally, by the way of hand test, detect the serviceability of slide fastener;After detection, carry out packing and store.
Present invention is disclosed the preparation method of a kind of self-moistening type resin teeth zipper, this preparation method procedure arrangement is reasonable, preparation Moderate cost, the one-tenth assignment system that its chain strip adoption is unique, make slide fastener in use possess self-lubricity energy, effectively avoid Slide fastener in use produces stuck phenomenon with medicated clothing, and it is the most convenient to provide for daily life.
Accompanying drawing explanation
The present invention is further detailed explanation with detailed description of the invention below in conjunction with the accompanying drawings:
Fig. 1 is the process figure of the preparation method of embodiment of the present invention self-moistening type resin teeth zipper.
Detailed description of the invention
Below in conjunction with the accompanying drawings presently preferred embodiments of the present invention is described in detail, so that advantages and features of the invention energy It is easier to be readily appreciated by one skilled in the art, thus protection scope of the present invention is made apparent clear and definite defining.
Fig. 1 is the process figure of the preparation method of embodiment of the present invention self-moistening type resin teeth zipper;This preparation method includes Following steps: a) selection is got the raw materials ready, b) preparation of raw material, c) injection-molded discharge miaow, d) chain post processing, e) assembling detection.
Embodiment 1
The concrete preparation process of the self-moistening type resin teeth zipper that the present invention mentions is as follows:
A) selection is got the raw materials ready, and pull head, base band, upper stop member, lower stop member and latch square on slide fastener are outsourcing piece, in addition to base band its Material is usually engineering plastics or metal, the material terylene of base band, and thickness is 0.3mm;Chain on slide fastener is moulding, and it is main Composition and the percentage composition proportioning thereof is wanted to be: acetal resin 82%, self-lubricity filler 10%, remaining is auxiliary agent;Self-lubricity filler is Nano graphite powder and the compound of molybdenum bisuphide micropowder, mixed proportion is about 3:1, by the average particle size after milled processed is 550 mesh;Auxiliary agent by dispersant polyethylene glycol 200, heat stabilizer benzoate, antioxidant tea polyphenols, curing agent ethylene diamine with And formaldehyde absorbent composition;
B) preparation of raw material, process for preparation is as follows: first, acetal resin, heat stabilizer, antioxidant and formaldehyde absorbent is added Adding to melt compounding in high temperature batch mixer, batch mixer barrel temperature controls, at 180 DEG C-185 DEG C, fully to merge;Then, to barrel Middle interpolation self-lubricity filler and dispersant, barrel temperature is promoted to 5 DEG C-7 DEG C, and rotating speed controls at 450r/min;Finally, to barrel Middle interpolation firming agent, constant temperature is standby after stirring 25 minutes;
C) injection-molded discharge miaow, row microphone machine parameter is provided that screw diameter is chosen to be 20mm, and injection amount controls at 45g, injection pressure Controlling at 120Mpa, mold clamping force controls at 250KN, and injection temperature controls at 190 DEG C-195 DEG C;The injection mo(u)lding time control of chain After system processes 35 minutes after 3-4s, chain molding in 60 DEG C of baking ovens, it is cooled to room temperature in atmosphere;
D) chain post processing, aftertreatment technology includes washing and dries, and the deionized water using pressure to be 0.1-0.12Mpa washes away Chain, takes out the drying in oven at 30 DEG C-35 DEG C after unnecessary powder;
E) assembling detection, assembly technology is included in chain upper end and installs stop member and pull head, and stops under chain lower end is installed Part and latch square;After assembling, slide fastener is carried out spacing cut-out process;Finally, detect by the way of hand test and draw The serviceability of chain;After detection, carry out packing and store.
Embodiment 2
The concrete preparation process of the self-moistening type resin teeth zipper that the present invention mentions is as follows:
A) selection is got the raw materials ready, and pull head, base band, upper stop member, lower stop member and latch square on slide fastener are outsourcing piece, in addition to base band its Material is usually engineering plastics or metal, the material terylene of base band, and thickness is 0.35mm;Chain on slide fastener is moulding, its Main component and percentage composition proportioning thereof be: acetal resin 81%, self-lubricity filler 11%, remaining is auxiliary agent;Self-lubricity filler For Nano graphite powder and the compound of molybdenum bisuphide micropowder, mixed proportion is about 3:1, by the average particle size after milled processed It is 550 mesh;Auxiliary agent is by dispersant PEG400, heat stabilizer stearate, antioxidation Butylated hydroxyanisole, firming agent Diethylenetriamine and formaldehyde absorbent composition;
B) preparation of raw material, process for preparation is as follows: first, acetal resin, heat stabilizer, antioxidant and formaldehyde absorbent is added Adding to melt compounding in high temperature batch mixer, batch mixer barrel temperature controls, at 180 DEG C-185 DEG C, fully to merge;Then, to barrel Middle interpolation self-lubricity filler and dispersant, barrel temperature is promoted to 6 DEG C-8 DEG C, and rotating speed controls at 500r/min;Finally, to barrel Middle interpolation firming agent, constant temperature is standby after stirring 20 minutes;
C) injection-molded discharge miaow, row microphone machine parameter is provided that screw diameter is chosen to be 20mm, and injection amount controls at 48g, injection pressure Controlling at 125Mpa, mold clamping force controls at 260KN, and injection temperature controls at 195 DEG C-200 DEG C;The injection mo(u)lding time control of chain After system processes 30 minutes after 3-4s, chain molding in 65 DEG C of baking ovens, it is cooled to room temperature in atmosphere;
D) chain post processing, aftertreatment technology includes washing and dries, and the deionized water using pressure to be 0.1-0.12Mpa washes away Chain, takes out the drying in oven at 30 DEG C-35 DEG C after unnecessary powder;
E) assembling detection, assembly technology is included in chain upper end and installs stop member and pull head, and stops under chain lower end is installed Part and latch square;After assembling, slide fastener is carried out spacing cut-out process;Finally, detect by the way of hand test and draw The serviceability of chain;After detection, carry out packing and store.
Present invention is disclosed the preparation method of a kind of self-moistening type resin teeth zipper, be characterized in: this preparation method procedure arrangement Rationally, preparation cost is moderate, the one-tenth assignment system that its chain strip adoption is unique, makes slide fastener in use possess self-lubricity energy, has The slide fastener that avoids of effect in use produces stuck phenomenon with medicated clothing, provides the most just for daily life Prompt.
The above, the only detailed description of the invention of the present invention, but protection scope of the present invention is not limited thereto, and any Those of ordinary skill in the art in the technical scope that disclosed herein, the change that can expect without creative work or Replace, all should contain within protection scope of the present invention.Therefore, protection scope of the present invention should be limited with claims Fixed protection domain is as the criterion.

Claims (6)

1. the preparation method of a self-moistening type resin teeth zipper, it is characterised in that this preparation method comprises the steps: that a) selection is standby Material, b) preparation of raw material, c) injection-molded discharge miaow, d) chain post processing, e) assembling detection.
The preparation method of self-moistening type resin teeth zipper the most according to claim 1, it is characterised in that in described step a), Pull head, base band, upper stop member, lower stop member and latch square on slide fastener are outsourcing piece, the material terylene of base band;Chain on slide fastener Bar is moulding, its main component: acetal resin, self-lubricity filler and auxiliary agent;Self-lubricity filler is Nano graphite powder and two The compound of molybdenum sulfide micropowder, the average particle size after milled processed is 500-600 mesh;Auxiliary agent is by dispersant polyethylene glycol 200 Or PEG400, heat stabilizer benzoate or stearate, antioxidant tea polyphenols or Butylated hydroxyanisole, solidification Agent ethylenediamine or diethylenetriamine and formaldehyde absorbent form.
The preparation method of self-moistening type resin teeth zipper the most according to claim 1, it is characterised in that in described step b), Process for preparation is as follows: first, adds acetal resin, heat stabilizer, antioxidant and formaldehyde absorbent to high temperature batch mixer Middle melt compounding, batch mixer barrel temperature controls, at 180 DEG C-185 DEG C, fully to merge;Then, in barrel, add self-lubricity to fill out Material and dispersant, barrel temperature is promoted to 5 DEG C-10 DEG C, and rotating speed controls at 450-500r/min;Finally, add admittedly in barrel Agent, constant temperature is standby after stirring 20-25 minute.
The preparation method of self-moistening type resin teeth zipper the most according to claim 1, it is characterised in that in described step c), Row microphone machine parameter is provided that screw diameter is chosen to be 20mm, and injection amount controls at 45-50g, and injection Stress control is at 120- 130Mpa, mold clamping force controls at 250-280KN, and injection temperature controls at 190 DEG C-200 DEG C;The injection mo(u)lding time of chain controls After processing 30-35 minute in 60 DEG C of-65 DEG C of baking ovens after 3-4s, chain molding, it is cooled to room temperature in atmosphere.
The preparation method of self-moistening type resin teeth zipper the most according to claim 1, it is characterised in that in described step d), Aftertreatment technology includes washing and dries, and the deionized water using pressure to be 0.1-0.12Mpa washes away chain, takes out unnecessary powder After the drying in oven of 30 DEG C-35 DEG C.
The preparation method of self-moistening type resin teeth zipper the most according to claim 1, it is characterised in that in described step e), Assembly technology is included in chain upper end and installs stop member and pull head, and stop member and latch square under chain lower end is installed;Dress After joining, slide fastener is carried out spacing cut-out process;Finally, by the way of hand test, detect the serviceability of slide fastener;Inspection After survey, carry out packing and store.
CN201610711718.0A 2016-08-24 2016-08-24 A kind of preparation method of self-moistening type resin teeth zipper Pending CN106235536A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108783771A (en) * 2018-07-08 2018-11-13 李少琴 A kind of wear-resisting type resin teeth zipper and its production method

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Publication number Priority date Publication date Assignee Title
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CN102558753A (en) * 2010-12-27 2012-07-11 合肥杰事杰新材料股份有限公司 Reinforced toughened self-lubricating polyformaldehyde composite material and preparation method thereof
CN103096750A (en) * 2010-09-17 2013-05-08 Ykk株式会社 Slide fastener and method of producing slide fastener
CN103554827A (en) * 2013-10-28 2014-02-05 大英县斯佩克新材料有限公司 Long-glass-fiber composite material composited with polyoxymethylene, and preparation method of composite material
CN103613903A (en) * 2013-11-25 2014-03-05 大连路阳科技开发有限公司 Friction-resistant composite material and preparation method thereof
CN103613902A (en) * 2013-11-25 2014-03-05 大连路阳科技开发有限公司 Heat-conducting friction-resistant polyformaldehyde composite material and preparation method thereof
CN103992614A (en) * 2014-06-09 2014-08-20 云南云天化股份有限公司 Polyacetal resin composition and preparation method thereof
CN106213698A (en) * 2016-08-24 2016-12-14 道晟拉链科技(太仓)有限公司 A kind of preparation method of flame-retardant resin slide fastener

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101619155A (en) * 2009-08-07 2010-01-06 苏州工业园区富事达塑业有限责任公司(苏州塑料一厂) Wear-resistant and heat-resistant acetal resin
CN103096750A (en) * 2010-09-17 2013-05-08 Ykk株式会社 Slide fastener and method of producing slide fastener
CN102558753A (en) * 2010-12-27 2012-07-11 合肥杰事杰新材料股份有限公司 Reinforced toughened self-lubricating polyformaldehyde composite material and preparation method thereof
CN103554827A (en) * 2013-10-28 2014-02-05 大英县斯佩克新材料有限公司 Long-glass-fiber composite material composited with polyoxymethylene, and preparation method of composite material
CN103613903A (en) * 2013-11-25 2014-03-05 大连路阳科技开发有限公司 Friction-resistant composite material and preparation method thereof
CN103613902A (en) * 2013-11-25 2014-03-05 大连路阳科技开发有限公司 Heat-conducting friction-resistant polyformaldehyde composite material and preparation method thereof
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CN106213698A (en) * 2016-08-24 2016-12-14 道晟拉链科技(太仓)有限公司 A kind of preparation method of flame-retardant resin slide fastener

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108783771A (en) * 2018-07-08 2018-11-13 李少琴 A kind of wear-resisting type resin teeth zipper and its production method
CN108783771B (en) * 2018-07-08 2020-12-18 浙江达威拉链有限公司 Wear-resistant resin zipper and production method thereof

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Application publication date: 20161221