CN106219633A - Anion water purification filtering material and preparation method thereof - Google Patents

Anion water purification filtering material and preparation method thereof Download PDF

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Publication number
CN106219633A
CN106219633A CN201610755853.5A CN201610755853A CN106219633A CN 106219633 A CN106219633 A CN 106219633A CN 201610755853 A CN201610755853 A CN 201610755853A CN 106219633 A CN106219633 A CN 106219633A
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layer
anion
parts
water purification
purification filtering
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CN201610755853.5A
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CN106219633B (en
Inventor
傅陆军
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Hangzhou Kaiyue New Material Co Ltd
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Hangzhou Kaiyue New Material Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/001Processes for the treatment of water whereby the filtration technique is of importance
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D39/00Filtering material for liquid or gaseous fluids
    • B01D39/14Other self-supporting filtering material ; Other filtering material
    • B01D39/16Other self-supporting filtering material ; Other filtering material of organic material, e.g. synthetic fibres
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D39/00Filtering material for liquid or gaseous fluids
    • B01D39/14Other self-supporting filtering material ; Other filtering material
    • B01D39/20Other self-supporting filtering material ; Other filtering material of inorganic material, e.g. asbestos paper, metallic filtering material of non-woven wires
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/68Treatment of water, waste water, or sewage by addition of specified substances, e.g. trace elements, for ameliorating potable water
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2239/00Aspects relating to filtering material for liquid or gaseous fluids
    • B01D2239/04Additives and treatments of the filtering material
    • B01D2239/0407Additives and treatments of the filtering material comprising particulate additives, e.g. adsorbents
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2239/00Aspects relating to filtering material for liquid or gaseous fluids
    • B01D2239/10Filtering material manufacturing

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Geology (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Water Treatment By Sorption (AREA)
  • Water Treatment By Electricity Or Magnetism (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)

Abstract

nullThe present invention relates to a kind of anion water purification filtering material and preparation method thereof,Described anion water purification filtering material is the lamination layer structure being made up of internal layer and outer layer,Internal layer is to be entered layer by protection、Anion filter course、Reinforcement structure changes layer、Anion synthesis layer and purification switching layer are composited,Outer layer is latex functional layer,Described protection enters layer and uses spun laced fabric material,Anion filter course uses terylene encryption screen cloth,Reinforcement structure changes layer and uses terylene intersection pin to prick cloth,Anion synthesis layer is gross porosity negative ion cloth,Purifying switching layer is terylene interwoven,The component of described latex functional layer and weight portion composition are as follows: latex 45 65 parts,Synthetic resin 10 30 parts,Anion powder 5 10 parts,20 40 parts of bamboo carbon fiber powder,Diatom ooze 5 15 parts,38 parts of the order mesoporous medium of magnetic.The harmful substances such as the anion water purification filtering material of the present invention, can be effectively isolated and purify the barium existed in water, chlorine, nitrite, hydrargyrum, lead.

Description

Anion water purification filtering material and preparation method thereof
Technical field
The present invention relates to a kind of anion water purification filtering material and preparation method thereof.
Background technology
Along with expanding economy, the extensive application of chemical products, causing water to pollute and be further exacerbated by, the quality problem of water becomes Obtain more prominent.Water quality and the health of human body have close relationship, anion water purification filtering material to be a kind of for water Matter filters, and stops the harmful substance in water, improves the material of hardness.Existing water purification filter material is a lot, mostly It is to stop for harmful substance, but relatively weak to improvement and reinforcement water quality.
Summary of the invention
It is an object of the invention to solve the deficiencies in the prior art, it is provided that a kind of anion water purification filtering material.
Further object is that the preparation method that a kind of anion water purification filtering material is provided.
The technical solution adopted for the present invention to solve the technical problems is:
Anion water purification filtering material, described anion water purification filtering material is be made up of internal layer and outer layer compound Rotating fields, internal layer is to be entered layer, anion filter course, reinforcement structure change layer, anion synthesis layer by protection and purify exchange Layer is composited, and outer layer is latex functional layer, and described protection enters layer and uses spun laced fabric material, and anion filter course uses terylene Encryption screen cloth, reinforcement structure changes layer and uses terylene intersection pin to prick cloth, and anion synthesis layer is gross porosity negative ion cloth, purifies exchange Layer is terylene interwoven, and the component of described latex functional layer and weight portion composition are as follows: latex 45-65 part, synthetic resin 10-30 Part, anion powder 5-10 part, bamboo carbon fiber powder 20-40 part, diatom ooze 5-15 part, magnetic order mesoporous medium 3-8 part.
Preferably, the component of described latex functional layer and weight portion composition are as follows: latex 50 parts, and synthetic resin 18 parts is negative 7 parts of ion powder, 30 parts of bamboo carbon fiber powder, diatom ooze 10 parts, 4 parts of the order mesoporous medium of magnetic.
Preferably, the order mesoporous medium of described magnetic is magnetic ordered mesoporous carbon or the order mesoporous nickel ferrite based magnetic loaded of magnetic.
It is furthermore preferred that the order mesoporous medium of described magnetic is the order mesoporous nickel ferrite based magnetic loaded of magnetic, its preparation method is as follows:
1) by Ni (NO3)2·6H2O and Fe (NO3)3·9H2O is dissolved in methanol, and appropriate porous silicon KIT-6 is put into Sheng Have in the polytetrafluoroethylcontainer container of normal hexane, be sufficiently stirred for;
2) by solution 1) raw material be added dropwise over step 2) in, the mixed solution formed is sufficiently stirred for, and adds in 50-60 DEG C Hot 8-12h;
3) step 2) gained solid calcination 4-5h at 250-280 DEG C;
4) by step 3) gained solid is cooled to room temperature, in the polished round-bottomed flask being transferred to fill NaOH solution, Centrifugal recovery after return stirring 24-36h under 40-50 DEG C of water bath condition;
5) by step 4) gained solid cleans to neutrality repeatedly with ethanol and deionized water respectively, vacuum dried i.e. Can.
Magnetic ordered mesoporous carbon of the present invention or the order mesoporous nickel ferrite based magnetic loaded of magnetic possess huge specific surface area and Abundant three dimensional pore structures, high-specific surface area is conducive to the adsorption storage of anion powder and diatom ooze;Regular orderly opening Property duct, the aperture of size adjustable be that anion produces and provides path, beneficially anion slowly persistently produces for a long time, carries The using effect of high-negative ion water purification filter material, extends its service life.
Preferably, described synthetic resin is any one in commercial resins for universal use, such as polyethylene, polypropylene, polychlorostyrene second Alkene, polystyrene and ABS.
A kind of preparation method of anion water purification filtering material, preparation method is as follows:
(1) five layer material tilings of internal layer, use the multiply fine water jet injection fibre web that high pressure produces, and water jet passes After fibre web, the bounce-back of net of being commissioned, water jet penetrates fibre web again, the water that in fibre web, fiber interts at different directions high-speed water jet Produce displacement under power effect, intert, entanglement, obvolvent, reinforce fibre web, obtain internal layer stock;
(2) the latex functional layer component of formula ratio is sufficiently stirred for by blender, the micro-frequency of emulsion high temperature after stirring 10-30min, is placed in impregnation glue groove standby;
The micro-frequency of high temperature refers to, under 110-130 DEG C of high temperature, process through stable frequency of vibration, such as 10- 200Hz, so that slurry is full and uniform;
(3) by machine on internal layer stock, internal layer stock and emulsion is made fully to infiltrate, at impregnation process by impregnation The micro-frequency of middle high temperature, so that base material is uniformly starched, is formed two-in-one material of main part by slurry base material by extruding, and material of main part is producing Through hot extrusion on line, stentering forming, subsequently enter (a kind of work that can produce heat-flash gas impact air-flow of hot-air pump negative pressure cabin Storehouse), heat-flash gas impact air-flow upper and lower in storehouse run through, hit logical material of main part, form some micropores, be distributed in each portion of material Point, form anion water scavenging material semi-finished product;
(4) semi-finished product pass through shear history, are excised by redundance, after storing solidification cooling, enter Product checking.
The invention has the beneficial effects as follows: the anion water purification filtering material of the present invention, can be effectively isolated in purification water and deposit Barium, chlorine, nitrite, hydrargyrum, the harmful substance such as lead, leave calcium ions and magnesium ions, making water is alkalescence;Simultaneously in material bear from Son can effectively sterilize, and softens the basis improving water the most once again.
Detailed description of the invention
Below by specific embodiment, technical scheme is described in further detail.
Embodiment 1:
Anion water purification filtering material, described anion water purification filtering material is be made up of internal layer and outer layer compound Rotating fields, internal layer is to be entered layer, anion filter course, reinforcement structure change layer, anion synthesis layer by protection and purify exchange Layer is composited, and outer layer is latex functional layer, and described protection enters layer and uses spun laced fabric material, and anion filter course uses terylene Encryption screen cloth, reinforcement structure changes layer and uses terylene intersection pin to prick cloth, and anion synthesis layer is gross porosity negative ion cloth, purifies exchange Layer is terylene interwoven, and the component of described latex functional layer and weight portion composition are as follows: latex 45 parts, and synthetic resin 10 parts is negative 5 parts of ion powder, 20 parts of bamboo carbon fiber powder, diatom ooze 5 parts, 3 parts of the order mesoporous medium of magnetic, the order mesoporous medium of described magnetic is Magnetic ordered mesoporous carbon, described synthetic resin is any one in commercial resins for universal use, such as polyethylene.
The preparation method of anion water purification filtering material, preparation method is as follows:
(1) five layer material tilings of internal layer, use the multiply fine water jet injection fibre web that high pressure produces, and water jet passes After fibre web, the bounce-back of net of being commissioned, water jet penetrates fibre web again, the water that in fibre web, fiber interts at different directions high-speed water jet Produce displacement under power effect, intert, entanglement, obvolvent, reinforce fibre web, obtain internal layer stock;
(2) the latex functional layer component of formula ratio is sufficiently stirred for by blender, the micro-frequency of emulsion high temperature after stirring 10min, is placed in impregnation glue groove standby;
(3) by machine on internal layer stock, internal layer stock and emulsion is made fully to infiltrate, at impregnation process by impregnation The micro-frequency of middle high temperature, so that base material is uniformly starched, is formed two-in-one material of main part by slurry base material by extruding, and material of main part is producing Through hot extrusion on line, stentering forming, subsequently enter hot-air pump negative pressure cabin, heat-flash gas impact air-flow upper and lower in storehouse pass through Wear, hit logical material of main part, form some micropores, be distributed in material each several part, form anion water scavenging material semi-finished product;
(4) semi-finished product pass through shear history, are excised by redundance, after storing solidification cooling, enter Product checking.
Embodiment 2:
Anion water purification filtering material, described anion water purification filtering material is be made up of internal layer and outer layer compound Rotating fields, internal layer is to be entered layer, anion filter course, reinforcement structure change layer, anion synthesis layer by protection and purify exchange Layer is composited, and outer layer is latex functional layer, and described protection enters layer and uses spun laced fabric material, and anion filter course uses terylene Encryption screen cloth, reinforcement structure changes layer and uses terylene intersection pin to prick cloth, and anion synthesis layer is gross porosity negative ion cloth, purifies exchange Layer is terylene interwoven, and the component of described latex functional layer and weight portion composition are as follows: latex 65 parts, and synthetic resin 30 parts is negative 10 parts of ion powder, 40 parts of bamboo carbon fiber powder, diatom ooze 15 parts, 8 parts of the order mesoporous medium of magnetic, the order mesoporous medium of described magnetic For magnetic ordered mesoporous carbon, described synthetic resin is any one in commercial resins for universal use, such as polypropylene.
The preparation method of anion water purification filtering material, preparation method is as follows:
(1) five layer material tilings of internal layer, use the multiply fine water jet injection fibre web that high pressure produces, and water jet passes After fibre web, the bounce-back of net of being commissioned, water jet penetrates fibre web again, the water that in fibre web, fiber interts at different directions high-speed water jet Produce displacement under power effect, intert, entanglement, obvolvent, reinforce fibre web, obtain internal layer stock;
(2) the latex functional layer component of formula ratio is sufficiently stirred for by blender, the micro-frequency of emulsion high temperature after stirring 30min, is placed in impregnation glue groove standby;
(3) by machine on internal layer stock, internal layer stock and emulsion is made fully to infiltrate, at impregnation process by impregnation The micro-frequency of middle high temperature, so that base material is uniformly starched, is formed two-in-one material of main part by slurry base material by extruding, and material of main part is producing Through hot extrusion on line, stentering forming, subsequently enter hot-air pump negative pressure cabin, heat-flash gas impact air-flow upper and lower in storehouse pass through Wear, hit logical material of main part, form some micropores, be distributed in material each several part, form anion water scavenging material semi-finished product;
(4) semi-finished product pass through shear history, are excised by redundance, after storing solidification cooling, enter Product checking.
Embodiment 3:
Anion water purification filtering material, described anion water purification filtering material is be made up of internal layer and outer layer compound Rotating fields, internal layer is to be entered layer, anion filter course, reinforcement structure change layer, anion synthesis layer by protection and purify exchange Layer is composited, and outer layer is latex functional layer, and described protection enters layer and uses spun laced fabric material, and anion filter course uses terylene Encryption screen cloth, reinforcement structure changes layer and uses terylene intersection pin to prick cloth, and anion synthesis layer is gross porosity negative ion cloth, purifies exchange Layer is terylene interwoven, and the component of described latex functional layer and weight portion composition are as follows: latex 50 parts, and synthetic resin 18 parts is negative 7 parts of ion powder, 30 parts of bamboo carbon fiber powder, diatom ooze 10 parts, 4 parts of the order mesoporous medium of magnetic, the order mesoporous medium of described magnetic For the order mesoporous nickel ferrite based magnetic loaded of magnetic, described synthetic resin is any one in commercial resins for universal use, such as polrvinyl chloride.
The preparation method of anion water purification filtering material, preparation method is as follows:
(1) five layer material tilings of internal layer, use the multiply fine water jet injection fibre web that high pressure produces, and water jet passes After fibre web, the bounce-back of net of being commissioned, water jet penetrates fibre web again, the water that in fibre web, fiber interts at different directions high-speed water jet Produce displacement under power effect, intert, entanglement, obvolvent, reinforce fibre web, obtain internal layer stock;
(2) the latex functional layer component of formula ratio is sufficiently stirred for by blender, the micro-frequency of emulsion high temperature after stirring 20min, is placed in impregnation glue groove standby;
(3) by machine on internal layer stock, internal layer stock and emulsion is made fully to infiltrate, at impregnation process by impregnation The micro-frequency of middle high temperature, so that base material is uniformly starched, is formed two-in-one material of main part by slurry base material by extruding, and material of main part is producing Through hot extrusion on line, stentering forming, subsequently enter hot-air pump negative pressure cabin, heat-flash gas impact air-flow upper and lower in storehouse pass through Wear, hit logical material of main part, form some micropores, be distributed in material each several part, form anion water scavenging material semi-finished product;
(4) semi-finished product pass through shear history, are excised by redundance, after storing solidification cooling, enter Product checking.
Magnetic ordered mesoporous carbon of the present invention or the order mesoporous nickel ferrite based magnetic loaded of magnetic possess huge specific surface area and Abundant three dimensional pore structures, high-specific surface area is conducive to the adsorption storage of anion powder and diatom ooze;Regular orderly opening Property duct, the aperture of size adjustable be that anion produces and provides path, beneficially anion slowly persistently produces for a long time, carries The using effect of high-negative ion water purification filter material, extends its service life.
The invention has the beneficial effects as follows: the anion water purification filtering material of the present invention, can be effectively isolated in purification water and deposit Barium, chlorine, nitrite, hydrargyrum, the harmful substance such as lead, leave calcium ions and magnesium ions, making water is alkalescence;Simultaneously in material bear from Son can effectively sterilize, and softens the basis improving water the most once again.
Embodiment described above is the one preferably scheme of the present invention, not makees the present invention any pro forma Limit, on the premise of without departing from the technical scheme described in claim, also have other variant and remodeling.

Claims (5)

1. anion water purification filtering material, it is characterised in that: described anion water purification filtering material is by internal layer and outer layer The lamination layer structure constituted, internal layer is to be entered layer, anion filter course, reinforcement structure change layer, anion synthesis layer by protection Being composited with purifying switching layer, outer layer is latex functional layer, and described protection enters layer and uses spun laced fabric material, and anion filters Layer use terylene encryption screen cloth, reinforcement structure change layer use terylene intersect pin prick cloth, anion synthesis layer be gross porosity anion Cloth, purifying switching layer is terylene interwoven, and the component of described latex functional layer and weight portion composition are as follows: latex 45-65 part, close Resin 10-30 part, anion powder 5-10 part, bamboo carbon fiber powder 20-40 part, diatom ooze 5-15 part, the order mesoporous medium of magnetic 3-8 part.
Anion water purification filtering material the most according to claim 1, it is characterised in that: the component of described latex functional layer And weight portion composition is as follows: latex 50 parts, synthetic resin 18 parts, anion powder 7 parts, 30 parts of bamboo carbon fiber powder, diatom ooze 10 parts, 4 parts of the order mesoporous medium of magnetic.
Anion water purification filtering material the most according to claim 1 and 2, it is characterised in that: described magnetic is order mesoporous Medium is magnetic ordered mesoporous carbon or the order mesoporous nickel ferrite based magnetic loaded of magnetic.
Anion water purification filtering material the most according to claim 1 and 2, it is characterised in that: described synthetic resin is city Purchase in resins for universal use any one.
5. the preparation method of the anion water purification filtering material described in a claim 1-4 any one, it is characterised in that: Preparation method is as follows:
(1) five layer material tilings of internal layer, use the multiply fine water jet injection fibre web that high pressure produces, and water jet passes fibre web After, the bounce-back of net of being commissioned, water jet penetrates fibre web again, and the waterpower that in fibre web, fiber interts at different directions high-speed water jet is made With lower generation displacement, intert, entanglement, obvolvent, reinforce fibre web, obtain internal layer stock;
(2) the latex functional layer component of formula ratio is sufficiently stirred for by blender, the emulsion high temperature micro-frequency 10-after stirring 30min, is placed in impregnation glue groove standby;
(3) by machine on internal layer stock, internal layer stock and emulsion is made fully to infiltrate by impregnation, high in impregnation process The micro-frequency of temperature, so that base material is uniformly starched, is formed two-in-one material of main part by slurry base material by extruding, and material of main part is on a production line Through hot extrusion, stentering forming, subsequently enter hot-air pump negative pressure cabin, heat-flash gas impact air-flow upper and lower in storehouse run through, hit Logical material of main part, forms some micropores, is distributed in material each several part, forms anion water scavenging material semi-finished product;
(4) semi-finished product pass through shear history, are excised by redundance, after storing solidification cooling, enter Product checking.
CN201610755853.5A 2016-08-28 2016-08-28 Anion water purification filtering material and preparation method thereof Active CN106219633B (en)

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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4906263A (en) * 1988-04-22 1990-03-06 Bluecher Hasso Von Adsorption filter with high air permeability
CN103572586A (en) * 2012-08-08 2014-02-12 丛安 Environment-friendly material capable of purifying air as well as preparation method thereof
CN105754436A (en) * 2016-04-24 2016-07-13 龙泉市嘉文木业有限公司 Water and mildew resistant paint for wooden wireless loudspeaker tea set box and preparing method thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4906263A (en) * 1988-04-22 1990-03-06 Bluecher Hasso Von Adsorption filter with high air permeability
CN103572586A (en) * 2012-08-08 2014-02-12 丛安 Environment-friendly material capable of purifying air as well as preparation method thereof
CN105754436A (en) * 2016-04-24 2016-07-13 龙泉市嘉文木业有限公司 Water and mildew resistant paint for wooden wireless loudspeaker tea set box and preparing method thereof

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