CN106223056A - A kind of environmental protection cleaning wiping cloth and preparation method thereof - Google Patents

A kind of environmental protection cleaning wiping cloth and preparation method thereof Download PDF

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Publication number
CN106223056A
CN106223056A CN201610578651.8A CN201610578651A CN106223056A CN 106223056 A CN106223056 A CN 106223056A CN 201610578651 A CN201610578651 A CN 201610578651A CN 106223056 A CN106223056 A CN 106223056A
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CN
China
Prior art keywords
time
environmental protection
cleaning wiping
base cloth
wiping cloth
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610578651.8A
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Chinese (zh)
Inventor
葛慧宪
李鹏
杨沛
张红芸
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CTA HI-TECH TEXTILES Co Ltd
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CTA HI-TECH TEXTILES Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Publication date
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Priority to CN201610578651.8A priority Critical patent/CN106223056A/en
Publication of CN106223056A publication Critical patent/CN106223056A/en
Pending legal-status Critical Current

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Classifications

    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/12Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins
    • D06N3/14Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins with polyurethanes
    • D06N3/145Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins with polyurethanes two or more layers of polyurethanes
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0002Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate
    • D06N3/0011Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate using non-woven fabrics
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0043Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by their foraminous structure; Characteristics of the foamed layer or of cellular layers
    • D06N3/005Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by their foraminous structure; Characteristics of the foamed layer or of cellular layers obtained by blowing or swelling agent
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0086Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the application technique
    • D06N3/0088Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the application technique by directly applying the resin
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2211/00Specially adapted uses
    • D06N2211/08Cleaning articles

Abstract

The invention provides a kind of environmental protection cleaning wiping cloth and preparation method thereof, and including base cloth layer, the two sides of described base cloth layer is equipped with coating, wherein: described base cloth layer is spun-laced nonwoven fabric, and the weight of described base cloth layer is 50 200g/m2;Described coating includes the component of following mass fraction: 90 110 parts of foaming agent of aqueous PU resin 16 parts;Foam stabilizer 18 parts;Levelling agent 0.1 2 parts;Thickening agent 1.5 2 parts.The invention overcomes the deficiencies in the prior art, soaks and wrings out rear cleaning glass window and paint bright finish, glass and the clean water stain-free of lacquer painting, wipe dirty cleaning wiping cloth put into after water cleans clean the most as before, be the economic and environment-friendly type cleaning wiping cloth of a high efficiency, repeatable utilization.

Description

A kind of environmental protection cleaning wiping cloth and preparation method thereof
Technical field
The invention belongs to cleaning wiping cloth field, especially relates to a kind of environmental protection cleaning wiping cloth and preparation method thereof.
Background technology
Mostly cleaning wiping cloth of the prior art is cotton material, and dirt-removing power is poor, and service life is low, and wiping complete after can at thing Surface stays water stain.
Summary of the invention
In view of this, the invention is directed to a kind of environmental protection cleaning wiping cloth and preparation method thereof, to overcome prior art Deficiency, soak and wring out rear cleaning glass window and paint bright finish, glass and the clean water stain-free of lacquer painting, wiping dirty cleaning wiping cloth, to put water into clear After washing the most as before, it is the economic and environment-friendly type cleaning wiping cloth of a high efficiency, repeatable utilization.
For reaching above-mentioned purpose, the technical scheme of the invention is achieved in that
A kind of environmental protection cleaning wiping cloth, including base cloth layer, the two sides of described base cloth layer is equipped with coating, wherein:
Described base cloth layer is spun-laced nonwoven fabric, and the weight of described base cloth layer is 50-200 gram/m2
Described coating includes the component of following mass fraction:
Further, the effect of described foaming agent is so that described aqueous PU is resin expanded, if the amount of described foaming agent Little, do not have the effect of foaming, if the amount of described foaming agent is excessive, then cause final products surface irregularity, be unfavorable for wiping Wipe and outward appearance unsightly;The effect of described foam stabilizer is to maintain the foam stabilization sent, will not rapid disruption.Described foam stabilizer Addition determine according to the addition of described foaming agent, if addition is excessive, foam stability can more preferably, but wash resistant is just Can be deteriorated;If too small, then do not have the effect of stable foaming.
Further, described coating also includes aqueous color paste 0.5-2 part, and aqueous color paste plays an aesthetic, but, If aqueous color paste addition is excessive, mill base precipitation phenomenon can be caused, thus affect the using effect of finished product, therefore water in the present invention The consumption of property mill base is preferable amount.
Further, aqueous PU resin is aqueous foaming PU resin, and aqueous PU resin is aqueous foaming PU resin, described Aqueous PU foam resin viscosity at a temperature of 25 DEG C is 3000-10000Pa.s, solids content 30-50%, and 100% modulus is 0.5-3MPa, if the viscosity of described aqueous PU foam resin is excessive, then slurry difficulty of transportation, also it is unfavorable for foaming;Viscosity mistake The easy rapid disruption of another typical material.
Further, described foaming agent is anionic high fatty alcohol sulfuric acid ester foaming agent.
Further, described foam stabilizer is stearic acid ammonia solution, and in described ammonium stearate solution, the quality of ammonium stearate contains Amount is 50%-80%.
Further, described levelling agent is silicone levelling agent, and described thickening agent is polyurethanes non-alkaline thickening agent. It is smooth smooth with surface that the effect of levelling agent is to maintain coating, and the beneficially rub resistance of product, when being applied to wiping field, adds Enter described levelling agent and can extend the service life of described cleaning wiping cloth.
The preparation method of a kind of environmental protection cleaning wiping cloth, comprises the following steps:
(1) after each component in described coating being stirred evenly, utilizing mechanical foaming machine to foam, expansion ratio is 2-6 times;
(2) the described coating after foaming is coated on the one side of described base cloth layer;
(3) described step (2) products obtained therefrom is dried for the first time;
(4) the described coating after foaming is coated to the another side of described base cloth layer;
(5) described step (4) products obtained therefrom second time is dried.
Further, the expansion ratio in described step (1) refers to, volume and the ratio of foaming front volume after foaming.
Further, the coating in described step (2) and described step (4) refers to utilize scraper to coat.
Further, the drying temperature that described first time dries in drying with described second time is 90-150 DEG C, during drying Between be 2-5min, after drying the quality of described base cloth layer be 50-300 gram/.
Further, described first time dries and described second time is dried and is syllogic drying, and described first time dries The drying temperature dried with second time is followed successively by 90 DEG C, 120 DEG C, 150 DEG C, the drying that described first time dries and second time is dried Total time is 2-5min, it is preferred that described three sections of every section of drying times dried are equal.
Relative to prior art, the invention has the advantage that
(1) multiple structure, service life is long.
(2) soak wring out rear cleaning glass window and paint bright finish, glass and the clean water stain-free of lacquer painting.This product can keep wiping Only not staying water stain, its principle is that this product surface is similar to spongy body, and spongy body is effectively bonded together with non-woven fabrics again, water Part is adsorbed by non-woven fabrics always, and surface spongy body is always maintained at dry condition, so glass and paint bright finish ensure that clean nothing Water stain.
Detailed description of the invention
Unless otherwise indicated, term used herein is respectively provided with the implication that those skilled in the art's routine understands, in order to Readily appreciate the present invention, terms more used herein have been carried out following definitions.
Using in the specification and in the claims, odd number type " " and " this " include plural reference, unless on The most separately have and clearly state.Such as, term " (one) cell " includes the cell of plural number, including its mixture.
All of Digital ID, such as pH, temperature, time, concentration, including scope, be all approximation.It is to be understood that, although Term " about " is all added before all of Digital ID of the clearest and the most definite narration.Simultaneously it will also be understood that, although the clearest and the most definite Narration, reagent described herein is only example, and its equivalent is known in the art.
The invention is described in detail below in conjunction with embodiment.
Embodiment 1
A kind of environmental protection cleaning wiping cloth, including base cloth layer, the two sides of described base cloth layer is equipped with coating, wherein:
Described base cloth layer is spun-laced nonwoven fabric, and the weight of described base cloth layer is 50 grams/m2
Described coating includes the component of following mass fraction:
The preparation method of described a kind of environmental protection cleaning wiping cloth, comprises the following steps:
(1) after each component in described coating being stirred evenly, utilizing mechanical foaming machine to foam, expansion ratio is 2 times;
(2) the described coating after foaming is coated on the one side of described base cloth layer;
(3) being dried for the first time by described step (2) products obtained therefrom, drying temperature is 90 DEG C;
(4) the described coating after foaming is coated to the another side of described base cloth layer;
(5) described step (4) products obtained therefrom second time being dried, drying temperature is 90 DEG C.
Coating in described step (2) and described step (4) refers to utilize scraper to coat.
Second time dry after the unit are weightening finish of described base cloth layer be 50 grams/.
Described first time dries and described second time is dried and is syllogic drying, and described first time dries and second time is dried Dry drying temperature is followed successively by 90 DEG C, 120 DEG C, 150 DEG C, and the drying total time that described first time dries and second time is dried is 2- 5min, it is preferred that described three sections of every section of drying times dried are equal.
Embodiment 2
A kind of environmental protection cleaning wiping cloth, including base cloth layer, the two sides of described base cloth layer is equipped with coating, wherein:
Described base cloth layer is spun-laced nonwoven fabric, and the weight of described base cloth layer is 100 grams/m2
Described coating includes the component of following mass fraction:
The preparation method of described a kind of environmental protection cleaning wiping cloth, comprises the following steps:
(1) after each component in described coating being stirred evenly, utilizing mechanical foaming machine to foam, expansion ratio is 4 times;
(2) the described coating after foaming is coated on the one side of described base cloth layer;
(3) being dried for the first time by described step (2) products obtained therefrom, drying temperature is 90 DEG C;
(4) the described coating after foaming is coated to the another side of described base cloth layer;
(5) described step (4) products obtained therefrom second time being dried, drying temperature is 90 DEG C.
Coating in described step (2) and described step (4) refers to utilize scraper to coat.
Second time dry after the unit are weightening finish of described base cloth layer be 50 grams/.
Described first time dries and described second time is dried and is syllogic drying, and described first time dries and second time is dried Dry drying temperature is followed successively by 90 DEG C, 120 DEG C, 150 DEG C, and described first time dries and the drying total time of second time drying is 3min, described three sections of every section of drying times dried are equal.
Embodiment 3
A kind of environmental protection cleaning wiping cloth, including base cloth layer, the two sides of described base cloth layer is equipped with coating, wherein:
Described base cloth layer is spun-laced nonwoven fabric, and the weight of described base cloth layer is 200 grams/m2
Described coating includes the component of following mass fraction:
The preparation method of described a kind of environmental protection cleaning wiping cloth, comprises the following steps:
(1) after each component in described coating being stirred evenly, utilizing mechanical foaming machine to foam, expansion ratio is 2 times;
(2) the described coating after foaming is coated on the one side of described base cloth layer;
(3) being dried for the first time by described step (2) products obtained therefrom, drying temperature is 90 DEG C;
(4) the described coating after foaming is coated to the another side of described base cloth layer;
(5) described step (4) products obtained therefrom second time being dried, drying temperature is 90 DEG C.
Coating in described step (2) and described step (4) refers to utilize scraper to coat.
Second time dry after the unit are weightening finish of described base cloth layer be 200 grams/.
Described first time dries and described second time is dried and is syllogic drying, and described first time dries and second time is dried Dry drying temperature is followed successively by 90 DEG C, 120 DEG C, 150 DEG C, and described first time dries and the drying total time of second time drying is 5min, described three sections of every section of drying times dried are equal.
Table 1 is embodiment 1 and the performance comparison of comparative example 1, wherein, and described comparative example 1 and the formula base of described embodiment 1 This is identical, and described comparative example 1 is with the difference of described embodiment 1, and described comparative example 1 uses aqueous acrylic resin Replace waterborne polyurethane resin.
Table 1: embodiment 1 and comparative example 1 and wiping properties compare
As it can be seen from table 1 the product surface that water soluble acrylic acid is made is tacky, after long-time washing, there is dissolution phenomena, and Aqueous polyurethane does not then have this phenomenon, so this product preferably aqueous polyurethane is main material.
Table 2 is the impact on product foaming relation of the different foaming agent addition, comparative example 3-comparative example 5 and embodiment 1 Formula is essentially identical, and comparative example 3-comparative example 5 is with the difference of described embodiment 1, and the foaming agent number of interpolation is different.
Table 2: foaming agent addition and foaming relation
Foaming agent consumption is the biggest as can be seen from Table 2 more easily foams.
Table 3 is foam stabilizer addition and foam stability and properties of product relation, and wherein, comparative example 6-comparative example 8 is with real The formula executing example 1 is essentially identical, and comparative example 6-comparative example 8 is with the difference of described embodiment 1, foam stabilizer part of interpolation Number difference.
Table 3: foam stabilizer addition and foam stability and properties of product relation
The addition of stabilizer more macrofoam is the most stable as can be seen from Table 3, but water-fastness just not as 4 parts after being added to 7 parts Following is good, so foam stabiliser is preferably 4 parts.
Table 4: expansion ratio and outward appearance and wiping properties relation
The low surfaces of tacky of expansion ratio as can be seen from Table 4, wiping effect is the most bad, expansion ratio the highest wiping effect meeting The best, but expansion ratio is transferred to apparent effect when 6 times and rough phenomenon is occurred, and expansion ratio is outward appearance and wiping when 4 times Effect is best, thus finally with expansion ratio 4 times be optimal.
The foregoing is only the preferred embodiment of the invention, not in order to limit the invention, all at this Within the spirit of innovation and creation and principle, any modification, equivalent substitution and improvement etc. made, should be included in the invention Protection domain within.

Claims (10)

1. an environmental protection cleaning wiping cloth, it is characterised in that: include that base cloth layer, the two sides of described base cloth layer are equipped with coating, wherein:
Described base cloth layer is spun-laced nonwoven fabric, and the weight of described base cloth layer is 50-200 gram/m2
Described coating includes the component of following mass fraction:
A kind of environmental protection cleaning wiping cloth the most according to claim 1, it is characterised in that: described coating also includes aqueous color paste 0.5- 2 parts.
A kind of environmental protection cleaning wiping cloth the most according to claim 1, it is characterised in that: aqueous PU resin is aqueous foaming PU tree Fat, described aqueous PU foam resin viscosity at a temperature of 25 DEG C is 3000-10000Pa.s, solids content 30-50%, 100% mould Amount is 0.5-3MPa.
A kind of environmental protection cleaning wiping cloth the most according to claim 1, it is characterised in that: described foaming agent is the senior fat of anionic Fat alcohol sulfuric acid ester foaming agent.
A kind of environmental protection cleaning wiping cloth the most according to claim 1, it is characterised in that: described foam stabilizer is stearic acid ammonia solution, In described ammonium stearate solution, the mass content of ammonium stearate is 50%-80%.
A kind of environmental protection cleaning wiping cloth the most according to claim 1, it is characterised in that: described levelling agent is silicone levelling Agent, described thickening agent is polyurethanes non-alkaline thickening agent.
7. the preparation method of a kind of environmental protection cleaning wiping cloth described in claim 1 or 2, it is characterised in that: comprise the following steps:
(1) after each component in described coating being stirred evenly, utilizing mechanical foaming machine to foam, expansion ratio is 2-6 times;
(2) the described coating after foaming is coated on the one side of described base cloth layer;
(3) described step (2) products obtained therefrom is dried for the first time;
(4) the described coating after foaming is coated to the another side of described base cloth layer;
(5) described step (4) products obtained therefrom second time is dried.
The preparation method of a kind of environmental protection cleaning wiping cloth the most according to claim 7, it is characterised in that: described step (2) and institute State the coating in step (4) to refer to utilize scraper to coat.
The preparation method of a kind of environmental protection cleaning wiping cloth the most according to claim 7, it is characterised in that: described first time dry and Drying temperature during described second time is dried is 90-150 DEG C, and drying time is 2-5min, described base cloth layer after second time drying Unit are weightening finish for 50-300 gram/.
The preparation method of a kind of environmental protection cleaning wiping cloth the most according to claim 9, it is characterised in that: described first time dries Drying with described second time and be syllogic drying, the drying temperature that described first time dries and second time is dried is followed successively by 90 DEG C, 120 DEG C, 150 DEG C, described first time dry and second time dry drying total time be 2-5min, it is preferred that described three sections The every section of drying time dried is equal.
CN201610578651.8A 2016-07-19 2016-07-19 A kind of environmental protection cleaning wiping cloth and preparation method thereof Pending CN106223056A (en)

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Application Number Priority Date Filing Date Title
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Publication Number Publication Date
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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108252106A (en) * 2016-12-29 2018-07-06 天津圣奥无纺布有限公司 A kind of antibacterial nonwoven cloth
CN108796913A (en) * 2018-07-10 2018-11-13 浙江美欣达纺织印染科技有限公司 Double-side different color coating process
CN109881370A (en) * 2019-04-08 2019-06-14 江西昊瑞工业材料有限公司 A kind of non-woven fabrics wiper of excellent adsorption and preparation method thereof
CN110904693A (en) * 2019-12-12 2020-03-24 上海自见新材料科技有限公司 Waterborne polyurethane double-sided wiping leather and production method thereof

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108252106A (en) * 2016-12-29 2018-07-06 天津圣奥无纺布有限公司 A kind of antibacterial nonwoven cloth
CN108796913A (en) * 2018-07-10 2018-11-13 浙江美欣达纺织印染科技有限公司 Double-side different color coating process
CN109881370A (en) * 2019-04-08 2019-06-14 江西昊瑞工业材料有限公司 A kind of non-woven fabrics wiper of excellent adsorption and preparation method thereof
CN110904693A (en) * 2019-12-12 2020-03-24 上海自见新材料科技有限公司 Waterborne polyurethane double-sided wiping leather and production method thereof

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