CN106221645B - A kind of roof roof waterproof and heat-insulating glue and the preparation method and application thereof - Google Patents
A kind of roof roof waterproof and heat-insulating glue and the preparation method and application thereof Download PDFInfo
- Publication number
- CN106221645B CN106221645B CN201610616868.3A CN201610616868A CN106221645B CN 106221645 B CN106221645 B CN 106221645B CN 201610616868 A CN201610616868 A CN 201610616868A CN 106221645 B CN106221645 B CN 106221645B
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- China
- Prior art keywords
- roof
- heat
- insulating glue
- waterproof
- roof waterproof
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- 239000003292 glue Substances 0.000 title claims abstract description 39
- 238000002360 preparation method Methods 0.000 title claims description 6
- 239000003054 catalyst Substances 0.000 claims abstract description 13
- 239000002994 raw material Substances 0.000 claims abstract description 11
- 239000004615 ingredient Substances 0.000 claims abstract description 10
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 9
- 239000003063 flame retardant Substances 0.000 claims abstract description 9
- 239000004088 foaming agent Substances 0.000 claims abstract description 9
- 238000002156 mixing Methods 0.000 claims abstract description 9
- 238000004078 waterproofing Methods 0.000 claims abstract description 9
- 229920000877 Melamine resin Polymers 0.000 claims abstract description 7
- 229920000570 polyether Polymers 0.000 claims abstract description 7
- 239000004640 Melamine resin Substances 0.000 claims abstract description 6
- 238000001802 infusion Methods 0.000 claims abstract description 6
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 claims description 14
- 238000003756 stirring Methods 0.000 claims description 13
- 238000010792 warming Methods 0.000 claims description 11
- PZBFGYYEXUXCOF-UHFFFAOYSA-N TCEP Chemical compound OC(=O)CCP(CCC(O)=O)CCC(O)=O PZBFGYYEXUXCOF-UHFFFAOYSA-N 0.000 claims description 7
- 239000010426 asphalt Substances 0.000 claims description 7
- 229920002545 silicone oil Polymers 0.000 claims description 5
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 claims description 4
- DGYMCGCIUWHSNH-UHFFFAOYSA-N C(CCC)[Sn]CCCC.C(CCCCCCCCCCC)[S] Chemical compound C(CCC)[Sn]CCCC.C(CCCCCCCCCCC)[S] DGYMCGCIUWHSNH-UHFFFAOYSA-N 0.000 claims description 3
- UKLDJPRMSDWDSL-UHFFFAOYSA-L [dibutyl(dodecanoyloxy)stannyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)O[Sn](CCCC)(CCCC)OC(=O)CCCCCCCCCCC UKLDJPRMSDWDSL-UHFFFAOYSA-L 0.000 claims description 3
- 239000012975 dibutyltin dilaurate Substances 0.000 claims description 3
- 239000012188 paraffin wax Substances 0.000 claims description 3
- YACLCMMBHTUQON-UHFFFAOYSA-N 1-chloro-1-fluoroethane Chemical compound CC(F)Cl YACLCMMBHTUQON-UHFFFAOYSA-N 0.000 claims description 2
- OOSUHIIJYDMCCW-UHFFFAOYSA-N cyanamide;formaldehyde Chemical compound O=C.NC#N OOSUHIIJYDMCCW-UHFFFAOYSA-N 0.000 claims description 2
- 239000012467 final product Substances 0.000 claims description 2
- FBAFATDZDUQKNH-UHFFFAOYSA-M iron chloride Chemical compound [Cl-].[Fe] FBAFATDZDUQKNH-UHFFFAOYSA-M 0.000 claims description 2
- RGSFGYAAUTVSQA-UHFFFAOYSA-N pentamethylene Natural products C1CCCC1 RGSFGYAAUTVSQA-UHFFFAOYSA-N 0.000 claims description 2
- 125000004817 pentamethylene group Chemical group [H]C([H])([*:2])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[*:1] 0.000 claims description 2
- 229920005989 resin Polymers 0.000 claims description 2
- 239000011347 resin Substances 0.000 claims description 2
- 239000000344 soap Substances 0.000 claims description 2
- 238000005829 trimerization reaction Methods 0.000 claims description 2
- ISKQADXMHQSTHK-UHFFFAOYSA-N [4-(aminomethyl)phenyl]methanamine Chemical compound NCC1=CC=C(CN)C=C1 ISKQADXMHQSTHK-UHFFFAOYSA-N 0.000 claims 1
- ZFSLODLOARCGLH-UHFFFAOYSA-N isocyanuric acid Chemical compound OC1=NC(O)=NC(O)=N1 ZFSLODLOARCGLH-UHFFFAOYSA-N 0.000 claims 1
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical group NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 claims 1
- 230000032683 aging Effects 0.000 abstract description 6
- 231100000252 nontoxic Toxicity 0.000 abstract description 2
- 230000003000 nontoxic effect Effects 0.000 abstract description 2
- 239000011368 organic material Substances 0.000 abstract description 2
- 239000002574 poison Substances 0.000 abstract description 2
- 231100000614 poison Toxicity 0.000 abstract description 2
- 229920000642 polymer Polymers 0.000 abstract description 2
- 238000004321 preservation Methods 0.000 abstract description 2
- 230000009967 tasteless effect Effects 0.000 abstract description 2
- 238000012360 testing method Methods 0.000 description 9
- 239000000047 product Substances 0.000 description 5
- 239000004568 cement Substances 0.000 description 4
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 3
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 3
- 238000011049 filling Methods 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- RZYKUPXRYIOEME-UHFFFAOYSA-N CCCCCCCCCCCC[S] Chemical compound CCCCCCCCCCCC[S] RZYKUPXRYIOEME-UHFFFAOYSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- 238000002485 combustion reaction Methods 0.000 description 2
- 238000005336 cracking Methods 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000004088 simulation Methods 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- HRERZDNDUWVRSY-UHFFFAOYSA-N C(C)F.[O] Chemical class C(C)F.[O] HRERZDNDUWVRSY-UHFFFAOYSA-N 0.000 description 1
- XADCESSVHJOZHK-UHFFFAOYSA-N Meperidine Chemical compound C=1C=CC=CC=1C1(C(=O)OCC)CCN(C)CC1 XADCESSVHJOZHK-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- LUZSPGQEISANPO-UHFFFAOYSA-N butyltin Chemical compound CCCC[Sn] LUZSPGQEISANPO-UHFFFAOYSA-N 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- AYOHIQLKSOJJQH-UHFFFAOYSA-N dibutyltin Chemical compound CCCC[Sn]CCCC AYOHIQLKSOJJQH-UHFFFAOYSA-N 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 230000008595 infiltration Effects 0.000 description 1
- 238000001764 infiltration Methods 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- ZQKXQUJXLSSJCH-UHFFFAOYSA-N melamine cyanurate Chemical compound NC1=NC(N)=NC(N)=N1.O=C1NC(=O)NC(=O)N1 ZQKXQUJXLSSJCH-UHFFFAOYSA-N 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 235000006408 oxalic acid Nutrition 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 238000007719 peel strength test Methods 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 238000012797 qualification Methods 0.000 description 1
- 239000005871 repellent Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J175/00—Adhesives based on polyureas or polyurethanes; Adhesives based on derivatives of such polymers
- C09J175/04—Polyurethanes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/4009—Two or more macromolecular compounds not provided for in one single group of groups C08G18/42 - C08G18/64
- C08G18/4027—Mixtures of compounds of group C08G18/54 with other macromolecular compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/4829—Polyethers containing at least three hydroxy groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/54—Polycondensates of aldehydes
- C08G18/544—Polycondensates of aldehydes with nitrogen compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
- C08G18/76—Polyisocyanates or polyisothiocyanates cyclic aromatic
- C08G18/7657—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings
- C08G18/7664—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings containing alkylene polyphenyl groups
- C08G18/7671—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings containing alkylene polyphenyl groups containing only one alkylene bisphenyl group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
- C08J9/14—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
- C08J9/141—Hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/08—Macromolecular additives
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04D—ROOF COVERINGS; SKY-LIGHTS; GUTTERS; ROOF-WORKING TOOLS
- E04D13/00—Special arrangements or devices in connection with roof coverings; Protection against birds; Roof drainage ; Sky-lights
- E04D13/16—Insulating devices or arrangements in so far as the roof covering is concerned, e.g. characterised by the material or composition of the roof insulating material or its integration in the roof structure
- E04D13/1606—Insulation of the roof covering characterised by its integration in the roof structure
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04D—ROOF COVERINGS; SKY-LIGHTS; GUTTERS; ROOF-WORKING TOOLS
- E04D13/00—Special arrangements or devices in connection with roof coverings; Protection against birds; Roof drainage ; Sky-lights
- E04D13/16—Insulating devices or arrangements in so far as the roof covering is concerned, e.g. characterised by the material or composition of the roof insulating material or its integration in the roof structure
- E04D13/1606—Insulation of the roof covering characterised by its integration in the roof structure
- E04D13/1668—Insulation of the roof covering characterised by its integration in the roof structure the insulating material being masses or granules applied in situ
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2101/00—Manufacture of cellular products
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2170/00—Compositions for adhesives
- C08G2170/60—Compositions for foaming; Foamed or intumescent adhesives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2203/00—Foams characterized by the expanding agent
- C08J2203/14—Saturated hydrocarbons, e.g. butane; Unspecified hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2375/00—Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
- C08J2375/04—Polyurethanes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Engineering & Computer Science (AREA)
- Architecture (AREA)
- Civil Engineering (AREA)
- Structural Engineering (AREA)
- Materials Engineering (AREA)
- Building Environments (AREA)
- Sealing Material Composition (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The present invention relates to high-molecular organic material fields, specifically provide a kind of roof roof waterproof and heat-insulating glue.The raw material of the roof roof waterproof and heat-insulating glue includes the ingredient of following mass parts: 100 parts of melamine resin (MF)；20~40 parts of tetrahydroxy polyethers；Equal 1~10 part of infusion；0.1~1 part of catalyst；20~40 parts of fire retardant；5~25 parts of foaming agent；150~300 parts of MD1；4~15 parts of waterproofing agent.Roof waterproof and heat-insulating glue in roof provided by the invention, it is synthesized using nuisanceless raw material MF, in MF mixing, it is added to catalyst, fire retardant, foaming agent, polymer, waterproofing agent etc., make its winter low temperature resistant summer high temperature resistant, it is non-ignitable to meet fire, is discharged without the molten gas of any poison, plays the role of summer heat-insulated winter heat preservation.In addition, product of the present invention is non-toxic and tasteless, the product of existing water-proof function is overcome, the service life is short, not ageing-resistant, not heat-insulated, fireproof is not insufficient.
Description
Technical field
The present invention relates to high-molecular organic material fields, specifically, being related to a kind of roof roof glue of waterproof and heat-insulating.
Background technique
Waterproof material, waterproof roll and water-repellent paint used in the flat roof of building for a long time, these waterproof materials
Fatal disadvantage is that the waterproof service life is short, only leakage infiltration just occurs within several years.The decades in service life of one building are to more than 100 years, light
The light maintenance overhaul of waterproof is done again must be tens times, cause trouble to the production and living of people, cause to national economy serious
Economic loss.Show annual area in all parts of the country only used in part house waterproof repairment according to the investigation of the relevant departments such as the Ministry of Construction
Expense is as high as tens hundred million, and these waterproof material use are all again unification waterproofs.
Existing marine glue product can only do water-proof function, the service life is short, it is not ageing-resistant, not low temperature resistant, not heat-insulated, do not prevent
Fire.
Summary of the invention
In order to solve the problems in the existing technology, strong the object of the present invention is to provide a kind of low temperature resistant, extensibility
Roof roof waterproof and heat-insulating glue.
In order to achieve the object of the present invention, technical scheme is as follows:
Present invention firstly provides a kind of roof roof waterproof and heat-insulating glue, the raw material packet of the roof roof waterproof and heat-insulating glue
Include the ingredient of following mass parts:
Wherein, the equal infusion is selected from silicone oil AK8830 (dolantin), H-3202 (Dong Jun chemical company, Zhongshan city) or L-
One of 5304 (Mai Tu companies, the U.S.) are a variety of.The catalyst is selected from ten (dodecyl sulphur) dibutyl tins, oxalic acid
One of dibutyl tin or DBTL are a variety of；The foaming agent is selected from one of pentane, pentamethylene or chloro fluoroethane
Or it is a variety of.The fire retardant is selected from one of melamine cyanurate, chlorinated paraffin or TCEP or a variety of.The waterproofing agent
Selected from one of aluminium chloride, emulsified asphalt, iron chloride or metallic soap or a variety of.
Preferably, the raw material of the roof roof waterproof and heat-insulating glue includes the ingredient of following mass parts:
More preferably, the raw material of the roof roof waterproof and heat-insulating glue includes the ingredient of following mass parts:
In the above-mentioned more preferably technical solution, the present invention still further preferably equal infusion, catalyst, fire retardant,
The raw material of the specific ingredient of foaming agent and waterproofing agent, i.e., the described roof roof waterproof and heat-insulating glue includes the ingredient of following mass parts:
In one particular embodiment of the present invention, above-mentioned roof roof waterproof and heat-insulating glue is in heat-insulated, high temperature resistant, caking property
Aspect has more preferably excellent performance.
Second aspect, the present invention also provides the preparation method of aforementioned roof roof waterproof and heat-insulating glue, specifically: by trimerization
Cyanamide formaldehyde resin is warming up to 40~50 DEG C, and tetrahydroxy polyethers, waterproofing agent, fire retardant is added, and stirs 10~20 minutes, mixing liter
Temperature is added MDI and stirs evenly i.e. to 55~65 DEG C plus equal infusion, catalyst and foaming agent after 60~70 DEG C are stirred 1 hour
?.
The melamine resin, tetrahydroxy polyethers, waterproofing agent, fire retardant stir 10~20 points at 40~50 DEG C
Clock can preferably be conducive to homogeneous reaction, mixing is warming up to 55~65 DEG C later, equal infusion, catalyst and foaming agent is added,
Be conducive to product qualification.
Preferably, melamine resin is warming up to 45 DEG C, tetrahydroxy polyethers, emulsified asphalt, TCEP is added, stirs
It mixes 15 minutes, mixing is warming up to 60 DEG C plus silicone oil AK8830, (dodecyl sulphur) dibutyl tin of catalyst ten and pentane, in 65
DEG C stirring 1 hour after, be added MDI stir evenly to obtain the final product.
The third aspect, the present invention provides aforementioned roof roof waterproof and heat-insulating glue answering in building top insulating water-proof
With.
The roof roof of building trade can be applied to, do heat retaining and insulated waterproof layer, play that its is heat-resisting, heat-insulated, no
Permeable advantage.
The beneficial effects of the present invention are:
Roof waterproof and heat-insulating glue in roof provided by the invention is synthesized using nuisanceless raw material MF, in MF mixing, is added to
Catalyst, fire retardant, foaming agent, polymer, waterproofing agent etc. make its winter low temperature resistant summer high temperature resistant, and chance fire is non-ignitable, does not appoint
Summer heat-insulated winter heat preservation is played the role of in the molten gas release of what poison.In addition, product of the present invention is non-toxic and tasteless, overcome existing
The product of water-proof function, the service life is short, not ageing-resistant, not heat-insulated, fireproof is not insufficient.
Specific embodiment
Embodiment of the present invention is described in detail below in conjunction with embodiment, but those skilled in the art will
Understand, the following example is merely to illustrate the present invention, and should not be taken as limiting the scope of the invention.It is not specified in embodiment specific
Condition person carries out according to conventional conditions or manufacturer's recommended conditions.Reagents or instruments used without specified manufacturer is
It can be with conventional products that are commercially available.
Embodiment 1
1, it forms
2, preparation method:
Melamine resin is warming up to 45 DEG C, tetrahydroxy polyethers, emulsified asphalt, TCEP is added, is stirred 15 minutes,
Mixing is warming up to 60 DEG C plus silicone oil AK8830, (dodecyl sulphur) dibutyl tin of catalyst ten and pentane, small in 65 DEG C of stirrings 1
Shi Hou is added MDI and stirs evenly up to the roof roof waterproof and heat-insulating glue.
Embodiment 2
The present embodiment the difference from embodiment 1 is that: the emulsified asphalt is replaced with into aluminium oxide.Embodiment 3
The present embodiment the difference from embodiment 1 is that: the pentane is replaced with into three oxygen fluoroethanes.
Embodiment 4
The present embodiment the difference from embodiment 1 is that: the TCEP is replaced with into chlorinated paraffin.
Embodiment 5
The present embodiment the difference from embodiment 1 is that: melamine resin is warming up to 40 DEG C, it is poly- that tetrahydroxy is added
Ether, emulsified asphalt, TCEP are stirred 10 minutes, and mixing is warming up to 55 DEG C plus silicone oil AK8830, catalyst ten (dodecyl sulphur) two
Butyl tin and pentane are added MDI and stir evenly up to the roof roof waterproof and heat-insulating glue after 60 DEG C are stirred 1 hour.
Embodiment 6
The present embodiment the difference from embodiment 1 is that: composition is different, as follows:
Embodiment 7
The present embodiment the difference from embodiment 1 is that: composition is different, as follows:
Embodiment 8
The present embodiment the difference from embodiment 1 is that: composition is different, as follows:
Embodiment 9
The present embodiment the difference from embodiment 1 is that: composition is different, as follows:
1 cold test of experimental example
It is 10m that roof waterproof and heat-insulating glue in roof described in Examples 1 to 9, which is applied to surface area,2Cement plane (simulation room
Attic top) on, 72 hours or more under the conditions of being placed in -30 DEG C, observation cracking situation the results are shown in Table 1:
The cracking situation of roof roof waterproof and heat-insulating glue under the conditions of 1-30 DEG C of table
| Test group | Crack situation |
| Embodiment 1 | It does not crack |
| Embodiment 2 | It does not crack |
| Embodiment 3 | It does not crack |
| Embodiment 4 | It does not crack |
| Embodiment 5 | It does not crack |
| Embodiment 6 | It does not crack |
| Embodiment 7 | It does not crack |
| Embodiment 8 | It does not crack |
| Embodiment 9 | It does not crack |
2 fire resistance test of experimental example
Gap-filling glue described in Examples 1 to 9 is applied in cement plane (simulation roof roof), tested using open fire described in
Whether gap-filling glue can be ignited by open fire, the results are shown in Table 2:
The combustion case of gap-filling glue under the conditions of 2-30 DEG C of table
| Test group | Combustion case |
| Embodiment 1 | It is non-ignitable |
| Embodiment 2 | It is non-ignitable |
| Embodiment 3 | It is non-ignitable |
| Embodiment 4 | It is non-ignitable |
| Embodiment 5 | It is non-ignitable |
| Embodiment 6 | It is non-ignitable |
| Embodiment 7 | It is non-ignitable |
| Embodiment 8 | It is non-ignitable |
| Embodiment 9 | It is non-ignitable |
3 waterproof of experimental example, heat-resisting, ageing-resistant performance test
1, waterproof performance: it is 10m that roof roof waterproof and heat-insulating glue described in Examples 1 to 9 is applied to surface area respectively2's
On cement concave surface, and water is piled in concave surface, simulates the ponding situation of roof roof.It is carried out continuously test 3 months, without leakage
Water, nothing fall off, without peeling.
2, heat-resisting, ageing-resistant performance:
It is 1m that roof roof waterproof and heat-insulating glue described in Examples 1 to 9 is applied to surface area respectively2Cement plane on,
And 10 times/day of high-temperature baking at 60 DEG C, 4 minutes every time, it is carried out continuously test 3 months, as a result, it has been found that not cracked phenomenon,
Also there is not aging phenomenon.
4 cementation test of experimental example
The roof roof waterproof and heat-insulating glue described in Examples 1 to 9 carries out peel strength test under normal temperature conditions
(GB279 and GB8808 as defined in test method), compares its caking property, the results are shown in Table 2:
3 cementation test of table
| Test group | Caking property |
| Embodiment 1 | It is excellent |
| Embodiment 2 | It is excellent |
| Embodiment 3 | It is excellent |
| Embodiment 4 | It is excellent |
| Embodiment 5 | It is excellent |
| Embodiment 6 | It is excellent |
| Embodiment 7 | It is excellent |
| Embodiment 8 | Generally |
| Embodiment 9 | Generally |
Although above the present invention is described in detail with a general description of the specific embodiments,
On the basis of the present invention, it can be made some modifications or improvements, this will be apparent to those skilled in the art.Cause
This, these modifications or improvements, fall within the scope of the claimed invention without departing from theon the basis of the spirit of the present invention.
Claims (9)
1. a kind of roof roof waterproof and heat-insulating glue, which is characterized in that the raw material of the roof roof waterproof and heat-insulating glue includes as follows
The ingredient of mass parts:
2. roof waterproof and heat-insulating glue in roof according to claim 1, which is characterized in that the roof roof waterproof and heat-insulating glue
Raw material include following mass parts ingredient:
3. roof waterproof and heat-insulating glue in roof according to claim 2, which is characterized in that the roof roof waterproof and heat-insulating glue
Raw material include following mass parts ingredient:
4. described in any item roof roof waterproof and heat-insulating glue according to claim 1~3, which is characterized in that the catalyst choosing
From one of two (dodecyl sulphur) dibutyl tin, dibutyltin diacetate or DBTL or a variety of；The foaming agent is selected from just
One of pentane, pentamethylene or chloro fluoroethane are a variety of.
5. roof waterproof and heat-insulating glue in roof according to claim 4, which is characterized in that the fire retardant is selected from melamine
One of cyanurate, chlorinated paraffin or TCEP or a variety of；The waterproofing agent be selected from aluminium chloride, emulsified asphalt, iron chloride or
One of metallic soap is a variety of.
6. roof waterproof and heat-insulating glue in roof according to claim 5, which is characterized in that the roof roof waterproof and heat-insulating glue
Raw material include following mass parts ingredient:
7. the preparation method of the described in any item roof roof waterproof and heat-insulating glue of claim 1~6, which is characterized in that by trimerization
Cyanamide formaldehyde resin is warming up to 40~50 DEG C, and tetrahydroxy polyethers, waterproofing agent, fire retardant is added, and stirs 10~20 minutes, mixing liter
Temperature is added MDI and stirs evenly i.e. to 55~65 DEG C plus equal infusion, catalyst and foaming agent after 60~70 DEG C are stirred 1 hour
?.
8. preparation method according to claim 7, which is characterized in that melamine resin is warming up to 45 DEG C, is added
Enter tetrahydroxy polyethers, emulsified asphalt, TCEP, stir 15 minutes, mixing be warming up to 60 DEG C plus silicone oil AK8830, catalyst DBTL and
Pentane is added MDI and stirs evenly after 65 DEG C are stirred 1 hour to obtain the final product.
9. application of the described in any item roof roof waterproof and heat-insulating glue of claim 1~6 in building top insulating water-proof.
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| CN102559123A (en) * | 2011-12-15 | 2012-07-11 | 成都富路其鞋业有限公司 | Water-based adhesive for shoes |
| CN103572503A (en) * | 2012-07-24 | 2014-02-12 | 陈照峰 | Hydrophobic type glass wool blanket and adhesive proportion thereof |
| CN103641970A (en) * | 2013-12-04 | 2014-03-19 | 中国林业科学研究院林产化学工业研究所 | Preparation method of high-solid-content melamino-formaldehyde-base resin |
| CN104293213A (en) * | 2014-10-28 | 2015-01-21 | 成都纳硕科技有限公司 | High-ductility low-toxicity ultraviolet light polymerization glue and preparation method thereof |
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| CN102559123A (en) * | 2011-12-15 | 2012-07-11 | 成都富路其鞋业有限公司 | Water-based adhesive for shoes |
| CN103572503A (en) * | 2012-07-24 | 2014-02-12 | 陈照峰 | Hydrophobic type glass wool blanket and adhesive proportion thereof |
| CN103641970A (en) * | 2013-12-04 | 2014-03-19 | 中国林业科学研究院林产化学工业研究所 | Preparation method of high-solid-content melamino-formaldehyde-base resin |
| CN104293213A (en) * | 2014-10-28 | 2015-01-21 | 成都纳硕科技有限公司 | High-ductility low-toxicity ultraviolet light polymerization glue and preparation method thereof |
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