CN107891639A - A kind of high sound-absorbing polyurethane automobile ceiling of high intensity and preparation method thereof - Google Patents

A kind of high sound-absorbing polyurethane automobile ceiling of high intensity and preparation method thereof Download PDF

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Publication number
CN107891639A
CN107891639A CN201711077116.5A CN201711077116A CN107891639A CN 107891639 A CN107891639 A CN 107891639A CN 201711077116 A CN201711077116 A CN 201711077116A CN 107891639 A CN107891639 A CN 107891639A
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CN
China
Prior art keywords
glue
layer
glass layer
layers
ceiling
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201711077116.5A
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Chinese (zh)
Inventor
朱维珍
尹立健
郭焕祥
杜迎梅
李海帆
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Yantai Zheng Hai He Tai Science And Technology Co Ltd
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Yantai Zheng Hai He Tai Science And Technology Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Publication date
Application filed by Yantai Zheng Hai He Tai Science And Technology Co Ltd filed Critical Yantai Zheng Hai He Tai Science And Technology Co Ltd
Priority to CN201711077116.5A priority Critical patent/CN107891639A/en
Publication of CN107891639A publication Critical patent/CN107891639A/en
Pending legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/40Layered products comprising a layer of synthetic resin comprising polyurethanes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/12Layered products comprising a layer of synthetic resin next to a fibrous or filamentary layer
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/0038Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding involving application of liquid to the layers prior to lamination, e.g. wet laminating
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/10Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the pressing technique, e.g. using action of vacuum or fluid pressure
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/22Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed
    • B32B5/24Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer
    • B32B5/26Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer another layer next to it also being fibrous or filamentary
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B60VEHICLES IN GENERAL
    • B60RVEHICLES, VEHICLE FITTINGS, OR VEHICLE PARTS, NOT OTHERWISE PROVIDED FOR
    • B60R13/00Elements for body-finishing, identifying, or decorating; Arrangements or adaptations for advertising purposes
    • B60R13/02Internal Trim mouldings ; Internal Ledges; Wall liners for passenger compartments; Roof liners
    • B60R13/0212Roof or head liners
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2255/00Coating on the layer surface
    • B32B2255/02Coating on the layer surface on fibrous or filamentary layer
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/10Inorganic fibres
    • B32B2262/101Glass fibres
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/10Properties of the layers or laminate having particular acoustical properties
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/70Other properties
    • B32B2307/724Permeability to gases, adsorption
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2605/00Vehicles
    • B32B2605/08Cars

Abstract

The invention discloses high sound absorption qualities automotive interior roof of a kind of high intensity and preparation method thereof, it is characterized in, it is by backing layer nonwoven layer(70), the 3rd glue glass layer(60), the 2nd PU layers(50), the second glue glass layer(40), the first PU layers(30), the first glue glass layer(20), topcoat(10)Molding is combined;The density of first PU layers is more than the density of the 2nd PU layers;Preparation method is that glue glass layer, hot-die shaping manufacture automotive interior roof is made in glass mat polyurethane coating glue;The PU layers of different densities can absorb the noise of different frequency range, enhance absorbing sound and lowering noise function, and the product has good intensity and good sound absorption qualities.

Description

A kind of high sound-absorbing polyurethane automobile ceiling of high intensity and preparation method thereof
Technical field:
The present invention relates to roof of the vehicle technical field, the high sound-absorbing polyurethane automobile ceiling of specifically a kind of high intensity and its system Preparation Method;For high-end vehicle ceiling, be a kind of high intensity, high sound-absorbing, glass mat gluing substitute traditional PU layers gluing, The roof of the vehicle that double-deck PU layers synchronously use.
Background technology:
The preparation method of conventional polyurethanes roof of the vehicle is PU layer plastic rolls at present, the opening shape of PU foam insides and cellular Structure serves good sound absorption, but porous material is poor to lower frequency sounds acoustically effective, i.e., being absorbed sound in low frequency range is Number is smaller.In the Patents announced at present, the manufacture craft of the high sound-absorbing polyurethane ceiling of high intensity has following three class:
Dry process:Patents have the B of Chinese patent CN 103101256, and the technique being related to is Rigid foam polyurethane by under The bottom fabric that is overlapped successively on and, glued membrane fiber type felt, PU bubbles plate, glued membrane fiber type felt and netted hot melt adhesive film it is compound and Into, for glued membrane fiber type felt using reinforcing fiber as center core layer, upper and lower surface is compounded with the netted hot melt adhesive film of different grammes per square metres respectively, but This method belongs to dry process, and needs to prepare special glued membrane fiber type felt in advance, the long ceiling processing work of technological process Skill narrow range.
Double PU layer process:Patents have the U of Chinese patent CN 205272708, and the preparation method being related to is first by nonwoven Layer of cloth 1 sprays liquid rubber and sprinkles glass, and epoxy glue is sprayed on PU plates 1 and uniformly spreads ox-hide, is sprayed on PU plates 25 Epoxy glue simultaneously sprinkles glass, and then nonwoven layer 1, PU plates 1 and PU plates 25 are stacked with interior finish coat 7 and is hot pressed into Type, last water are cut into the ceiling of high sound absorption properties, due to having used double PU layers of different densities, add ceiling to different frequency range Sound-absorbing effect, enhance absorbing sound and lowering noise function;But because the smell of epoxy glue is larger, influence the smell and VOC of ceiling Can, and epoxy glue is sprayed in production process can be atomized volatilization and cut and spread glass dust problem etc. and cause production environment severe.
Glass plastic roll technique:Patents have the B of Chinese patent CN 102795086, and the preparation method being related to is to select PU Foam is top matrix, plastic roll, sprinkling pure water is carried out respectively to upper and lower glass fibre, then according to knitting fabric, upper strata glass Glass fiber, PU foams, lower floor's glass fibre, non-ventilating tunic, non-woven fabrics stone successively, are pressed, this method is Glass mat plastic roll, realizes lightweight and improves blocking of the conventional PU layers plastic roll to PU abscesses and be advantageous to polyurethane ceiling Sound-absorbing effect;But because ceiling backing layer has used non-ventilating tunic, non-ventilating tunic intermediate layer is polyamide, polyamide Film layers that 220 DEG C or so of fusing point can remain intact under the conditions of the use of technological temperature being 130 DEG C, and film sound absorption structure is total to Vibration frequency is about 0.3-0.4 generally in 200-1000Hz scopes, maximum acoustic absorptivity, the use of non-ventilating tunic, can weaken PU Absorption of the layer to high band noise, causes the sound absorption qualities of final ceiling still not ideal enough, can not meet client to full frequency band The requirement of high sound absorption qualities.
In the prior art, the high-strength high sound-absorbing of ceiling mainly increases PU thickness degree and increases rolling trial of strength, but PU layers The space that plastic roll easily blocks PU foams reduces its sound absorption qualities;PU layer plastic rolls, required glue amount is excessive, and cost is too high.
The content of the invention:
The purpose of the present invention is to overcome the shortcomings of above-mentioned prior art, so as to provide a kind of high intensity high sound-absorbing polyurethane automobile top Canopy.
It is a further object of the present invention to provide a kind of preparation method of the high sound-absorbing polyurethane automobile ceiling of high intensity.
Present invention mainly solves the high sound-absorbing polyurethane automobile ceiling of existing high intensity its low sound absorption qualities are poor and cost The problem of high.
The technical scheme is that:A kind of high sound-absorbing polyurethane automobile ceiling of high intensity, it is characterized in that, under According to this by backing layer nonwoven layer, the 3rd glue glass layer, the 2nd PU layers, the second glue glass layer, the first PU layers, the first glue glass layer, face on and Decorations layer is combined;Described the first glue glass layer, the second glue glass layer, the 3rd glue glass layer are to coat different grammes per square metres by glass mat Glue be process;Described first layer PU layers density is more than the 2nd PU layer density.
Further, described adhesive is that environment friendly wet solidifies polyurethane adhesive.
A kind of preparation method of the high sound-absorbing polyurethane automobile ceiling of high intensity of the present invention, it is characterized in that, including Following processing step:
A plastic rolls:Take glass mat to carry out glue spreader plastic roll and the first glue glass layer, the second glue glass layer and the 3rd glue glass layer, glue is made 15-45 DEG C of roll temperature, rubber roll height 1-3mm, the plastic roll amount of every layer of glue glass layer are:First layer glue glass layer 17-23g/m2, the second layer Glue glass layer 25-30 g/m2, third layer glue glass layer 30-35g/m2
B sprays softened water:PU layers are taken, pure water, the watering amount 20-30 of one side are sprayed using double-faced uniform of the water sprayer in PU layers g/m2
C stones:According to topcoat from top to down, the first glue glass layer, the first PU layers, the second glue glass layer, the 2nd PU layers, the 3rd glue glass Layer, the neat stone of backing layer non-woven fabrics order;
D is compressing:The material that stone is completed is placed in mould, ceiling just type, mold temperature 100- are obtained after compressing 140 DEG C, briquetting pressure 8-9MPa, it is molded dwell time 30-45S;
E cooling and shapings:Type at the beginning of ceiling after will be compressing is placed in cooling and shaping in shaper, shaping time 30-45S;
F robots high pressure waterjet:Type at the beginning of ceiling after cooling and shaping is put into cutting die, high pressure waterjet is carried out, cuts away side Ceiling is made after corner material;Cutting pressure 2500-3500Pa;
G examines storage:Through examining qualified ceiling, vanning storage.
Further, described glass mat is wet method felt, grammes per square metre 80-150g/m2
High sound-absorbing polyurethane automobile ceiling of a kind of high intensity of the present invention and preparation method thereof, compared with the prior art With prominent substantive distinguishing features and marked improvement, 1, glass mat plastic roll substitute traditional PU layer plastic rolls, reduce poly- ammonia Ester adhesive improves the gas permeability and sound absorption qualities of product to the closure probability in PU porous materials space;2nd, different densities are double-deck The use of PU layers, the noise of different frequency range can be absorbed, enhance absorption of the PU porous materials to full frequency band noise, enhance top The intensity and absorbing sound and lowering noise performance of canopy;3rd, there is no harmful substance generation, Environmental Safety in whole production process;4th, it is straight with topcoat The glue amount of the first layer glue glass layer of contact is 17-23g/m2, trial of strength is rolled far below traditional PU layers, reduces the seep throughs such as facial ornament Bad risk, improve the accepted product percentage of production process.
Brief description of the drawings:
Fig. 1 is the structural representation of the present invention.
Embodiment:
Embodiment 1, for a better understanding and implementation, providing specific embodiment below in conjunction with the accompanying drawings describes the present invention in detail;Institute It is only used for explaining the present invention for embodiment, is not intended to limit the scope of the present invention.
Embodiment 1, referring to Fig. 1, the high sound-absorbing polyurethane automobile ceiling of high intensity is prepared using following technique:
(1)Plastic roll:Take glass mat to carry out glue spreader plastic roll and glue glass layer is made, glass mat is wet method felt, and grammes per square metre is 80g/m2;40 DEG C of rubber roll temperature, rubber roll height 1.5mm, the plastic roll amount of every layer of glue glass layer are:First layer 17-23g/m2, the second layer 25-30 g/m2, third layer 30-35g/m2;Glue is that environment friendly wet solidifies polyurethane adhesive;
(2)Spray softened water:PU layers are taken, pure water, the watering amount 20- of one side are sprayed using double-faced uniform of the water sprayer in PU layers 30 g/m2
(3)Stone:According to from bottom to top successively lay backing layer nonwoven layer(70), the 3rd glue glass layer(60), the 2nd PU layers(50)、 Second glue glass layer(40), the first PU layers(30), the first glue glass layer(20), topcoat(10);First PU layers(30)Density:32± 3Kg/m3, the 2nd PU layers(50)Density:26±3Kg/m3
(4)It is compressing:The material laid is placed in mould, ceiling just type, mold temperature 110 are obtained after compressing DEG C, briquetting pressure 9MPa, it is molded dwell time 35s;
(5)Cooling and shaping:Type at the beginning of ceiling after will be compressing is placed in cooling and shaping in mould, shaping time 35s;
(6)Robot high pressure waterjet:Type at the beginning of ceiling after cooling and shaping is put into cutting die, according to the cutting process of regulation High pressure waterjet is carried out, the high sound-absorbing polyurethane automobile ceiling of high intensity is made after cutting away leftover pieces;Cutting pressure 3000Pa;
(7)Examine storage:Through examining qualified ceiling, vanning storage.
Embodiment 2, with embodiment 1, the rubber roll temperature for being a difference in that plastic roll step is 15 DEG C, and rubber roll is highly 1mm;Pressure The mold temperature of forming step processed is 100 DEG C, and briquetting pressure is 9 MPa, is molded dwell time 45s;Cooling and shaping step is determined The type time is 30s;The cutting pressure of robot water knife cutting step is 2500 Pa.
Embodiment 3, with embodiment 1, the rubber roll temperature for being a difference in that plastic roll step is 45 DEG C, and rubber roll is highly 3mm;Pressure The mold temperature of forming step processed is 140 DEG C, and briquetting pressure is 8 MPa, is molded dwell time 30s;Cooling and shaping step is determined The type time is 45s;The cutting pressure of robot water knife cutting step is 3500 Pa.
A kind of high sound-absorbing polyurethane automobile ceiling of high intensity and preparation method of the present invention, glue glass layer is by glass mat The environment friendly wet solidification polyurethane adhesive for coating different grammes per square metres forms, and first layer PU layers density is more than the 2nd PU layer density, different close Degree can absorb the noise of different frequency range, effectively strengthen the absorbing sound and lowering noise effect of ceiling.

Claims (4)

1. a kind of high sound-absorbing polyurethane automobile ceiling of high intensity, it is characterised in that from below to up according to this by backing layer nonwoven layer (70), the 3rd glue glass layer(60), the 2nd PU layers(50), the second glue glass layer(40), the first PU layers(30), the first glue glass layer(20)、 Topcoat(10)It is combined;The first described glue glass layer(20), the second glue glass layer(40), the 3rd glue glass layer(60)It is by glass The glue that fibrofelt coats different grammes per square metres is process;Described first layer PU layers(30)Density is more than the 2nd PU layers(50)Density.
2. the high sound-absorbing polyurethane automobile ceiling of a kind of high intensity according to claim 1, it is characterised in that described glue is Environment friendly wet solidifies polyurethane adhesive.
3. right will show the preparation method for seeking a kind of high sound-absorbing polyurethane automobile ceiling of high intensity described in 1 or 2, its feature exists In comprising the technical steps that:
A plastic rolls:Take glass mat to carry out glue spreader plastic roll and the first glue glass layer, the second glue glass layer and the 3rd glue glass layer, glue is made 15-45 DEG C of roll temperature, rubber roll height 1-3mm, the plastic roll amount of every layer of glue glass layer are:First layer glue glass layer 17-23g/m2, the second layer Glue glass layer 25-30 g/m2, third layer glue glass layer 30-35g/m2
B sprays softened water:PU layers are taken, pure water, the watering amount 20-30 of one side are sprayed using double-faced uniform of the water sprayer in PU layers g/m2
C stones:According to topcoat from top to down, the first glue glass layer, the first PU layers, the second glue glass layer, the 2nd PU layers, the 3rd glue glass Layer, the neat stone of backing layer non-woven fabrics order;
D is compressing:The material that stone is completed is placed in mould, ceiling just type, mold temperature 100- are obtained after compressing 140 DEG C, briquetting pressure 8-9MPa, it is molded dwell time 30-45S;
E cooling and shapings:Type at the beginning of ceiling after will be compressing is placed in cooling and shaping in shaper, shaping time 30-45S;
F robots high pressure waterjet:Type at the beginning of ceiling after cooling and shaping is put into cutting die, high pressure waterjet is carried out, cuts away side Ceiling is made after corner material;Cutting pressure 2500-3500Pa;
G examines storage:Through examining qualified ceiling, vanning storage.
4. right will show the preparation method for seeking a kind of high sound-absorbing polyurethane automobile ceiling of high intensity described in 3, it is characterised in that a Glass mat described in step is wet method felt, grammes per square metre 80-150g/m2
CN201711077116.5A 2017-11-06 2017-11-06 A kind of high sound-absorbing polyurethane automobile ceiling of high intensity and preparation method thereof Pending CN107891639A (en)

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CN201711077116.5A CN107891639A (en) 2017-11-06 2017-11-06 A kind of high sound-absorbing polyurethane automobile ceiling of high intensity and preparation method thereof

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CN201711077116.5A CN107891639A (en) 2017-11-06 2017-11-06 A kind of high sound-absorbing polyurethane automobile ceiling of high intensity and preparation method thereof

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113523592A (en) * 2021-06-29 2021-10-22 无锡吉兴汽车声学部件科技有限公司 Laser cutting process for automobile roof microphone hole
EP4169717A1 (en) * 2021-10-25 2023-04-26 NVH Korea, Inc. Method of manufacturing headlining using moisture-curing adhesive and headlining manufactured thereby

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102381256A (en) * 2011-09-10 2012-03-21 无锡吉兴汽车声学部件科技有限公司 Wet-method roof producing process by glass fibers spread with adhesive
CN103434251A (en) * 2013-08-09 2013-12-11 无锡吉兴汽车声学部件科技有限公司 One-step forming process for roof by wet method
CN103481751A (en) * 2013-08-22 2014-01-01 烟台正海汽车内饰件有限公司 High-strength PU (polyurethane) skylight pulling plate with sandwich structure and preparation method thereof
CN205272708U (en) * 2015-12-30 2016-06-01 长安马自达汽车有限公司 Ceiling of sound nature is inhaled to height

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102381256A (en) * 2011-09-10 2012-03-21 无锡吉兴汽车声学部件科技有限公司 Wet-method roof producing process by glass fibers spread with adhesive
CN103434251A (en) * 2013-08-09 2013-12-11 无锡吉兴汽车声学部件科技有限公司 One-step forming process for roof by wet method
CN103481751A (en) * 2013-08-22 2014-01-01 烟台正海汽车内饰件有限公司 High-strength PU (polyurethane) skylight pulling plate with sandwich structure and preparation method thereof
CN205272708U (en) * 2015-12-30 2016-06-01 长安马自达汽车有限公司 Ceiling of sound nature is inhaled to height

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113523592A (en) * 2021-06-29 2021-10-22 无锡吉兴汽车声学部件科技有限公司 Laser cutting process for automobile roof microphone hole
EP4169717A1 (en) * 2021-10-25 2023-04-26 NVH Korea, Inc. Method of manufacturing headlining using moisture-curing adhesive and headlining manufactured thereby

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Application publication date: 20180410