CN106222552A - High-strength wearable type steel for ball mill steel ball and preparation method thereof - Google Patents

High-strength wearable type steel for ball mill steel ball and preparation method thereof Download PDF

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Publication number
CN106222552A
CN106222552A CN201610686778.1A CN201610686778A CN106222552A CN 106222552 A CN106222552 A CN 106222552A CN 201610686778 A CN201610686778 A CN 201610686778A CN 106222552 A CN106222552 A CN 106222552A
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steel
ball
ball mill
wearable type
strength wearable
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Inventor
房少卿
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Rong Tai Mechanical Fitting Co Ltd Of Dengfeng City
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Rong Tai Mechanical Fitting Co Ltd Of Dengfeng City
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Priority to CN201610686778.1A priority Critical patent/CN106222552A/en
Publication of CN106222552A publication Critical patent/CN106222552A/en
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    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/04Ferrous alloys, e.g. steel alloys containing manganese
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21CPROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
    • C21C7/00Treating molten ferrous alloys, e.g. steel, not covered by groups C21C1/00 - C21C5/00
    • C21C7/04Removing impurities by adding a treating agent
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21CPROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
    • C21C7/00Treating molten ferrous alloys, e.g. steel, not covered by groups C21C1/00 - C21C5/00
    • C21C7/04Removing impurities by adding a treating agent
    • C21C7/064Dephosphorising; Desulfurising
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21CPROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
    • C21C7/00Treating molten ferrous alloys, e.g. steel, not covered by groups C21C1/00 - C21C5/00
    • C21C7/10Handling in a vacuum
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/005Modifying the physical properties by deformation combined with, or followed by, heat treatment of ferrous alloys
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C33/00Making ferrous alloys
    • C22C33/04Making ferrous alloys by melting
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/02Ferrous alloys, e.g. steel alloys containing silicon
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/12Ferrous alloys, e.g. steel alloys containing tungsten, tantalum, molybdenum, vanadium, or niobium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/14Ferrous alloys, e.g. steel alloys containing titanium or zirconium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Mechanical Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Heat Treatment Of Steel (AREA)

Abstract

The invention discloses a kind of high-strength wearable type steel for ball mill steel ball, including following components in percentage by weight: C 0.9~1.0%, Si 0.2~0.4%, Mn 0.8~1.2%, Cr 1.0~1.3%, W 0.15~0.23%, Ti 0.04~0.10%, P≤0.03%, S≤0.03%, surplus is Fe and a small amount of impurity, its preparation method is: S1: melting, first to W, and Fe, Cr and Ti carries out melting, obtains melting molten steel;S2: refine, goes in refining furnace by melting molten steel, adds C, Si, Mn, P and S and refining agent carries out preliminary refine, then carry out vacuum outgas and desulfurization process, obtain refining liquid;S3: be placed in conticaster by refining liquid, through molding, cools down and cuts and i.e. obtain strand, and strand i.e. obtains high-strength wearable type steel for ball mill steel ball through roughing and finishing rolling step again.The steel that the present invention proposes, intensity and hardness are high, and anti-wear performance is strong, and service life is long, and purity is high, and degassing and rate of sulphur expulsion are fast, effective.

Description

High-strength wearable type steel for ball mill steel ball and preparation method thereof
Technical field
The present invention relates to smelting iron and steel technical field, particularly relate to a kind of high-strength wearable type steel for ball mill steel ball and system thereof Preparation Method.
Background technology
Ball mill steel ball is the medium of ball mill equipment grinding material, by between ball mill steel ball and steel ball, steel ball with Collision friction between material produces mill stripping effect, is the main abrasive media of ball mill.Steel ball is in the national economic development especially It is that heavy industry plays great function, is widely used in cement plant, ore dressing plant and alumina producer etc..Due to the merit that steel ball is special Can, the requirement being therefore used for material is the highest.Though existing steel for ball mill steel ball of preparing has certain anti-wear performance, But intensity is the highest, the scope of application of prepared ball mill steel ball is narrower, and life-time service also can cause steel ball surface serious wear, Affecting its mill stripping ability, service life is the most relatively low.And commonly use in the preparation method of steel for ball mill steel ball, the desulfurization work of steel Sequence often needs 30~60min, the longest.
Summary of the invention
The invention aims to solve shortcoming present in prior art, and a kind of high-strength wearable type ball milling proposed Machine steel ball steel and preparation method thereof.
High-strength wearable type steel for ball mill steel ball, including following components in percentage by weight: C 0.9~1.0%, Si 0.2 ~0.4%, Mn 0.8~1.2%, Cr 1.0~1.3%, W 0.15~0.23%, Ti 0.04~0.10%, P≤0.03%, S≤0.03%, surplus is Fe and a small amount of impurity.
Preferably, described high-strength wearable type steel for ball mill steel ball, including following components in percentage by weight: C 0.9~ 1.0%, Si 0.25~0.35%, Mn 0.85~1.15%, Cr 1.1~1.3%, W 0.18~0.20%, Ti 0.05~ 0.10%, P≤0.02%, S≤0.03%, surplus is Fe and a small amount of impurity.
Preferably, described high-strength wearable type steel for ball mill steel ball, including following components in percentage by weight: C 0.95%, Si 0.3%, Mn 0.95%, Cr 1.2%, W 0.19%, Ti 0.08%, P 0.01%, S 0.02%, surplus For Fe and a small amount of impurity.
The invention allows for the preparation method of high-strength wearable type steel for ball mill steel ball, comprise the following steps:
S1: melting, is heated to the temperature of smelting furnace 1600~1800 DEG C, and W, Fe, Cr and the Ti of corresponding proportion is added Enter in smelting furnace and carry out melting, after all melting, obtain melting molten steel;
S2: refine, is transferred to above-mentioned melting molten steel in refining furnace at a temperature of 1450~1500 DEG C, add accordingly than C, Si, Mn, P and the S of weight, is simultaneously introduced refining agent and carries out preliminary refine, more above-mentioned refining liquid is carried out vacuum outgas and desulfurization Operation, obtains refining liquid;
S3: be placed in conticaster by above-mentioned refining liquid, through molding, cools down and cuts and i.e. obtain strand, strand again through 400~ The roughing of 500 DEG C and finishing rolling step i.e. obtain high-strength wearable type steel for ball mill steel ball.
Preferably, described refining agent is hexachlorethane.
Preferably, in described vacuum outgas operation, the Stress control of vacuum chamber is 50~80Pa, every time degassing 2~4min, Degassing 2~4 times repeatedly.
Preferably, the desulfurization time in described desulfurization process is 3~5min, and is stirred behaviour while desulfurization process Making, and mixing speed is 300~400r/min, mixing time is identical with desulfurization time.
Preferably, in described roughing and finishing rolling step, mill speed is 3~5m/s.
The steel for ball mill steel ball that the present invention proposes, anti-wear performance is excellent, and hot strength is high, the increasing of C content in steel constituent Add and can be obviously improved yield of steel and tensile strength, and the addition of Cr both can strengthen intensity and the hardness of steel, with Time also can be obviously enhanced the wearability of steel so that it is anti-fight and friction resistant ability in use strengthen, and improve steel ball Mill stripping ability, extends the service life of steel ball;W has stronger hardness and anti-wear performance, and its addition can become carbonization with C-shaped Tungsten, therefore adding W in steel can be with the hardness of service hoisting steel ball and abrasive resistance;Relatively big owing to adding the proportion of C, so steel Aging sensitivity and cold brittleness are higher, and add Ti and can effectively reduce aging sensitivity and the cold brittleness of steel, it is ensured that steel is drawing While stretching intensity raising, aging sensitivity and cold brittleness keep constant;In refining process, add refining agent can accelerate essence Practice speed, improve refine purity, vacuum outgas operation uses the mode the most repeatedly deaerated, degassing speed can be effectively improved Degree, and while desulfurization process, it is stirred operation, rate of sulphur expulsion can be significantly improved, and then improve refining efficiency, Using roughing and finish rolling compounding practice in the operation of rolling, effect of rolling can be made more preferable, the Steel Properties of preparation is higher.
Detailed description of the invention
Below in conjunction with specific embodiment, the present invention is explained orally further.
Embodiment one
The high-strength wearable type steel for ball mill steel ball that the present invention proposes, including following components in percentage by weight: C 0.95%, Si 0.3%, Mn 0.95%, Cr 1.2%, W 0.19%, Ti 0.08%, P 0.01%, S 0.02%, surplus For Fe and a small amount of impurity.
Its preparation method, comprises the following steps:
S1: melting, melting, the temperature of smelting furnace is heated to 1700 DEG C, and W, Fe, Cr and the Ti of corresponding proportion are added In smelting furnace, carry out melting, after all melting, obtain melting molten steel;
S2: refine, is transferred to above-mentioned melting molten steel in refining furnace at a temperature of 1480 DEG C, adds the C of corresponding proportion, Si, Mn, P and S, be simultaneously introduced hexachlorethane and carry out preliminary refine, then the molten steel after preliminary refine is carried out vacuum outgas operation, The pressure of control vacuum chamber is 50~80Pa, and the 3min that every time deaerates, and degassing 3 times, carry out the desulfurization work of 4min more repeatedly Sequence, is stirred operation simultaneously, and to control mixing speed is 350r/min, obtain refining liquid;
S3: be placed in conticaster by above-mentioned refining liquid, through molding, cools down and cuts and i.e. obtain strand, and strand through rolling temperature is again 450 DEG C and roughing and finishing rolling step that mill speed is 4m/s i.e. obtain high-strength wearable type steel for ball mill steel ball.
Embodiment two
The high-strength wearable type steel for ball mill steel ball that the present invention proposes, including following components in percentage by weight: C 1.0%, Si 0.2%, Mn 1.2%, Cr 1.3%, W 0.23%, Ti 0.10%, P 0.01%, S≤0.02%, surplus is Fe and a small amount of impurity.
Its preparation method, comprises the following steps:
S1: melting, is heated to the temperature of smelting furnace 1600 DEG C, and joins molten by W, Fe, Cr and the Ti of corresponding proportion Furnace carries out melting, after all melting, obtains melting molten steel;
S2: refine, is transferred to above-mentioned melting molten steel in refining furnace at a temperature of 1500 DEG C, adds the C of corresponding proportion, Si, Mn, P and S, be simultaneously introduced hexachlorethane and carry out preliminary refine, then the molten steel after preliminary refine is carried out vacuum outgas operation, The pressure of control vacuum chamber is 50~80Pa, and the 2min that every time deaerates, and degassing 4 times, carry out the desulfurization work of 3min more repeatedly Sequence, is stirred operation simultaneously, and to control mixing speed is 400r/min, obtain refining liquid;
S3: be placed in conticaster by above-mentioned refining liquid, through molding, cools down and cuts and i.e. obtain strand, and strand through rolling temperature is again 500 DEG C and roughing and finishing rolling step that mill speed is 3m/s i.e. obtain high-strength wearable type steel for ball mill steel ball.
Embodiment three
The high-strength wearable type steel for ball mill steel ball that the present invention proposes, including following components in percentage by weight: C 0.9%, Si 0.3%, Mn 0.8%, Cr 1.0%, W 0.23%, Ti 0.04%, P 0.02%, S 0.03%, surplus is Fe and a small amount of impurity.
Its preparation method, comprises the following steps:
S1: melting, is heated to the temperature of smelting furnace 1800 DEG C, and joins molten by W, Fe, Cr and the Ti of corresponding proportion Furnace carries out melting, after all melting, obtains melting molten steel;
S2: refine, is transferred to above-mentioned melting molten steel in refining furnace at a temperature of 1450 DEG C, adds the C of corresponding proportion, Si, Mn, P and S, be simultaneously introduced hexachlorethane and carry out preliminary refine, then the molten steel after preliminary refine is carried out vacuum outgas operation, The pressure of control vacuum chamber is 50~80Pa, and the 3min that every time deaerates, and degassing 3 times, carry out the desulfurization work of 4min more repeatedly Sequence, is stirred operation simultaneously, and to control mixing speed is 350r/min, obtain refining liquid;
S3: be placed in conticaster by above-mentioned refining liquid, through molding, cools down and cuts and i.e. obtain strand, and strand through rolling temperature is again 450 DEG C and roughing and finishing rolling step that mill speed is 4m/s i.e. obtain high-strength wearable type steel for ball mill steel ball.
Embodiment four
The high-strength wearable type steel for ball mill steel ball that the present invention proposes, including following components in percentage by weight: C 1.0%, Si 0.4%, Mn 0.95%, Cr 1.2%, W 0.19%, Ti 0.06%, P 0.01%, S 0.01%, surplus is Fe and a small amount of impurity.
Its preparation method, comprises the following steps:
S1: melting, is heated to the temperature of smelting furnace 1700 DEG C, and joins molten by W, Fe, Cr and the Ti of corresponding proportion Furnace carries out melting, after all melting, obtains melting molten steel;
S2: refine, is transferred to above-mentioned melting molten steel in refining furnace at a temperature of 1450 DEG C, adds the C of corresponding proportion, Si, Mn, P and S, be simultaneously introduced hexachlorethane and carry out preliminary refine, then the molten steel after preliminary refine is carried out vacuum outgas operation, The pressure of control vacuum chamber is 50~80Pa, and the 4min that every time deaerates, and degassing 2 times, carry out the desulfurization work of 5min more repeatedly Sequence, is stirred operation simultaneously, and to control mixing speed is 300r/min, obtain refining liquid;
S3: be placed in conticaster by above-mentioned refining liquid, through molding, cools down and cuts and i.e. obtain strand, and strand through rolling temperature is again 400 DEG C and roughing and finishing rolling step that mill speed is 4m/s i.e. obtain high-strength wearable type steel for ball mill steel ball.
Embodiment five
The high-strength wearable type steel for ball mill steel ball that the present invention proposes, including following components in percentage by weight: C 0.95%, Si 0.3%, Mn 1.0%, Cr 1.3%, W 0.15%, Ti 0.1%, P 0.03%, S 0.01%, surplus is Fe and a small amount of impurity.
Its preparation method, comprises the following steps:
S1: melting, is heated to the temperature of smelting furnace 1750 DEG C, and joins molten by W, Fe, Cr and the Ti of corresponding proportion Furnace carries out melting, after all melting, obtains melting molten steel;
S2: refine, is transferred to above-mentioned melting molten steel in refining furnace at a temperature of 1480 DEG C, adds the C of corresponding proportion, Si, Mn, P and S, be simultaneously introduced hexachlorethane and carry out preliminary refine, then the molten steel after preliminary refine is carried out vacuum outgas operation, The pressure of control vacuum chamber is 50~80Pa, and the 3min that every time deaerates, and degassing 3 times, carry out the desulfurization work of 4min more repeatedly Sequence, is stirred operation simultaneously, and to control mixing speed is 350r/min, obtain refining liquid;
S3: be placed in conticaster by above-mentioned refining liquid, through molding, cools down and cuts and i.e. obtain strand, and strand through rolling temperature is again 400 DEG C and roughing and finishing rolling step that mill speed is 5m/s i.e. obtain high-strength wearable type steel for ball mill steel ball.
The steel and traditional GCr15,90CrMnTi and the B2 steel that use above-described embodiment one~five preparation lead to respectively The method crossing hot pressing is prepared as steel ball, then carries out hardness, impact flexibility and wearability detection, and testing result is as follows:
It can be seen that it has the characteristic of manganese steel from the chemical composition of the steel ball steel of present invention proposition, steel add Entering Ti can make steel internal organizational structure fine and close, makes crystal grain more refine, from above-mentioned test result it can also be seen that carry according to the present invention In steel ball prepared by the steel formula gone out, the impact flexibility of embodiment five is maximum, and the impact flexibility of embodiment four is minimum, and impact The minimum also impact flexibility than tradition steel GCr15,90CrMnTi and B2 of toughness is big, and showing to add Ti in steel formula can Effectively to weaken the cold short phenomenon caused by carbon content height, it is effectively improved the impact flexibility of steel, and steel increases appropriate metal W, can make W form tungsten carbide with carbon, significantly improve hardness and the wearability of steel, also improve its its red hardness and heat resistance simultaneously, From above-mentioned test result, can be seen that the ball hardness prepared of steel formula proposed according to the present invention and wearability are the most excellent In tradition steel.
The above, the only present invention preferably detailed description of the invention, but protection scope of the present invention is not limited thereto, Any those familiar with the art in the technical scope that the invention discloses, according to technical scheme and Inventive concept equivalent or change in addition, all should contain within protection scope of the present invention.

Claims (8)

1. high-strength wearable type steel for ball mill steel ball, it is characterised in that include following components in percentage by weight: C 0.9~ 1.0%, Si 0.2~0.4%, Mn 0.8~1.2%, Cr 1.0~1.3%, W 0.15~0.23%, Ti 0.04~ 0.10%, P≤0.03%, S≤0.03%, surplus is Fe and a small amount of impurity.
High-strength wearable type steel for ball mill steel ball the most according to claim 1, it is characterised in that include following weight percent The component of ratio: C 0.9~1.0%, Si 0.25~0.35%, Mn 0.85~1.15%, Cr 1.1~1.3%, W 0.18~ 0.20%, Ti 0.05~0.10%, P≤0.02%, S≤0.03%, surplus is Fe and a small amount of impurity.
High-strength wearable type steel for ball mill steel ball the most according to claim 1, it is characterised in that include following weight percent The component of ratio: C 0.95%, Si 0.3%, Mn 0.95%, Cr 1.2%, W 0.19%, Ti 0.08%, P 0.01%, S 0.02%, surplus is Fe and a small amount of impurity.
4. the preparation method of high-strength wearable type steel for ball mill steel ball, it is characterised in that comprise the following steps:
S1: melting, is heated to the temperature of smelting furnace 1600~1800 DEG C, and W, Fe, Cr and the Ti of corresponding proportion is joined Smelting furnace carries out melting, after all melting, obtains melting molten steel;
S2: refine, is transferred to above-mentioned melting molten steel in refining furnace at a temperature of 1450~1500 DEG C, adds corresponding proportion C, Si, Mn, P and S, be simultaneously introduced refining agent and carry out preliminary refine, more above-mentioned refining liquid is carried out vacuum outgas and desulfurization process, Obtain refining liquid;
S3: be placed in conticaster by above-mentioned refining liquid, through molding, cools down and cuts and i.e. obtain strand, and strand is again through 400~500 DEG C Roughing and finishing rolling step i.e. obtain high-strength wearable type steel for ball mill steel ball.
The preparation method of high-strength wearable type steel for ball mill steel ball the most according to claim 4, it is characterised in that described essence Refining agent is hexachlorethane.
The preparation method of high-strength wearable type steel for ball mill steel ball the most according to claim 4, it is characterised in that described very In empty degassing process, the Stress control of vacuum chamber is 50~80Pa, every time degassing 2~4min, repeatedly degassing 2~4 times.
The preparation method of high-strength wearable type steel for ball mill steel ball the most according to claim 4, it is characterised in that described de- Desulfurization time in sulfur operation is 3~5min, and be stirred while desulfurization process operation, and mixing speed be 300~ 400r/min, mixing time is identical with desulfurization time.
The preparation method of high-strength wearable type steel for ball mill steel ball the most according to claim 4, it is characterised in that described slightly Rolling with mill speed in finishing rolling step is 3~5m/s.
CN201610686778.1A 2016-08-18 2016-08-18 High-strength wearable type steel for ball mill steel ball and preparation method thereof Pending CN106222552A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110846557A (en) * 2019-12-05 2020-02-28 宝钢特钢韶关有限公司 High-carbon chromium grinding ball steel and preparation method thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1152623A (en) * 1996-09-23 1997-06-25 魁永生 High carbon low alloy steel miniature abrasive ball and making method
CN101962734A (en) * 2010-09-28 2011-02-02 莱芜钢铁股份有限公司 Steel for ball mill steel ball and preparation method thereof
JP2013185248A (en) * 2012-03-09 2013-09-19 Kobe Steel Ltd Steel sheet for hot pressing, press-molded product and method for manufacturing the press-molded product
CN104120365A (en) * 2014-08-01 2014-10-29 宁国市南方耐磨材料有限公司 Impact-resistant steel ball for ball mill

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1152623A (en) * 1996-09-23 1997-06-25 魁永生 High carbon low alloy steel miniature abrasive ball and making method
CN101962734A (en) * 2010-09-28 2011-02-02 莱芜钢铁股份有限公司 Steel for ball mill steel ball and preparation method thereof
JP2013185248A (en) * 2012-03-09 2013-09-19 Kobe Steel Ltd Steel sheet for hot pressing, press-molded product and method for manufacturing the press-molded product
CN104120365A (en) * 2014-08-01 2014-10-29 宁国市南方耐磨材料有限公司 Impact-resistant steel ball for ball mill

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110846557A (en) * 2019-12-05 2020-02-28 宝钢特钢韶关有限公司 High-carbon chromium grinding ball steel and preparation method thereof
CN110846557B (en) * 2019-12-05 2020-11-27 宝钢特钢韶关有限公司 High-carbon chromium grinding ball steel and preparation method thereof

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Application publication date: 20161214