CN106221504A - A kind of antibacterial impermeabilisation insulating layer of external wall of building coating - Google Patents

A kind of antibacterial impermeabilisation insulating layer of external wall of building coating Download PDF

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CN106221504A
CN106221504A CN201610739942.0A CN201610739942A CN106221504A CN 106221504 A CN106221504 A CN 106221504A CN 201610739942 A CN201610739942 A CN 201610739942A CN 106221504 A CN106221504 A CN 106221504A
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component
weight
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impermeabilisation
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迟利山
朱国庆
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Anhui Building Materials Co Ltd
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Anhui Building Materials Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D163/00Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/40Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
    • C08G59/62Alcohols or phenols
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/14Paints containing biocides, e.g. fungicides, insecticides or pesticides
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/18Fireproof paints including high temperature resistant paints
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/014Additives containing two or more different additives of the same subgroup in C08K
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/14Polymer mixtures characterised by other features containing polymeric additives characterised by shape
    • C08L2205/16Fibres; Fibrils

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Health & Medical Sciences (AREA)
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Abstract

The invention discloses a kind of antibacterial impermeabilisation insulating layer of external wall of building coating, including first component, component B, first component is 10:2~5 with the weight ratio of component B;The raw material of first component includes by weight: bisphenol A type epoxy resin 40~80 parts, modified montmorillonoid 5~15 parts, nano titanium oxide 2~10 parts, sepiolite powder 5~12 parts, silk fiber 6~12 parts, Graphene 2~8 parts, disproportionated rosin 1~4 parts, dispersant 0.5~1.5 parts, defoamer 0.5~1.5 parts, thickening agent 0.5~1.5 parts, aqueous color paste 1~2 parts;The raw material of component B includes by weight: phenolic aldehyde amine 5~15 parts, deionized water 10~30 parts.Anti-microbial property of the present invention is good, and adhesion is strong, and anti-permeability performance is excellent.

Description

A kind of antibacterial impermeabilisation insulating layer of external wall of building coating
Technical field
The present invention relates to thermal insulation coatings technical field, particularly relate to a kind of antibacterial impermeabilisation insulating layer of external wall of building coating.
Background technology
Along with progress and mankind's attention to living environment quality of science and technology, coatings industry is towards environment-friendly type, aqueous Changing direction to develop, current insulating layer of external wall of building field is just at active development water paint, to adapt to heat-insulation layer body of wall to aqueous The demand of environment-friendly type coating product.The development speed of recent year water paint is very fast, and heat-insulation layer is by water paint demand For urgently, but the most urgently exploitation adhesion strength is high, and anti-microbial property is good, and anti-permeability performance is excellent, and environmental protection is of value to body The aqueous industrial coating that the heart is healthy.
Summary of the invention
The technical problem existed based on background technology, the present invention proposes a kind of antibacterial impermeabilisation insulating layer of external wall of building and is coated with Material, anti-microbial property is good, and adhesion is strong, and anti-permeability performance is excellent.
The one antibacterial impermeabilisation insulating layer of external wall of building coating that the present invention proposes, including first component, component B, first component It is 10:2~5 with the weight ratio of component B;The raw material of first component includes by weight: bisphenol A type epoxy resin 40~80 parts, changes Property montmorillonite 5~15 parts, nano titanium oxide 2~10 parts, sepiolite powder 5~12 parts, silk fiber 6~12 parts, Graphene 2~ 8 parts, disproportionated rosin 1~4 parts, dispersant 0.5~1.5 parts, defoamer 0.5~1.5 parts, thickening agent 0.5~1.5 parts, aqueous color Starch 1~2 part;The raw material of component B includes by weight: phenolic aldehyde amine 5~15 parts, deionized water 10~30 parts.
Preferably, modified montmorillonoid uses following technique to prepare: by chitosan, acetic acid, water mix homogeneously, adds nanometer high Ridge soil mix homogeneously, sends in syringe under room temperature and extrudes, and the container equipped with ethanol solution is receiving device, filters, and vacuum is done Dry obtain modified Nano Kaolin;By montmorillonite, water mix and blend, add soybean lecithin, silver sulfadiazine stirring, send into micro- Reaction in ripple reactor, adds modified Nano Kaolin mix and blend, filters, and washs, vacuum drying, and pulverizing obtains modified illiteracy and takes off Soil.
Preferably, modified montmorillonoid uses following technique to prepare: by weight by 2~6 parts of chitosans, 0.2~0.8 part of second Acid, 10~20 parts of water mix homogeneously, add 1~3 part of nano kaoline mix homogeneously, sends in syringe and extrude under room temperature, dress The container having concentration to be 75~85wt% ethanol solution is receiving device, filters, and vacuum drying obtains modified Nano Kaolin;Press Weight portion by 1~5 part of montmorillonite, 20~50 parts of water mix and blends, add 0.1~0.18 part of soybean lecithin, 0.15~0.3 part Silver sulfadiazine stirs, and sends in microwave reactor and reacts, adds 1~3 part of modified Nano Kaolin mix and blend, filters, washes Wash, vacuum drying, pulverize and obtain modified montmorillonoid.
Preferably, modified montmorillonoid uses following technique to prepare: by weight by 2~6 parts of chitosans, 0.2~0.8 part of second Acid, 10~20 parts of water mix homogeneously, add 1~3 part of nano kaoline mix homogeneously, sends in syringe, control note under room temperature Emitter extruded velocity is 1~2mL/h, and injection pressure is 0.5~1.5kPa, equipped with the appearance that concentration is 75~85wt% ethanol solution Device is receiving device, filters, and 65~75 DEG C of vacuum drying obtain modified Nano Kaolin;By weight by 1~5 part of montmorillonite, 20~50 parts of water mix and blends 5~12min, mixing speed is 1500~1800r/min, adds 0.1~0.18 part of Semen sojae atricolor ovum phosphorus Fat, 0.15~0.3 part of silver sulfadiazine stirring 20~50min, whipping temp is 60~80 DEG C, mixing speed be 800~ 1400r/min, sends into and reacts 2~8min in microwave reactor, and microwave power is 400~600W, adds 1~3 part of modified Nano Kaolin mix and blend 5~15min, filters, washing, and vacuum drying is pulverized and obtained modified montmorillonoid.
Preferably, first component is 10:3~4 with the weight ratio of component B.
Preferably, modified montmorillonoid, nano titanium oxide, sepiolite powder, silk fiber, the weight ratio of Graphene be 8~ 12:4~8:6~10:8~10:4~6.
Preferably, including first component, component B, first component is 10:3~4 with the weight ratio of component B;The raw material of first component Include by weight: bisphenol A type epoxy resin 50~70 parts, modified montmorillonoid 8~12 parts, nano titanium oxide 4~8 parts, sea Afrodite powder 6~10 parts, silk fiber 8~10 parts, Graphene 4~6 parts, disproportionated rosin 2~3 parts, dispersant 0.8~1.2 parts, disappear Infusion 0.8~1.2 parts, thickening agent 0.8~1.2 parts, aqueous color paste 1.2~1.8 parts;The raw material of component B includes by weight: Phenolic aldehyde amine 8~12 parts, deionized water 15~25 parts.
The present invention uses conventional fabrication process to prepare.
The present invention is with bisphenol A type epoxy resin as major ingredient, under the cooperation of modified montmorillonoid, uses phenolic aldehyde amine solidification, no Dispersion and emulsion excellent performance only each other, after solidification, mechanical property is good, waterproof, and anti-permeability performance is excellent, and anti-microbial property is good, bonding Power is strong;In modified montmorillonoid, montmorillonite is after pretreatment, in colloidal state, further with soybean lecithin, sulfadiazine Silver effect, through high-speed stirred and microwave action, ion exchange is inserted between cheating engaging layer, inserts with polymeric matrix further Layer, is evenly distributed each other, makes silver sulfadiazine directly to spread, owing to silver sulfadiazine sustained release performance is good, so that changing Property montmorillonite anti-microbial property excellent, and emulsifying, solubilizing effect are good;When surface sulfadiazine silver concentration reduces, Semen sojae atricolor Under the effect of lecithin, internal silver sulfadiazine can be migrated by polymeric matrix interior, and sustained anti-microbial effect is strong, with Time modified Nano Kaolin become Nano microsphere structure particle diameter fabulous, can to above-mentioned substance part intercalation, thus cause modified cover de- Soil dispersibility further enhances;Modified montmorillonoid is under the cooperation of disproportionated rosin, with nano titanium oxide, sepiolite powder, silkworm silk Fiber, the effect of Graphene, good dispersion, on the basis of ensureing hardness of the present invention, wear-resisting, good toughness, resistance to elevated temperatures is excellent Different, make the present invention for building heat preserving body of wall, long shelf-life, free from environmental pollution.
Detailed description of the invention
Below, by specific embodiment, technical scheme is described in detail.
Embodiment 1
The one antibacterial impermeabilisation insulating layer of external wall of building coating that the present invention proposes, including first component, component B, first component It is 10:2 with the weight ratio of component B;The raw material of first component includes by weight: bisphenol A type epoxy resin 80 parts, and modified illiteracy takes off 5 parts of soil, nano titanium oxide 10 parts, sepiolite powder 5 parts, silk fiber 12 parts, Graphene 2 parts, disproportionated rosin 4 parts, dispersant 0.5 part, defoamer 1.5 parts, thickening agent 0.5 part, aqueous color paste 2 parts;The raw material of component B includes by weight: phenolic aldehyde amine 5 parts, Deionized water 30 parts.
Embodiment 2
The one antibacterial impermeabilisation insulating layer of external wall of building coating that the present invention proposes, including first component, component B, first component It is 10:5 with the weight ratio of component B;The raw material of first component includes by weight: bisphenol A type epoxy resin 40 parts, and modified illiteracy takes off 15 parts of soil, nano titanium oxide 2 parts, sepiolite powder 12 parts, silk fiber 6 parts, Graphene 8 parts, disproportionated rosin 1 part, dispersant 1.5 parts, defoamer 0.5 part, thickening agent 1.5 parts, aqueous color paste 1 part;The raw material of component B includes by weight: phenolic aldehyde amine 15 Part, deionized water 10 parts.
Modified montmorillonoid uses following technique to prepare: by chitosan, acetic acid, water mix homogeneously, adds nano kaoline and mixes Closing uniformly, send in syringe and extrude under room temperature, the container equipped with ethanol solution is receiving device, filters, and vacuum drying obtains Modified Nano Kaolin;By montmorillonite, water mix and blend, add soybean lecithin, silver sulfadiazine stirring, send into microwave reaction Device reacts, adds modified Nano Kaolin mix and blend, filter, washing, vacuum drying, pulverize and obtain modified montmorillonoid.
Embodiment 3
The one antibacterial impermeabilisation insulating layer of external wall of building coating that the present invention proposes, including first component, component B, first component It is 10:3 with the weight ratio of component B;The raw material of first component includes by weight: bisphenol A type epoxy resin 70 parts, and modified illiteracy takes off 8 parts of soil, nano titanium oxide 8 parts, sepiolite powder 6 parts, silk fiber 10 parts, Graphene 4 parts, disproportionated rosin 3 parts, dispersant 0.8 part, defoamer 1.2 parts, thickening agent 0.8 part, aqueous color paste 1.8 parts;The raw material of component B includes by weight: phenolic aldehyde amine 8 Part, deionized water 25 parts.
Modified montmorillonoid uses following technique to prepare: by weight by 2 parts of chitosans, 0.8 part of acetic acid, 10 parts of water mixing all Even, add 3 parts of nano kaoline mix homogeneously, send in syringe under room temperature, controlling syringe extruded velocity is 1mL/h, note Injection pressure is 1.5kPa, is receiving device equipped with the container that concentration is 75wt% ethanol solution, filters, and 75 DEG C of vacuum drying obtain Modified Nano Kaolin;By weight by 1 part of montmorillonite, 50 parts of water mix and blend 5min, mixing speed is 1800r/min, adds Entering 0.1 part of soybean lecithin, 0.3 part of silver sulfadiazine stirring 20min, whipping temp is 80 DEG C, and mixing speed is 800r/min, Sending into and react 8min in microwave reactor, microwave power is 400W, adds 3 parts of modified Nano Kaolin mix and blend 5min, mistake Filter, washing, vacuum drying, pulverize and obtain modified montmorillonoid.
Embodiment 4
The one antibacterial impermeabilisation insulating layer of external wall of building coating that the present invention proposes, including first component, component B, first component It is 10:4 with the weight ratio of component B;The raw material of first component includes by weight: bisphenol A type epoxy resin 50 parts, and modified illiteracy takes off 12 parts of soil, nano titanium oxide 4 parts, sepiolite powder 10 parts, silk fiber 8 parts, Graphene 6 parts, disproportionated rosin 2 parts, dispersant 1.2 parts, defoamer 0.8 part, thickening agent 1.2 parts, aqueous color paste 1.2 parts;The raw material of component B includes by weight: phenolic aldehyde amine 12 Part, deionized water 15 parts.
Modified montmorillonoid uses following technique to prepare: by weight by 6 parts of chitosans, 0.2 part of acetic acid, 20 parts of water mixing all Even, add 1 part of nano kaoline mix homogeneously, send in syringe under room temperature, controlling syringe extruded velocity is 2mL/h, note Injection pressure is 0.5kPa, is receiving device equipped with the container that concentration is 85wt% ethanol solution, filters, and 65 DEG C of vacuum drying obtain Modified Nano Kaolin;By weight by 5 parts of montmorillonites, 20 parts of water mix and blend 12min, mixing speed is 1500r/min, adds Entering 0.18 part of soybean lecithin, 0.15 part of silver sulfadiazine stirring 50min, whipping temp is 60 DEG C, and mixing speed is 1400r/ Min, sends into and reacts 2min in microwave reactor, and microwave power is 600W, adds 1 part of modified Nano Kaolin mix and blend 15min, filters, washing, and vacuum drying is pulverized and obtained modified montmorillonoid.
Embodiment 5
The one antibacterial impermeabilisation insulating layer of external wall of building coating that the present invention proposes, including first component, component B, first component It is 10:3.5 with the weight ratio of component B;The raw material of first component includes by weight: bisphenol A type epoxy resin 60 parts, modified illiteracy 10 parts of de-soil, nano titanium oxide 6 parts, sepiolite powder 8 parts, silk fiber 9 parts, Graphene 5 parts, disproportionated rosin 2.5 parts, dispersion Agent 1 part, defoamer 1 part, thickening agent 1 part, aqueous color paste 1.5 parts;The raw material of component B includes by weight: phenolic aldehyde amine 10 parts, Deionized water 20 parts.
Modified montmorillonoid uses following technique to prepare: by weight by 4 parts of chitosans, 0.5 part of acetic acid, 15 parts of water mixing all Even, add 2 parts of nano kaoline mix homogeneously, send in syringe under room temperature and extrude, be 80wt% ethanol solution equipped with concentration Container be receiving device, filter, vacuum drying obtain modified Nano Kaolin;By weight 3 parts of montmorillonites, 35 parts of water are mixed Close stirring, add 0.14 part of soybean lecithin, 0.2 part of silver sulfadiazine stirring, send in microwave reactor and react, add 2 parts Modified Nano Kaolin mix and blend, filters, washing, and vacuum drying is pulverized and obtained modified montmorillonoid.
The above, the only present invention preferably detailed description of the invention, but protection scope of the present invention is not limited thereto, Any those familiar with the art in the technical scope that the invention discloses, according to technical scheme and Inventive concept equivalent or change in addition, all should contain within protection scope of the present invention.

Claims (7)

1. an antibacterial impermeabilisation insulating layer of external wall of building coating, it is characterised in that include first component, component B, first component with The weight ratio of component B is 10:2~5;The raw material of first component includes by weight: bisphenol A type epoxy resin 40~80 parts, modified Montmorillonite 5~15 parts, nano titanium oxide 2~10 parts, sepiolite powder 5~12 parts, silk fiber 6~12 parts, Graphene 2~8 Part, disproportionated rosin 1~4 parts, dispersant 0.5~1.5 parts, defoamer 0.5~1.5 parts, thickening agent 0.5~1.5 parts, aqueous color paste 1~2 part;The raw material of component B includes by weight: phenolic aldehyde amine 5~15 parts, deionized water 10~30 parts.
The most antibacterial impermeabilisation insulating layer of external wall of building coating, it is characterised in that modified montmorillonoid uses Prepared by following technique: by chitosan, acetic acid, water mix homogeneously, adds nano kaoline mix homogeneously, sends into syringe under room temperature Middle extrusion, the container equipped with ethanol solution is receiving device, filters, and vacuum drying obtains modified Nano Kaolin;By montmorillonite, Water mix and blend, adds soybean lecithin, silver sulfadiazine stirring, sends in microwave reactor and react, add modified Nano high Ridge soil mix and blend, filters, washing, and vacuum drying is pulverized and obtained modified montmorillonoid.
Antibacterial impermeabilisation insulating layer of external wall of building coating the most according to claim 1 or claim 2, it is characterised in that modified montmorillonoid Following technique is used to prepare: by weight by 2~6 parts of chitosans, 0.2~0.8 part of acetic acid, 10~20 parts of water mix homogeneously, to add Enter 1~3 part of nano kaoline mix homogeneously, send in syringe under room temperature and extrude, be that 75~85wt% ethanol are molten equipped with concentration The container of liquid is receiving device, filters, and vacuum drying obtains modified Nano Kaolin;By weight by 1~5 part of montmorillonite, 20 ~50 parts of water mix and blends, add 0.1~0.18 part of soybean lecithin, 0.15~0.3 part of silver sulfadiazine stirring, send into microwave Reactor reacts, adds 1~3 part of modified Nano Kaolin mix and blend, filter, washing, vacuum drying, pulverize and obtain modification Montmorillonite.
4. according to impermeabilisation insulating layer of external wall of building coating antibacterial described in any one of claim 1-3, it is characterised in that modified illiteracy De-soil uses following technique to prepare: by weight by 2~6 parts of chitosans, 0.2~0.8 part of acetic acid, 10~20 parts of water mixing all Even, add 1~3 part of nano kaoline mix homogeneously, send in syringe under room temperature, control syringe extruded velocity be 1~ 2mL/h, injection pressure is 0.5~1.5kPa, is receiving device equipped with the container that concentration is 75~85wt% ethanol solution, mistake Filter, 65~75 DEG C of vacuum drying obtain modified Nano Kaolin;By weight 1~5 part of montmorillonite, 20~50 parts of water mixing are stirred Mixing 5~12min, mixing speed is 1500~1800r/min, adds 0.1~0.18 part of soybean lecithin, 0.15~0.3 part of sulphur Amic metadiazine silver stirring 20~50min, whipping temp is 60~80 DEG C, and mixing speed is 800~1400r/min, sends into microwave anti- Answer in device react 2~8min, microwave power is 400~600W, add 1~3 part of modified Nano Kaolin mix and blend 5~ 15min, filters, washing, and vacuum drying is pulverized and obtained modified montmorillonoid.
5. according to impermeabilisation insulating layer of external wall of building coating antibacterial described in any one of claim 1-4, it is characterised in that first component It is 10:3~4 with the weight ratio of component B.
6. according to impermeabilisation insulating layer of external wall of building coating antibacterial described in any one of claim 1-5, it is characterised in that modified illiteracy De-soil, nano titanium oxide, sepiolite powder, silk fiber, the weight ratio of Graphene are 8~12:4~8:6~10:8~10:4 ~6.
7. according to impermeabilisation insulating layer of external wall of building coating antibacterial described in any one of claim 1-6, it is characterised in that include first Component, component B, first component is 10:3~4 with the weight ratio of component B;The raw material of first component includes by weight: bisphenol A-type Epoxy resin 50~70 parts, modified montmorillonoid 8~12 parts, nano titanium oxide 4~8 parts, sepiolite powder 6~10 parts, silk fibroin Tie up 8~10 parts, Graphene 4~6 parts, disproportionated rosin 2~3 parts, dispersant 0.8~1.2 parts, defoamer 0.8~1.2 parts, thickening Agent 0.8~1.2 parts, aqueous color paste 1.2~1.8 parts;The raw material of component B includes by weight: phenolic aldehyde amine 8~12 parts, deionization Water 15~25 parts.
CN201610739942.0A 2016-08-26 2016-08-26 A kind of antibacterial impermeabilisation insulating layer of external wall of building coating Pending CN106221504A (en)

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113604131A (en) * 2021-07-24 2021-11-05 苏州拓翰聚科技有限公司 Breathable anti-corrosion coating and preparation method thereof

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Application publication date: 20161214