CN106221584A - A kind of low VOC clean taste antimicrobial chamber interior trim emulsion paint and preparation method thereof - Google Patents

A kind of low VOC clean taste antimicrobial chamber interior trim emulsion paint and preparation method thereof Download PDF

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Publication number
CN106221584A
CN106221584A CN201610737133.6A CN201610737133A CN106221584A CN 106221584 A CN106221584 A CN 106221584A CN 201610737133 A CN201610737133 A CN 201610737133A CN 106221584 A CN106221584 A CN 106221584A
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agent
emulsion paint
emulsion
interior trim
chamber interior
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CN201610737133.6A
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Chinese (zh)
Inventor
方学平
李金明
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GUANGDONG BADESE CHEMICAL CO Ltd
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GUANGDONG BADESE CHEMICAL CO Ltd
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Priority to CN201610737133.6A priority Critical patent/CN106221584A/en
Publication of CN106221584A publication Critical patent/CN106221584A/en
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D201/00Coating compositions based on unspecified macromolecular compounds
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/03Powdery paints
    • C09D5/033Powdery paints characterised by the additives
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/14Paints containing biocides, e.g. fungicides, insecticides or pesticides

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Plant Pathology (AREA)
  • Paints Or Removers (AREA)

Abstract

A kind of low VOC clean taste antimicrobial chamber interior trim emulsion paint and preparation method thereof, this emulsion paint is to add major part water, hydroxyethyl cellulose and pH adjusting agent in reactor, dispersed with stirring, it is subsequently added into freeze-thaw stabiliser FT100, wetting agent, dispersant and part defoamer, dispersed with stirring, put into titanium dioxide, Kaolin and calcium carbonate again, stir to fineness≤50um, finally put into coalescents COASOL, Tao Shi silver-ion antibiotic emulsion, antifungus agent, antibacterial, thickening agent, remaining water and remaining defoamer, stirring, to obtain final product.The present invention uses Tao Shi silver-ion antibiotic emulsion to be basic emulsion, make the silver ion with polymer complex can be along with ambient humidity self regulation emission levels, to maintain concentration of silver ions long-acting, stable and suitable, effectively kill harmful microorganism, extend the antibacterial timeliness of metope, be difficult to eluting of swiping, and there is self-cleaning function, wall color sustains its quality through age, and more has the active function of self-regeneration.

Description

A kind of low VOC clean taste antimicrobial chamber interior trim emulsion paint and preparation method thereof
Technical field
The invention belongs to paint field, relate to a kind of interior decoration emulsion paint, be specifically related to a kind of low VOC clean taste antimicrobial chamber Interior trim emulsion paint, also relates to the preparation method of this emulsion paint.
Background technology
Along with people are increasingly stronger to the pursuit of healthy clean ecology living environment, new environmental regulation requires increasingly Strictly, make coating industry the most wilful.The organic volatile of indoor decorative paint release, such as benzene, Tvoc and formaldehyde etc., is to cause One major reason of indoor pollution so that the emulsion paint with water as diluent is also faced with more challenge.Moist metope Mould mark is full of stains or spots, and long-term difficulty is removed, and is the hotbed of antibacterial, mycete, more can cause the allergic condition such as skin eczema, asthma.Public environment The pathogenic bacteria naked eyes that middle circulation is grown cannot be discovered at all, the most out of hand, it is likely that causes fearful infectious disease tide.Additionally by Constantly making a variation and drug resistance ground strengthens day by day in superbacteria, the threat of the mankind is made academia and media more by it in recent years More pay close attention to.For protection human health, all circles are devoted to research and develop various new technique and product, make every effort to restrain and the harmful micro-life of prevention The propagation growth of thing.Although the most also there being some emulsion paints passing through to add sterilization auxiliary agent, it uses the initial stage to antibacterial Really have and kill and inhibitory action, but along with the constantly variation of antibacterial ground and drug resistance ground strengthen day by day, the sterilization in emulsion paint Amount of auxiliary is also increasing, and antibacterial gradually loses effect, and the auxiliary agent itself that sterilizes also has certain harm to environment.In view of above-mentioned The shortcoming of interior decoration paint, the antibacterial interior decoration emulsion paint of research and development health environment-friendly, clean taste is to face the class being badly in need of solving Topic.
Summary of the invention
The technical problem to be solved is: the raw material existed for above-mentioned prior art interior decoration emulsion paint The difficult control of safety, the deficiency of the aspect such as the most lasting of bactericidal property, it is provided that a kind of low VOC clean taste antimicrobial chamber interior trim emulsion paint and Preparation method, by effectively controlling VOC content, selects abnormal smells from the patient antibacterial breast ultralow, that prepare without formaldehyde and APEO antimicrobial emulsion Shellac varnish, makes metope reach more stable, safe, lasting antibacterial effect.
In order to solve the problems referred to above, the technical solution adopted in the present invention is: a kind of low VOC clean taste antimicrobial chamber interior trim breast Shellac varnish, this emulsion paint is made up of following substances by weight: the silver-ion antibiotic emulsion 25 of Dow Chemical~32 parts, film forming Auxiliary agent COASOL 0.8~1.5 parts, hydroxyethyl cellulose 0.3~0.5 part, pH adjusting agent 0.05~0.1 part, freeze-thaw stabiliser FT-100 0.5~1.0 parts, wetting agent 0.1~0.2 part, dispersant 0.5~1.0 parts, defoamer 0.4~0.6 part, titanium dioxide 20 ~25 parts, Kaolin 5~10 parts, calcium carbonate 10~15 parts, antifungus agent 0.2~0.5 part, antibacterial 0.2~0.3 part, thickening agent 0.3~0.6 part and water 21~27 parts.
Above-mentioned pH adjusting agent is selected from BS168 (Wacker Chemical Co., Ltd of Germany), Rheinamin VP195 (Germany's BASF Company) or AMP95 (DOW chemical company of the U.S.).
Above-mentioned wetting agent selected from BD-405 (DOW chemical company of the U.S.), E9289 (Germany BASF chemical company) or LCN407 (Clariant chemical company of Germany).
Above-mentioned dispersant is selected from fast easily dispersant (DOW chemical company of the U.S.), 731A (DOW chemical company of the U.S.) or SN- DISPERSANT5040 (chemical company of Sheng Ruopu section of Japan).
Above-mentioned defoamer is selected from AP7015 (this chemical company of sea name of the U.S.), CF1366 (England Blackburn chemical company) Or ST2410 (BASF chemical company of Germany).
Above-mentioned antifungus agent selected from 678 (TROY chemical companies of the U.S.), TRYSAN107 (TROY chemical company of the U.S.) or CF1100 (DOW chemical company of the U.S.).
(Germany's Clariant chemical industry is public selected from LXE (DOW chemical company of the U.S.) or Nipacide CI15HS for above-mentioned antibacterial Department).
Above-mentioned thickening agent is selected from RHEOLATE420 (this chemical company of sea name of the U.S.), TT-935 (DOW chemical company of the U.S.) Or DR-180 (DOW chemical company of the U.S.).
Present invention simultaneously provides the preparation method of above-mentioned low VOC clean taste antimicrobial chamber interior trim emulsion paint, the method be prior to Reactor adds the total consumption of water 80~the water of 85%, hydroxyethyl cellulose and pH adjusting agent, to be not less than turning of 600r/min Speed disperses at least 8min, is subsequently added into freeze-thaw stabiliser FT100, wetting agent, dispersant and 50~the defoamer of 60% weight, and Disperse at least 2min with same rotating speed, then put into titanium dioxide, Kaolin and calcium carbonate, divide being not less than the rotating speed of 1000r/min It is dissipated to fineness≤50um, finally puts into coalescents COASOL, silver-ion antibiotic emulsion, the antifungus agent of Dow Chemical, kill Microbial inoculum, thickening agent, remaining water and remaining defoamer, stir at least 10min being not less than the rotating speed of 600r/min,.
Preferably, the method is prior to adding the total consumption of water 80~the water of 85%, hydroxyethyl cellulose and pH in reactor Regulator, the rotating speed with 600~800r/min disperses 8~12min, is subsequently added into freeze-thaw stabiliser FT100, wetting agent, dispersion Agent and 50~60% defoamer of weight, and disperse 2~3min with the rotating speed of 600~800r/min, then put into titanium dioxide, kaolinite Soil and calcium carbonate, be dispersed to fineness≤50um with the rotating speed of 1000~1200r/min, finally put into coalescents COASOL, pottery The silver-ion antibiotic emulsion of family name chemical company, antifungus agent, antibacterial, thickening agent, remaining water and remaining defoamer, with 600 ~the rotating speed stirring 10~20min of 800r/min,.
The low VOC clean taste antimicrobial chamber interior trim emulsion paint that the present invention provides is the present inventor through deep theory analysis and anti- Retrial is tested, and sieve especially has selected the basic emulsion using Tao Shi silver-ion antibiotic emulsion as emulsion paint, with the freeze thawing of Sol dimension Diamond Search Stabilizer FT-100 is as emulsion paint freeze-thaw stabiliser, with watt gram BS168, Rheinamin VP195 or AMP95 as pH regulator Agent.The present invention is using Sol dimension freeze-thaw stabiliser FT-100 as emulsion paint freeze-thaw stabiliser, with conventional antifreezing agent (propylene glycol or second Glycol) compare, without organic volatile, considerably reduce VOC content, and improve the low temperature freeze-thaw resistance property of emulsion paint. The pH adjusting agent selected, the most effectively controls pH value, product other 2-amino-2-methyl-1-propanol on year-on-year basis itself Abnormal smells from the patient is lower.The basic emulsion of emulsion paint selects low abnormal smells from the patient, silver-ion antibiotic emulsion without APEO, itself has self-crosslinking performance Good and low minimum film formation temperature MFT, it is not necessary to be equipped with more coalescents as conventional emulsions, be only equipped with lesser amount of low The coalescents COASOL of abnormal smells from the patient Diamond Search, and without APEO, therefore prepared emulsion paint has clean taste, the feature of low VOC, Having reached DB44/T1105-2012 " low VOCs synthetic resin emulsion coating " standard (see table 1), HG/T3950-2007 is " antibacterial Coating " test result see table 2, is the interior decoration emulsion paint of a kind of zero VOC.
Every Testing index of table 1 product emulsion paint of the present invention
Table 2 emulsion paint of the present invention presses HG/T3950-2007 " antibiotic paint " test result
The low VOC of the one clean taste antimicrobial chamber interior trim emulsion paint that the present invention provides, selected Tao Shi silver-ion antibiotic breast Liquid is organic silver ion antibacterial emulsion, the organic silver ion emulsion technique of Tao Shi original creation, makes the silver ion energy with polymer complex Along with ambient humidity self regulation emission levels, to maintain concentration of silver ions long-acting, stable and suitable, effectively kill thin The harmful microorganisms such as bacterium, superbacteria MRSA, mycete and algae.It is micro-that metope through the process of this antibiotic emulsion paint provides mushroom The biological environment that cannot replicate survival, had both extended the antibacterial timeliness of metope, is difficult to eluting of swiping, has again self-cleaning function, wall Color sustains its quality through age, and more has the active function of self-regeneration.
Detailed description of the invention
Below by specific embodiment, the present invention is described further, in order to be more readily understood that the present invention. But it is important to note that the invention is not restricted to the form described by example below, those skilled in the art is not In the case of paying creative work, also can design other form easily, the most should be by example given below It is interpreted as protection scope of the present invention and protection scope of the present invention is limited in given embodiment.
Embodiment 1
The component of emulsion paint of the present invention is calculated as by weight: Tao Shi silver-ion antibiotic emulsion 25 parts, coalescents COASOL 0.8 part, hydroxyethyl cellulose 0.3 part, BS168 0.08 part, freeze-thaw stabiliser FT-100 0.5 part, LCN407 wetting agent 0.1 Part, fast easily dispersant 0.5 part, ST2410 defoamer 0.4 part, titanium dioxide 20 parts, Kaolin 10 parts, calcium carbonate 15 parts, TRYSAN107 antifungus agent 0.3 part, LXE antibacterial 0.2 part, TT-935 thickening agent 0.6 part and 27 parts of water.
Preparation method: add water, hydroxyethyl cellulose and the BS168 of 80% in reactor, with the rotating speed of 600r/min Dispersion 12min, is subsequently added into freeze-thaw stabiliser FT100, LCN407 wetting agent, fast easily dispersant and the ST2410 froth breaking of 50% Agent, and disperse 3min with the rotating speed of 600r/min, then put into titanium dioxide, Kaolin and calcium carbonate, divide with the rotating speed of 1200r/min It is dissipated to fineness≤50um, finally puts into coalescents COASOL, Tao Shi silver-ion antibiotic emulsion, TRYSAN107 antifungus agent, LXE Antibacterial, TT-935 thickening agent, remaining water and remaining ST2410 defoamer, stir 10min with the rotating speed of 800r/min, i.e. Obtain the emulsion paint of the present invention.
Embodiment 2
The component of emulsion paint of the present invention is calculated as by weight: Tao Shi silver-ion antibiotic emulsion 32 parts, coalescents COASOL 1.5 parts, hydroxyethyl cellulose 0.5 part, Rheinamin VP195 0.1 part, freeze-thaw stabiliser FT-100 1.0 parts, E9289 profit Humectant 0.2 part, 731A dispersant 1.0 parts, CF1366 defoamer 0.6 part, titanium dioxide 25 parts, Kaolin 5 parts, calcium carbonate 10 parts, CF1100 antifungus agent 0.2 part, LXE antibacterial 0.3 part, RHEOLATE420 thickening agent 0.3 part and 25 parts of water.
Preparation method: add water, hydroxyethyl cellulose and the Rheinamin VP195 of 85% in reactor, with 800r/ The rotating speed dispersion 8min of min, is subsequently added into freeze-thaw stabiliser FT100, E9289 wetting agent, 731A dispersant and 60% CF1366 defoamer, and disperse 2min with the rotating speed of 800r/min, then put into titanium dioxide, Kaolin and calcium carbonate, with 1000r/ The rotating speed of min is dispersed to fineness≤50um, and finally input coalescents COASOL, Tao Shi silver-ion antibiotic emulsion, CF1100 prevent Mould dose, LXE antibacterial, RHEOLATE420 thickening agent, remaining water and remaining CF1366 defoamer, turning with 600r/min Speed stirring 20min, obtains the emulsion paint of the present invention.
Embodiment 3
The component of emulsion paint of the present invention is calculated as by weight: Tao Shi silver-ion antibiotic emulsion 30 parts, coalescents COASOL 1.2 parts, hydroxyethyl cellulose 0.4 part, AMP95 0.05 part, freeze-thaw stabiliser FT-100 0.8 part, BD-405 wetting agent 0.15 Part, SN-DISPERSANT5040 dispersant 0.8 part, AP7015 defoamer 0.5 part, titanium dioxide 23 parts, Kaolin 8 parts, calcium carbonate 12.5 parts, 678 antifungus agent 0.5 part, Nipacide CI15HS antibacterial 0.2 part, DR-180 thickening agent 0.4 part and 21 parts of water.
Preparation method: add water, hydroxyethyl cellulose and the AMP95 of 82% in reactor, with the rotating speed of 700r/min Dispersion 10min, is subsequently added into freeze-thaw stabiliser FT100, BD-405 wetting agent, SN-DISPERSANT5040 dispersant and 55% AP7015 defoamer, and disperse 3min with the rotating speed of 700r/min, then put into titanium dioxide, Kaolin and calcium carbonate, with The rotating speed of 1100r/min is dispersed to fineness≤50um, finally put into coalescents COASOL, Tao Shi silver-ion antibiotic emulsion, 678 Antifungus agent, NipacideCI15HS antibacterial, DR-180 thickening agent, remaining AP7015 defoamer and remaining water, with 700r/ The rotating speed stirring 15min of min, obtains the emulsion paint of the present invention.

Claims (10)

1. a low VOC clean taste antimicrobial chamber interior trim emulsion paint, it is characterised in that this emulsion paint is by weight by following substances system Become: the silver-ion antibiotic emulsion 25 of Dow Chemical~32 parts, coalescents COASOL0.8~1.5 parts, hydroxyethyl cellulose 0.3~0.5 part, pH adjusting agent 0.05~0.1 part, freeze-thaw stabiliser FT-100 0.5~1.0 parts, wetting agent 0.1~0.2 part, Dispersant 0.5~1.0 parts, defoamer 0.4~0.6 part, titanium dioxide 20~25 parts, Kaolin 5~10 parts, calcium carbonate 10~15 Part, antifungus agent 0.2~0.5 part, antibacterial 0.2~0.3 part, thickening agent 0.3~0.6 part and water 21~27 parts.
A kind of low VOC the most as claimed in claim 1 clean taste antimicrobial chamber interior trim emulsion paint, it is characterised in that described pH regulator Agent is BS168, Rheinamin VP195 or AMP-95.
A kind of low VOC the most as claimed in claim 1 clean taste antimicrobial chamber interior trim emulsion paint, it is characterised in that described wetting agent For BD-405, E9289 or LCN407.
A kind of low VOC the most as claimed in claim 1 clean taste antimicrobial chamber interior trim emulsion paint, it is characterised in that described dispersant For fast easily dispersant, 731A or SN-DISPERSANT5040.
A kind of low VOC the most as claimed in claim 1 clean taste antimicrobial chamber interior trim emulsion paint, it is characterised in that described defoamer For AP7015, CF1366 or ST2410.
A kind of low VOC the most as claimed in claim 1 clean taste antimicrobial chamber interior trim emulsion paint, it is characterised in that described antifungus agent Be 678, TRYSAN107 and CF1100.
A kind of low VOC the most as claimed in claim 1 clean taste antimicrobial chamber interior trim emulsion paint, it is characterised in that described antibacterial For LXE or Nipacide CI15HS.
A kind of low VOC the most as claimed in claim 1 clean taste antimicrobial chamber interior trim emulsion paint, it is characterised in that described thickening agent For RHEOLATE420, TT-935 or DR-180.
9. the method for the preparation a kind of low VOC clean taste antimicrobial chamber interior trim emulsion paint according to any one of claim 1-8, it is special Levying and be, the method is prior to adding the total consumption of water 80~the water of 85%, hydroxyethyl cellulose and pH adjusting agent in reactor, with The rotating speed being not less than 600r/min disperses at least 8min, be subsequently added into freeze-thaw stabiliser FT100, wetting agent, dispersant and 50~ The defoamer of 60% weight, and disperse at least 2min with same rotating speed, then put into titanium dioxide, Kaolin and calcium carbonate, with the lowest Rotating speed in 1000r/min is dispersed to fineness≤50um, finally puts into coalescents COASOL, the silver ion of Dow Chemical Antimicrobial emulsion, antifungus agent, antibacterial, thickening agent, remaining water and remaining defoamer, stir being not less than the rotating speed of 600r/min Mix at least 10min,.
10. preparation method as claimed in claim 9, it is characterised in that the method is prior to adding the total consumption of water in reactor 80~the water of 85%, hydroxyethyl cellulose and pH adjusting agent, the rotating speed with 600~800r/min disperses 8~12min, then adds Enter freeze-thaw stabiliser FT100, wetting agent, dispersant and 50~the defoamer of 60% weight, and with the rotating speed of 600~800r/min Dispersion 2~3min, then puts into titanium dioxide, Kaolin and calcium carbonate, with the rotating speed of 1000~1200r/min be dispersed to fineness≤ 50um, finally puts into coalescents COASOL, the silver-ion antibiotic emulsion of Dow Chemical, antifungus agent, antibacterial, thickening Agent, remaining water and remaining defoamer, the rotating speed with 600~800r/min stirs 10~20min,.
CN201610737133.6A 2016-08-26 2016-08-26 A kind of low VOC clean taste antimicrobial chamber interior trim emulsion paint and preparation method thereof Pending CN106221584A (en)

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107903726A (en) * 2017-11-24 2018-04-13 成都巴德士涂料有限公司 A kind of environmentally friendly low VOC interiro wall latex paints of net taste and preparation method thereof
FR3065861A1 (en) * 2017-05-04 2018-11-09 Hbco Herbals And Bio Chemicals Outsourcing USE OF MONOMETHYLSILANETRIOL AND / OR ITS SALTS TO PROTECT CROPS
CN111363478A (en) * 2019-12-28 2020-07-03 福州贝克朗新型材料有限公司 Environment-friendly antibacterial waterproof coating for culture pond and preparation method thereof
CN111560193A (en) * 2020-06-10 2020-08-21 三棵树涂料股份有限公司 Antibacterial and antiviral interior wall latex paint and preparation method thereof
CN112680108A (en) * 2020-12-18 2021-04-20 三棵树(上海)新材料研究有限公司 Silver carbon nitride formaldehyde-removing antibacterial coating and preparation method thereof

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CN103351747A (en) * 2013-06-21 2013-10-16 天长市开林化工有限公司 Antibacterial environmentally-friendly interior wall coating
CN103897538A (en) * 2014-03-20 2014-07-02 中华制漆(深圳)有限公司 Protective water-based antibacterial mould-proof coating and preparation method thereof

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CN102702828A (en) * 2012-06-14 2012-10-03 天长市银狐漆业有限公司 Long-acting antibacterial water-resistant environment-friendly inner wall putty composition
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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR3065861A1 (en) * 2017-05-04 2018-11-09 Hbco Herbals And Bio Chemicals Outsourcing USE OF MONOMETHYLSILANETRIOL AND / OR ITS SALTS TO PROTECT CROPS
CN107903726A (en) * 2017-11-24 2018-04-13 成都巴德士涂料有限公司 A kind of environmentally friendly low VOC interiro wall latex paints of net taste and preparation method thereof
CN111363478A (en) * 2019-12-28 2020-07-03 福州贝克朗新型材料有限公司 Environment-friendly antibacterial waterproof coating for culture pond and preparation method thereof
CN111560193A (en) * 2020-06-10 2020-08-21 三棵树涂料股份有限公司 Antibacterial and antiviral interior wall latex paint and preparation method thereof
CN112680108A (en) * 2020-12-18 2021-04-20 三棵树(上海)新材料研究有限公司 Silver carbon nitride formaldehyde-removing antibacterial coating and preparation method thereof

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Application publication date: 20161214