CN106221308A - The modified dual cladding based aluminum pigment of a kind of wear-resisting toughening type inhibition - Google Patents
The modified dual cladding based aluminum pigment of a kind of wear-resisting toughening type inhibition Download PDFInfo
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- CN106221308A CN106221308A CN201610595083.2A CN201610595083A CN106221308A CN 106221308 A CN106221308 A CN 106221308A CN 201610595083 A CN201610595083 A CN 201610595083A CN 106221308 A CN106221308 A CN 106221308A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
- C09C1/62—Metallic pigments or fillers
- C09C1/64—Aluminium
- C09C1/648—Aluminium treated with inorganic and organic, e.g. polymeric, compounds
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C3/00—Treatment in general of inorganic materials, other than fibrous fillers, to enhance their pigmenting or filling properties
- C09C3/006—Combinations of treatments provided for in groups C09C3/04 - C09C3/12
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C3/00—Treatment in general of inorganic materials, other than fibrous fillers, to enhance their pigmenting or filling properties
- C09C3/06—Treatment with inorganic compounds
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C3/00—Treatment in general of inorganic materials, other than fibrous fillers, to enhance their pigmenting or filling properties
- C09C3/06—Treatment with inorganic compounds
- C09C3/063—Coating
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C3/00—Treatment in general of inorganic materials, other than fibrous fillers, to enhance their pigmenting or filling properties
- C09C3/08—Treatment with low-molecular-weight non-polymer organic compounds
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C3/00—Treatment in general of inorganic materials, other than fibrous fillers, to enhance their pigmenting or filling properties
- C09C3/10—Treatment with macromolecular organic compounds
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
- C09D7/62—Additives non-macromolecular inorganic modified by treatment with other compounds
Abstract
nullThe invention discloses the modified dual cladding based aluminum pigment of a kind of wear-resisting toughening type inhibition，It is characterized in that，It is made up of the raw material of following weight portion: flake aluminum 40 45、Isopropanol 100 110、Copper sulfate crystal 0.3 0.35、Deionized water is appropriate、2, 2-Oxydiphenol type phosphate ester 4 4.5、Dehydrated alcohol is appropriate、Tetraethyl orthosilicate 9 10、VTES 67、Concentration is the ammonia 9 10 of 20wt%、Butyl acetate 200 220、Acrylic acid 56、Methacrylic acid 56、Dibenzoyl peroxide 0.6 0.65、Propylene glycol monomethyl ether 13 15、Nano-calcium carbonate Ca45、Borax 0.8 1、Re-dispersible glue powder 23、Stearic acid 0.3 0.4、Titanate coupling agent TCF0.7 0.9、Silicone oil 23.
Description
Technical field
The present invention relates to pigment technology field, particularly relate to the modified dual cladding aqueous aluminum face of a kind of wear-resisting toughening type inhibition
Material.
Background technology
Aluminum pigment is one of important metallic pigments, because of aesthetic and the anti-corrosive properties of its uniqueness, is coated with in anticorrosion in recent years
Material, industrial coating, car paint, architecture indoor exterior decoration coating, paint for domestic electric appliance, printing-ink and Plastics Processing Industry obtain
Obtain and extensively apply.Along with constantly strengthening and government's environmental regulation the most perfect of people's environmental consciousness, conventional organic solvents
Type coating will necessarily be replaced by environment-friendlywater-based water-based paint, the aluminum pigment of the aluminum pigment used by water paint and solvent based coating
Having different requirements: first, surface of pigments must be hydrophilic, can be effectively dispersed in water, secondly must keep in aqueous medium
Higher chemical stability.But, the chemical property of aluminum is relatively more active, easily reacts with oxygen or water, and this not only corrodes
Aluminum surface of pigments, have impact on metallic luster and the stability of aluminum, the most also can cause blast, bring unsafe factor to production.
Therefore the Water-borne modification research of aluminum pigment becomes focus, and achieved with certain progress.
In " copper ion alumina powder strengthens the phosphate ester corrosion inhibition to aluminum pigment " literary composition, use copper ion alumina powder
Realizing aluminium powder surface hydroxylation, then using 2, 2-Oxydiphenol type phosphate ester as corrosion inhibiter, preparation method is simple, is harmful to without to organism
Chromate, molybdate, the composition such as nitrite, have certain affinity with aluminum surface of pigments, rate of metal corrosion can be made bright
Aobvious reduction.Although the method adding inhibitor in aluminum pigments system can suppress the corrosion rate of aluminum, but corrosion mitigating effect has
Limit, extends and contacts with water-based system coating, ink etc., and aluminum pigment still can cause certain corrosion, reduces metallic luster
There is also potential safety hazard simultaneously.This is accomplished by the basis of original inhibitor modification being modified, and improves aluminum pigment further
Corrosion resistance, thus improve application in the product such as water paint, ink.
Summary of the invention
The object of the invention is contemplated to make up the defect of prior art, it is provided that a kind of wear-resisting toughening type inhibition modification dual packet
Cover based aluminum pigment.
The present invention is achieved by the following technical solutions:
The modified dual cladding based aluminum pigment of a kind of wear-resisting toughening type inhibition, is made up of the raw material of following weight portion: lamellar
Aluminium powder 40-45, isopropanol 100-110, copper sulfate crystal 0.3-0.35, deionized water are appropriate, 2, 2-Oxydiphenol type phosphate ester 4-4.5, nothing
Water-ethanol is appropriate, tetraethyl orthosilicate 9-10, VTES 6-7, concentration are the ammonia 9-10 of 20wt%, acetic acid fourth
Ester 200-220, acrylic acid 5-6, methacrylic acid 5-6, dibenzoyl peroxide 0.6-0.65, propylene glycol monomethyl ether 13-15, receive
Rice calcium carbonate 4-5, Borax 0.8-1, re-dispersible glue powder 2-3, stearic acid 0.3-0.4, titanate coupling agent TCF0.7-0.9, silicon
Oil 2-3.
The modified dual cladding based aluminum pigment of described one wear-resisting toughening type inhibition, is made up of step in detail below:
(1) flake aluminum is put in reactor, add isopropanol, 2, 2-Oxydiphenol type phosphate ester, be heated to 40-50 DEG C, stirring reaction
60-80 minute, copper sulfate crystal is dissolved in the deionized water of 40-50 times amount formation solution and is slowly added to above-mentioned reaction system
In, controlling to add for 15-20 minute, constant temperature stirs 90-120 minute, sucking filtration, is vacuum dried at 55-60 DEG C, obtains inhibition modified
Aluminium powder；
(2) tetraethyl orthosilicate is mixed with VTES, add the dehydrated alcohol of total amount 2-2.5 times amount, formed
Mixed liquor A is stand-by；In the ammonia that concentration is 20wt%, add the deionized water of 1.5-2 times amount, the dehydrated alcohol of 3-4 times amount, stir
Mix that to be formed uniformly mixed liquid B stand-by；Is added the dehydrated alcohol of 10-12 times amount, so in the inhibition modified aluminium powder that step (1) is obtained
After be warming up to 50-60 DEG C, mixed liquor A and B drip are added in reaction system, after dropping, are incubated 4-5 hour, stop
Heating, filters, and uses absolute ethanol washing product, is finally vacuum dried at 50-60 DEG C, obtains monolayer cladding aluminium powder；
(3) acrylic acid, methacrylic acid, dibenzoyl peroxide are added the formation that stirs in the butyl acetate of half amount mixed
Conjunction liquid is stand-by；The butyl acetate adding surplus in once cladding aluminium powder step (2) obtained is total, ultrasonic disperse 120-150
Minute, be subsequently adding above-mentioned mixed liquor, with 350-400 turn/speed of part is stirred and heated to 85 DEG C, insulation reaction 5-6 hour,
It is cooled to sucking filtration after room temperature, is vacuum dried at 55-60 DEG C, obtains dual cladding aluminium powder；
(4) by Borax adds the deionized water of 20-25 times amount, stir with the speed of 300-400 rev/min, be warming up to 80-90
DEG C, after insulated and stirred 20-30 minute, add re-dispersible glue powder, stearic acid, continue insulated and stirred 60-90 minute, suspended
Liquid, is spray-dried, obtains mixed powder；Mixed powder is mixed with remaining residual components in addition to propylene glycol monomethyl ether, puts
Enter in batch mixer, stir 10-13 minute with the speed of 800-1000 rev/min, discharging, obtain adding auxiliary agent；
(5) the interpolation auxiliary agent that dual cladding aluminium powder step (3) obtained obtains with step (4) mixes, and adds propylene glycol list first
Ether, puts in kneader and mediates 30-40 minute, be finally vacuum dried, obtain the present invention.
The invention have the advantage that the present invention first passes through copper ion aluminium oxide and realizes aluminium powder surface hydroxylation, can adsorb
2, 2-Oxydiphenol type phosphate ester, has certain corrosion inhibition；Then by a series of technique by silicon dioxide and polyacrylate
Be respectively coated by inhibition modified aluminium powder surface, form fine and close nucleocapsid structure, can effectively shield aluminium powder core, prevent aluminum pigment with
Water or air dielectric come in contact reaction, and dual cladding significantly improves the corrosion resistance of aluminum pigment；The aluminum pigment of preparation is applied to be coated with
Good dispersion property in material, appearance of film flat smooth, glossiness is good, good to the adhesive force of coating.
The composition such as nano-calcium carbonate, re-dispersible glue powder is added to the preparation of product by the present invention by series of process
In, the aluminum pigment anti-wear performance made is good, can be uniformly dispersed in water-based system product, the film good toughness made, viscosity
Good, adhesive force is good, practical, and production technology is easy to Industry Control, is worthy to be popularized.
Detailed description of the invention
The modified dual cladding based aluminum pigment of a kind of wear-resisting toughening type inhibition, is prepared by the raw material of following weight portion (kilogram)
Make: flake aluminum 40, isopropanol 100, copper sulfate crystal 0.3, deionized water are appropriate, 2, 2-Oxydiphenol type phosphate ester 4, dehydrated alcohol are suitable
Amount, tetraethyl orthosilicate 9, VTES 6, concentration are the ammonia 9 of 20wt%, butyl acetate 200, acrylic acid 5, first
Base acrylic acid 5, dibenzoyl peroxide 0.6, propylene glycol monomethyl ether 13, nano-calcium carbonate 4, Borax 0.8, re-dispersible glue powder 2,
Stearic acid 0.3, titanate coupling agent TCF0.7, silicone oil 2.
The modified dual cladding based aluminum pigment of described one wear-resisting toughening type inhibition, is made up of step in detail below:
(1) flake aluminum is put in reactor, add isopropanol, 2, 2-Oxydiphenol type phosphate ester, be heated to 40 DEG C, stirring reaction 60 points
Clock, is dissolved in copper sulfate crystal in the deionized water of 40 times amount formation solution and is slowly added in above-mentioned reaction system, control 15 points
Clock adds, and constant temperature stirs 90 minutes, sucking filtration, is vacuum dried, obtains inhibition modified aluminium powder at 55 DEG C；
(2) tetraethyl orthosilicate is mixed with VTES, add the dehydrated alcohol of total amount 2 times amount, form mixing
Liquid A is stand-by；Adding the deionized water of 1.5 times amount, the dehydrated alcohol of 3 times amount in the ammonia that concentration is 20wt%, stir shape
Become mixed liquid B stand-by；Is added in the inhibition modified aluminium powder that step (1) is obtained the dehydrated alcohol of 10 times amount, then heats to 50
DEG C, mixed liquor A and B drip are added in reaction system, after dropping, are incubated 4 hours, stop heating, filter, with anhydrous
Washing with alcohol product, is finally vacuum dried at 50 DEG C, obtains monolayer cladding aluminium powder；
(3) acrylic acid, methacrylic acid, dibenzoyl peroxide are added the formation that stirs in the butyl acetate of half amount mixed
Conjunction liquid is stand-by；The butyl acetate adding surplus in once cladding aluminium powder step (2) obtained is total, ultrasonic disperse 120 minutes,
It is subsequently adding above-mentioned mixed liquor, is stirred and heated to 85 DEG C with the speed of 350 turns/part, insulation reaction 5 hours, it is cooled to room temperature
Rear sucking filtration, is vacuum dried at 55 DEG C, obtains dual cladding aluminium powder；
(4) Borax will add the deionized water of 20 times amount, stir with the speed of 300 revs/min, be warming up to 80 DEG C, insulated and stirred
After 20 minutes, add re-dispersible glue powder, stearic acid, continue insulated and stirred 60 minutes, obtain suspension, be spray-dried, obtain
Mixed powder；Mixed powder is mixed with remaining residual components in addition to propylene glycol monomethyl ether, puts in batch mixer, with 800
Rev/min speed stir 10 minutes, discharging, obtain add auxiliary agent；
(5) the interpolation auxiliary agent that dual cladding aluminium powder step (3) obtained obtains with step (4) mixes, and adds propylene glycol list first
Ether, puts in kneader and mediates 30 minutes, be finally vacuum dried, obtain the present invention.
Through inspection, product of the present invention good dispersion in water-based system, inhibition efficiency is 98.0%, and coating gloss is
110.4Gs。
Claims (2)
1. the modified dual cladding based aluminum pigment of wear-resisting toughening type inhibition, it is characterised in that by the raw material of following weight portion
Preparation is made: flake aluminum 40-45, isopropanol 100-110, copper sulfate crystal 0.3-0.35, deionized water are appropriate, 2, 2-Oxydiphenol type phosphorus
Acid esters 4-4.5, dehydrated alcohol are appropriate, tetraethyl orthosilicate 9-10, VTES 6-7, concentration are the ammonia of 20wt%
9-10, butyl acetate 200-220, acrylic acid 5-6, methacrylic acid 5-6, dibenzoyl peroxide 0.6-0.65, propylene glycol list
Methyl ether 13-15, nano-calcium carbonate 4-5, Borax 0.8-1, re-dispersible glue powder 2-3, stearic acid 0.3-0.4, titanate coupling agent
TCF0.7-0.9, silicone oil 2-3.
The modified dual cladding based aluminum pigment of a kind of wear-resisting toughening type inhibition, it is characterised in that by
Step is made in detail below:
(1) flake aluminum is put in reactor, add isopropanol, 2, 2-Oxydiphenol type phosphate ester, be heated to 40-50 DEG C, stirring reaction
60-80 minute, copper sulfate crystal is dissolved in the deionized water of 40-50 times amount formation solution and is slowly added to above-mentioned reaction system
In, controlling to add for 15-20 minute, constant temperature stirs 90-120 minute, sucking filtration, is vacuum dried at 55-60 DEG C, obtains inhibition modified
Aluminium powder；
(2) tetraethyl orthosilicate is mixed with VTES, add the dehydrated alcohol of total amount 2-2.5 times amount, formed
Mixed liquor A is stand-by；In the ammonia that concentration is 20wt%, add the deionized water of 1.5-2 times amount, the dehydrated alcohol of 3-4 times amount, stir
Mix that to be formed uniformly mixed liquid B stand-by；Is added the dehydrated alcohol of 10-12 times amount, so in the inhibition modified aluminium powder that step (1) is obtained
After be warming up to 50-60 DEG C, mixed liquor A and B drip are added in reaction system, after dropping, are incubated 4-5 hour, stop
Heating, filters, and uses absolute ethanol washing product, is finally vacuum dried at 50-60 DEG C, obtains monolayer cladding aluminium powder；
(3) acrylic acid, methacrylic acid, dibenzoyl peroxide are added the formation that stirs in the butyl acetate of half amount mixed
Conjunction liquid is stand-by；The butyl acetate adding surplus in once cladding aluminium powder step (2) obtained is total, ultrasonic disperse 120-150
Minute, be subsequently adding above-mentioned mixed liquor, with 350-400 turn/speed of part is stirred and heated to 85 DEG C, insulation reaction 5-6 hour,
It is cooled to sucking filtration after room temperature, is vacuum dried at 55-60 DEG C, obtains dual cladding aluminium powder；
(4) by Borax adds the deionized water of 20-25 times amount, stir with the speed of 300-400 rev/min, be warming up to 80-90
DEG C, after insulated and stirred 20-30 minute, add re-dispersible glue powder, stearic acid, continue insulated and stirred 60-90 minute, suspended
Liquid, is spray-dried, obtains mixed powder；Mixed powder is mixed with remaining residual components in addition to propylene glycol monomethyl ether, puts
Enter in batch mixer, stir 10-13 minute with the speed of 800-1000 rev/min, discharging, obtain adding auxiliary agent；
(5) the interpolation auxiliary agent that dual cladding aluminium powder step (3) obtained obtains with step (4) mixes, and adds propylene glycol list first
Ether, puts in kneader and mediates 30-40 minute, be finally vacuum dried, obtain the present invention.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610595083.2A CN106221308A (en) | 2016-07-27 | 2016-07-27 | The modified dual cladding based aluminum pigment of a kind of wear-resisting toughening type inhibition |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610595083.2A CN106221308A (en) | 2016-07-27 | 2016-07-27 | The modified dual cladding based aluminum pigment of a kind of wear-resisting toughening type inhibition |
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| CN106221308A true CN106221308A (en) | 2016-12-14 |
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| CN201610595083.2A Pending CN106221308A (en) | 2016-07-27 | 2016-07-27 | The modified dual cladding based aluminum pigment of a kind of wear-resisting toughening type inhibition |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109575646A (en) * | 2019-01-03 | 2019-04-05 | 长沙族兴新材料股份有限公司 | Aluminium pigment and preparation method thereof |
| CN111334108A (en) * | 2020-04-24 | 2020-06-26 | 河北青竹画材科技有限公司 | Solid acrylic painting pigment and preparation method thereof |
| CN114918024A (en) * | 2022-04-16 | 2022-08-19 | 吉安豫顺新材料有限公司 | Process method for grinding silicon micropowder by airflow |
Citations (3)
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|---|---|---|---|---|
| CN104479425A (en) * | 2014-12-18 | 2015-04-01 | 常熟市环虹化工颜料厂 | Preparation method of water-based aluminum pigment |
| CN104530776A (en) * | 2014-12-18 | 2015-04-22 | 常熟市环虹化工颜料厂 | Preparation method of corrosion-resistant aluminum pigment |
| CN105482514A (en) * | 2015-12-15 | 2016-04-13 | 常熟市环虹化工颜料厂 | Method for preparing corrosion inhibition waterborne aluminum pigment |
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2016
- 2016-07-27 CN CN201610595083.2A patent/CN106221308A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104479425A (en) * | 2014-12-18 | 2015-04-01 | 常熟市环虹化工颜料厂 | Preparation method of water-based aluminum pigment |
| CN104530776A (en) * | 2014-12-18 | 2015-04-22 | 常熟市环虹化工颜料厂 | Preparation method of corrosion-resistant aluminum pigment |
| CN105482514A (en) * | 2015-12-15 | 2016-04-13 | 常熟市环虹化工颜料厂 | Method for preparing corrosion inhibition waterborne aluminum pigment |
Non-Patent Citations (1)
| Title |
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| 汪晓春: "《新材料产业现状与发展前景》", 31 May 2015 * |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109575646A (en) * | 2019-01-03 | 2019-04-05 | 长沙族兴新材料股份有限公司 | Aluminium pigment and preparation method thereof |
| CN111334108A (en) * | 2020-04-24 | 2020-06-26 | 河北青竹画材科技有限公司 | Solid acrylic painting pigment and preparation method thereof |
| CN114918024A (en) * | 2022-04-16 | 2022-08-19 | 吉安豫顺新材料有限公司 | Process method for grinding silicon micropowder by airflow |
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