CN106221461A - A kind of fluorescence water-repellent paint - Google Patents
A kind of fluorescence water-repellent paint Download PDFInfo
- Publication number
- CN106221461A CN106221461A CN201610824716.2A CN201610824716A CN106221461A CN 106221461 A CN106221461 A CN 106221461A CN 201610824716 A CN201610824716 A CN 201610824716A CN 106221461 A CN106221461 A CN 106221461A
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- repellent paint
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/02—Homopolymers or copolymers of acids; Metal or ammonium salts thereof
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D179/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing nitrogen, with or without oxygen, or carbon only, not provided for in groups C09D161/00 - C09D177/00
- C09D179/04—Polycondensates having nitrogen-containing heterocyclic rings in the main chain; Polyhydrazides; Polyamide acids or similar polyimide precursors
- C09D179/08—Polyimides; Polyester-imides; Polyamide-imides; Polyamide acids or similar polyimide precursors
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/22—Luminous paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses a kind of fluorescence water-repellent paint, belong to building material field.This coating is made up of the raw material of following parts by weight: be made up of the raw material of following parts by weight: poly-aspartic-acid 3.2 4.5 parts, stearoxyl trimethyl silane 1.1 2.7 parts, Sr2Si5N8: Eu2+0.8 1.9 parts of fluorescent material, acrylic methacrylate copolymers 3.7 6.8 parts, oxide powder and zinc 2.4 3.2 parts, phenethyl phenol poly-oxypropylene polyoxyethylene ether 2.1 4.8 parts, potassium pyrophosphate 0.8 3.1 parts and Polyoxyethylene fatty amide 0.9 1.8 parts.The present invention is compared with existing water-repellent paint, free from environmental pollution, solidification effect good, has fluorescence.Its coating is waterproof, pliability good, have certain antibacterial action.This coating is with low cost simultaneously, has the advantage being prone to construct, low temperature resistant and storage stability is good.
Description
Technical field
The present invention relates to building material field, particularly to a kind of fluorescence water-repellent paint.
Background technology
Coating act as decoration and protection, protects the surface being coated with jewelry, prevent from extraneous light, oxygen, chemical substance,
The erosion of solvent etc., improves the service life being applied thing, paint finishing material surface, changes its color, decorative pattern, gloss, matter
Senses etc., improve the aesthetic value of object.Building coating mode classification is various, and row are as by using environment to divide inner-outer wall, ground and top
Canopy coating；Organic and inorganic and organic-inorganic hybrid coatings is divided by main film forming substance；Water is divided by the state of main film forming substance
Dissolubility, type of latex type and solvent borne powder-type；Planomural shape, sand wall-like and three-dimensional pattern shape is divided according to decoration functions；By specific function
Divide fire prevention, waterproof, mildew-resistant and anti-condensation etc..
In existing decoration of exterior wall protection technique, people, in order to protect decoration of exterior wall, coat anti-on exterior wall
Water paint.But, the most common existing exterior wall fluorescence water-repellent paint, its product quality is uneven, the short time after coating
On still there is the most waterproof and illumination effect.But, increase over time, conventional coating arise that whiting, jaundice,
, generally there is the aging resistance phase short in emetine phenomenon, dirty dirt, ink can not clean, moisture-proof, the shortcoming such as water-fast, washing fastness is poor, luminous
Performance is short for service life at outdoor buildings end face.Fluorescent material in water-repellent paint there will be hydrolysis now in water-based system simultaneously
As, cause coating pH value to raise, lump, finally make coating complete failure.Owing to the powder body of fine grain easily disperses in coating
And it is difficult to precipitation, in order to improve the film property of luminous paint, luminosity and service life, coating all selection of small grains in recent years
The fluorescent material in footpath, but fluorescent material easily occurs the problem that chemical stability reduces after super-refinement, is particularly applied and prevents in aqueous
Time in pseudo-ink, coating, can shorten its service life.These all limit the application of fluorescent material.
Summary of the invention
It is an object of the invention to overcome the above-mentioned deficiency in the presence of prior art, it is provided that a kind of fluorescence water-repellent paint,
Having and be prone to construction, fluorescent effect is good, the advantage that waterproof and storage stability is good.
In order to realize foregoing invention purpose, the invention provides techniques below scheme:
A kind of fluorescence water-repellent paint, is made up of the raw material of following parts by weight: be made up of the raw material of following parts by weight: poly-
Aspartic acid 3.2-4.5 part, stearoxyl trimethyl silane 1.1-2.7 part, Sr2Si5N8: Eu2+Fluorescent material 0.8-1.9 part, third
Olefin(e) acid-ethyl acrylate copolymer 3.7-6.8 part, oxide powder and zinc 2.4-3.2 part, phenethyl phenol poly-oxypropylene polyoxyethylene ether
2.1-4.8 part, potassium pyrophosphate 0.8-3.1 part and Polyoxyethylene fatty amide 0.9-1.8 part.
Preferably, above-mentioned fluorescence water-repellent paint, it is made up of the raw material of following parts by weight: poly-aspartic-acid 3.5-4.2
Part, stearoxyl trimethyl silane 1.2-2.5 part, Sr2Si5N8: Eu2+Fluorescent material 0.9-1.7 part, acrylic acid-acrylic acetoacetic ester are altogether
Polymers 3.9-6.5 part, oxide powder and zinc 2.5-3.1 part, phenethyl phenol poly-oxypropylene polyoxyethylene ether 2.3-4.4 part, potassium pyrophosphate
0.9-2.9 part and Polyoxyethylene fatty amide 1.1-1.7 part.
It is furthermore preferred that above-mentioned fluorescence water-repellent paint, it is made up of the raw material of following parts by weight: poly-aspartic-acid 3.6-
3.9 parts, stearoxyl trimethyl silane 1.6-2.2 part, Sr2Si5N8: Eu2+Fluorescent material 1.2-1.5 part, acrylic acid-acrylic acid second
Ester copolymer 4.1-6.2 part, oxide powder and zinc 2.7-3 part, phenethyl phenol poly-oxypropylene polyoxyethylene ether 2.6-3.9 part, pyrophosphoric acid
Potassium 1.2-2.6 part and Polyoxyethylene fatty amide 1.3-1.5 part.
Most preferably, above-mentioned fluorescence water-repellent paint, it is made up of the raw material of following parts by weight: poly-aspartic-acid 3.8 parts,
Stearoxyl trimethyl silane 1.9 parts, Sr2Si5N8: Eu2+1.3 parts of fluorescent material, acrylic acid-acrylic acetoacetic ester copolymer 5.4 parts,
Oxide powder and zinc 2.9 parts, phenethyl phenol poly-oxypropylene polyoxyethylene ether 3.1 parts, potassium pyrophosphate 2.2 parts and Polyoxyethylene fatty amide
1.4 part.
Compared with prior art, beneficial effects of the present invention:
The present invention is compared with existing fluorescent paint, free from environmental pollution, solidification effect good, has fluorescence.Its coating
Waterproof, pliability good, has certain antibacterial action.This coating is with low cost simultaneously, has and is prone to construction, low temperature resistant and store steady
Qualitative good advantage.
Detailed description of the invention
Below in conjunction with test example and detailed description of the invention, the present invention is described in further detail.But this should not understood
Scope for the above-mentioned theme of the present invention is only limitted to below example, and all technology realized based on present invention belong to this
The scope of invention
Embodiment 1
The present invention is a kind of fluorescence water-repellent paint, is made up of the raw material of following parts by weight: poly-aspartic-acid 3.8 parts,
Stearoxyl trimethyl silane 1.9 parts, Sr2Si5N8: Eu2+1.3 parts of fluorescent material, acrylic acid-acrylic acetoacetic ester copolymer 5.4 parts,
Oxide powder and zinc 2.9 parts, phenethyl phenol poly-oxypropylene polyoxyethylene ether 3.1 parts, potassium pyrophosphate 2.2 parts and Polyoxyethylene fatty amide
1.4 part.
Embodiment 2
The present invention is a kind of fluorescence water-repellent paint, is made up of the raw material of following parts by weight: poly-aspartic-acid 3.2 parts,
Stearoxyl trimethyl silane 1.1 parts, Sr2Si5N8: Eu2+0.8 part of fluorescent material, acrylic acid-acrylic acetoacetic ester copolymer 6.8 parts,
Oxide powder and zinc 2.4 parts, phenethyl phenol poly-oxypropylene polyoxyethylene ether 4.8 parts, potassium pyrophosphate 3.1 parts and Polyoxyethylene fatty amide
1.8 part.
Embodiment 3
The present invention is a kind of fluorescence water-repellent paint, is made up of the raw material of following parts by weight: poly-aspartic-acid 4.5 parts,
Stearoxyl trimethyl silane 2.7 parts, Sr2Si5N8: Eu2+1.9 parts of fluorescent material, acrylic acid-acrylic acetoacetic ester copolymer 3.7 parts,
Oxide powder and zinc 3.2 parts, phenethyl phenol poly-oxypropylene polyoxyethylene ether 2.1 parts, potassium pyrophosphate 0.8 part and Polyoxyethylene fatty amide
0.9 part.
Embodiment 4
The present invention is a kind of fluorescence water-repellent paint, is made up of the raw material of following parts by weight: poly-aspartic-acid 4.2 parts,
Stearoxyl trimethyl silane 1.6 parts, Sr2Si5N8: Eu2+1.5 parts of fluorescent material, acrylic acid-acrylic acetoacetic ester copolymer 6 parts, oxygen
Change zinc powder 2.5 parts, phenethyl phenol poly-oxypropylene polyoxyethylene ether 3.6 parts, potassium pyrophosphate 2.4 parts and Polyoxyethylene fatty amide
1.6 part.
Embodiment 5
The present invention is a kind of fluorescence water-repellent paint, is made up of the raw material of following parts by weight: poly-aspartic-acid 3.8 parts,
Stearoxyl trimethyl silane 2.2 parts, Sr2Si5N8: Eu2+1.3 parts of fluorescent material, acrylic acid-acrylic acetoacetic ester copolymer 6.8 parts,
Oxide powder and zinc 2.9 parts, phenethyl phenol poly-oxypropylene polyoxyethylene ether 3.1 parts, potassium pyrophosphate 2.4 parts and Polyoxyethylene fatty amide
1.4 part.
Water-repellent paint obtained by above example, it is as follows for construction method and the requirement of external wall:
Substrate surface is clean, is dried, and cleaning, free from dust, without greasy dirt, as untreated in basic unit good, the easy peeling of film can affect
Waterproof effect.The crack of metope, hole position should mix putty with marine glue interpolation cement in advance and repair smooth.External wall construction is not
Must be less than two times, every square of 0.8-1.2kg of film consumption, with painting brush, Cylinder coating brush.
Certainly, described above is not limitation of the present invention, and the present invention is also not limited to the example above, the art
Those of ordinary skill, in the essential scope of the present invention, the change made, retrofit, add or replace, all should belong to the present invention
Protection domain.
Claims (4)
1. a fluorescence water-repellent paint, it is characterised in that: it is made up of the raw material of following parts by weight: poly-aspartic-acid 3.2-
4.5 parts, stearoxyl trimethyl silane 1.1-2.7 part, Sr2Si5N8: Eu2+Fluorescent material 0.8-1.9 part, acrylic acid-acrylic acid second
Ester copolymer 3.7-6.8 part, oxide powder and zinc 2.4-3.2 part, phenethyl phenol poly-oxypropylene polyoxyethylene ether 2.1-4.8 part, burnt phosphorus
Acid potassium 0.8-3.1 part and Polyoxyethylene fatty amide 0.9-1.8 part.
Fluorescence water-repellent paint the most according to claim 1, it is characterised in that: it is made up of the raw material of following parts by weight: poly-
Aspartic acid 3.5-4.2 part, stearoxyl trimethyl silane 1.2-2.5 part, Sr2Si5N8: Eu2+Fluorescent material 0.9-1.7 part, third
Olefin(e) acid-ethyl acrylate copolymer 3.9-6.5 part, oxide powder and zinc 2.5-3.1 part, phenethyl phenol poly-oxypropylene polyoxyethylene ether
2.3-4.4 part, potassium pyrophosphate 0.9-2.9 part and Polyoxyethylene fatty amide 1.1-1.7 part.
Fluorescence water-repellent paint the most according to claim 2, it is characterised in that: it is made up of the raw material of following parts by weight: poly-
Aspartic acid 3.6-3.9 part, stearoxyl trimethyl silane 1.6-2.2 part, Sr2Si5N8: Eu2+Fluorescent material 1.2-1.5 part, third
Olefin(e) acid-ethyl acrylate copolymer 4.1-6.2 part, oxide powder and zinc 2.7-3 part, phenethyl phenol poly-oxypropylene polyoxyethylene ether 2.6-
3.9 parts, potassium pyrophosphate 1.2-2.6 part and Polyoxyethylene fatty amide 1.3-1.5 part.
Fluorescence water-repellent paint the most according to claim 3, it is characterised in that: poly-aspartic-acid 3.8 parts, stearic epoxide three
Methyl-monosilane 1.9 parts, Sr2Si5N8: Eu2+1.3 parts of fluorescent material, acrylic acid-acrylic acetoacetic ester copolymer 5.4 parts, oxide powder and zinc 2.9
Part, phenethyl phenol poly-oxypropylene polyoxyethylene ether 3.1 parts, potassium pyrophosphate 2.2 parts and Polyoxyethylene fatty amide 1.4 parts.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610824716.2A CN106221461A (en) | 2016-09-14 | 2016-09-14 | A kind of fluorescence water-repellent paint |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610824716.2A CN106221461A (en) | 2016-09-14 | 2016-09-14 | A kind of fluorescence water-repellent paint |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106221461A true CN106221461A (en) | 2016-12-14 |
Family
ID=58075534
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610824716.2A Pending CN106221461A (en) | 2016-09-14 | 2016-09-14 | A kind of fluorescence water-repellent paint |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106221461A (en) |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101803577A (en) * | 2009-07-17 | 2010-08-18 | 广东海洋大学 | Preparation method of colored noctilucent bead core |
| CN104194600A (en) * | 2014-08-27 | 2014-12-10 | 句容市石狮冲压件厂 | Antibacterial fluorescent coating for outdoor deck chair and preparation method of antibacterial fluorescent coating |
| CN104341898A (en) * | 2013-08-06 | 2015-02-11 | 青岛益群漆业集团有限公司 | Water-proof flame-retardant luminescent sign board coating |
| CN104559651A (en) * | 2013-10-25 | 2015-04-29 | 青岛德固建筑材料有限公司 | Fluorescent paint |
-
2016
- 2016-09-14 CN CN201610824716.2A patent/CN106221461A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101803577A (en) * | 2009-07-17 | 2010-08-18 | 广东海洋大学 | Preparation method of colored noctilucent bead core |
| CN104341898A (en) * | 2013-08-06 | 2015-02-11 | 青岛益群漆业集团有限公司 | Water-proof flame-retardant luminescent sign board coating |
| CN104559651A (en) * | 2013-10-25 | 2015-04-29 | 青岛德固建筑材料有限公司 | Fluorescent paint |
| CN104194600A (en) * | 2014-08-27 | 2014-12-10 | 句容市石狮冲压件厂 | Antibacterial fluorescent coating for outdoor deck chair and preparation method of antibacterial fluorescent coating |
Non-Patent Citations (1)
| Title |
|---|
| 张丹慧等: "《贵金属-石墨烯纳米复合材料的合成及性能》", 31 December 2015, 国防工业出版社 * |
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Application publication date: 20161214 |
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