CN106221524A - A kind of anti-scratch coating of electric cooker and preparation method thereof - Google Patents

A kind of anti-scratch coating of electric cooker and preparation method thereof Download PDF

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Publication number
CN106221524A
CN106221524A CN201610668022.4A CN201610668022A CN106221524A CN 106221524 A CN106221524 A CN 106221524A CN 201610668022 A CN201610668022 A CN 201610668022A CN 106221524 A CN106221524 A CN 106221524A
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CN
China
Prior art keywords
parts
coating
preparation
electric cooker
mixed liquor
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610668022.4A
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Chinese (zh)
Inventor
何新凤
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Anqing City Qin Source Electrical Appliance Co Ltd
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Anqing City Qin Source Electrical Appliance Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Publication date
Application filed by Anqing City Qin Source Electrical Appliance Co Ltd filed Critical Anqing City Qin Source Electrical Appliance Co Ltd
Priority to CN201610668022.4A priority Critical patent/CN106221524A/en
Publication of CN106221524A publication Critical patent/CN106221524A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D167/00Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
    • C09D167/08Polyesters modified with higher fatty oils or their acids, or with natural resins or resin acids
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/63Additives non-macromolecular organic
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention discloses a kind of anti-scratch coating of electric cooker, be made up of following raw materials according: alkyd resin, hydroxymethyl cellulose, melmac, aliphatic dicarboxylic acid, mica powder, propylene glycol, calcium carbonate superfine powder, glycol ether, deionized water are appropriate, catalyst, firming agent, organic silica gel;Its preparation method comprises the steps: (1) preparation just batch mixing;(2) intermediate liquid is prepared;(3) mixed liquor is prepared;(4) it is ground mixed liquor processing, sieves and get product.The present invention, by using the preparation method of science, is optimized combination to high-molecular organic material, improves the anti-scratch performance of compositions, the coating gloss retention obtained is good, the indexs such as smooth surface is fine and smooth, hot strength are superior to common coating, can meet the use requirement of coated-body;Its energy-conserving and environment-protective, cost is relatively low, with short production cycle, is suitable to industrialized mass production.

Description

A kind of anti-scratch coating of electric cooker and preparation method thereof
Technical field
The invention belongs to coating industry technical field, particularly relate to a kind of anti-scratch coating of electric cooker and preparation method thereof.
Background technology
Coating refers to that coating body surface can form thin film under certain conditions and play protection, decoration or other special merits Can the class I liquid I of (insulation, antirust, mildew-resistant, heat-resisting etc.) or solid material.Coating belongs to organic chemical industry's macromolecular material, institute's shape The film become belongs to macromolecular compound type.According to the classification of the chemical products that the modern times pass through, coating belongs to fine chemistry industry and produces Product.Modern coating the most progressively becomes a polyfunctional engineering material of class, is an important industry in chemical industry.Mesh Before, the coating industry of China is the most ripe, in addition under the overall situation of green economy globalization, needs to implement promotion green science and technology The development of industry.
Along with the development of society, the covering with paint of traditional household electrical appliance has had bigger change, the water paint of environmental protection Gradually substitute thermohardening lacquer, but different electrical equipment has different requirements due to the difference of the aspects such as function to coating, need Use environmental protection and more personalized coating.The market demand huge in the face of household electrical appliances coating and ever-increasing application prospect, have Necessity is strengthened research and development capabilities, and updates and improving product performance, accelerates product quality upgrading, develops technically, cost Above, there is in performance the household electrical appliances coating of powerful competitive advantage.
Summary of the invention
The invention aims to overcome the deficiencies in the prior art, it is provided that a kind of anti-scratch coating of electric cooker and Its preparation method, the coating products excellent combination property obtained, also there is good anti-scratch performance, be suitable to popularization and application.
For solve above-mentioned technical problem, the present invention by the following technical solutions:
A kind of anti-scratch coating of electric cooker, it is characterised in that be prepared by the raw materials in: alkyd resin 30~45 Part, hydroxymethyl cellulose 20~35 parts, melmac 15~25 parts, aliphatic dicarboxylic acid 8~15 parts, mica powder 3~6 Part, propylene glycol 1~3 parts, calcium carbonate superfine powder 2~5 parts, glycol ether 5~12 parts, deionized water be appropriate, catalyst 1~3 parts, solid Agent 1~2.5 parts, organic silica gel 4~10 parts;
Its preparation method in turn includes the following steps:
(1) alkyd resin, hydroxymethyl cellulose, melmac and aliphatic dicarboxylic acid are mixed to join batch mixing Machine, stirs, and is heated to 60~75 DEG C, continues stirring 30~50 minutes, obtains just batch mixing;
(2) mica powder, propylene glycol, calcium carbonate superfine powder, glycol ether and appropriate amount of deionized water are added sequentially to step (1) In the first batch mixing obtained, being stirred continuously and be warming up to 150~165 DEG C, under 900~1100 revs/min, stirring reaction 1.5~3 is little Time, obtain intermediate liquid;
(3) intermediate liquid that step (2) obtains is cooled to 60~70 DEG C, adds catalyst and firming agent and constantly stir Mix, be eventually adding organic silica gel, mix and blend 50~90 minutes, obtain mixed liquor;
(4) it is ground the mixed liquor that step (3) obtains processing, sieves and get product.
Preferably, described catalyst is dibutyl tin laurate.
Preferably, described firming agent is isocyanates.
The beneficial effects of the present invention is:
The present invention, by using the preparation method of science, is optimized combination to high-molecular organic material, improves combination The anti-scratch performance of thing, the indexs such as the coating gloss retention obtained is good, and smooth surface is fine and smooth, hot strength are superior to common coating, The use requirement of coated-body can be met;Present invention achieves making full use of of resource and the energy, energy-conserving and environment-protective, cost is relatively low, raw The product cycle is short, is suitable to industrialized mass production.
Detailed description of the invention
Below in conjunction with embodiment, the invention will be further described.
Embodiment 1:
A kind of anti-scratch coating of electric cooker, it is characterised in that be prepared by the raw materials in: alkyd resin 30 parts, Hydroxymethyl cellulose 20 parts, melmac 15 parts, aliphatic dicarboxylic acid 8 parts, mica powder 3 parts, propylene glycol 1 part, ultra-fine carbon Acid calcium 2 parts, glycol ether 5 parts, deionized water are appropriate, catalyst 1 part, 1 part of firming agent, organic silica gel 4 parts;
Its preparation method in turn includes the following steps:
(1) alkyd resin, hydroxymethyl cellulose, melmac and aliphatic dicarboxylic acid are mixed to join batch mixing Machine, stirs, and is heated to 60~75 DEG C, continues stirring 30 minutes, obtains just batch mixing;
(2) mica powder, propylene glycol, calcium carbonate superfine powder, glycol ether and appropriate amount of deionized water are added sequentially to step (1) In the first batch mixing obtained, it is stirred continuously and is warming up to 150~165 DEG C, stirring reaction 3 hours under 900~1100 revs/min, To intermediate liquid;
(3) intermediate liquid that step (2) obtains is cooled to 60~70 DEG C, adds catalyst and firming agent and constantly stir Mix, be eventually adding organic silica gel, mix and blend 50 minutes, obtain mixed liquor;
(4) it is ground the mixed liquor that step (3) obtains processing, sieves and get product.
Embodiment 2:
A kind of anti-scratch coating of electric cooker, it is characterised in that be prepared by the raw materials in: alkyd resin 45 parts, Hydroxymethyl cellulose 35 parts, melmac 25 parts, aliphatic dicarboxylic acid 15 parts, mica powder 6 parts, propylene glycol 3 parts, ultra-fine carbon Acid calcium 5 parts, glycol ether 12 parts, deionized water are appropriate, catalyst 3 parts, 2.5 parts of firming agent, organic silica gel 10 parts;
Its preparation method in turn includes the following steps:
(1) alkyd resin, hydroxymethyl cellulose, melmac and aliphatic dicarboxylic acid are mixed to join batch mixing Machine, stirs, and is heated to 60~75 DEG C, continues stirring 50 minutes, obtains just batch mixing;
(2) mica powder, propylene glycol, calcium carbonate superfine powder, glycol ether and appropriate amount of deionized water are added sequentially to step (1) In the first batch mixing obtained, it is stirred continuously and is warming up to 150~165 DEG C, stirring reaction 1.5 hours under 900~1100 revs/min, Obtain intermediate liquid;
(3) intermediate liquid that step (2) obtains is cooled to 60~70 DEG C, adds catalyst and firming agent and constantly stir Mix, be eventually adding organic silica gel, mix and blend 90 minutes, obtain mixed liquor;
(4) it is ground the mixed liquor that step (3) obtains processing, sieves and get product.
In the above embodiment of the present invention: described catalyst is dibutyl tin laurate, described firming agent is isocyanates.
In the embodiment of the present invention, by high-molecular organic material is optimized combination, improve the anti-scratch of compositions Performance, the indexs such as the coating gloss retention obtained is good, and smooth surface is fine and smooth, hot strength are superior to common coating, can meet application The use requirement of body, and energy-conserving and environment-protective, cost is relatively low, with short production cycle.
Finally it should be noted that above example only in order to illustrative not limiting technical scheme, although reference The present invention has been described in detail by above-described embodiment, it will be appreciated by those skilled in the art that and still can carry out the present invention Amendment or equivalent, any modification or partial replacement without departing from the spirit and scope of the present invention, it all should be contained In scope of the presently claimed invention.

Claims (3)

1. the anti-scratch coating of electric cooker, it is characterised in that be prepared by the raw materials in: alkyd resin 30~45 Part, hydroxymethyl cellulose 20~35 parts, melmac 15~25 parts, aliphatic dicarboxylic acid 8~15 parts, mica powder 3~6 Part, propylene glycol 1~3 parts, calcium carbonate superfine powder 2~5 parts, glycol ether 5~12 parts, deionized water be appropriate, catalyst 1~3 parts, solid Agent 1~2.5 parts, organic silica gel 4~10 parts;
Its preparation method in turn includes the following steps:
(1) alkyd resin, hydroxymethyl cellulose, melmac and aliphatic dicarboxylic acid are mixed to join batch mixer, stir Mix uniformly, be heated to 60~75 DEG C, continue stirring 30~50 minutes, obtain just batch mixing;
(2) mica powder, propylene glycol, calcium carbonate superfine powder, glycol ether and appropriate amount of deionized water are added sequentially to step (1) obtain First batch mixing in, be stirred continuously and be warming up to 150~165 DEG C, under 900~1100 revs/min stirring reaction 1.5~3 hours, To intermediate liquid;
(3) intermediate liquid that step (2) obtains is cooled to 60~70 DEG C, adds catalyst and firming agent and be stirred continuously, Rear addition organic silica gel, mix and blend 50~90 minutes, obtain mixed liquor;
(4) it is ground the mixed liquor that step (3) obtains processing, sieves and get product.
A kind of anti-scratch coating of electric cooker the most according to claim 1, it is characterised in that described catalyst is tin dilaurate Dibutyl tin.
A kind of anti-scratch coating of electric cooker the most according to claim 1, it is characterised in that described firming agent is Carbimide. Ester.
CN201610668022.4A 2016-08-14 2016-08-14 A kind of anti-scratch coating of electric cooker and preparation method thereof Pending CN106221524A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610668022.4A CN106221524A (en) 2016-08-14 2016-08-14 A kind of anti-scratch coating of electric cooker and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610668022.4A CN106221524A (en) 2016-08-14 2016-08-14 A kind of anti-scratch coating of electric cooker and preparation method thereof

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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2081139C1 (en) * 1995-06-14 1997-06-10 Научно-исследовательский институт полимерных материалов Nitrate cellulose lusterless varnish
DE69915511T2 (en) * 1998-11-13 2005-01-27 Owens Corning, Toledo SUPER ABSORBENT WATER RESISTANT COATINGS FOR FIBER REINFORCED ARTICLES
CN104762004A (en) * 2015-03-24 2015-07-08 田福东 Alkyd resin fireproof paint

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2081139C1 (en) * 1995-06-14 1997-06-10 Научно-исследовательский институт полимерных материалов Nitrate cellulose lusterless varnish
DE69915511T2 (en) * 1998-11-13 2005-01-27 Owens Corning, Toledo SUPER ABSORBENT WATER RESISTANT COATINGS FOR FIBER REINFORCED ARTICLES
CN104762004A (en) * 2015-03-24 2015-07-08 田福东 Alkyd resin fireproof paint

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