CN106220126B - A kind of grouting material of foundation stabilization - Google Patents

A kind of grouting material of foundation stabilization Download PDF

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Publication number
CN106220126B
CN106220126B CN201610652831.6A CN201610652831A CN106220126B CN 106220126 B CN106220126 B CN 106220126B CN 201610652831 A CN201610652831 A CN 201610652831A CN 106220126 B CN106220126 B CN 106220126B
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parts
water
mesh
fineness
cement
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Expired - Fee Related
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CN201610652831.6A
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CN106220126A (en
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周宇
孟祥华
陈思远
袁佳
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Jiamusi University
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Jiamusi University
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/24Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing alkyl, ammonium or metal silicates; containing silica sols
    • C04B28/26Silicates of the alkali metals
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/34Non-shrinking or non-cracking materials
    • C04B2111/343Crack resistant materials
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2201/00Mortars, concrete or artificial stone characterised by specific physical values
    • C04B2201/50Mortars, concrete or artificial stone characterised by specific physical values for the mechanical strength

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)
  • Soil Conditioners And Soil-Stabilizing Materials (AREA)

Abstract

The present invention proposes a kind of grouting material of foundation stabilization, selection portland cement is major ingredient, add the admixtures such as sulphate aluminium cement, slag micropowder, flyash, gypsum, lime, waterglass, Paris white, calcium hydroxide, low-viscosity cellulose, slurries are made, by script loose earth or crack cementation solidifying, new Seed harvest is formed, the various aspects all have been changed such as ingredient, seepage flow performance, chemical stability and mechanical property of soil structures has better engineering properties.

Description

A kind of grouting material of foundation stabilization
Technical field
The present invention relates to a kind of grouting materials of foundation stabilization.
Background technology
Slip casting also known as be in the milk, with force feed equipment by pressure by the slurry curing materials centainly matched be injected into soil layer or In crack, and new calculus object is spread, is gelled and is formed by curing, for reinforcing soil layer and impervious leakage-stopping, is built with reaching building Build engineering construction requirement.
Slurry injection technique had more than 200 years history at present, and development experience four-stage is followed successively by:(1802-1857 Year) original clay slurries developing stage, (1858-1919) primary cement slurries developing stage, (1920-1969) middle rankization Learn slurries slip casting developing stage, (after 1969) modern slip casting developing stage.Slip casting method mainly have permeation grouting method, filling or Crack grouting method, fracture grouting method, press injecting method, jet groutinl method and electronic chemical slip casting method etc., cover hydrodynamics, Numerous subjects such as chemistry, rock mechanics, soil mechanics, the extensive use in the engineerings such as traffic, water conservancy, mining, subway, tunnel, place It is with obvious effects to manage antiseepage, water blockoff and reinforcing etc..
Ground can usually encounter sedimentation or deformation, Carrying Capacity in highway and railway engineering, need to carry out ground Strengthening reconstruction.It is bad using the direct consolidation effect of Portland cement slurries, this is because slurries setting time is longer, slurries The deficiencies of calculus after-contraction is big, stability is poor influences consolidation effect.Mix flyash, clay, volcanic ash, swelled ground, waterglass Equal admixtures, are effectively improved the mechanical property of ordinary cement slurries, with good stability, do not occur bleed precipitation, solidify Calculus is more closely knit firm afterwards, and therefore, research novel slurry filling material becomes the key problem in technology captured.
Invention content
Based on the above shortcoming, the present invention proposes a kind of grouting material of foundation stabilization, chooses based on portland cement Material, addition sulphate aluminium cement, slag micropowder, flyash, gypsum, lime, waterglass, Paris white, calcium hydroxide, low viscosity The admixtures such as cellulose are made slurries by script loose earth or crack cementation solidifying, form new Seed harvest, soil structures Many-sided all have been changed such as ingredient, seepage flow performance, chemical stability and mechanical property, there is better engineering properties.
In order to realize that the purpose of foregoing invention, technical solution of the present invention are as follows:
A kind of grouting material of foundation stabilization, formula are as follows by weight ratio:45-55 parts of portland cement;Aluminium sulfate Cement 10-14;5-8 parts of slag micropowder;8-12 parts of flyash;6-10 parts of gypsum;5-8 parts of lime;8-10 parts of waterglass;Calcium carbonate 3-5 parts of powder;0.6-1.2 parts of calcium hydroxide;0.02-0.03 parts of low-viscosity cellulose;3-6 parts of swelling agent;1-1.5 parts of water-reducing agent.
The present invention also has following technical characteristic:
Further, the portland cement is the Portland cement that strength grade is higher than 42.5, and portland cement is Be in the milk major ingredient, shortens setting time, the premise adjusted for setting time;The sulphate aluminium cement is that strength grade is higher than 42.5 Sulphate aluminium cement, for early stage rapid condensation harden, enhance early strength, adjust setting time.
Further, the fineness of slag is 300-450 mesh, specific surface area 500-700m2/ kg can increase service life, Enhance the impermeability and sulfate resistance of Seed harvest after grouting material hardens.
Further, the waterglass is solid sodium silicate.
Further, the Paris white fineness is 350-500 mesh.
Further, the calcium hydroxide fineness is 600-700 mesh.
Further, the low-viscosity cellulose viscosity is 100-300mpas, for prevent the layering of composite material with it is heavy Drop.
Further, the swelling agent is calper calcium peroxide, sodium peroxide and calcium sulphoaluminate mixture, mass ratio 2-4:2-3: 2-5, fineness are 300-400 mesh, and calper calcium peroxide is compensated for early-age plastic shrinkage, and sodium peroxide is used for mid-term shrinkage-compensating, sulphur Calcium aluminate is compensated for final set after-contraction.Composite expanding agent can compensate for cement grouting material contraction, material microdilatancy, body after grouting Product is relatively stablized.
Further, the water-reducing agent is polycarboxylate water-reducer, and water-reducing rate 25-35%, water-reducing rate is high, is had with cement good Good compatibility can reduce amount of water, increase composite fluidity.
In use, a certain amount of water need to be added, slurries, water content 14-22% is made.
According to water content difference, slurries fluidity is different, and physico mechanical characteristic index is different.In test, according to needed for The difference of fluidity, to adjust amount of water and raw material proportioning.
The raw material of constant weight is mixed evenly with water according to the ratio first in construction for grouting material, ensures slurries Fluidity be more than 150mm, it is closer for transportation range, will be stirred the static 15min of slurries i.e. can transport, for transport away from From distant, pumping mode can be used.
The compression strength of the soil body can be improved in the composite material that the present invention matches, and solving cement grout, there are contraction fissures to ask Topic, can effectively control the expansion rate of the soil body, and expansion rate has small expansion but not generate spalling, to reach ground within 0.5% Base is reinforced, prevents the requirements such as crack.
The grouting grout cures of the present invention are fast, setting time is adjustable, the construction time is short, and consolidation effect is good, Seed harvest is strong Degree is high, material loss is few, effect is very fast, is easy to the vibration that construction, construction is simple, at low cost, noise is small in work progress, generates It is weak, small to surrounding environment influence, operating surface is can be applied to than narrow sitework, and the depth of grouting and reinforcing can be according to needs The depth is controlled, is widely used in the fields such as traffic engineering, civil engineering, tunnel, water conservancy and hydropower, hypogee, brings huge Economic benefit and social value.
Specific implementation mode
Embodiment 1
Suitable for place, narrow, the more complicated place situation of landform, raw material are formulated as follows this example:Portland cement 55Kg;Sulphate aluminium cement 12Kg;Slag micropowder 8Kg;Flyash 10Kg;Gypsum 6Kg;Lime 6Kg;Solid sodium silicate 9Kg; Paris white 3Kg;Calcium hydroxide 0.6Kg;Low-viscosity cellulose 0.02Kg;Swelling agent 3Kg;Water-reducing agent 1.2Kg.
In this example, portland cement is 42.5 Portland cement of strength grade;Sulphate aluminium cement is intensity etc. 52.5 sulphate aluminium cements of grade;Slag micropowder fineness is 450 mesh, specific surface area 500m2/kg;Low-viscosity cellulose viscosity is 100mpa·s;The Paris white fineness is 350 mesh;The calcium hydroxide fineness is 600 mesh;Swelling agent is calper calcium peroxide, mistake Sodium oxide molybdena and calcium sulphoaluminate mass ratio are 4:3:5 mixtures, fineness are 300 mesh;Water-reducing agent is polycarboxylate water-reducer, and water-reducing rate is 25%;Amount of water is total weight 18%.
Embodiment 2
This example is suitable for common slip casting situation, and raw material is formulated as follows:Portland cement 48Kg;Sulphate aluminium cement 10Kg;Slag micropowder 6Kg;Flyash 8Kg;Gypsum 10Kg;Lime 8Kg;Waterglass 8Kg;Paris white 4Kg;Calcium hydroxide 1Kg;Low-viscosity cellulose 0.03Kg;Swelling agent 6Kg;Water-reducing agent 1.5Kg.
In this example, portland cement is 52.5 Portland cement of strength grade;Sulphate aluminium cement is intensity etc. 42.5 sulphate aluminium cements of grade;Slag micropowder fineness is 400 mesh, specific surface area 700m2/kg;Low-viscosity cellulose viscosity is 300mpa·s;The Paris white fineness is 500 mesh;The calcium hydroxide fineness is 700 mesh;Swelling agent is calper calcium peroxide, mistake Sodium oxide molybdena and calcium sulphoaluminate mass ratio are 3:2:3 mixtures, fineness are 400 mesh;Water-reducing agent is polycarboxylate water-reducer, and water-reducing rate is 35%;Amount of water is total weight 22%.
Embodiment 3
This example is suitable for engineering reinforcement situation, and raw material is formulated as follows:Portland cement 45Kg;Sulphate aluminium cement 14Kg;Slag micropowder 5Kg;Flyash 12Kg;Gypsum 8Kg;Lime 5Kg;Waterglass 10Kg;Paris white 5Kg;Calcium hydroxide 1.2Kg;Low-viscosity cellulose 0.025Kg;Swelling agent 5Kg;Water-reducing agent 1Kg.
In this example, portland cement is 52.5 Portland cement of strength grade;Sulphate aluminium cement is intensity etc. 52.5 sulphate aluminium cements of grade;Slag micropowder fineness is 300 mesh, specific surface area 650m2/kg;Low-viscosity cellulose viscosity is 250mpa·s;The Paris white fineness is 400 mesh;The calcium hydroxide fineness is 650 mesh;Swelling agent is calper calcium peroxide, mistake Sodium oxide molybdena and calcium sulphoaluminate mass ratio are 2:2:5 mixtures, fineness are 350 mesh;Water-reducing agent is polycarboxylate water-reducer, and water-reducing rate is 30%;Amount of water is total weight 14%.
Embodiment 4
The different case study on implementation technical indicator tables of table 1

Claims (2)

1. a kind of grouting material of foundation stabilization, which is characterized in that formula is as follows by weight ratio:45-55 parts of portland cement, 10-14 parts of sulphate aluminium cement, 5-8 parts of slag micropowder, 8-12 parts of flyash, 6-10 parts of gypsum, 5-8 parts of lime, waterglass 8- 10 parts, 3-5 parts of Paris white, 0.6-1.2 parts of calcium hydroxide, 0.02-0.03 parts of low-viscosity cellulose, 3-6 parts of swelling agent and subtract 1-1.5 parts of aqua;The portland cement is the Portland cement that strength grade is higher than 42.5;The sulphate aluminium cement It is higher than 42.5 sulphate aluminium cement for strength grade;The fineness of slag is 300-450 mesh, specific surface area 500-700m2/ kg;The waterglass is solid sodium silicate;The Paris white fineness is 350-500 mesh;The calcium hydroxide fineness is 600-700 mesh;The low-viscosity cellulose viscosity is 100-300mpas;The swelling agent be calper calcium peroxide, sodium peroxide and Calcium sulphoaluminate mixture, mass ratio 2-4:2-3:2-5, fineness are 300-400 mesh;The water-reducing agent is polycarboxylate water-reducer, Water-reducing rate is 25-35%.
2. a kind of grouting material of foundation stabilization according to claim 1, it is characterised in that:In use, need to be added certain Slurries, water content 14-22% is made in the water of amount.
CN201610652831.6A 2016-08-10 2016-08-10 A kind of grouting material of foundation stabilization Expired - Fee Related CN106220126B (en)

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CN106746895B (en) * 2017-03-01 2019-02-15 天津天盈新型建材有限公司 A kind of composite expanding agent that the compensation cement material plasticity stage shrinks
CN107793101A (en) * 2017-11-21 2018-03-13 淮南久辉工贸有限责任公司 A kind of inorganic reinforcing composite mortar and preparation method thereof
CN108558335A (en) * 2018-01-12 2018-09-21 广东省建筑科学研究院集团股份有限公司 A kind of high-performance cement base grouting material
CN109626944A (en) * 2019-01-25 2019-04-16 国网山西省电力公司经济技术研究院 A kind of high-tension line disc type ground perfusion materia and its preparation method and application
CN111807779B (en) * 2020-06-09 2022-04-19 重庆中航建设(集团)有限公司 High-strength waterproof soil consolidation agent
CN111908949A (en) * 2020-08-13 2020-11-10 上海宝冶集团有限公司 Mixed slurry for foundation treatment engineering and preparation method thereof
CN112341118B (en) * 2020-10-27 2022-08-23 西北矿冶研究院 Grouting material for reinforcing confined water-containing coal seam mining bottom plate
CN112592143B (en) * 2020-12-16 2022-05-10 哈尔滨工业大学 Clay-slag-based harbor seismic strengthening mineral grouting material and preparation method thereof
CN113391056A (en) * 2021-06-02 2021-09-14 中国电建集团西北勘测设计研究院有限公司 Method for improving shrinkage cracking performance of cement-based grouting material
CN114262198A (en) * 2021-12-16 2022-04-01 四川聚力建材科技有限公司 Rapid curing and complex doping system grouting material for subway engineering and preparation method thereof

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CN1262510C (en) * 2003-08-19 2006-07-05 张振秋 Molified low alkalinity thioaluminate cement
CN101798208B (en) * 2010-02-22 2013-12-18 湖北中桥科技有限公司 High fluidity grouting material and production method thereof
CN103011716A (en) * 2012-10-15 2013-04-03 上海弘路建设发展有限公司 Grouting material for roadbed reinforcement
CN104529358A (en) * 2014-11-27 2015-04-22 山西省建筑科学研究院 High-admixture low-cost grouting material and preparation method thereof
CN105439512A (en) * 2015-11-13 2016-03-30 江苏苏博特新材料股份有限公司 Ultrahigh strength cement-based grouting material easy to stir
CN105503068B (en) * 2015-11-30 2017-06-16 天津天盈新型建材有限公司 Aqueous epoxy resins are modified cement grouting material

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