CN106221366A - A kind of plastic basis material is by low temperature resistant ink preparation method - Google Patents
A kind of plastic basis material is by low temperature resistant ink preparation method Download PDFInfo
- Publication number
- CN106221366A CN106221366A CN201610775334.5A CN201610775334A CN106221366A CN 106221366 A CN106221366 A CN 106221366A CN 201610775334 A CN201610775334 A CN 201610775334A CN 106221366 A CN106221366 A CN 106221366A
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- CN
- China
- Prior art keywords
- low temperature
- parts
- temperature resistant
- pigment
- resistant ink
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/102—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/106—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The invention discloses a kind of use low temperature resistant ink preparation method on plastic basis material.The preparation process of this ink includes first 12 25 parts of modified epoxies, 10 35 parts of pigment and 10 20 parts of organic solvents being mixed to prepare mill base, again by after 20 35 parts of fluorocarbon resins, 25 parts of isocyanate curing agents and 25 parts of SiO 2 powder mixed grindings, join in 10 20 parts of organic solvents, to add 0.5 3 parts of defoamer afterwards after mixed for mill base stirring, fully dispersed after obtain low temperature resistant ink.This low temperature resistant ink adhesive strength is high, it is possible to meet the decoration performance of outdoor plastics goods, especially strong to the low temperature environment toleration of less than 20 DEG C, high for China's the Northeast's suitability, is worthy to be popularized.
Description
Technical field
The present invention relates to a kind of ink, especially a kind of use on plastic basis material show under ultra-low temperature surroundings out of doors excellent
Different low temperature resistant ink preparation method.
Background technology
Ink (ink) is the important materials for printing, and it is by printing by pattern, literal table the most on the substrate.Oil
Ink includes main component and auxiliary element, and they mix equably and form a kind of stickiness colloidal fluid through repeat-rolling.By
Resin, pigment, filler, auxiliary agent and solvent etc. form.Each for books and periodicals, packing and decorating, building decoration and electronic circuit sheet material etc.
Plant printing.Along with social need increases, ink kind and yield also respective extension and growth.The main component of plastics is resin,
Resin accounts for the 40%～100% of plastics gross weight.The key property of plastics depends mainly on the person's character of resin, but additive also rises
Important function.Some plastics is substantially made up of synthetic resin, does not contains or less containing additive, such as lucite, polyphenyl
Ethylene etc..Along with the development in epoch, plastics get more and more in the use of furnishing fields, the most therefore to using ink to be designed
All decorative patterns to be preferably carried on plastics.We are vast in territory, especially the Northeast's either capital construction
Still publicizing popularization, the consumption to plastics and ink is all great, but existing ink type is not well positioned to meet east
Use scene under backlands district winter extremely low temperature, thus cause often occurring ink xanthochromia, fade, the problem such as explosion, it is impossible to
Meet this area's requirement to ink performance.
Summary of the invention
Prepared by a kind of use that the present invention seeks to solve above-mentioned deficiency and proposes low temperature resistant ink on plastic basis material
Method.
In order to achieve the above object, a kind of plastic basis material involved in the present invention low temperature resistant ink preparation method, its system
Standby process comprises the steps of
(1) 12-25 part modified epoxy, 20-35 part fluorocarbon resin, 10-35 part pigment, 20-45 part organic solvent, 2-5 are taken
Part isocyanate curing agent, 2-5 part SiO 2 powder, 0.5-3 part defoamer are standby；
(2) by joining after modified epoxy, pigment grind in 10-20 part organic solvent, mill base is made；
(3) fluorocarbon resin, isocyanate curing agent and SiO 2 powder are mixed, join 10-20 part after grinding organic molten
In agent, fully mix；
(4) mill base of step (2) is added in the mixture of step (3), add defoamer after stirring, be sufficiently stirred for mixing
Close, filter, obtain low temperature resistant ink.
Wherein, described modified epoxy is phenol aldehyde modified bisphenol A type epoxy resin, and described fluorocarbon resin refers to
Polyvinylidene fluoride resin, described pigment refers to that described pigment is the inorganic ceramic pigment or organic colored face that weatherability is strong
Material, described organic solvent refers to the one in butyl acetate, 2-ethyl hexyl ethanoate, acetone, butanone, Ketohexamethylene, propylene-glycol ethyl ether
Or multiple, described defoamer is polyester modification polydimethylsiloxane defoamer or polyacrylate defoamer.
By the ink product prepared by the present invention, in addition to the performance of common ink, its adhesive strength is high, it is possible to meet
The various different decoration performance requirements of outdoor plastics goods, the low temperature environment toleration of the most p-less than 20 DEG C is strong, for me
State's the Northeast's suitability is high, is worthy to be popularized.
Detailed description of the invention
Embodiment 1
(1) take phenol aldehyde modified for 20kg bisphenol A type epoxy resin, 30kg polyvinylidene fluoride resin, 18kg organic color pigment,
10kg butyl acetate, 32kg butanone, 5kg Ketohexamethylene, 3.1kg isocyanate curing agent, 2.6kg SiO 2 powder, 1.5kg are poly-
Ester modified polydimethylsiloxane defoamer, standby；
(2) after phenol aldehyde modified bisphenol A type epoxy resin, inorganic ceramic pigment grind, 20kg mixed organic solvents is joined
In, make mill base；
(3) polyvinylidene fluoride resin, isocyanate curing agent and SiO 2 powder are mixed, after grinding, join 27kg mixing
In organic solvent, fully mix；
(4) mill base of step (2) is added in the mixture of step (3), after stirring, add 1.5kg polyester modification poly-two
Methylsiloxane defoamer, is thoroughly mixed, and filters, obtains low temperature resistant ink.
Embodiment 2
(1) take phenol aldehyde modified for 30kg bisphenol A type epoxy resin, 38kg polyvinylidene fluoride resin, 25kg inorganic ceramic pigment,
10kg 2-ethyl hexyl ethanoate, 45kg Ketohexamethylene, 20kg propylene glycol monomethyl ether, 4.5kg isocyanate curing agent, 3.5kg silicon dioxide powder
End, 2.2kg polyacrylate defoamer, standby；
(2) after phenol aldehyde modified bisphenol A type epoxy resin, inorganic ceramic pigment grind, 35kg mixed organic solvents is joined
In, make mill base；
(3) polyvinylidene fluoride resin, isocyanate curing agent and SiO 2 powder are mixed, after grinding, join 40kg mixing
In organic solvent, fully mix；
(4) mill base of step (2) is added in the mixture of step (3), add 2.2kg polyacrylate after stirring and disappear
Infusion, is thoroughly mixed, and filters, obtains low temperature resistant ink.
Claims (2)
1. a plastic basis material is by low temperature resistant ink preparation method, it is characterised in that its preparation process comprises the steps of
(1) 12-25 part modified epoxy, 20-35 part fluorocarbon resin, 10-35 part pigment, 20-45 part organic solvent, 2-5 are taken
Part isocyanate curing agent, 2-5 part SiO 2 powder, 0.5-3 part defoamer are standby；
(2) by joining after modified epoxy, pigment grind in 10-20 part organic solvent, mill base is made；
(3) fluorocarbon resin, isocyanate curing agent and SiO 2 powder are mixed, join 10-20 part after grinding organic molten
In agent, fully mix；
(4) mill base of step (2) is added in the mixture of step (3), add defoamer after stirring, be sufficiently stirred for mixing
Close, filter, obtain low temperature resistant ink.
A kind of plastic basis material the most according to claim 1 is by low temperature resistant ink preparation method, it is characterised in that step (1)
Described modified epoxy is phenol aldehyde modified bisphenol A type epoxy resin, and fluorocarbon resin refers to polyvinylidene fluoride resin, pigment
Referring to that described pigment is the inorganic ceramic pigment or organic color pigment that weatherability is strong, organic solvent refers to butyl acetate, second
One or more in acid different monooctyl ester, acetone, butanone, Ketohexamethylene, propylene-glycol ethyl ether, defoamer is polyester modification poly dimethyl silicon
Oxygen alkane defoamer or polyacrylate defoamer.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610775334.5A CN106221366A (en) | 2016-08-31 | 2016-08-31 | A kind of plastic basis material is by low temperature resistant ink preparation method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610775334.5A CN106221366A (en) | 2016-08-31 | 2016-08-31 | A kind of plastic basis material is by low temperature resistant ink preparation method |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106221366A true CN106221366A (en) | 2016-12-14 |
Family
ID=58072741
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610775334.5A Pending CN106221366A (en) | 2016-08-31 | 2016-08-31 | A kind of plastic basis material is by low temperature resistant ink preparation method |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106221366A (en) |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101885947A (en) * | 2010-07-15 | 2010-11-17 | 东莞市贝特利新材料有限公司 | Low-temperature cured high abrasion resistant protective printing ink |
| CN102492353A (en) * | 2011-11-28 | 2012-06-13 | 江苏兰陵高分子材料有限公司 | Novel fast-set anticorrosion and wear-resistant epoxy powder coating and preparation process thereof |
| CN103113786A (en) * | 2013-03-07 | 2013-05-22 | 苏州牛剑新材料有限公司 | Graphene conductive ink and preparation method thereof |
-
2016
- 2016-08-31 CN CN201610775334.5A patent/CN106221366A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101885947A (en) * | 2010-07-15 | 2010-11-17 | 东莞市贝特利新材料有限公司 | Low-temperature cured high abrasion resistant protective printing ink |
| CN102492353A (en) * | 2011-11-28 | 2012-06-13 | 江苏兰陵高分子材料有限公司 | Novel fast-set anticorrosion and wear-resistant epoxy powder coating and preparation process thereof |
| CN103113786A (en) * | 2013-03-07 | 2013-05-22 | 苏州牛剑新材料有限公司 | Graphene conductive ink and preparation method thereof |
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| C06 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WD01 | Invention patent application deemed withdrawn after publication | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20161214 |