CN106222351A - A kind of rotary hearth furnace multilamellar pelletizing synchronizes the method for reduction - Google Patents

A kind of rotary hearth furnace multilamellar pelletizing synchronizes the method for reduction Download PDF

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Publication number
CN106222351A
CN106222351A CN201610606055.6A CN201610606055A CN106222351A CN 106222351 A CN106222351 A CN 106222351A CN 201610606055 A CN201610606055 A CN 201610606055A CN 106222351 A CN106222351 A CN 106222351A
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China
Prior art keywords
pelletizing
reduction
rotary hearth
hearth furnace
balls
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CN201610606055.6A
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胡途
廖雪峰
彭金辉
张利波
杨黎
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Kunming University of Science and Technology
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Kunming University of Science and Technology
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Priority to CN201610606055.6A priority Critical patent/CN106222351A/en
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    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21BMANUFACTURE OF IRON OR STEEL
    • C21B13/00Making spongy iron or liquid steel, by direct processes
    • C21B13/08Making spongy iron or liquid steel, by direct processes in rotary furnaces
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21BMANUFACTURE OF IRON OR STEEL
    • C21B13/00Making spongy iron or liquid steel, by direct processes
    • C21B13/006Starting from ores containing non ferrous metallic oxides

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Manufacture Of Iron (AREA)
  • Manufacture And Refinement Of Metals (AREA)

Abstract

The present invention relates to a kind of method that rotary hearth furnace multilamellar pelletizing synchronizes reduction, belong to non-blast furnace ironmaking technical field.V-ti magnetite concentrate is mixed with carbonaceous reducing agent and carries out pelletizing, pressure ball or mixing briquetting, pelletizing, pressure ball or mixing briquetting are placed in rotary hearth furnace formation multilamellar layers of balls, top layers of balls does not adds additive in pelletizing, pressure ball or mixing briquetting process, adjacent layers of balls down is incremented by addition additive by pelletizing, pressure ball or the 0.01 of mixing briquette quality~30%, then carries out synchronizing reduction process and obtains being available for the reducting pellet that electric furnace steel making uses.The present invention accelerates the rate of reduction of bottom layers of balls carbonaceous pelletizing, shortens the recovery time, make the highest degree of metalization that the whole bed of material can reach under the conditions of reaching a certain specific reducing process after reduction certain time simultaneously, realize rotary hearth furnace carbonaceous pelletizing polytrope and synchronize reduction, weaken the top layer carbonaceous pelletizing secondary oxidation degree in the reduction later stage to greatest extent.

Description

A kind of rotary hearth furnace multilamellar pelletizing synchronizes the method for reduction
Technical field
The present invention relates to a kind of method that rotary hearth furnace multilamellar pelletizing synchronizes reduction, belong to non-blast furnace ironmaking technical field.
Background technology
Rotary hearth furnace Coal-based Direct Reduction Technologies is a kind of Coal-based Direct Reduction Technologies for roasting carbon containing mineral aggregate pelletizing, its Process characteristic is: by material containing metal oxide and solid coal dust mixed pelletizing, carbonaceous pelletizing can be equably by material distributing machine Cloth is on furnace bottom, along with the spacious flame under the high temperature of 900~1400 DEG C that rotates of furnace bottom heats, it is achieved the fast restore of material is to obtain Obtain reduzate.The carbonaceous pelletizing time of staying in stove can be according to the speed of its rate of reduction by controlling furnace bottom velocity of rotation It is adjusted.Therefore rotary hearth furnace coal-based DR process have that reduction temperature is high, the time is short, furnace charge and furnace bottom geo-stationary, The features such as flexible operation, obtain in fields such as complicated metalliferous mineral extraction, metallurgical waste comprehensive utilization and ferroalloy productions Commonly used.
In rotary hearth furnace, energy is transferred to the bed of material from top to bottom mainly by radiant heat transfer, and heat transfer efficiency is low, can only carry out thin The bed of material operates, generally 1 ~ 2 layer;In addition metallized pellet is in the reduction later stage inevitably by the secondary oxidation of furnace gas, causes Make rotary hearth furnace production efficiency low, limit the large-scale application of rotary hearth furnace coal-based DR process.Therefore, thickness of feed layer is improved It it is the important channel realizing the direct-reduction process scale extension of v-ti magnetite concentrate rotary hearth furnace.Owing to being passed by heat in rotary hearth furnace The mode feature of passing is determined, after the bed of material number of plies increases, top layer carbonaceous pelletizing is heated at first and starts reduction.Bottom bed of material carbonaceous pelletizing Owing to being blocked by its last layer carbonaceous pelletizing, direct heating surface area is less so that it is temperature is lower than last layer carbonaceous pelletizing and rises Temperature speed is slow, thus rate of reduction is slow.So, along with the carrying out of reaction, at the end of top layer carbonaceous pelletizing is already close to reduction, Bottom bed of material carbonaceous pelletizing the most fully reduces.In order to obtain high degree of metalization, need to ensure that carbonaceous pelletizing is at furnace high-temperature district foot The enough long time, this most easily caused the secondary oxygen of upper strata carbonaceous pelletizing so that bottom bed of material carbonaceous pelletizing is fully reduced Changing, degree of metalization reduces, and ultimately results in overall bed of material average metal rate and reduces.Therefore, it is achieved rotary hearth furnace carbonaceous pelletizing multilamellar It is significant that ball synchronizes reduction.
Summary of the invention
The problem existed for above-mentioned prior art and deficiency, the present invention provides a kind of rotary hearth furnace multilamellar pelletizing to synchronize reduction Method.By in Different layer of the compost carbonaceous pelletizing with addition of the different amounts of additive that can improve Reduction of Pellet Containing Coal Char speed, with Accelerate the rate of reduction of bottom layers of balls carbonaceous pelletizing, shorten the recovery time, make the whole bed of material reach after reduction certain time simultaneously The highest degree of metalization that can reach under the conditions of a certain specific reducing process, it is achieved rotary hearth furnace carbonaceous pelletizing polytrope synchronizes also Former, weaken the top layer carbonaceous pelletizing secondary oxidation degree in the reduction later stage to greatest extent, the present invention is by the following technical programs Realize.
A kind of rotary hearth furnace multilamellar pelletizing synchronizes the method for reduction, and it specifically comprises the following steps that v-ti magnetite concentrate and carbonaceous Reducing agent mixing carries out pelletizing, pressure ball or mixing briquetting, and pelletizing, pressure ball or mixing briquetting are placed in rotary hearth furnace formation polytrope Layer, top layers of balls does not adds additive in pelletizing, pressure ball or mixing briquetting process, and adjacent layers of balls down presses pelletizing, pressure ball Or mixing briquette quality 0.01~30% be incremented by add additive, then carry out synchronize reduction process obtain being available for electric furnace steel making The reducting pellet used.
Described additive is aluminium powder.
Described multilamellar layers of balls >=2 layer, bed of material gross thickness >=10mm.
The invention has the beneficial effects as follows: there is raising rotary hearth furnace production efficiency, capacity usage ratio and metallized pellet gold The advantage belonging to rate, provides beneficial pathways for rotary hearth furnace popularizationization.
Accompanying drawing explanation
Fig. 1 is the embodiment of the present invention 1 reduction result figure;
Fig. 2 is prior art reduction result figure of the present invention.
Detailed description of the invention
Below in conjunction with the accompanying drawings and detailed description of the invention, the invention will be further described.
Embodiment 1
This rotary hearth furnace multilamellar pelletizing synchronizes the method for reduction, and it specifically comprises the following steps that
(1) v-ti magnetite concentrate (is included following mass percent component: TFe52.62%, FeO32%, TiO212%、 V2O50.6%) mix according to volume ratio 10:2 make with carbonaceous reducing agent (wherein fixed carbon mass percent is not less than 80%) Ball;
(2) pelletizing is placed in rotary hearth furnace three layers of layers of balls of formation, and top layers of balls does not adds additive, the second layer in balling process With the addition of the aluminium powder additive of pelletizing quality 1% in balling process, third layer with the addition of pelletizing quality 3% in balling process Aluminium powder additive, then at 1350 DEG C, CO/CO in atmosphere2Volume ratio ratio is to carry out 35min under conditions of 2 to synchronize reduction Process obtains being available for the reducting pellet that electric furnace steel making uses.
Contrast test
V-ti magnetite concentrate mixing is carried out pelletizing, pelletizing is placed in rotary hearth furnace three layers of layers of balls of formation, balling process does not adds Enter additive aluminium powder, then at 1350 DEG C, CO/CO in atmosphere2Volume ratio ratio is to carry out 45min under conditions of 2 to synchronize also Former process obtains being available for the reducting pellet that electric furnace steel making uses, and other Parameter Conditions are same as in Example 1.
Embodiment 1 reduction result figure as it is shown in figure 1, contrast test reduction result figure as shown in Figure 2;Embodiment 1 is in reduction After 35min, overall bed of material average metal rate has reached 90.67%, it is achieved that synchronize reduction, and after contrast test reduction 45min Overall bed of material average metal rate is only 87%.
Embodiment 2
This rotary hearth furnace multilamellar pelletizing synchronizes the method for reduction, and it specifically comprises the following steps that
(1) v-ti magnetite concentrate (is included following mass percent component: TFe52.62%, FeO32%, TiO212%、V2O 0.6%) mix according to volume ratio 10:2 with carbonaceous reducing agent (wherein fixed carbon mass percent is not less than 80%) and carry out pelletizing;
(2) pelletizing is placed in rotary hearth furnace three layers of layers of balls of formation, and top layers of balls does not adds additive, the second layer in balling process With the addition of the aluminium powder additive of pelletizing quality 3% in balling process, third layer with the addition of pelletizing quality 6% in balling process Aluminium powder additive, then at 1350 DEG C, CO/CO in atmosphere2Volume ratio ratio is to carry out 32min under conditions of 2 to synchronize reduction Process obtains being available for the reducting pellet that electric furnace steel making uses, and overall bed of material average metal rate has reached 91.51%, it is achieved that with Step reduction.
Embodiment 3
This rotary hearth furnace multilamellar pelletizing synchronizes the method for reduction, and it specifically comprises the following steps that
(1) v-ti magnetite concentrate (is included following mass percent component: TFe52.62%, FeO32%, TiO212%、 V2O50.6%) mix according to volume ratio 10:2 make with carbonaceous reducing agent (wherein fixed carbon mass percent is not less than 80%) Ball;
(2) pelletizing is placed in rotary hearth furnace formation three layers of layers of balls, bed of material gross thickness >=10mm, top layers of balls in balling process not Adding additive, the second layer with the addition of the aluminium powder additive of pelletizing quality 6% in balling process, and third layer is in balling process With the addition of the aluminium powder additive of pelletizing quality 9%, then at 1350 DEG C, CO/CO in atmosphere2Under conditions of volume ratio ratio is 2 Carrying out 30min synchronization reduction process and obtain being available for the reducting pellet that electric furnace steel making uses, overall bed of material average metal rate reaches 90.96%, it is achieved that synchronize reduction.
Embodiment 4
This rotary hearth furnace multilamellar pelletizing synchronizes the method for reduction, and it specifically comprises the following steps that
(1) v-ti magnetite concentrate (is included following mass percent component: TFe52.62%, FeO32%, TiO212%、 V2O50.6%) mix according to volume ratio 10:2 make with carbonaceous reducing agent (wherein fixed carbon mass percent is not less than 80%) Ball;
(2) pelletizing is placed in rotary hearth furnace formation three layers of layers of balls, bed of material gross thickness >=10mm, top layers of balls in balling process not Adding additive, the second layer with the addition of the aluminium powder additive of pelletizing quality 6% in balling process, and third layer is in balling process With the addition of the aluminium powder additive of pelletizing quality 9%, then at 1350 DEG C, CO/CO in atmosphere2Under conditions of volume ratio ratio is 2 Carrying out 35min synchronization reduction process and obtain being available for the reducting pellet that electric furnace steel making uses, overall bed of material average metal rate reaches 91.24%, it is achieved that synchronize reduction.
Embodiment 5
This rotary hearth furnace multilamellar pelletizing synchronizes the method for reduction, and it specifically comprises the following steps that
(1) v-ti magnetite concentrate (is included following mass percent component: TFe52.62%, FeO32%, TiO212%、 V2O50.6%) mix according to volume ratio 10:2 press with carbonaceous reducing agent (wherein fixed carbon mass percent is not less than 80%) Ball;
(2) pressure ball is placed in rotary hearth furnace formation ten layers of layers of balls, bed of material gross thickness >=10mm, top layers of balls in balling process not Add additive, the second layer to the tenth layer with the addition of successively in balling process pressure ball quality 0.01%, 0.05%, 0.10%, 0.15%, the aluminium powder additive of 0.20%, 0.25%, 0.3%, 0.35%, 0.4%, then at 1350 DEG C, CO/CO in atmosphere2Volume It is to carry out 30min under conditions of 2 to synchronize reduction process and obtain being available for the reducting pellet that electric furnace steel making uses, the overall bed of material than ratio Average metal rate has reached 88.47%, it is achieved that synchronize reduction.
Embodiment 6
This rotary hearth furnace multilamellar pelletizing synchronizes the method for reduction, and it specifically comprises the following steps that
(1) v-ti magnetite concentrate (is included following mass percent component: TFe52.62%, FeO32%, TiO212%、 V2O50.6%) mix according to volume ratio 10:2 with carbonaceous reducing agent (wherein fixed carbon mass percent is not less than 80%) Briquetting;
(2) mixing briquetting is placed in rotary hearth furnace ten layers of layers of balls of formation, and bed of material gross thickness >=10mm, top layers of balls is at balling process In do not add additive, the second layer to the tenth layer with the addition of successively in balling process mixing briquette quality 20%, 21%, 22%, 23%, the aluminium powder additive of 24%, 25%, 26%, 27%, 28%, then at 1350 DEG C, CO/CO in atmosphere2Volume ratio ratio is 2 Under conditions of carry out 30min and synchronize reduction process and obtain being available for the reducting pellet that electric furnace steel making uses, overall bed of material average metal Rate has reached 92.31%, it is achieved that synchronize reduction.
Above in association with accompanying drawing, the detailed description of the invention of the present invention is explained in detail, but the present invention is not limited to above-mentioned Embodiment, in the ken that those of ordinary skill in the art are possessed, it is also possible to before without departing from present inventive concept Put that various changes can be made.

Claims (3)

1. the method that a rotary hearth furnace multilamellar pelletizing synchronizes reduction, it is characterised in that specifically comprise the following steps that v-ti magnetite concentrate Mix with carbonaceous reducing agent and carry out pelletizing, pressure ball or mixing briquetting, pelletizing, pressure ball or mixing briquetting are placed in rotary hearth furnace formation Multilamellar layers of balls, top layers of balls does not adds additive in pelletizing, pressure ball or mixing briquetting process, and adjacent layers of balls down is by making Ball, pressure ball or the 0.01 of mixing briquette quality~30% are incremented by addition additive, then carry out synchronizing reduction process and obtain powering The reducting pellet that stove steel-making uses.
Rotary hearth furnace multilamellar pelletizing the most according to claim 1 synchronizes the method for reduction, it is characterised in that: described additive is Aluminium powder.
Rotary hearth furnace multilamellar pelletizing the most according to claim 1 synchronizes the method for reduction, it is characterised in that: described multilamellar layers of balls >=2 layers, bed of material gross thickness >=10mm.
CN201610606055.6A 2016-07-29 2016-07-29 A kind of rotary hearth furnace multilamellar pelletizing synchronizes the method for reduction Pending CN106222351A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107904345A (en) * 2017-11-15 2018-04-13 江苏省冶金设计院有限公司 A kind of method for realizing the reduction of rotary hearth furnace deep bed sintering
CN108531677A (en) * 2018-06-13 2018-09-14 上海宝幢新能源科技有限公司 A kind of method and system for realizing the reduction of deep bed sintering pelletizing using rotary hearth furnace
CN110788113A (en) * 2019-10-17 2020-02-14 宝武集团环境资源科技有限公司 Method for inhibiting zinc-containing dust pellets from reduction degradation in rotary hearth furnace

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105087902A (en) * 2015-08-04 2015-11-25 江苏省冶金设计院有限公司 Novel pellet metallurgy method

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105087902A (en) * 2015-08-04 2015-11-25 江苏省冶金设计院有限公司 Novel pellet metallurgy method

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
N.J. WELHAM: "Mechanochemical reaction between ilmenite (FeTiO3)and aluminium", 《JOURNAL OF ALLOYS AND COMPOUNDS》 *
胡途: "钒钛磁铁精矿转底炉多层球还原基础研究", 《中国博士学位论文全文数据库 工程科技Ⅰ辑》 *

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107904345A (en) * 2017-11-15 2018-04-13 江苏省冶金设计院有限公司 A kind of method for realizing the reduction of rotary hearth furnace deep bed sintering
CN108531677A (en) * 2018-06-13 2018-09-14 上海宝幢新能源科技有限公司 A kind of method and system for realizing the reduction of deep bed sintering pelletizing using rotary hearth furnace
CN110788113A (en) * 2019-10-17 2020-02-14 宝武集团环境资源科技有限公司 Method for inhibiting zinc-containing dust pellets from reduction degradation in rotary hearth furnace
CN110788113B (en) * 2019-10-17 2021-06-29 宝武集团环境资源科技有限公司 Method for inhibiting zinc-containing dust pellets from reduction degradation in rotary hearth furnace

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