CN108239316A - A kind of formula of refractory polyethylene plastic pellet - Google Patents

A kind of formula of refractory polyethylene plastic pellet Download PDF

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Publication number
CN108239316A
CN108239316A CN201611204157.1A CN201611204157A CN108239316A CN 108239316 A CN108239316 A CN 108239316A CN 201611204157 A CN201611204157 A CN 201611204157A CN 108239316 A CN108239316 A CN 108239316A
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CN
China
Prior art keywords
parts
plastic pellet
formula
polyethylene plastic
refractory polyethylene
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
CN201611204157.1A
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Chinese (zh)
Inventor
孙宏立
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Cixi Qingquan Electric Appliance Co Ltd
Original Assignee
Cixi Qingquan Electric Appliance Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Cixi Qingquan Electric Appliance Co Ltd filed Critical Cixi Qingquan Electric Appliance Co Ltd
Priority to CN201611204157.1A priority Critical patent/CN108239316A/en
Publication of CN108239316A publication Critical patent/CN108239316A/en
Withdrawn legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04Homopolymers or copolymers of ethene
    • C08L23/06Polyethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/02Flame or fire retardant/resistant
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Processes Of Treating Macromolecular Substances (AREA)

Abstract

A kind of formula of refractory polyethylene plastic pellet, refractory polyethylene plastic pellet include following components by weight percent:75 85 parts of polyethylene, 5 10 parts of silane, 1.5 2 parts of stabilizer, 1.8 3.2 parts of plasticizer, 0.5 2 parts of carbon black, 2 3.5 parts of diatomite, 23 parts of crosslinking agent, 23 parts of anti-impact modifier.The plastic pellet that the present invention is obtained has excellent heat-resisting quantity, insulating properties, physical mechanical property, elasticity, resistance to ag(e)ing, corrosion resistance, anti-flammability, weatherability etc., cheap, high yield rate, function admirable, environmental protection.

Description

A kind of formula of refractory polyethylene plastic pellet
Technical field
The present invention relates to a kind of formulas of refractory polyethylene plastic pellet.
Background technology
Vinyon has good electricity, mechanics, resistance to low temperature, and cost-effective, be widely used in life and The every field of industry.However the relatively low intensity of polyethylene and SC service ceiling temperature limiting its use scope, therefore, need Will be certain change improves its ceiling temperature and mechanical property, expands the application field of polyethylene.
Invention content
Above-mentioned in order to overcome the shortcomings of to exist in the prior art, the present invention provides a kind of cheap, high yield rate, performance The formula of excellent, environmentally friendly refractory polyethylene plastic pellet.
The present invention the technical solution to solve the technical problem is that:A kind of formula of refractory polyethylene plastic pellet, this is resistance to High temperature polyethylene plastic pellet includes following components by weight percent:75-85 parts of polyethylene, 1.5-2 parts of stabilizer, increases 5-10 parts of silane Mould 1.8-3.2 parts of agent, 0.5-2 parts of carbon black, 2-3.5 parts of diatomite, 2-3 parts of crosslinking agent, 2-3 parts of anti-impact modifier.
Preferably, the plasticizer is dioctyl sebacate.
Preferably, the crosslinking agent is flame-retardant agent.
Preferably, the stabilizer is tri-thiol 2-ethyl hexyl ethanoate antimony.
Preferably, the anti-impact modifier is one styrol copolymer of metacrylate-butadiene.
The beneficial effects of the present invention are:The plastic pellet that is obtained of the present invention have excellent heat-resisting quantity, insulating properties, Physical mechanical property, elasticity, resistance to ag(e)ing, corrosion resistance, anti-flammability, weatherability etc., cheap, high yield rate, performance are excellent It is good, environmentally friendly.
Specific embodiment
The present invention is described in further detail With reference to embodiment.
A kind of formula of refractory polyethylene plastic pellet, the refractory polyethylene plastic pellet include following weight group Point:75-85 parts of polyethylene, 5-10 parts of silane, 1.5-2 parts of stabilizer, 1.8-3.2 parts of plasticizer, 0.5-2 parts of carbon black, diatomite 2-3.5 parts, 2-3 parts of crosslinking agent, 2-3 parts of anti-impact modifier.Basic material of the polyethylene as plastic pellet, present invention selection Basic material of the DFDA-7042 types polyethylene as formula.Silane serves as a connection when improving polyethylene, ensures that reaction is smooth It carries out.Stabilizer has stability to polyethylene, it can slow down reaction, keeps chemical balance, reduces surface tension, prevents The effects that light, thermal decomposition or oxygenolysis, stabilizer of the invention use tri-thiol 2-ethyl hexyl ethanoate antimony, have preferably bonding Property, and reduce cost.Plasticizer can control polyethylene soft hardness, increase gloss, and plasticizer of the invention uses decanedioic acid Dioctyl ester.Carbon black is while being a kind of colorant or good UV resistant agent, addition carbon black cause material in coloring On the basis of can also make material have good weatherability.Diatomite can improve the extensibility of polyethylene, have higher stretching Intensity and impact strength.Crosslinking agent can improve the intensity and elasticity of polyethylene, and crosslinking agent of the invention uses flame-retardant agent.It is anti- Impact modifying agent makes polyethylene have shock resistance, and anti-impact modifier of the invention uses metacrylate-butadiene One styrol copolymer, one styrol copolymer of metacrylate-butadiene, that is, MBS are a kind of novel high polymer materials, by Methyl methacrylate(M), butadiene(B)And styrene(S)It is prepared using emulsion grafting polymerization method.The resin is in sub-micro Seeing has typical nucleocapsid structure in form, core is the rubber phase globose nucleus of an a diameter of 10~100nm, and outside is benzene The shell of ethylene and methyl methacrylate composition.In the preparation, it is preferable that by 80 kilograms of polyethylene, 8 kilograms of silane, 2 Kilogram dioctyl sebacate, 1 kilogram of tri-thiol 2-ethyl hexyl ethanoate antimony, 2 kilograms of carbon blacks, 3 diatomite, 2 kilograms of flame-proof cross-linking Agent, 2 kilograms of one styrol copolymer of metacrylate-butadiene are put into blender and are sufficiently stirred to obtain mixed raw material, Then mixed raw material is put into feeder, then passes through extruder by mixing time 8-15 minutes, 110-130 DEG C of whipping temp Extrusion mixing raw material, the rotating speed 20-25 of feeder turn, and the rotating speed 35-40 of extruder turns, and is then put into the mixed raw material of extrusion 10-20 DEG C is cooled at water cooling plant, then by mixed raw material be put into double-screw extruding pelletizing machine be plasticized at 200-220 DEG C and Pelletizing is up to the refractory polyethylene plastic pellet.The plastic pellet that is obtained of the present invention has excellent heat-resisting quantity, absolutely Edge, physical mechanical property, elasticity, resistance to ag(e)ing, corrosion resistance, anti-flammability, weatherability etc., cheap, high yield rate, property It can be excellent, environmentally friendly.

Claims (5)

1. a kind of formula of refractory polyethylene plastic pellet, it is characterised in that:The refractory polyethylene plastic pellet include with Lower components by weight percent:75-85 parts of polyethylene, 5-10 parts of silane, 1.5-2 parts of stabilizer, 1.8-3.2 parts of plasticizer, carbon black 0.5-2 Part, 2-3.5 parts of diatomite, 2-3 parts of crosslinking agent, 2-3 parts of anti-impact modifier.
2. a kind of formula of refractory polyethylene plastic pellet according to claim 1, it is characterised in that:The plasticizer For dioctyl sebacate.
3. a kind of formula of refractory polyethylene plastic pellet according to claim 1, it is characterised in that:The crosslinking Agent is flame-retardant agent.
4. a kind of formula of refractory polyethylene plastic pellet according to claim 1, it is characterised in that:The stabilizer For tri-thiol 2-ethyl hexyl ethanoate antimony.
5. a kind of formula of refractory polyethylene plastic pellet according to claim 1, it is characterised in that:The shock resistance Modifying agent is one styrol copolymer of metacrylate-butadiene.
CN201611204157.1A 2016-12-23 2016-12-23 A kind of formula of refractory polyethylene plastic pellet Withdrawn CN108239316A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201611204157.1A CN108239316A (en) 2016-12-23 2016-12-23 A kind of formula of refractory polyethylene plastic pellet

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201611204157.1A CN108239316A (en) 2016-12-23 2016-12-23 A kind of formula of refractory polyethylene plastic pellet

Publications (1)

Publication Number Publication Date
CN108239316A true CN108239316A (en) 2018-07-03

Family

ID=62703832

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201611204157.1A Withdrawn CN108239316A (en) 2016-12-23 2016-12-23 A kind of formula of refractory polyethylene plastic pellet

Country Status (1)

Country Link
CN (1) CN108239316A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112662032A (en) * 2020-12-03 2021-04-16 江苏格兰特管业有限公司 Corrosion-resistant plastic particles and preparation method thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112662032A (en) * 2020-12-03 2021-04-16 江苏格兰特管业有限公司 Corrosion-resistant plastic particles and preparation method thereof

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Application publication date: 20180703