CN106221103A - High shiny black high glaze exempts from the material and preparation method thereof that sprays paint - Google Patents

High shiny black high glaze exempts from the material and preparation method thereof that sprays paint Download PDF

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Publication number
CN106221103A
CN106221103A CN201610634256.7A CN201610634256A CN106221103A CN 106221103 A CN106221103 A CN 106221103A CN 201610634256 A CN201610634256 A CN 201610634256A CN 106221103 A CN106221103 A CN 106221103A
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CN
China
Prior art keywords
fire retardant
shiny black
compound
antioxidant
sprays paint
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610634256.7A
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Chinese (zh)
Inventor
刘菊初
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
SUZHOU CHUANGJIA PLASTIC Co Ltd
Original Assignee
SUZHOU CHUANGJIA PLASTIC Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by SUZHOU CHUANGJIA PLASTIC Co Ltd filed Critical SUZHOU CHUANGJIA PLASTIC Co Ltd
Priority to CN201610634256.7A priority Critical patent/CN106221103A/en
Publication of CN106221103A publication Critical patent/CN106221103A/en
Pending legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L51/04—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L69/00—Compositions of polycarbonates; Compositions of derivatives of polycarbonates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
    • C08L77/06—Polyamides derived from polyamines and polycarboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/08—Stabilised against heat, light or radiation or oxydation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Processes Of Treating Macromolecular Substances (AREA)

Abstract

The invention discloses a kind of high shiny black high glaze and exempt from the material that sprays paint, including following component: ASA plastic: 20～30wt%, glass fibre: 10～20wt%, fire retardant 8010:0.3～0.9wt%, antioxidant 1098:0.35～0.45wt%, PA66/6:10～30wt%, solid-state polymer amount epoxy resin: 5～9wt%, adjuvant: 1～3wt%, surplus is PC material, and this material of exempting to spray paint has high shiny black high glaze performance.

Description

High shiny black high glaze exempts from the material and preparation method thereof that sprays paint
Technical field
The present invention relates to plastic material technical field, be specifically related to a kind of high shiny black high glaze and exempt from spray paint material and preparation thereof Method.
Background technology
Existing exempt to spray paint that plastic material glossiness is inadequate, black luminance is inadequate.
Summary of the invention
It is an object of the invention to provide a kind of high shiny black high glaze and exempt from the material and preparation method thereof that sprays paint, this exempts from the material that sprays paint Material has high shiny black high glaze performance.
For achieving the above object, the technical scheme is that
A kind of high shiny black high glaze exempts from the material that sprays paint, including following component:
ASA plastic: 20～30wt%,
Glass fibre: 10～20wt%,
Fire retardant 8010:0.3～0.9wt%,
Antioxidant 1098:0.35～0.45wt%,
PA66/6:10～30wt%,
Solid-state polymer amount epoxy resin: 5～9wt%,
Adjuvant: 1～3wt%,
Surplus is PC material,
The bromine content of fire retardant 8010 is 78-80%；The copolymer nylon that caprolactam monomer content is 10-12% of PA66/6；Gu The epoxide number of state high molecular expoxy resin is 1800-2200.
A kind of high shiny black high glaze is exempted to spray paint the preparation method of material, comprises the following steps:
1) get the raw materials ready according to percentage by weight；
2) dry 3-4 hour at a temperature of 100 DEG C-110 DEG C after PC material, ASA plastic, PA66/6 mixing, obtain compound A；
3) by glass fibre, fire retardant 8010, antioxidant 1098, solid-state polymer amount epoxy resin, adjuvant mixing, compound is obtained B；
4) under 260 DEG C of-272 DEG C of extrusion temperatures by compound A and compound B respectively from the different charge doors of double screw extruder Successively add, melt blending, extruding pelletization.
In the present invention, ASA plastic is by the material by the rubber copolymerized conjunction of styrene, acrylonitrile and acryl；PC material For makrolon material；Fire retardant 8010(TDE).Glass fiber material forms certain friendship when moulded products The product high temperature tolerance time is improved by conjuncted system.PC material, ASA plastic, the mixing of PA66/6 make material have high glaze, be somebody's turn to do Shiny black performance, PA66/6 is cheap.
Detailed description of the invention
Below in conjunction with embodiment, the detailed description of the invention of the present invention is further described.Following example are only used for more Add and clearly demonstrate technical scheme, and can not limit the scope of the invention with this.
The technical scheme that the present invention is embodied as is:
Embodiment 1
A kind of high shiny black high glaze exempts from the material that sprays paint, including following component:
ASA plastic: 30wt%,
Glass fibre: 20wt%,
Fire retardant 8010:0.9wt%,
Antioxidant 1098:0.45wt%,
PA66/6:30wt%,
Solid-state polymer amount epoxy resin: 9wt%,
Adjuvant: 3wt%,
Surplus is PC material,
The bromine content of fire retardant 8010 is 78-80%；The copolymer nylon that caprolactam monomer content is 10-12% of PA66/6；Gu The epoxide number of state high molecular expoxy resin is 1800-2200.
Embodiment 2
A kind of high shiny black high glaze exempts from the material that sprays paint, including following component:
ASA plastic: 20wt%,
Glass fibre: 10wt%,
Fire retardant 8010:0.3wt%,
Antioxidant 1098:0.35wt%,
PA66/6:10wt%,
Solid-state polymer amount epoxy resin: 5wt%,
Adjuvant: 1wt%,
Surplus is PC material,
The bromine content of fire retardant 8010 is 78-80%；The copolymer nylon that caprolactam monomer content is 10-12% of PA66/6；Gu The epoxide number of state high molecular expoxy resin is 1800-2200.
Embodiment 3
A kind of high shiny black high glaze exempts from the material that sprays paint, including following component:
ASA plastic: 25wt%,
Glass fibre: 15wt%,
Fire retardant 8010:0.6wt%,
Antioxidant 1098:0.4wt%,
PA66/6:20wt%,
Solid-state polymer amount epoxy resin: 7wt%,
Adjuvant: 2wt%,
Surplus is PC material,
The bromine content of fire retardant 8010 is 78-80%；The copolymer nylon that caprolactam monomer content is 10-12% of PA66/6；Gu The epoxide number of state high molecular expoxy resin is 1800-2200.
A kind of high shiny black high glaze is exempted to spray paint the preparation method of material, comprises the following steps:
1) get the raw materials ready according to percentage by weight；
2) dry 3-4 hour at a temperature of 100 DEG C-110 DEG C after PC material, ASA plastic, PA66/6 mixing, obtain compound A；
3) by glass fibre, fire retardant 8010, antioxidant 1098, solid-state polymer amount epoxy resin, adjuvant mixing, compound is obtained B；
4) under 260 DEG C of-272 DEG C of extrusion temperatures by compound A and compound B respectively from the different charge doors of double screw extruder Successively add, melt blending, extruding pelletization.
The above is only the preferred embodiment of the present invention, it is noted that come for those skilled in the art Saying, on the premise of without departing from the technology of the present invention principle, it is also possible to make some improvements and modifications, these improvements and modifications also should It is considered as protection scope of the present invention.

Claims (2)

1. one kind high shiny black high glaze exempts from the material that sprays paint, it is characterised in that include following component:
ASA plastic: 20～30wt%,
Glass fibre: 10～20wt%,
Fire retardant 8010:0.3～0.9wt%,
Antioxidant 1098:0.35～0.45wt%,
PA66/6:10～30wt%,
Solid-state polymer amount epoxy resin: 5～9wt%,
Adjuvant: 1～3wt%,
Surplus is PC material,
The bromine content of fire retardant 8010 is 78-80%；The copolymer nylon that caprolactam monomer content is 10-12% of PA66/6；Gu The epoxide number of state high molecular expoxy resin is 1800-2200.
2. the shiny black high glaze of height described in claim 1 is exempted to spray paint the preparation method of material, it is characterised in that include following step Rapid:
1) get the raw materials ready according to percentage by weight；
2) dry 3-4 hour at a temperature of 100 DEG C-110 DEG C after PC material, ASA plastic, PA66/6 mixing, obtain compound A；
3) by glass fibre, fire retardant 8010, antioxidant 1098, solid-state polymer amount epoxy resin, adjuvant mixing, compound is obtained B；
4) under 260 DEG C of-272 DEG C of extrusion temperatures by compound A and compound B respectively from the different charge doors of double screw extruder Successively add, melt blending, extruding pelletization.
CN201610634256.7A 2016-08-05 2016-08-05 High shiny black high glaze exempts from the material and preparation method thereof that sprays paint Pending CN106221103A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610634256.7A CN106221103A (en) 2016-08-05 2016-08-05 High shiny black high glaze exempts from the material and preparation method thereof that sprays paint

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610634256.7A CN106221103A (en) 2016-08-05 2016-08-05 High shiny black high glaze exempts from the material and preparation method thereof that sprays paint

Publications (1)

Publication Number Publication Date
CN106221103A true CN106221103A (en) 2016-12-14

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Citations (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1516721A (en) * 2001-06-08 2004-07-28 ��һë֯��ʽ���� Flame retardant thermoplastic resin composition
CN1810862A (en) * 2006-02-23 2006-08-02 广州金发科技股份有限公司 Continuous long fiber reinforced fire-retardant thermoplastic resin and its prepn
CN101759982A (en) * 2008-12-23 2010-06-30 上海普利特复合材料股份有限公司 Antistatic and ultraviolet resistant PC/ASA material composition
CN101851430A (en) * 2009-04-03 2010-10-06 上海锦湖日丽塑料有限公司 Method of improving gloss of polymer alloy
CN102337025A (en) * 2010-07-19 2012-02-01 哈尔滨鑫达高分子材料工程中心有限责任公司 High notched impact PA/ASA alloy material and its preparation method
CN102344677A (en) * 2011-06-28 2012-02-08 深圳市科聚新材料有限公司 Polyamide 6-ASA resin alloy material and its preparation method
CN102476455A (en) * 2010-11-29 2012-05-30 上海杰事杰新材料(集团)股份有限公司 Manufacturing method of thermoplastic composite vehicle door
CN102731903A (en) * 2011-04-15 2012-10-17 黄云清 Composite material of imitated glass reinforced plastic, its manufacture method and its application
CN102796370A (en) * 2005-09-22 2012-11-28 富士通株式会社 Plant-based resin containing composition and plant-based resin containing molded body using same
CN102993691A (en) * 2012-08-20 2013-03-27 安徽凯迪电气有限公司 ASA-modified nylon PA66 particle material and preparation method and application thereof on automobile
CN103387709A (en) * 2012-05-08 2013-11-13 合肥杰事杰新材料股份有限公司 Thermoplastic composite material, and preparation method and application thereof
CN104962055A (en) * 2015-04-28 2015-10-07 深圳市联懋塑胶有限公司 Environmental protection flame retardation type glass fiber reinforcement polycarbonate alloy material and preparation method thereof

Patent Citations (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1516721A (en) * 2001-06-08 2004-07-28 ��һë֯��ʽ���� Flame retardant thermoplastic resin composition
CN102796370A (en) * 2005-09-22 2012-11-28 富士通株式会社 Plant-based resin containing composition and plant-based resin containing molded body using same
CN1810862A (en) * 2006-02-23 2006-08-02 广州金发科技股份有限公司 Continuous long fiber reinforced fire-retardant thermoplastic resin and its prepn
CN101759982A (en) * 2008-12-23 2010-06-30 上海普利特复合材料股份有限公司 Antistatic and ultraviolet resistant PC/ASA material composition
CN101851430A (en) * 2009-04-03 2010-10-06 上海锦湖日丽塑料有限公司 Method of improving gloss of polymer alloy
CN102337025A (en) * 2010-07-19 2012-02-01 哈尔滨鑫达高分子材料工程中心有限责任公司 High notched impact PA/ASA alloy material and its preparation method
CN102476455A (en) * 2010-11-29 2012-05-30 上海杰事杰新材料(集团)股份有限公司 Manufacturing method of thermoplastic composite vehicle door
CN102731903A (en) * 2011-04-15 2012-10-17 黄云清 Composite material of imitated glass reinforced plastic, its manufacture method and its application
CN102344677A (en) * 2011-06-28 2012-02-08 深圳市科聚新材料有限公司 Polyamide 6-ASA resin alloy material and its preparation method
CN103387709A (en) * 2012-05-08 2013-11-13 合肥杰事杰新材料股份有限公司 Thermoplastic composite material, and preparation method and application thereof
CN102993691A (en) * 2012-08-20 2013-03-27 安徽凯迪电气有限公司 ASA-modified nylon PA66 particle material and preparation method and application thereof on automobile
CN104962055A (en) * 2015-04-28 2015-10-07 深圳市联懋塑胶有限公司 Environmental protection flame retardation type glass fiber reinforcement polycarbonate alloy material and preparation method thereof

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* Cited by examiner, † Cited by third party
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周殿明 主编: "《塑料成型技术》", 31 October 2014, 机械工业出版社 *

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Application publication date: 20161214

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